#------------------------------------------------------------------------------
#$Date: 2016-03-26 02:37:28 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180148 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/45/7104589.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7104589
loop_
_publ_author_name
'Hooper, Thomas N'
'Green, Michael'
'McGrady, John E'
'Patel, Jaynika R'
'Russell, Christopher A'
_publ_section_title
;
 Synthesis and structural characterisation of stable cationic gold(I)
 alkene complexes.
;
_journal_issue                   26
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              3877
_journal_page_last               3879
_journal_paper_doi               10.1039/b908109g
_journal_volume                  34
_journal_year                    2009
_chemical_formula_moiety         'C19 H35 Au P, F6 Sb, C H2 Cl2'
_chemical_formula_sum            'C20 H37 Au Cl2 F6 P Sb'
_chemical_formula_weight         812.08
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 100.338(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.7603(7)
_cell_length_b                   13.7090(8)
_cell_length_c                   16.9906(10)
_cell_measurement_reflns_used    9502
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      29.531
_cell_measurement_theta_min      2.750
_cell_volume                     2694.8(3)
_computing_cell_refinement       'Apex II (Bruker-AXS, 2007)'
_computing_data_collection       'Apex II (Bruker-AXS, 2007)'
_computing_data_reduction
;
SAINT v7.34A (Bruker-AXS, 2007) & XPREP v2005/4 (Bruker-AXS, 2005)
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 8.366
_diffrn_detector_type            'Bruker-AXS SMART APEX'
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_details      'frames, 0.3° width'
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Bruker-AXS Kappa'
_diffrn_measurement_method       'ω & φ scans'
_diffrn_measurement_specimen_support
;
glass fibre
;
_diffrn_radiation_collimation    '0.5 mm double pinhole'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71074
_diffrn_reflns_av_R_equivalents  0.0737
_diffrn_reflns_av_sigmaI/netI    0.0426
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            37200
_diffrn_reflns_theta_full        29.58
_diffrn_reflns_theta_max         29.58
_diffrn_reflns_theta_min         1.92
_diffrn_source                   'sealed X-ray tube'
_diffrn_source_current           40
_diffrn_source_power             2
_diffrn_source_size              '0.4 x 8 mm fine focus'
_diffrn_source_target            Mo
_diffrn_source_type              'Bruker-AXS KFF Mo 2K 90\% Ceramic'
_diffrn_source_voltage           50
_exptl_absorpt_coefficient_mu    6.746
_exptl_absorpt_correction_T_max  0.509
_exptl_absorpt_correction_T_min  0.214
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS-2007/4
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.002
_exptl_crystal_density_method    none
_exptl_crystal_description       shard
_exptl_crystal_F_000             1560
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.10
_refine_diff_density_max         4.603
_refine_diff_density_min         -4.150
_refine_diff_density_rms         0.433
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.416
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     289
_refine_ls_number_reflns         7510
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.416
_refine_ls_R_factor_all          0.0472
_refine_ls_R_factor_gt           0.0387
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0550P)²+2.3421P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0955
_refine_ls_wR_factor_ref         0.1237
_reflns_number_gt                6529
_reflns_number_total             7510
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b908109g.txt
_cod_data_source_block           3
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_diffrn_radiation_probe' value 'X-ray' changed to 'x-ray'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7104589
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.225320(16) 0.348294(14) 0.115625(12) 0.01517(8) Uani 1 1 d . . .
C1 C 0.1412(4) 0.4068(4) 0.2165(3) 0.0171(10) Uani 1 1 d . . .
H1 H 0.2152 0.4000 0.2464 0.020 Uiso 1 1 calc R . .
C2 C 0.1089(5) 0.4680(4) 0.1526(4) 0.0253(13) Uani 1 1 d . . .
H2 H 0.1561 0.5108 0.1308 0.030 Uiso 1 1 calc R . .
C3 C -0.0211(5) 0.4516(5) 0.1244(4) 0.0323(15) Uani 1 1 d . . .
H3 H -0.0547 0.4741 0.0705 0.039 Uiso 1 1 calc R . .
C4 C -0.0309(5) 0.3412(5) 0.1424(5) 0.0326(16) Uani 1 1 d . . .
H4A H -0.1102 0.3194 0.1384 0.039 Uiso 1 1 calc R . .
H4B H 0.0099 0.3002 0.1100 0.039 Uiso 1 1 calc R . .
C5 C 0.0329(5) 0.3515(4) 0.2293(4) 0.0202(12) Uani 1 1 d . . .
H5 H 0.0444 0.2920 0.2618 0.024 Uiso 1 1 calc R . .
C6 C -0.0446(5) 0.4309(4) 0.2551(4) 0.0221(12) Uani 1 1 d . . .
H6 H -0.0658 0.4364 0.3051 0.027 Uiso 1 1 calc R . .
C7 C -0.0757(5) 0.4897(5) 0.1942(4) 0.0308(14) Uani 1 1 d . . .
H7 H -0.1224 0.5446 0.1934 0.037 Uiso 1 1 calc R . .
P1 P 0.34388(11) 0.25419(9) 0.05324(8) 0.0120(2) Uani 1 1 d . . .
C8 C 0.4941(4) 0.2617(4) 0.1171(3) 0.0167(10) Uani 1 1 d . . .
C9 C 0.4850(5) 0.2574(5) 0.2067(4) 0.0226(12) Uani 1 1 d . . .
H9A H 0.4585 0.1940 0.2191 0.034 Uiso 1 1 calc R . .
H9B H 0.4312 0.3059 0.2179 0.034 Uiso 1 1 calc R . .
H9C H 0.5596 0.2697 0.2387 0.034 Uiso 1 1 calc R . .
C10 C 0.5479(5) 0.3623(4) 0.1059(4) 0.0216(12) Uani 1 1 d . . .
H10A H 0.6203 0.3682 0.1422 0.032 Uiso 1 1 calc R . .
H10B H 0.4963 0.4128 0.1167 0.032 Uiso 1 1 calc R . .
H10C H 0.5607 0.3683 0.0519 0.032 Uiso 1 1 calc R . .
C11 C 0.5781(5) 0.1821(4) 0.0986(4) 0.0217(11) Uani 1 1 d . . .
H11A H 0.5828 0.1842 0.0428 0.033 Uiso 1 1 calc R . .
H11B H 0.5505 0.1193 0.1114 0.033 Uiso 1 1 calc R . .
H11C H 0.6533 0.1934 0.1300 0.033 Uiso 1 1 calc R . .
C12 C 0.3438(4) 0.3047(4) -0.0505(3) 0.0153(10) Uani 1 1 d . . .
C13 C 0.3416(5) 0.4174(4) -0.0464(4) 0.0207(11) Uani 1 1 d . . .
H13A H 0.3440 0.4440 -0.0983 0.031 Uiso 1 1 calc R . .
H13B H 0.4074 0.4400 -0.0090 0.031 Uiso 1 1 calc R . .
H13C H 0.2720 0.4383 -0.0293 0.031 Uiso 1 1 calc R . .
C14 C 0.4472(5) 0.2724(4) -0.0874(4) 0.0210(11) Uani 1 1 d . . .
H14A H 0.4505 0.2025 -0.0884 0.031 Uiso 1 1 calc R . .
H14B H 0.5172 0.2975 -0.0561 0.031 Uiso 1 1 calc R . .
H14C H 0.4388 0.2971 -0.1411 0.031 Uiso 1 1 calc R . .
C15 C 0.2325(5) 0.2747(4) -0.1078(4) 0.0198(11) Uani 1 1 d . . .
H15A H 0.2310 0.3048 -0.1590 0.030 Uiso 1 1 calc R . .
H15B H 0.1664 0.2956 -0.0863 0.030 Uiso 1 1 calc R . .
H15C H 0.2307 0.2051 -0.1139 0.030 Uiso 1 1 calc R . .
C16 C 0.2879(4) 0.1239(4) 0.0482(3) 0.0162(10) Uani 1 1 d . . .
C17 C 0.3108(5) 0.0806(4) 0.1329(4) 0.0210(11) Uani 1 1 d . . .
H17A H 0.2738 0.0181 0.1323 0.031 Uiso 1 1 calc R . .
H17B H 0.2804 0.1235 0.1687 0.031 Uiso 1 1 calc R . .
H17C H 0.3926 0.0730 0.1507 0.031 Uiso 1 1 calc R . .
C18 C 0.1553(5) 0.1235(4) 0.0217(4) 0.0207(11) Uani 1 1 d . . .
H18A H 0.1278 0.0574 0.0179 0.031 Uiso 1 1 calc R . .
H18B H 0.1353 0.1545 -0.0296 0.031 Uiso 1 1 calc R . .
H18C H 0.1203 0.1583 0.0602 0.031 Uiso 1 1 calc R . .
C19 C 0.3417(5) 0.0584(4) -0.0080(4) 0.0208(11) Uani 1 1 d . . .
H19A H 0.4244 0.0615 0.0060 0.031 Uiso 1 1 calc R . .
H19B H 0.3177 0.0802 -0.0621 0.031 Uiso 1 1 calc R . .
H19C H 0.3166 -0.0076 -0.0031 0.031 Uiso 1 1 calc R . .
Sb1 Sb 0.17928(3) 0.76210(3) 0.07685(2) 0.01447(9) Uani 1 1 d . . .
F1 F 0.2486(3) 0.6658(3) 0.0238(3) 0.0324(9) Uani 1 1 d . . .
F2 F 0.2255(3) 0.6969(3) 0.1739(2) 0.0322(9) Uani 1 1 d . . .
F3 F 0.3171(3) 0.8333(2) 0.0950(2) 0.0230(7) Uani 1 1 d . . .
F4 F 0.1103(3) 0.8598(3) 0.1305(3) 0.0293(9) Uani 1 1 d . . .
F5 F 0.1336(3) 0.8302(3) -0.0190(2) 0.0299(8) Uani 1 1 d . . .
F6 F 0.0408(3) 0.6913(3) 0.0591(2) 0.0281(8) Uani 1 1 d . . .
Cl1 Cl 0.67763(13) 0.51535(14) 0.28611(10) 0.0327(4) Uani 1 1 d . . .
Cl2 Cl 0.43400(13) 0.57033(12) 0.25166(11) 0.0309(3) Uani 1 1 d . . .
C20 C 0.5494(5) 0.5281(5) 0.3250(4) 0.0263(13) Uani 1 1 d . . .
H20A H 0.5623 0.5737 0.3694 0.032 Uiso 1 1 calc R . .
H20B H 0.5288 0.4656 0.3453 0.032 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 P1 158.37(15) . . ?
C1 Au1 C2 34.9(2) . . ?
P1 Au1 C2 166.00(16) . . ?
C2 C1 C5 107.2(5) . . ?
C2 C1 Au1 73.5(3) . . ?
C5 C1 Au1 114.8(4) . . ?
C2 C1 H1 126.4 . . ?
C5 C1 H1 126.4 . . ?
Au1 C1 H1 83.5 . . ?
C1 C2 C3 106.1(5) . . ?
C1 C2 Au1 71.6(3) . . ?
C3 C2 Au1 114.8(4) . . ?
C1 C2 H2 126.9 . . ?
C3 C2 H2 126.9 . . ?
Au1 C2 H2 85.0 . . ?
C2 C3 C7 103.9(5) . . ?
C2 C3 C4 100.7(5) . . ?
C7 C3 C4 97.1(5) . . ?
C2 C3 H3 117.3 . . ?
C7 C3 H3 117.3 . . ?
C4 C3 H3 117.3 . . ?
C5 C4 C3 93.4(5) . . ?
C5 C4 H4A 113.0 . . ?
C3 C4 H4A 113.0 . . ?
C5 C4 H4B 113.0 . . ?
C3 C4 H4B 113.0 . . ?
H4A C4 H4B 110.4 . . ?
C1 C5 C6 104.0(4) . . ?
C1 C5 C4 100.5(5) . . ?
C6 C5 C4 97.3(5) . . ?
C1 C5 H5 117.3 . . ?
C6 C5 H5 117.3 . . ?
C4 C5 H5 117.3 . . ?
C7 C6 C5 107.9(5) . . ?
C7 C6 H6 126.1 . . ?
C5 C6 H6 126.1 . . ?
C6 C7 C3 107.7(5) . . ?
C6 C7 H7 126.1 . . ?
C3 C7 H7 126.1 . . ?
C12 P1 C16 111.1(3) . . ?
C12 P1 C8 110.9(2) . . ?
C16 P1 C8 110.8(2) . . ?
C12 P1 Au1 109.00(17) . . ?
C16 P1 Au1 108.37(16) . . ?
C8 P1 Au1 106.57(17) . . ?
C11 C8 C10 108.3(4) . . ?
C11 C8 C9 109.5(5) . . ?
C10 C8 C9 104.9(5) . . ?
C11 C8 P1 114.1(4) . . ?
C10 C8 P1 109.7(4) . . ?
C9 C8 P1 109.8(4) . . ?
C8 C9 H9A 109.5 . . ?
C8 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C8 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C8 C10 H10A 109.5 . . ?
C8 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C8 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C8 C11 H11A 109.5 . . ?
C8 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C8 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C14 C12 C15 108.1(5) . . ?
C14 C12 C13 109.2(4) . . ?
C15 C12 C13 106.0(4) . . ?
C14 C12 P1 114.1(4) . . ?
C15 C12 P1 110.5(4) . . ?
C13 C12 P1 108.7(4) . . ?
C12 C13 H13A 109.5 . . ?
C12 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C12 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C12 C14 H14A 109.5 . . ?
C12 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C12 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C12 C15 H15A 109.5 . . ?
C12 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C12 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C19 C16 C17 109.6(5) . . ?
C19 C16 C18 108.9(5) . . ?
C17 C16 C18 105.7(4) . . ?
C19 C16 P1 113.7(4) . . ?
C17 C16 P1 108.7(4) . . ?
C18 C16 P1 109.9(4) . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C16 C18 H18A 109.5 . . ?
C16 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C16 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C16 C19 H19A 109.5 . . ?
C16 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C16 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
F1 Sb1 F2 90.3(2) . . ?
F1 Sb1 F3 90.46(16) . . ?
F2 Sb1 F3 89.87(17) . . ?
F1 Sb1 F5 90.87(19) . . ?
F2 Sb1 F5 178.61(18) . . ?
F3 Sb1 F5 89.31(17) . . ?
F1 Sb1 F6 89.90(17) . . ?
F2 Sb1 F6 90.03(17) . . ?
F3 Sb1 F6 179.63(17) . . ?
F5 Sb1 F6 90.78(17) . . ?
F1 Sb1 F4 179.61(18) . . ?
F2 Sb1 F4 89.71(19) . . ?
F3 Sb1 F4 89.15(17) . . ?
F5 Sb1 F4 89.15(19) . . ?
F6 Sb1 F4 90.49(17) . . ?
Cl1 C20 Cl2 111.6(3) . . ?
Cl1 C20 H20A 109.3 . . ?
Cl2 C20 H20A 109.3 . . ?
Cl1 C20 H20B 109.3 . . ?
Cl2 C20 H20B 109.3 . . ?
H20A C20 H20B 108.0 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 2.273(5) . ?
Au1 P1 2.2939(12) . ?
Au1 C2 2.296(5) . ?
C1 C2 1.370(9) . ?
C1 C5 1.531(8) . ?
C1 H1 0.9300 . ?
C2 C3 1.534(9) . ?
C2 H2 0.9300 . ?
C3 C7 1.538(9) . ?
C3 C4 1.553(10) . ?
C3 H3 0.9800 . ?
C4 C5 1.539(10) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C5 C6 1.533(8) . ?
C5 H5 0.9800 . ?
C6 C7 1.311(9) . ?
C6 H6 0.9300 . ?
C7 H7 0.9300 . ?
P1 C12 1.893(6) . ?
P1 C16 1.900(5) . ?
P1 C8 1.903(5) . ?
C8 C11 1.542(7) . ?
C8 C10 1.543(8) . ?
C8 C9 1.546(8) . ?
C9 H9A 0.9600 . ?
C9 H9B 0.9600 . ?
C9 H9C 0.9600 . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C11 H11A 0.9600 . ?
C11 H11B 0.9600 . ?
C11 H11C 0.9600 . ?
C12 C14 1.531(7) . ?
C12 C15 1.542(8) . ?
C12 C13 1.547(8) . ?
C13 H13A 0.9600 . ?
C13 H13B 0.9600 . ?
C13 H13C 0.9600 . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C16 C19 1.528(7) . ?
C16 C17 1.535(8) . ?
C16 C18 1.544(7) . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C19 H19A 0.9600 . ?
C19 H19B 0.9600 . ?
C19 H19C 0.9600 . ?
Sb1 F1 1.866(4) . ?
Sb1 F2 1.868(4) . ?
Sb1 F3 1.869(3) . ?
Sb1 F5 1.870(4) . ?
Sb1 F6 1.874(3) . ?
Sb1 F4 1.884(3) . ?
Cl1 C20 1.761(6) . ?
Cl2 C20 1.768(7) . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P1 Au1 C1 C2 170.2(3) . . . . ?
P1 Au1 C1 C5 -88.0(5) . . . . ?
C2 Au1 C1 C5 101.7(5) . . . . ?
C5 C1 C2 C3 -0.1(6) . . . . ?
Au1 C1 C2 C3 111.4(4) . . . . ?
C5 C1 C2 Au1 -111.4(4) . . . . ?
P1 Au1 C2 C1 -165.0(5) . . . . ?
C1 Au1 C2 C3 -99.7(6) . . . . ?
P1 Au1 C2 C3 95.3(8) . . . . ?
C1 C2 C3 C7 66.4(6) . . . . ?
Au1 C2 C3 C7 143.2(5) . . . . ?
C1 C2 C3 C4 -33.8(6) . . . . ?
Au1 C2 C3 C4 43.0(6) . . . . ?
C2 C3 C4 C5 51.4(5) . . . . ?
C7 C3 C4 C5 -54.2(5) . . . . ?
C2 C1 C5 C6 -66.1(6) . . . . ?
Au1 C1 C5 C6 -145.5(4) . . . . ?
C2 C1 C5 C4 34.2(6) . . . . ?
Au1 C1 C5 C4 -45.1(5) . . . . ?
C3 C4 C5 C1 -51.2(5) . . . . ?
C3 C4 C5 C6 54.5(5) . . . . ?
C1 C5 C6 C7 66.4(6) . . . . ?
C4 C5 C6 C7 -36.4(6) . . . . ?
C5 C6 C7 C3 0.5(7) . . . . ?
C2 C3 C7 C6 -67.7(7) . . . . ?
C4 C3 C7 C6 35.2(7) . . . . ?
C1 Au1 P1 C12 -169.3(4) . . . . ?
C2 Au1 P1 C12 -13.0(8) . . . . ?
C1 Au1 P1 C16 69.7(4) . . . . ?
C2 Au1 P1 C16 -134.0(7) . . . . ?
C1 Au1 P1 C8 -49.6(4) . . . . ?
C2 Au1 P1 C8 106.7(7) . . . . ?
C12 P1 C8 C11 -77.6(4) . . . . ?
C16 P1 C8 C11 46.3(5) . . . . ?
Au1 P1 C8 C11 164.0(4) . . . . ?
C12 P1 C8 C10 44.2(4) . . . . ?
C16 P1 C8 C10 168.0(4) . . . . ?
Au1 P1 C8 C10 -74.3(4) . . . . ?
C12 P1 C8 C9 159.0(4) . . . . ?
C16 P1 C8 C9 -77.1(4) . . . . ?
Au1 P1 C8 C9 40.6(4) . . . . ?
C16 P1 C12 C14 -80.3(4) . . . . ?
C8 P1 C12 C14 43.3(5) . . . . ?
Au1 P1 C12 C14 160.3(4) . . . . ?
C16 P1 C12 C15 41.7(4) . . . . ?
C8 P1 C12 C15 165.3(4) . . . . ?
Au1 P1 C12 C15 -77.7(4) . . . . ?
C16 P1 C12 C13 157.6(3) . . . . ?
C8 P1 C12 C13 -78.8(4) . . . . ?
Au1 P1 C12 C13 38.2(4) . . . . ?
C12 P1 C16 C19 47.2(5) . . . . ?
C8 P1 C16 C19 -76.5(5) . . . . ?
Au1 P1 C16 C19 166.9(4) . . . . ?
C12 P1 C16 C17 169.6(3) . . . . ?
C8 P1 C16 C17 45.9(4) . . . . ?
Au1 P1 C16 C17 -70.7(4) . . . . ?
C12 P1 C16 C18 -75.2(4) . . . . ?
C8 P1 C16 C18 161.1(4) . . . . ?
Au1 P1 C16 C18 44.5(4) . . . . ?
