#------------------------------------------------------------------------------
#$Date: 2016-03-26 03:11:52 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180172 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/68/7106897.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7106897
loop_
_publ_author_name
'Christina Knispel'
'Christian Limberg'
'Carolin Tschersich'
_publ_section_title
;
 A molecular Mo4Bi4 framework composed exclusively of unsupported
 metal-metal bonds
;
_journal_name_full               Chem.Commun.
_journal_page_first              10794
_journal_paper_doi               10.1039/c1cc14616e
_journal_volume                  47
_journal_year                    2011
_chemical_formula_moiety         'C48 H54 Bi4 Mo4 O2, C7 H8'
_chemical_formula_sum            'C55 H62 Bi4 Mo4 O2'
_chemical_formula_weight         1974.73
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                106.590(5)
_cell_angle_beta                 94.813(5)
_cell_angle_gamma                100.864(5)
_cell_formula_units_Z            1
_cell_length_a                   7.7041(4)
_cell_length_b                   12.8566(8)
_cell_length_c                   13.6517(8)
_cell_measurement_reflns_used    22428
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      29.53
_cell_measurement_theta_min      3.33
_cell_volume                     1258.97(13)
_computing_cell_refinement       'X-AREA (Stoe & Cie, 2002)'
_computing_data_collection       'X-AREA (Stoe & Cie, 2002)'
_computing_data_reduction        'X-RED (Stoe & Cie, 2002)'
_computing_molecular_graphics    'DIAMOND (Brandenburg & Berndt, 1999)'
_computing_publication_material  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR2004 (Burla et al., 2005)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 6.67
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device       'Stoe IPDS-2t diffractometer'
_diffrn_measurement_method       'ω-rotation,ω-incr.=1°,263 exposures'
_diffrn_radiation_collimation    '0.5 mm diameter monocapillary'
_diffrn_radiation_monochromator  'planar graphite'
_diffrn_radiation_source         'long fine focus sealed X-ray tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0608
_diffrn_reflns_av_sigmaI/netI    0.0573
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            14759
_diffrn_reflns_theta_full        29.23
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         3.39
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    14.928
_exptl_absorpt_correction_T_max  0.5223
_exptl_absorpt_correction_T_min  0.0501
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
;
The crystal faces were indexed by microscope on the diffractometer. After
that a numerical absorption correction basing on a Gaussian algorithsm
was applied, which is implemented in the X-RED program (Stoe, 2002).
;
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    2.605
_exptl_crystal_density_method    none
_exptl_crystal_description       needle
_exptl_crystal_F_000             908
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_refine_diff_density_max         2.906
_refine_diff_density_min         -2.293
_refine_diff_density_rms         0.313
_refine_ls_extinction_coef       0.0015(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.128
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     261
_refine_ls_number_reflns         6754
_refine_ls_number_restraints     15
_refine_ls_restrained_S_all      1.128
_refine_ls_R_factor_all          0.0766
_refine_ls_R_factor_gt           0.0547
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0391P)²+13.7268P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1105
_refine_ls_wR_factor_ref         0.1170
_reflns_number_gt                4714
_reflns_number_total             5746
_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            c1cc14616e.txt
_cod_data_source_block           3
_cod_database_code               7106897
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.3327(18) 0.3388(13) 0.1201(10) 0.033(3) Uani 1 1 d . . .
H1A H 0.2589 0.3507 0.0668 0.039 Uiso 1 1 calc R . .
C2 C 0.4306(17) 0.4213(11) 0.2107(11) 0.032(3) Uani 1 1 d . . .
H2A H 0.4317 0.4986 0.2303 0.038 Uiso 1 1 calc R . .
C3 C 0.5270(15) 0.3670(11) 0.2667(10) 0.027(2) Uani 1 1 d . . .
H3A H 0.6083 0.4028 0.3288 0.032 Uiso 1 1 calc R . .
C4 C 0.4833(14) 0.2541(10) 0.2162(8) 0.021(2) Uani 1 1 d . . .
H4A H 0.5247 0.1987 0.2390 0.026 Uiso 1 1 calc R . .
C5 C 0.3661(15) 0.2353(11) 0.1246(9) 0.024(2) Uani 1 1 d . . .
H5A H 0.3177 0.1650 0.0743 0.028 Uiso 1 1 calc R . .
C6 C -0.0483(14) 0.2727(10) 0.3141(10) 0.024(2) Uani 1 1 d . . .
H6A H -0.0535 0.2482 0.3734 0.028 Uiso 1 1 calc R . .
C7 C -0.0704(15) 0.2029(10) 0.2103(10) 0.026(2) Uani 1 1 d . . .
H7A H -0.0981 0.1238 0.1872 0.031 Uiso 1 1 calc R . .
C8 C -0.0433(15) 0.2737(12) 0.1480(10) 0.029(3) Uani 1 1 d . . .
H8A H -0.0450 0.2507 0.0753 0.034 Uiso 1 1 calc R . .
C9 C -0.0132(15) 0.3853(10) 0.2132(9) 0.024(2) Uani 1 1 d . . .
H9A H 0.0066 0.4498 0.1912 0.029 Uiso 1 1 calc R . .
C10 C -0.0174(14) 0.3846(10) 0.3146(10) 0.024(2) Uani 1 1 d . . .
H10A H -0.0021 0.4481 0.3736 0.029 Uiso 1 1 calc R . .
C11 C 0.6425(15) 0.1715(11) 0.4614(9) 0.031(3) Uani 1 1 d D . .
H11A H 0.6120 0.1216 0.3930 0.037 Uiso 1 1 calc R . .
C12 C 0.6788(14) 0.2882(10) 0.4889(10) 0.027(3) Uani 1 1 d . . .
H12A H 0.6765 0.3306 0.4423 0.032 Uiso 1 1 calc R . .
C13 C 0.7184(14) 0.3312(10) 0.5956(11) 0.030(3) Uani 1 1 d . . .
H13A H 0.7463 0.4076 0.6354 0.036 Uiso 1 1 calc R . .
C14 C 0.7092(16) 0.2401(13) 0.6329(9) 0.033(3) Uani 1 1 d . . .
H14A H 0.7336 0.2448 0.7036 0.039 Uiso 1 1 calc R . .
C15 C 0.6591(15) 0.1417(10) 0.5514(11) 0.032(3) Uani 1 1 d D . .
H15A H 0.6399 0.0682 0.5561 0.038 Uiso 1 1 calc R . .
C16 C 0.3321(16) 0.1433(9) 0.6764(9) 0.024(2) Uani 1 1 d . . .
H16A H 0.3931 0.0930 0.6960 0.029 Uiso 1 1 calc R . .
C17 C 0.1949(16) 0.1142(10) 0.5923(10) 0.027(2) Uani 1 1 d . . .
H17A H 0.1465 0.0417 0.5460 0.032 Uiso 1 1 calc R . .
C18 C 0.1415(15) 0.2145(10) 0.5895(9) 0.023(2) Uani 1 1 d U . .
H18A H 0.0524 0.2204 0.5401 0.028 Uiso 1 1 calc R . .
C19 C 0.2472(14) 0.3048(10) 0.6751(9) 0.022(2) Uani 1 1 d U . .
H19A H 0.2396 0.3807 0.6931 0.026 Uiso 1 1 calc R . .
C20 C 0.3647(16) 0.2585(10) 0.7271(9) 0.025(2) Uani 1 1 d U . .
H20A H 0.4510 0.2985 0.7862 0.030 Uiso 1 1 calc R . .
C21 C 0.305(2) -0.0350(17) 0.1687(16) 0.068(4) Uani 1 1 d D . .
H21 H 0.2965 0.0258 0.1376 0.081 Uiso 1 1 d R . .
C22 C 0.428(2) -0.0919(17) 0.1028(12) 0.054(5) Uani 1 1 d . . .
H22A H 0.3651 -0.1308 0.0326 0.065 Uiso 1 1 d R . .
H22B H 0.4716 -0.1451 0.1320 0.065 Uiso 1 1 d R . .
H22C H 0.5297 -0.0342 0.1005 0.065 Uiso 1 1 d R . .
C23 C 0.1219(18) -0.0939(17) 0.1559(16) 0.068(4) Uani 1 1 d D . .
H23 H 0.1193 -0.1454 0.1940 0.081 Uiso 1 1 d R . .
C24 C -0.036(2) -0.1051(17) 0.1157(16) 0.068(4) Uani 1 1 d D . .
H24A H -0.0770 -0.0631 0.0753 0.081 Uiso 1 1 d R . .
H24B H -0.1176 -0.1616 0.1306 0.081 Uiso 1 1 d R . .
C25 C 0.104(2) 0.521(2) -0.007(2) 0.055(3) Uiso 0.50 1 d PGDU A -1
C26 C -0.003(3) 0.4174(18) -0.0623(19) 0.055(3) Uiso 0.50 1 d PGDU A -1
H26 H 0.0447 0.3650 -0.1105 0.066 Uiso 0.50 1 calc PR A -1
C27 C -0.180(3) 0.3902(17) -0.0466(19) 0.055(3) Uiso 0.50 1 d PGU A -1
H27 H -0.2527 0.3193 -0.0841 0.066 Uiso 0.50 1 calc PR A -1
C28 C -0.249(2) 0.467(2) 0.024(2) 0.055(3) Uiso 0.50 1 d PGU A -1
H28 H -0.3701 0.4484 0.0346 0.066 Uiso 0.50 1 calc PR A -1
C29 C -0.142(3) 0.5707(18) 0.0788(18) 0.055(3) Uiso 0.50 1 d PGU A -1
H29 H -0.1901 0.6231 0.1270 0.066 Uiso 0.50 1 calc PR A -1
C30 C 0.034(3) 0.5979(17) 0.0631(19) 0.055(3) Uiso 0.50 1 d PGDU A -1
H30 H 0.1073 0.6688 0.1007 0.066 Uiso 0.50 1 calc PR A -1
C31 C 0.293(3) 0.552(3) -0.027(3) 0.055(3) Uiso 0.50 1 d PDU A -1
H31A H 0.3737 0.5785 0.0387 0.082 Uiso 0.50 1 d PR A -1
H31B H 0.3050 0.6110 -0.0602 0.082 Uiso 0.50 1 d PR A -1
H31C H 0.3233 0.4862 -0.0725 0.082 Uiso 0.50 1 d PR A -1
Bi1 Bi 0.32866(5) 0.41071(3) 0.48447(3) 0.01490(11) Uani 1 1 d . . .
Bi2 Bi 0.22288(5) 0.13162(3) 0.35629(3) 0.01675(11) Uani 1 1 d . . .
Mo1 Mo 0.21737(11) 0.30552(7) 0.25636(7) 0.01542(18) Uani 1 1 d . . .
Mo2 Mo 0.43323(11) 0.23268(7) 0.56191(7) 0.01528(18) Uani 1 1 d . . .
O1 O 0.3868(11) 0.0265(7) 0.2658(6) 0.0263(18) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
0 1 -1 0.0250
0 -1 1 0.0450
1 -1 -1 0.1600
-1 1 1 0.1700
-1 -6 -5 0.0120
1 6 5 0.0360
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C5 C1 C2 106.8(11) . .
C5 C1 Mo1 73.0(7) . .
C2 C1 Mo1 72.1(7) . .
C5 C1 H1A 126.6 . .
C2 C1 H1A 126.6 . .
Mo1 C1 H1A 120.2 . .
C1 C2 C3 107.4(11) . .
C1 C2 Mo1 71.0(7) . .
C3 C2 Mo1 75.5(7) . .
C1 C2 H2A 126.3 . .
C3 C2 H2A 126.3 . .
Mo1 C2 H2A 119.1 . .
C4 C3 C2 109.0(11) . .
C4 C3 Mo1 72.2(7) . .
C2 C3 Mo1 68.5(7) . .
C4 C3 H3A 125.5 . .
C2 C3 H3A 125.5 . .
Mo1 C3 H3A 125.4 . .
C3 C4 C5 108.0(10) . .
C3 C4 Mo1 73.5(7) . .
C5 C4 Mo1 70.0(6) . .
C3 C4 H4A 126.0 . .
C5 C4 H4A 126.0 . .
Mo1 C4 H4A 122.1 . .
C4 C5 C1 108.7(11) . .
C4 C5 Mo1 74.3(7) . .
C1 C5 Mo1 70.4(7) . .
C4 C5 H5A 125.7 . .
C1 C5 H5A 125.7 . .
Mo1 C5 H5A 121.3 . .
C10 C6 C7 108.7(11) . .
C10 C6 Mo1 74.5(7) . .
C7 C6 Mo1 72.8(6) . .
C10 C6 H6A 125.7 . .
C7 C6 H6A 125.7 . .
Mo1 C6 H6A 118.9 . .
C8 C7 C6 106.8(11) . .
C8 C7 Mo1 72.0(6) . .
C6 C7 Mo1 70.8(6) . .
C8 C7 H7A 126.6 . .
C6 C7 H7A 126.6 . .
Mo1 C7 H7A 122.3 . .
C7 C8 C9 108.0(11) . .
C7 C8 Mo1 72.1(6) . .
C9 C8 Mo1 73.6(6) . .
C7 C8 H8A 126.0 . .
C9 C8 H8A 126.0 . .
Mo1 C8 H8A 120.2 . .
C10 C9 C8 108.6(11) . .
C10 C9 Mo1 72.6(6) . .
C8 C9 Mo1 70.6(6) . .
C10 C9 H9A 125.7 . .
C8 C9 H9A 125.7 . .
Mo1 C9 H9A 122.7 . .
C9 C10 C6 107.8(11) . .
C9 C10 Mo1 72.6(7) . .
C6 C10 Mo1 69.7(6) . .
C9 C10 H10A 126.1 . .
C6 C10 H10A 126.1 . .
Mo1 C10 H10A 123.2 . .
C15 C11 C12 108.2(11) . .
C15 C11 Mo2 70.6(7) . .
C12 C11 Mo2 71.9(7) . .
C15 C11 H11A 125.9 . .
C12 C11 H11A 125.9 . .
Mo2 C11 H11A 123.3 . .
C13 C12 C11 108.6(11) . .
C13 C12 Mo2 70.6(7) . .
C11 C12 Mo2 72.6(7) . .
C13 C12 H12A 125.7 . .
C11 C12 H12A 125.7 . .
Mo2 C12 H12A 122.8 . .
C12 C13 C14 106.5(11) . .
C12 C13 Mo2 74.1(7) . .
C14 C13 Mo2 71.0(7) . .
C12 C13 H13A 126.8 . .
C14 C13 H13A 126.8 . .
Mo2 C13 H13A 120.1 . .
C15 C14 C13 109.9(11) . .
C15 C14 Mo2 73.2(7) . .
C13 C14 Mo2 72.7(6) . .
C15 C14 H14A 125.0 . .
C13 C14 H14A 125.0 . .
Mo2 C14 H14A 120.7 . .
C14 C15 C11 106.7(11) . .
C14 C15 Mo2 70.8(7) . .
C11 C15 Mo2 74.1(7) . .
C14 C15 H15A 126.6 . .
C11 C15 H15A 126.6 . .
Mo2 C15 H15A 120.3 . .
C17 C16 C20 109.3(11) . .
C17 C16 Mo2 72.5(7) . .
C20 C16 Mo2 72.6(7) . .
C17 C16 H16A 125.3 . .
C20 C16 H16A 125.3 . .
Mo2 C16 H16A 121.3 . .
C16 C17 C18 107.4(11) . .
C16 C17 Mo2 71.9(7) . .
C18 C17 Mo2 71.3(7) . .
C16 C17 H17A 126.3 . .
C18 C17 H17A 126.3 . .
Mo2 C17 H17A 122.1 . .
C17 C18 C19 107.8(10) . .
C17 C18 Mo2 72.2(7) . .
C19 C18 Mo2 72.6(6) . .
C17 C18 H18A 126.1 . .
C19 C18 H18A 126.1 . .
Mo2 C18 H18A 120.8 . .
C20 C19 C18 106.9(11) . .
C20 C19 Mo2 71.7(7) . .
C18 C19 Mo2 70.8(6) . .
C20 C19 H19A 126.6 . .
C18 C19 H19A 126.6 . .
Mo2 C19 H19A 122.6 . .
C16 C20 C19 108.6(11) . .
C16 C20 Mo2 71.8(7) . .
C19 C20 Mo2 72.5(6) . .
C16 C20 H20A 125.7 . .
C19 C20 H20A 125.7 . .
Mo2 C20 H20A 121.7 . .
O1 C21 C23 118.2(17) . .
O1 C21 C22 113.2(13) . .
C23 C21 C22 117.7(15) . .
O1 C21 H21 100.1 . .
C23 C21 H21 103.1 . .
C22 C21 H21 100.0 . .
C21 C22 H22A 109.9 . .
C21 C22 H22B 110.9 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 107.6 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C24 C23 C21 146(3) . .
C24 C23 H23 107.0 . .
C21 C23 H23 106.9 . .
C23 C24 H24A 127.1 . .
C23 C24 H24B 112.9 . .
H24A C24 H24B 120.0 . .
C26 C25 C30 120.0 . .
C26 C25 C31 120.1(10) . .
C30 C25 C31 119.9(10) . .
C25 C26 C27 120.0 . .
C25 C26 H26 120.0 . .
C27 C26 H26 120.0 . .
C26 C27 C28 120.0 . .
C26 C27 H27 120.0 . .
C28 C27 H27 120.0 . .
C29 C28 C27 120.0 . .
C29 C28 H28 120.0 . .
C27 C28 H28 120.0 . .
C30 C29 C28 120.0 . .
C30 C29 H29 120.0 . .
C28 C29 H29 120.0 . .
C29 C30 C25 120.0 . .
C29 C30 H30 120.0 . .
C25 C30 H30 120.0 . .
C25 C31 H31A 109.4 . .
C25 C31 H31B 110.3 . .
H31A C31 H31B 109.5 . .
C25 C31 H31C 108.7 . .
H31A C31 H31C 109.5 . .
H31B C31 H31C 109.5 . .
Mo2 Bi1 Mo1 105.50(3) . .
Mo2 Bi1 Bi1 106.28(2) . 2_666
Mo1 Bi1 Bi1 107.24(3) . 2_666
Mo2 Bi1 Bi2 53.827(19) . .
Mo1 Bi1 Bi2 54.051(19) . .
Bi1 Bi1 Bi2 131.92(2) 2_666 .
O1 Bi2 Mo2 104.9(2) . .
O1 Bi2 Mo1 103.6(2) . .
Mo2 Bi2 Mo1 108.71(3) . .
O1 Bi2 Bi1 129.3(2) . .
Mo2 Bi2 Bi1 55.610(19) . .
Mo1 Bi2 Bi1 55.63(2) . .
C1 Mo1 C2 36.8(5) . .
C1 Mo1 C6 140.8(4) . .
C2 Mo1 C6 149.6(4) . .
C1 Mo1 C5 36.6(5) . .
C2 Mo1 C5 60.4(5) . .
C6 Mo1 C5 141.7(5) . .
C1 Mo1 C8 81.2(5) . .
C2 Mo1 C8 108.5(5) . .
C6 Mo1 C8 60.0(4) . .
C5 Mo1 C8 93.1(4) . .
C1 Mo1 C7 111.6(5) . .
C2 Mo1 C7 144.1(5) . .
C6 Mo1 C7 36.4(5) . .
C5 Mo1 C7 105.9(5) . .
C8 Mo1 C7 36.0(5) . .
C1 Mo1 C10 119.6(5) . .
C2 Mo1 C10 113.9(4) . .
C6 Mo1 C10 35.8(4) . .
C5 Mo1 C10 149.8(4) . .
C8 Mo1 C10 59.3(4) . .
C7 Mo1 C10 59.8(4) . .
C1 Mo1 C9 86.6(5) . .
C2 Mo1 C9 94.6(4) . .
C6 Mo1 C9 59.1(4) . .
C5 Mo1 C9 115.3(4) . .
C8 Mo1 C9 35.8(5) . .
C7 Mo1 C9 59.5(4) . .
C10 Mo1 C9 34.8(4) . .
C1 Mo1 C4 60.4(4) . .
C2 Mo1 C4 59.7(4) . .
C6 Mo1 C4 150.4(4) . .
C5 Mo1 C4 35.7(4) . .
C8 Mo1 C4 128.3(4) . .
C7 Mo1 C4 129.7(4) . .
C10 Mo1 C4 170.4(4) . .
C9 Mo1 C4 146.9(4) . .
C1 Mo1 C3 59.9(5) . .
C2 Mo1 C3 36.0(4) . .
C6 Mo1 C3 157.5(4) . .
C5 Mo1 C3 58.5(4) . .
C8 Mo1 C3 141.0(5) . .
C7 Mo1 C3 163.5(4) . .
C10 Mo1 C3 136.3(4) . .
C9 Mo1 C3 129.5(4) . .
C4 Mo1 C3 34.3(4) . .
C1 Mo1 Bi2 133.6(4) . .
C2 Mo1 Bi2 133.9(3) . .
C6 Mo1 Bi2 72.8(3) . .
C5 Mo1 Bi2 97.0(3) . .
C8 Mo1 Bi2 112.6(3) . .
C7 Mo1 Bi2 77.6(3) . .
C10 Mo1 Bi2 104.6(3) . .
C9 Mo1 Bi2 131.2(3) . .
C4 Mo1 Bi2 78.5(3) . .
C3 Mo1 Bi2 98.1(3) . .
C1 Mo1 Bi1 132.2(4) . .
C2 Mo1 Bi1 95.5(4) . .
C6 Mo1 Bi1 79.2(3) . .
C5 Mo1 Bi1 133.1(3) . .
C8 Mo1 Bi1 133.7(3) . .
C7 Mo1 Bi1 114.3(3) . .
C10 Mo1 Bi1 75.0(3) . .
C9 Mo1 Bi1 105.5(3) . .
C4 Mo1 Bi1 97.9(3) . .
C3 Mo1 Bi1 78.3(3) . .
Bi2 Mo1 Bi1 70.32(2) . .
C14 Mo2 C13 36.3(5) . .
C14 Mo2 C15 36.0(5) . .
C13 Mo2 C15 60.6(4) . .
C14 Mo2 C18 143.9(4) . .
C13 Mo2 C18 150.9(4) . .
C15 Mo2 C18 141.8(4) . .
C14 Mo2 C16 86.8(5) . .
C13 Mo2 C16 118.4(5) . .
C15 Mo2 C16 87.7(4) . .
C18 Mo2 C16 59.9(4) . .
C14 Mo2 C12 58.9(5) . .
C13 Mo2 C12 35.4(5) . .
C15 Mo2 C12 59.5(4) . .
C18 Mo2 C12 155.6(4) . .
C16 Mo2 C12 144.5(4) . .
C14 Mo2 C17 119.3(5) . .
C13 Mo2 C17 153.8(5) . .
C15 Mo2 C17 105.4(4) . .
C18 Mo2 C17 36.4(4) . .
C16 Mo2 C17 35.6(4) . .
C12 Mo2 C17 158.3(4) . .
C14 Mo2 C20 84.9(4) . .
C13 Mo2 C20 100.8(5) . .
C15 Mo2 C20 105.8(5) . .
C18 Mo2 C20 60.1(4) . .
C16 Mo2 C20 35.6(4) . .
C12 Mo2 C20 136.1(5) . .
C17 Mo2 C20 59.8(4) . .
C14 Mo2 C11 58.8(4) . .
C13 Mo2 C11 59.5(4) . .
C15 Mo2 C11 35.4(4) . .
C18 Mo2 C11 149.1(4) . .
C16 Mo2 C11 120.2(5) . .
C12 Mo2 C11 35.5(4) . .
C17 Mo2 C11 123.2(5) . .
C20 Mo2 C11 140.6(4) . .
C14 Mo2 C19 116.0(4) . .
C13 Mo2 C19 115.1(4) . .
C15 Mo2 C19 141.6(4) . .
C18 Mo2 C19 36.6(4) . .
C16 Mo2 C19 59.8(4) . .
C12 Mo2 C19 141.1(4) . .
C17 Mo2 C19 60.5(4) . .
C20 Mo2 C19 35.8(4) . .
C11 Mo2 C19 174.3(4) . .
C14 Mo2 Bi2 135.6(3) . .
C13 Mo2 Bi2 125.2(4) . .
C15 Mo2 Bi2 102.4(4) . .
C18 Mo2 Bi2 74.9(3) . .
C16 Mo2 Bi2 111.7(3) . .
C12 Mo2 Bi2 90.0(3) . .
C17 Mo2 Bi2 77.7(3) . .
C20 Mo2 Bi2 133.6(3) . .
C11 Mo2 Bi2 77.4(3) . .
C19 Mo2 Bi2 108.1(3) . .
C14 Mo2 Bi1 124.4(4) . .
C13 Mo2 Bi1 88.3(3) . .
C15 Mo2 Bi1 137.2(3) . .
C18 Mo2 Bi1 78.9(3) . .
C16 Mo2 Bi1 134.7(3) . .
C12 Mo2 Bi1 78.1(3) . .
C17 Mo2 Bi1 113.6(3) . .
C20 Mo2 Bi1 108.5(3) . .
C11 Mo2 Bi1 104.7(3) . .
C19 Mo2 Bi1 76.2(3) . .
Bi2 Mo2 Bi1 70.56(2) . .
C21 O1 Bi2 114.0(9) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C5 1.420(18) .
C1 C2 1.42(2) .
C1 Mo1 2.241(12) .
C1 H1A 0.9500 .
C2 C3 1.424(17) .
C2 Mo1 2.255(12) .
C2 H2A 0.9500 .
C3 C4 1.379(17) .
C3 Mo1 2.346(12) .
C3 H3A 0.9500 .
C4 C5 1.411(15) .
C4 Mo1 2.330(11) .
C4 H4A 0.9500 .
C5 Mo1 2.274(11) .
C5 H5A 0.9500 .
C6 C10 1.411(16) .
C6 C7 1.421(18) .
C6 Mo1 2.264(11) .
C6 H6A 0.9500 .
C7 C8 1.413(18) .
C7 Mo1 2.290(11) .
C7 H7A 0.9500 .
C8 C9 1.420(18) .
C8 Mo1 2.288(11) .
C8 H8A 0.9500 .
C9 C10 1.390(17) .
C9 Mo1 2.326(10) .
C9 H9A 0.9500 .
C10 Mo1 2.325(11) .
C10 H10A 0.9500 .
C11 C15 1.390(14) .
C11 C12 1.404(18) .
C11 Mo2 2.310(12) .
C11 H11A 0.9500 .
C12 C13 1.386(19) .
C12 Mo2 2.301(12) .
C12 H12A 0.9500 .
C13 C14 1.398(19) .
C13 Mo2 2.256(11) .
C13 H13A 0.9500 .
C14 C15 1.389(19) .
C14 Mo2 2.235(11) .
C14 H14A 0.9500 .
C15 Mo2 2.265(11) .
C15 H15A 0.9500 .
C16 C17 1.406(17) .
C16 C20 1.407(17) .
C16 Mo2 2.295(11) .
C16 H16A 0.9500 .
C17 C18 1.435(17) .
C17 Mo2 2.302(12) .
C17 H17A 0.9500 .
C18 C19 1.444(16) .
C18 Mo2 2.290(11) .
C18 H18A 0.9500 .
C19 C20 1.420(16) .
C19 Mo2 2.314(11) .
C19 H19A 0.9500 .
C20 Mo2 2.305(12) .
C20 H20A 0.9500 .
C21 O1 1.361(19) .
C21 C23 1.442(16) .
C21 C22 1.51(2) .
C21 H21 1.0000 .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C23 C24 1.253(16) .
C23 H23 0.9500 .
C24 H24A 0.9500 .
C24 H24B 0.9500 .
C25 C26 1.3900 .
C25 C30 1.3900 .
C25 C31 1.502(12) .
C26 C27 1.3900 .
C26 H26 0.9500 .
C27 C28 1.3900 .
C27 H27 0.9500 .
C28 C29 1.3900 .
C28 H28 0.9500 .
C29 C30 1.3900 .
C29 H29 0.9500 .
C30 H30 0.9500 .
C31 H31A 0.9800 .
C31 H31B 0.9800 .
C31 H31C 0.9800 .
Bi1 Mo2 2.9899(9) .
Bi1 Mo1 2.9952(10) .
Bi1 Bi1 3.0647(8) 2_666
Bi1 Bi2 3.4167(6) .
Bi2 O1 2.213(8) .
Bi2 Mo2 2.9248(9) .
Bi2 Mo1 2.9376(10) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
C5 C1 C2 C3 2.1(14) .
Mo1 C1 C2 C3 67.3(9) .
C5 C1 C2 Mo1 -65.2(9) .
C1 C2 C3 C4 -3.3(14) .
Mo1 C2 C3 C4 61.1(9) .
C1 C2 C3 Mo1 -64.3(9) .
C2 C3 C4 C5 3.1(14) .
Mo1 C3 C4 C5 61.9(8) .
C2 C3 C4 Mo1 -58.8(9) .
C3 C4 C5 C1 -1.7(14) .
Mo1 C4 C5 C1 62.4(8) .
C3 C4 C5 Mo1 -64.2(8) .
C2 C1 C5 C4 -0.3(14) .
Mo1 C1 C5 C4 -64.9(9) .
C2 C1 C5 Mo1 64.7(9) .
C10 C6 C7 C8 3.0(12) .
Mo1 C6 C7 C8 -63.4(8) .
C10 C6 C7 Mo1 66.4(7) .
C6 C7 C8 C9 -2.6(12) .
Mo1 C7 C8 C9 -65.3(8) .
C6 C7 C8 Mo1 62.7(7) .
C7 C8 C9 C10 1.3(13) .
Mo1 C8 C9 C10 -63.0(8) .
C7 C8 C9 Mo1 64.3(8) .
C8 C9 C10 C6 0.6(12) .
Mo1 C9 C10 C6 -61.2(7) .
C8 C9 C10 Mo1 61.8(8) .
C7 C6 C10 C9 -2.2(12) .
Mo1 C6 C10 C9 63.1(8) .
C7 C6 C10 Mo1 -65.3(7) .
C15 C11 C12 C13 0.2(13) .
Mo2 C11 C12 C13 61.7(8) .
C15 C11 C12 Mo2 -61.6(8) .
C11 C12 C13 C14 1.0(13) .
Mo2 C12 C13 C14 64.1(8) .
C11 C12 C13 Mo2 -63.1(8) .
C12 C13 C14 C15 -1.9(13) .
Mo2 C13 C14 C15 64.3(9) .
C12 C13 C14 Mo2 -66.1(8) .
C13 C14 C15 C11 2.0(13) .
Mo2 C14 C15 C11 65.9(8) .
C13 C14 C15 Mo2 -63.9(8) .
C12 C11 C15 C14 -1.3(13) .
Mo2 C11 C15 C14 -63.8(8) .
C12 C11 C15 Mo2 62.4(8) .
C20 C16 C17 C18 0.7(14) .
Mo2 C16 C17 C18 -63.0(8) .
C20 C16 C17 Mo2 63.7(9) .
C16 C17 C18 C19 -1.1(13) .
Mo2 C17 C18 C19 -64.4(8) .
C16 C17 C18 Mo2 63.3(8) .
C17 C18 C19 C20 1.0(13) .
Mo2 C18 C19 C20 -63.1(8) .
C17 C18 C19 Mo2 64.1(8) .
C17 C16 C20 C19 -0.1(14) .
Mo2 C16 C20 C19 63.5(8) .
C17 C16 C20 Mo2 -63.6(9) .
C18 C19 C20 C16 -0.6(13) .
Mo2 C19 C20 C16 -63.1(8) .
C18 C19 C20 Mo2 62.5(8) .
O1 C21 C23 C24 118(3) .
C22 C21 C23 C24 -100(3) .
C30 C25 C26 C27 0.0 .
C31 C25 C26 C27 -178(3) .
C25 C26 C27 C28 0.0 .
C26 C27 C28 C29 0.0 .
C27 C28 C29 C30 0.0 .
C28 C29 C30 C25 0.0 .
C26 C25 C30 C29 0.0 .
C31 C25 C30 C29 178(3) .
Mo2 Bi1 Bi2 O1 -80.9(3) .
Mo1 Bi1 Bi2 O1 79.0(3) .
Bi1 Bi1 Bi2 O1 -1.9(3) 2_666
Mo1 Bi1 Bi2 Mo2 159.90(3) .
Bi1 Bi1 Bi2 Mo2 79.05(3) 2_666
Mo2 Bi1 Bi2 Mo1 -159.90(3) .
Bi1 Bi1 Bi2 Mo1 -80.84(3) 2_666
C5 C1 Mo1 C2 114.6(11) .
C5 C1 Mo1 C6 -115.6(9) .
C2 C1 Mo1 C6 129.8(8) .
C2 C1 Mo1 C5 -114.6(11) .
C5 C1 Mo1 C8 -107.4(8) .
C2 C1 Mo1 C8 138.0(8) .
C5 C1 Mo1 C7 -87.8(8) .
C2 C1 Mo1 C7 157.6(7) .
C5 C1 Mo1 C10 -154.3(7) .
C2 C1 Mo1 C10 91.0(8) .
C5 C1 Mo1 C9 -143.0(8) .
C2 C1 Mo1 C9 102.4(8) .
C5 C1 Mo1 C4 36.7(7) .
C2 C1 Mo1 C4 -77.9(8) .
C5 C1 Mo1 C3 76.5(8) .
C2 C1 Mo1 C3 -38.1(7) .
C5 C1 Mo1 Bi2 5.6(10) .
C2 C1 Mo1 Bi2 -109.1(8) .
C5 C1 Mo1 Bi1 109.1(7) .
C2 C1 Mo1 Bi1 -5.5(10) .
C3 C2 Mo1 C1 -114.6(11) .
C1 C2 Mo1 C6 -106.1(11) .
C3 C2 Mo1 C6 139.4(9) .
C1 C2 Mo1 C5 38.6(7) .
C3 C2 Mo1 C5 -76.0(8) .
C1 C2 Mo1 C8 -44.2(9) .
C3 C2 Mo1 C8 -158.8(7) .
C1 C2 Mo1 C7 -37.1(11) .
C3 C2 Mo1 C7 -151.7(8) .
C1 C2 Mo1 C10 -108.0(8) .
C3 C2 Mo1 C10 137.4(7) .
C1 C2 Mo1 C9 -78.0(8) .
C3 C2 Mo1 C9 167.4(8) .
C1 C2 Mo1 C4 80.0(8) .
C3 C2 Mo1 C4 -34.6(7) .
C1 C2 Mo1 C3 114.6(11) .
C1 C2 Mo1 Bi2 108.1(8) .
C3 C2 Mo1 Bi2 -6.5(10) .
C1 C2 Mo1 Bi1 175.9(7) .
C3 C2 Mo1 Bi1 61.3(7) .
C10 C6 Mo1 C1 -68.6(11) .
C7 C6 Mo1 C1 47.1(11) .
C10 C6 Mo1 C2 -3.1(13) .
C7 C6 Mo1 C2 112.6(11) .
C10 C6 Mo1 C5 -128.9(8) .
C7 C6 Mo1 C5 -13.2(10) .
C10 C6 Mo1 C8 -78.1(8) .
C7 C6 Mo1 C8 37.7(7) .
C10 C6 Mo1 C7 -115.7(10) .
C7 C6 Mo1 C10 115.7(10) .
C10 C6 Mo1 C9 -36.3(7) .
C7 C6 Mo1 C9 79.5(7) .
C10 C6 Mo1 C4 166.3(8) .
C7 C6 Mo1 C4 -78.0(10) .
C10 C6 Mo1 C3 83.2(13) .
C7 C6 Mo1 C3 -161.1(11) .
C10 C6 Mo1 Bi2 151.8(7) .
C7 C6 Mo1 Bi2 -92.4(6) .
C10 C6 Mo1 Bi1 79.3(7) .
C7 C6 Mo1 Bi1 -165.0(7) .
C4 C5 Mo1 C1 117.0(11) .
C4 C5 Mo1 C2 78.2(8) .
C1 C5 Mo1 C2 -38.8(8) .
C4 C5 Mo1 C6 -130.0(8) .
C1 C5 Mo1 C6 113.1(9) .
C4 C5 Mo1 C8 -172.2(8) .
C1 C5 Mo1 C8 70.8(8) .
C4 C5 Mo1 C7 -138.1(7) .
C1 C5 Mo1 C7 105.0(8) .
C4 C5 Mo1 C10 165.3(8) .
C1 C5 Mo1 C10 48.4(12) .
C4 C5 Mo1 C9 158.6(7) .
C1 C5 Mo1 C9 41.6(9) .
C1 C5 Mo1 C4 -117.0(11) .
C4 C5 Mo1 C3 36.2(7) .
C1 C5 Mo1 C3 -80.8(8) .
C4 C5 Mo1 Bi2 -59.0(7) .
C1 C5 Mo1 Bi2 -175.9(7) .
C4 C5 Mo1 Bi1 10.6(9) .
C1 C5 Mo1 Bi1 -106.4(7) .
C7 C8 Mo1 C1 147.9(8) .
C9 C8 Mo1 C1 -96.3(8) .
C7 C8 Mo1 C2 172.9(7) .
C9 C8 Mo1 C2 -71.3(8) .
C7 C8 Mo1 C6 -38.1(7) .
C9 C8 Mo1 C6 77.7(8) .
C7 C8 Mo1 C5 113.1(8) .
C9 C8 Mo1 C5 -131.1(8) .
C9 C8 Mo1 C7 115.8(11) .
C7 C8 Mo1 C10 -79.8(8) .
C9 C8 Mo1 C10 36.0(7) .
C7 C8 Mo1 C9 -115.8(11) .
C7 C8 Mo1 C4 107.3(8) .
C9 C8 Mo1 C4 -136.9(7) .
C7 C8 Mo1 C3 153.2(8) .
C9 C8 Mo1 C3 -91.1(9) .
C7 C8 Mo1 Bi2 14.2(8) .
C9 C8 Mo1 Bi2 130.0(7) .
C7 C8 Mo1 Bi1 -69.7(9) .
C9 C8 Mo1 Bi1 46.1(9) .
C8 C7 Mo1 C1 -34.4(9) .
C6 C7 Mo1 C1 -150.1(7) .
C8 C7 Mo1 C2 -11.5(12) .
C6 C7 Mo1 C2 -127.2(8) .
C8 C7 Mo1 C6 115.7(10) .
C8 C7 Mo1 C5 -72.7(8) .
C6 C7 Mo1 C5 171.6(6) .
C6 C7 Mo1 C8 -115.7(10) .
C8 C7 Mo1 C10 78.2(8) .
C6 C7 Mo1 C10 -37.5(6) .
C8 C7 Mo1 C9 37.7(7) .
C6 C7 Mo1 C9 -78.0(7) .
C8 C7 Mo1 C4 -103.2(8) .
C6 C7 Mo1 C4 141.1(7) .
C8 C7 Mo1 C3 -90.2(16) .
C6 C7 Mo1 C3 154.1(14) .
C8 C7 Mo1 Bi2 -166.6(8) .
C6 C7 Mo1 Bi2 77.7(6) .
C8 C7 Mo1 Bi1 132.0(7) .
C6 C7 Mo1 Bi1 16.2(7) .
C9 C10 Mo1 C1 20.1(9) .
C6 C10 Mo1 C1 137.3(7) .
C9 C10 Mo1 C2 61.1(9) .
C6 C10 Mo1 C2 178.3(7) .
C9 C10 Mo1 C6 -117.2(11) .
C9 C10 Mo1 C5 -10.7(12) .
C6 C10 Mo1 C5 106.5(10) .
C9 C10 Mo1 C8 -37.1(7) .
C6 C10 Mo1 C8 80.1(8) .
C9 C10 Mo1 C7 -79.0(8) .
C6 C10 Mo1 C7 38.2(7) .
C6 C10 Mo1 C9 117.2(11) .
C9 C10 Mo1 C3 96.2(9) .
C6 C10 Mo1 C3 -146.6(7) .
C9 C10 Mo1 Bi2 -145.0(7) .
C6 C10 Mo1 Bi2 -27.8(7) .
C9 C10 Mo1 Bi1 150.5(7) .
C6 C10 Mo1 Bi1 -92.3(7) .
C10 C9 Mo1 C1 -162.5(8) .
C8 C9 Mo1 C1 79.8(8) .
C10 C9 Mo1 C2 -126.6(8) .
C8 C9 Mo1 C2 115.7(8) .
C10 C9 Mo1 C6 37.3(7) .
C8 C9 Mo1 C6 -80.4(8) .
C10 C9 Mo1 C5 174.1(7) .
C8 C9 Mo1 C5 56.3(8) .
C10 C9 Mo1 C8 117.7(11) .
C10 C9 Mo1 C7 79.9(8) .
C8 C9 Mo1 C7 -37.8(7) .
C8 C9 Mo1 C10 -117.7(11) .
C10 C9 Mo1 C4 -163.0(8) .
C8 C9 Mo1 C4 79.3(10) .
C10 C9 Mo1 C3 -117.0(8) .
C8 C9 Mo1 C3 125.3(8) .
C10 C9 Mo1 Bi2 47.6(8) .
C8 C9 Mo1 Bi2 -70.1(8) .
C10 C9 Mo1 Bi1 -29.6(7) .
C8 C9 Mo1 Bi1 -147.3(7) .
C3 C4 Mo1 C1 79.0(8) .
C5 C4 Mo1 C1 -37.7(8) .
C3 C4 Mo1 C2 36.3(7) .
C5 C4 Mo1 C2 -80.5(8) .
C3 C4 Mo1 C6 -137.5(9) .
C5 C4 Mo1 C6 105.7(10) .
C3 C4 Mo1 C5 116.7(10) .
C3 C4 Mo1 C8 126.7(8) .
C5 C4 Mo1 C8 9.9(10) .
C3 C4 Mo1 C7 173.5(7) .
C5 C4 Mo1 C7 56.7(9) .
C3 C4 Mo1 C9 79.5(10) .
C5 C4 Mo1 C9 -37.2(11) .
C5 C4 Mo1 C3 -116.7(10) .
C3 C4 Mo1 Bi2 -123.5(7) .
C5 C4 Mo1 Bi2 119.8(7) .
C3 C4 Mo1 Bi1 -55.5(7) .
C5 C4 Mo1 Bi1 -172.2(7) .
C4 C3 Mo1 C1 -80.6(8) .
C2 C3 Mo1 C1 39.0(8) .
C4 C3 Mo1 C2 -119.6(11) .
C4 C3 Mo1 C6 119.6(11) .
C2 C3 Mo1 C6 -120.8(12) .
C4 C3 Mo1 C5 -37.7(7) .
C2 C3 Mo1 C5 81.9(8) .
C4 C3 Mo1 C8 -86.6(10) .
C2 C3 Mo1 C8 33.0(11) .
C4 C3 Mo1 C7 -17.8(19) .
C2 C3 Mo1 C7 101.8(17) .
C4 C3 Mo1 C10 176.7(7) .
C2 C3 Mo1 C10 -63.6(10) .
C4 C3 Mo1 C9 -135.9(7) .
C2 C3 Mo1 C9 -16.3(10) .
C2 C3 Mo1 C4 119.6(11) .
C4 C3 Mo1 Bi2 55.7(7) .
C2 C3 Mo1 Bi2 175.3(7) .
C4 C3 Mo1 Bi1 123.5(7) .
C2 C3 Mo1 Bi1 -116.9(8) .
O1 Bi2 Mo1 C1 1.5(5) .
Mo2 Bi2 Mo1 C1 112.7(5) .
Bi1 Bi2 Mo1 C1 130.1(5) .
O1 Bi2 Mo1 C2 -50.3(6) .
Mo2 Bi2 Mo1 C2 60.8(5) .
Bi1 Bi2 Mo1 C2 78.3(5) .
O1 Bi2 Mo1 C6 147.0(4) .
Mo2 Bi2 Mo1 C6 -101.9(3) .
Bi1 Bi2 Mo1 C6 -84.4(3) .
O1 Bi2 Mo1 C5 4.9(4) .
Mo2 Bi2 Mo1 C5 116.0(3) .
Bi1 Bi2 Mo1 C5 133.4(3) .
O1 Bi2 Mo1 C8 101.2(4) .
Mo2 Bi2 Mo1 C8 -147.7(4) .
Bi1 Bi2 Mo1 C8 -130.3(4) .
O1 Bi2 Mo1 C7 109.6(4) .
Mo2 Bi2 Mo1 C7 -139.2(3) .
Bi1 Bi2 Mo1 C7 -121.8(3) .
O1 Bi2 Mo1 C10 163.6(4) .
Mo2 Bi2 Mo1 C10 -85.3(3) .
Bi1 Bi2 Mo1 C10 -67.9(3) .
O1 Bi2 Mo1 C9 137.8(5) .
Mo2 Bi2 Mo1 C9 -111.1(4) .
Bi1 Bi2 Mo1 C9 -93.7(4) .
O1 Bi2 Mo1 C4 -25.8(4) .
Mo2 Bi2 Mo1 C4 85.4(3) .
Bi1 Bi2 Mo1 C4 102.8(3) .
O1 Bi2 Mo1 C3 -54.2(4) .
Mo2 Bi2 Mo1 C3 57.0(3) .
Bi1 Bi2 Mo1 C3 74.4(3) .
O1 Bi2 Mo1 Bi1 -128.6(2) .
Mo2 Bi2 Mo1 Bi1 -17.43(3) .
Mo2 Bi1 Mo1 C1 -114.8(5) .
Bi1 Bi1 Mo1 C1 -1.8(5) 2_666
Bi2 Bi1 Mo1 C1 -131.6(5) .
Mo2 Bi1 Mo1 C2 -118.1(3) .
Bi1 Bi1 Mo1 C2 -5.1(3) 2_666
Bi2 Bi1 Mo1 C2 -134.9(3) .
Mo2 Bi1 Mo1 C6 92.1(3) .
Bi1 Bi1 Mo1 C6 -154.9(3) 2_666
Bi2 Bi1 Mo1 C6 75.4(3) .
Mo2 Bi1 Mo1 C5 -64.2(4) .
Bi1 Bi1 Mo1 C5 48.8(4) 2_666
Bi2 Bi1 Mo1 C5 -81.0(4) .
Mo2 Bi1 Mo1 C8 119.6(5) .
Bi1 Bi1 Mo1 C8 -127.4(5) 2_666
Bi2 Bi1 Mo1 C8 102.9(5) .
Mo2 Bi1 Mo1 C7 82.4(3) .
Bi1 Bi1 Mo1 C7 -164.6(3) 2_666
Bi2 Bi1 Mo1 C7 65.7(3) .
Mo2 Bi1 Mo1 C10 128.6(3) .
Bi1 Bi1 Mo1 C10 -118.4(3) 2_666
Bi2 Bi1 Mo1 C10 111.9(3) .
Mo2 Bi1 Mo1 C9 145.5(3) .
Bi1 Bi1 Mo1 C9 -101.5(3) 2_666
Bi2 Bi1 Mo1 C9 128.8(3) .
Mo2 Bi1 Mo1 C4 -58.0(3) .
Bi1 Bi1 Mo1 C4 55.0(3) 2_666
Bi2 Bi1 Mo1 C4 -74.8(3) .
Mo2 Bi1 Mo1 C3 -86.4(3) .
Bi1 Bi1 Mo1 C3 26.6(3) 2_666
Bi2 Bi1 Mo1 C3 -103.1(3) .
Mo2 Bi1 Mo1 Bi2 16.73(3) .
Bi1 Bi1 Mo1 Bi2 129.72(2) 2_666
C15 C14 Mo2 C13 -117.8(11) .
C13 C14 Mo2 C15 117.8(11) .
C15 C14 Mo2 C18 112.5(9) .
C13 C14 Mo2 C18 -129.7(9) .
C15 C14 Mo2 C16 90.5(8) .
C13 C14 Mo2 C16 -151.7(8) .
C15 C14 Mo2 C12 -79.7(8) .
C13 C14 Mo2 C12 38.1(7) .
C15 C14 Mo2 C17 75.2(8) .
C13 C14 Mo2 C17 -167.0(7) .
C15 C14 Mo2 C20 126.2(8) .
C13 C14 Mo2 C20 -116.0(8) .
C15 C14 Mo2 C11 -38.0(7) .
C13 C14 Mo2 C11 79.8(8) .
C15 C14 Mo2 C19 144.5(7) .
C13 C14 Mo2 C19 -97.7(8) .
C15 C14 Mo2 Bi2 -27.8(10) .
C13 C14 Mo2 Bi2 90.0(9) .
C15 C14 Mo2 Bi1 -124.8(7) .
C13 C14 Mo2 Bi1 -7.0(9) .
C12 C13 Mo2 C14 114.2(10) .
C12 C13 Mo2 C15 77.6(8) .
C14 C13 Mo2 C15 -36.6(7) .
C12 C13 Mo2 C18 -134.8(9) .
C14 C13 Mo2 C18 110.9(10) .
C12 C13 Mo2 C16 146.8(7) .
C14 C13 Mo2 C16 32.6(9) .
C14 C13 Mo2 C12 -114.2(10) .
C12 C13 Mo2 C17 140.7(10) .
C14 C13 Mo2 C17 26.4(14) .
C12 C13 Mo2 C20 179.9(7) .
C14 C13 Mo2 C20 65.6(8) .
C12 C13 Mo2 C11 36.6(7) .
C14 C13 Mo2 C11 -77.6(8) .
C12 C13 Mo2 C19 -145.5(7) .
C14 C13 Mo2 C19 100.3(8) .
C12 C13 Mo2 Bi2 -6.9(8) .
C14 C13 Mo2 Bi2 -121.2(7) .
C12 C13 Mo2 Bi1 -71.6(7) .
C14 C13 Mo2 Bi1 174.2(7) .
C11 C15 Mo2 C14 -114.6(11) .
C14 C15 Mo2 C13 36.9(8) .
C11 C15 Mo2 C13 -77.7(8) .
C14 C15 Mo2 C18 -118.1(9) .
C11 C15 Mo2 C18 127.3(8) .
C14 C15 Mo2 C16 -87.7(8) .
C11 C15 Mo2 C16 157.7(8) .
C14 C15 Mo2 C12 78.0(8) .
C11 C15 Mo2 C12 -36.6(7) .
C14 C15 Mo2 C17 -119.0(8) .
C11 C15 Mo2 C17 126.4(8) .
C14 C15 Mo2 C20 -56.7(8) .
C11 C15 Mo2 C20 -171.3(8) .
C14 C15 Mo2 C11 114.6(11) .
C14 C15 Mo2 C19 -57.3(10) .
C11 C15 Mo2 C19 -171.9(7) .
C14 C15 Mo2 Bi2 160.5(7) .
C11 C15 Mo2 Bi2 45.9(8) .
C14 C15 Mo2 Bi1 85.8(9) .
C11 C15 Mo2 Bi1 -28.8(10) .
C17 C18 Mo2 C14 -62.8(11) .
C19 C18 Mo2 C14 53.1(11) .
C17 C18 Mo2 C13 -132.2(10) .
C19 C18 Mo2 C13 -16.3(13) .
C17 C18 Mo2 C15 -1.4(11) .
C19 C18 Mo2 C15 114.5(9) .
C17 C18 Mo2 C16 -37.2(7) .
C19 C18 Mo2 C16 78.7(7) .
C17 C18 Mo2 C12 143.3(10) .
C19 C18 Mo2 C12 -100.8(12) .
C19 C18 Mo2 C17 115.9(10) .
C17 C18 Mo2 C20 -78.5(7) .
C19 C18 Mo2 C20 37.4(7) .
C17 C18 Mo2 C11 62.2(11) .
C19 C18 Mo2 C11 178.1(8) .
C17 C18 Mo2 C19 -115.9(10) .
C17 C18 Mo2 Bi2 89.7(7) .
C19 C18 Mo2 Bi2 -154.4(7) .
C17 C18 Mo2 Bi1 162.3(7) .
C19 C18 Mo2 Bi1 -81.8(6) .
C17 C16 Mo2 C14 -156.8(8) .
C20 C16 Mo2 C14 85.6(8) .
C17 C16 Mo2 C13 -175.4(7) .
C20 C16 Mo2 C13 67.0(8) .
C17 C16 Mo2 C15 -120.8(8) .
C20 C16 Mo2 C15 121.6(8) .
C17 C16 Mo2 C18 38.0(7) .
C20 C16 Mo2 C18 -79.6(8) .
C17 C16 Mo2 C12 -142.3(8) .
C20 C16 Mo2 C12 100.1(10) .
C20 C16 Mo2 C17 -117.6(11) .
C17 C16 Mo2 C20 117.6(11) .
C17 C16 Mo2 C11 -106.1(8) .
C20 C16 Mo2 C11 136.3(7) .
C17 C16 Mo2 C19 80.5(8) .
C20 C16 Mo2 C19 -37.0(7) .
C17 C16 Mo2 Bi2 -18.3(8) .
C20 C16 Mo2 Bi2 -135.9(6) .
C17 C16 Mo2 Bi1 65.4(8) .
C20 C16 Mo2 Bi1 -52.2(8) .
C13 C12 Mo2 C14 -39.0(8) .
C11 C12 Mo2 C14 78.7(8) .
C11 C12 Mo2 C13 117.7(10) .
C13 C12 Mo2 C15 -81.2(8) .
C11 C12 Mo2 C15 36.5(6) .
C13 C12 Mo2 C18 123.4(11) .
C11 C12 Mo2 C18 -118.9(10) .
C13 C12 Mo2 C16 -56.0(11) .
C11 C12 Mo2 C16 61.7(11) .
C13 C12 Mo2 C17 -130.7(12) .
C11 C12 Mo2 C17 -13.0(15) .
C13 C12 Mo2 C20 -0.2(10) .
C11 C12 Mo2 C20 117.5(8) .
C13 C12 Mo2 C11 -117.7(10) .
C13 C12 Mo2 C19 54.8(10) .
C11 C12 Mo2 C19 172.5(6) .
C13 C12 Mo2 Bi2 174.3(7) .
C11 C12 Mo2 Bi2 -67.9(6) .
C13 C12 Mo2 Bi1 104.2(7) .
C11 C12 Mo2 Bi1 -138.1(7) .
C16 C17 Mo2 C14 26.8(9) .
C18 C17 Mo2 C14 143.0(7) .
C16 C17 Mo2 C13 9.2(14) .
C18 C17 Mo2 C13 125.4(10) .
C16 C17 Mo2 C15 62.9(8) .
C18 C17 Mo2 C15 179.1(7) .
C16 C17 Mo2 C18 -116.2(10) .
C18 C17 Mo2 C16 116.2(10) .
C16 C17 Mo2 C12 105.7(13) .
C18 C17 Mo2 C12 -138.1(11) .
C16 C17 Mo2 C20 -36.7(7) .
C18 C17 Mo2 C20 79.5(7) .
C16 C17 Mo2 C11 96.8(8) .
C18 C17 Mo2 C11 -147.1(7) .
C16 C17 Mo2 C19 -78.2(8) .
C18 C17 Mo2 C19 38.0(7) .
C16 C17 Mo2 Bi2 162.6(7) .
C18 C17 Mo2 Bi2 -81.2(7) .
C16 C17 Mo2 Bi1 -135.2(6) .
C18 C17 Mo2 Bi1 -19.0(8) .
C16 C20 Mo2 C14 -91.7(8) .
C19 C20 Mo2 C14 151.1(8) .
C16 C20 Mo2 C13 -124.5(7) .
C19 C20 Mo2 C13 118.4(7) .
C16 C20 Mo2 C15 -62.2(8) .
C19 C20 Mo2 C15 -179.4(7) .
C16 C20 Mo2 C18 79.0(8) .
C19 C20 Mo2 C18 -38.2(7) .
C19 C20 Mo2 C16 -117.2(10) .
C16 C20 Mo2 C12 -124.4(8) .
C19 C20 Mo2 C12 118.5(8) .
C16 C20 Mo2 C17 36.7(7) .
C19 C20 Mo2 C17 -80.5(8) .
C16 C20 Mo2 C11 -70.2(10) .
C19 C20 Mo2 C11 172.7(7) .
C16 C20 Mo2 C19 117.2(10) .
C16 C20 Mo2 Bi2 63.2(8) .
C19 C20 Mo2 Bi2 -54.0(8) .
C16 C20 Mo2 Bi1 143.7(6) .
C19 C20 Mo2 Bi1 26.5(7) .
C15 C11 Mo2 C14 38.6(8) .
C12 C11 Mo2 C14 -79.0(8) .
C15 C11 Mo2 C13 81.1(8) .
C12 C11 Mo2 C13 -36.5(7) .
C12 C11 Mo2 C15 -117.7(10) .
C15 C11 Mo2 C18 -106.9(9) .
C12 C11 Mo2 C18 135.4(9) .
C15 C11 Mo2 C16 -26.0(9) .
C12 C11 Mo2 C16 -143.7(7) .
C15 C11 Mo2 C12 117.7(10) .
C15 C11 Mo2 C17 -68.0(9) .
C12 C11 Mo2 C17 174.3(7) .
C15 C11 Mo2 C20 13.3(12) .
C12 C11 Mo2 C20 -104.4(9) .
C15 C11 Mo2 Bi2 -134.1(8) .
C12 C11 Mo2 Bi2 108.3(7) .
C15 C11 Mo2 Bi1 160.2(7) .
C12 C11 Mo2 Bi1 42.5(7) .
C20 C19 Mo2 C14 -32.4(9) .
C18 C19 Mo2 C14 -148.3(7) .
C20 C19 Mo2 C13 -72.7(8) .
C18 C19 Mo2 C13 171.3(7) .
C20 C19 Mo2 C15 1.0(11) .
C18 C19 Mo2 C15 -115.0(8) .
C20 C19 Mo2 C18 116.0(10) .
C20 C19 Mo2 C16 36.9(7) .
C18 C19 Mo2 C16 -79.1(7) .
C20 C19 Mo2 C12 -104.2(9) .
C18 C19 Mo2 C12 139.8(7) .
C20 C19 Mo2 C17 78.1(8) .
C18 C19 Mo2 C17 -37.8(7) .
C18 C19 Mo2 C20 -116.0(10) .
C20 C19 Mo2 Bi2 142.0(6) .
C18 C19 Mo2 Bi2 26.0(7) .
C20 C19 Mo2 Bi1 -154.2(7) .
C18 C19 Mo2 Bi1 89.9(6) .
O1 Bi2 Mo2 C14 8.0(6) .
Mo1 Bi2 Mo2 C14 -102.3(6) .
Bi1 Bi2 Mo2 C14 -119.7(6) .
O1 Bi2 Mo2 C13 54.4(4) .
Mo1 Bi2 Mo2 C13 -55.9(4) .
Bi1 Bi2 Mo2 C13 -73.3(4) .
O1 Bi2 Mo2 C15 -8.2(4) .
Mo1 Bi2 Mo2 C15 -118.5(3) .
Bi1 Bi2 Mo2 C15 -136.0(3) .
O1 Bi2 Mo2 C18 -149.0(4) .
Mo1 Bi2 Mo2 C18 100.7(3) .
Bi1 Bi2 Mo2 C18 83.3(3) .
O1 Bi2 Mo2 C16 -100.8(4) .
Mo1 Bi2 Mo2 C16 148.9(3) .
Bi1 Bi2 Mo2 C16 131.5(3) .
O1 Bi2 Mo2 C12 50.4(4) .
Mo1 Bi2 Mo2 C12 -59.9(3) .
Bi1 Bi2 Mo2 C12 -77.3(3) .
O1 Bi2 Mo2 C17 -111.6(4) .
Mo1 Bi2 Mo2 C17 138.1(3) .
Bi1 Bi2 Mo2 C17 120.7(3) .
O1 Bi2 Mo2 C20 -134.8(5) .
Mo1 Bi2 Mo2 C20 114.9(4) .
Bi1 Bi2 Mo2 C20 97.4(4) .
O1 Bi2 Mo2 C11 17.0(4) .
Mo1 Bi2 Mo2 C11 -93.3(4) .
Bi1 Bi2 Mo2 C11 -110.8(4) .
O1 Bi2 Mo2 C19 -164.7(4) .
Mo1 Bi2 Mo2 C19 85.0(3) .
Bi1 Bi2 Mo2 C19 67.6(3) .
O1 Bi2 Mo2 Bi1 127.7(2) .
Mo1 Bi2 Mo2 Bi1 17.43(3) .
Mo1 Bi1 Mo2 C14 115.8(4) .
Bi1 Bi1 Mo2 C14 2.2(4) 2_666
Bi2 Bi1 Mo2 C14 132.6(4) .
Mo1 Bi1 Mo2 C13 111.7(3) .
Bi1 Bi1 Mo2 C13 -2.0(3) 2_666
Bi2 Bi1 Mo2 C13 128.5(3) .
Mo1 Bi1 Mo2 C15 70.7(5) .
Bi1 Bi1 Mo2 C15 -43.0(5) 2_666
Bi2 Bi1 Mo2 C15 87.4(5) .
Mo1 Bi1 Mo2 C18 -94.6(3) .
Bi1 Bi1 Mo2 C18 151.8(3) 2_666
Bi2 Bi1 Mo2 C18 -77.8(3) .
Mo1 Bi1 Mo2 C16 -118.5(4) .
Bi1 Bi1 Mo2 C16 127.8(4) 2_666
Bi2 Bi1 Mo2 C16 -101.7(4) .
Mo1 Bi1 Mo2 C12 77.5(3) .
Bi1 Bi1 Mo2 C12 -36.1(3) 2_666
Bi2 Bi1 Mo2 C12 94.3(3) .
Mo1 Bi1 Mo2 C17 -83.2(3) .
Bi1 Bi1 Mo2 C17 163.1(3) 2_666
Bi2 Bi1 Mo2 C17 -66.4(3) .
Mo1 Bi1 Mo2 C20 -147.5(3) .
Bi1 Bi1 Mo2 C20 98.8(3) 2_666
Bi2 Bi1 Mo2 C20 -130.8(3) .
Mo1 Bi1 Mo2 C11 53.9(3) .
Bi1 Bi1 Mo2 C11 -59.8(3) 2_666
Bi2 Bi1 Mo2 C11 70.7(3) .
Mo1 Bi1 Mo2 C19 -131.9(3) .
Bi1 Bi1 Mo2 C19 114.4(3) 2_666
Bi2 Bi1 Mo2 C19 -115.2(3) .
Mo1 Bi1 Mo2 Bi2 -16.78(3) .
Bi1 Bi1 Mo2 Bi2 -130.44(2) 2_666
C23 C21 O1 Bi2 -46(2) .
C22 C21 O1 Bi2 170.9(14) .
Mo2 Bi2 O1 C21 175.3(12) .
Mo1 Bi2 O1 C21 -70.8(12) .
Bi1 Bi2 O1 C21 -127.3(12) .
