#------------------------------------------------------------------------------
#$Date: 2016-03-26 03:21:29 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180179 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/75/7107554.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7107554
loop_
_publ_author_name
'Nicola Giri'
'William Clegg'
'Ross W. Harrington'
'Peter N. Horton'
'Michael B. Hursthouse'
'Stuart L. James'
_publ_section_title
;
 Selective formation of a polar incomplete coordination cage induced by
 remote ligand substituents
;
_journal_name_full               Chem.Commun.
_journal_page_first              4061
_journal_paper_doi               10.1039/c2cc17832j
_journal_volume                  48
_journal_year                    2012
_chemical_formula_moiety
'C216 H276 Ag6 F12 N24 O12 P12 S4 2+,2 C F3 O3 S -'
_chemical_formula_sum            'C218 H276 Ag6 F18 N24 O18 P12 S2'
_chemical_formula_weight         5073.94
_chemical_name_systematic
;
?
;
_space_group_IT_number           159
_symmetry_cell_setting           trigonal
_symmetry_space_group_name_Hall  'P 3 -2c'
_symmetry_space_group_name_H-M   'P 3 1 c'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            4
_cell_length_a                   26.8708(8)
_cell_length_b                   26.8708(8)
_cell_length_c                   51.831(3)
_cell_measurement_reflns_used    9896
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      17.48
_cell_measurement_theta_min      2.25
_cell_volume                     32410(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL and local programs'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'Bruker APEX2 CCD diffractometer'
_diffrn_measurement_method       'thin-slice ω scans'
_diffrn_radiation_monochromator  'silicon 111'
_diffrn_radiation_source         'Daresbury SRS station 9.8'
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     0.6926
_diffrn_reflns_av_R_equivalents  0.0551
_diffrn_reflns_av_sigmaI/netI    0.0405
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       47
_diffrn_reflns_limit_l_min       -47
_diffrn_reflns_number            85791
_diffrn_reflns_theta_full        18.38
_diffrn_reflns_theta_max         18.38
_diffrn_reflns_theta_min         2.13
_exptl_absorpt_coefficient_mu    0.51
_exptl_absorpt_correction_T_max  0.955
_exptl_absorpt_correction_T_min  0.910
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.040
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             10464
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.362
_refine_diff_density_min         -0.294
_refine_diff_density_rms         0.054
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.06(3)
_refine_ls_extinction_coef       0.0025(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1882
_refine_ls_number_reflns         16753
_refine_ls_number_restraints     7688
_refine_ls_restrained_S_all      1.008
_refine_ls_R_factor_all          0.0706
_refine_ls_R_factor_gt           0.0644
_refine_ls_shift/su_max          0.056
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1582P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1821
_refine_ls_wR_factor_ref         0.1913
_reflns_number_gt                14610
_reflns_number_total             16753
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            c2cc17832j.txt
_cod_data_source_block           ssg0146
_cod_database_code               7107554
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'y, x, z+1/2'
'x-y, -y, z+1/2'
'-x, -x+y, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.46153(4) 0.80922(4) -0.04696(2) 0.1360(4) Uani 1 1 d . A .
Ag2 Ag 0.47097(3) 0.66714(4) 0.051519(18) 0.1235(4) Uani 1 1 d . . .
P1 P 0.54544(13) 0.79830(14) -0.04812(7) 0.1293(10) Uani 1 1 d . . .
P2 P 0.44500(13) 0.58175(14) -0.06246(6) 0.1258(10) Uani 1 1 d . . .
P3 P 0.53889(12) 0.66356(14) 0.02245(6) 0.1208(9) Uani 1 1 d . . .
P4 P 0.44069(10) 0.66372(10) 0.09568(5) 0.0970(7) Uani 1 1 d . . .
C1 C 0.5533(4) 0.7457(5) -0.0289(2) 0.127(3) Uani 1 1 d U A .
H1A H 0.5888 0.7464 -0.0346 0.152 Uiso 1 1 calc R . .
H1B H 0.5593 0.7588 -0.0107 0.152 Uiso 1 1 calc R . .
C2 C 0.4939(5) 0.6570(4) -0.0565(2) 0.116(3) Uani 1 1 d U A .
H2A H 0.5321 0.6659 -0.0631 0.139 Uiso 1 1 calc R . .
H2B H 0.4811 0.6790 -0.0673 0.139 Uiso 1 1 calc R . .
C3 C 0.5211(4) 0.6470(5) -0.0110(2) 0.118(3) Uani 1 1 d U A .
H3A H 0.5550 0.6482 -0.0191 0.141 Uiso 1 1 calc R . .
H3B H 0.4899 0.6064 -0.0116 0.141 Uiso 1 1 calc R . .
C4 C 0.5023(5) 0.6805(5) -0.0295(2) 0.119(3) Uani 1 1 d U . .
C5 C 0.4464(4) 0.6765(4) -0.01851(18) 0.097(2) Uani 1 1 d U A .
H5A H 0.4535 0.6919 -0.0009 0.145 Uiso 1 1 calc R . .
H5B H 0.4156 0.6362 -0.0183 0.145 Uiso 1 1 calc R . .
H5C H 0.4350 0.6989 -0.0294 0.145 Uiso 1 1 calc R . .
C6 C 0.3667(3) 0.6383(3) 0.1041(2) 0.094(2) Uani 1 1 d U . .
H6A H 0.3448 0.5970 0.0997 0.113 Uiso 1 1 calc R . .
H6B H 0.3651 0.6410 0.1231 0.113 Uiso 1 1 calc R . .
C7 C 0.3333 0.6667 0.0924(3) 0.087(4) Uani 1 3 d SU . .
C8 C 0.3333 0.6667 0.0648(3) 0.093(4) Uani 1 3 d SU . .
H8A H 0.3151 0.6270 0.0584 0.139 Uiso 0.33 1 calc PR . .
H8B H 0.3730 0.6881 0.0584 0.139 Uiso 0.33 1 calc PR . .
H8C H 0.3119 0.6849 0.0584 0.139 Uiso 0.33 1 calc PR . .
C9 C 0.6010(9) 0.8637(8) -0.0421(5) 0.132(7) Uani 0.61(2) 1 d PDU A 1
C10 C 0.6431(9) 0.8716(8) -0.0246(4) 0.132(6) Uani 0.61(2) 1 d PDU A 1
H10 H 0.6414 0.8386 -0.0171 0.159 Uiso 0.61(2) 1 calc PR A 1
C11 C 0.6881(9) 0.9255(8) -0.0174(4) 0.146(7) Uani 0.61(2) 1 d PDU A 1
H11 H 0.7156 0.9280 -0.0052 0.175 Uiso 0.61(2) 1 calc PR A 1
C12 C 0.6931(11) 0.9746(7) -0.0274(5) 0.166(8) Uani 0.61(2) 1 d PDU A 1
C13 C 0.6537(10) 0.9679(8) -0.0459(5) 0.164(7) Uani 0.61(2) 1 d PDU A 1
H13 H 0.6581 1.0010 -0.0546 0.197 Uiso 0.61(2) 1 calc PR A 1
C14 C 0.6069(9) 0.9140(8) -0.0523(5) 0.146(7) Uani 0.61(2) 1 d PDU A 1
H14 H 0.5787 0.9120 -0.0640 0.175 Uiso 0.61(2) 1 calc PR A 1
N1 N 0.7404(11) 1.0305(7) -0.0204(5) 0.213(9) Uani 0.61(2) 1 d PDU A 1
C15 C 0.7863(15) 1.0368(14) -0.0028(7) 0.262(18) Uani 0.61(2) 1 d PDU A 1
H15A H 0.8133 1.0777 0.0001 0.394 Uiso 0.61(2) 1 calc PR A 1
H15B H 0.8066 1.0187 -0.0105 0.394 Uiso 0.61(2) 1 calc PR A 1
H15C H 0.7693 1.0182 0.0137 0.394 Uiso 0.61(2) 1 calc PR A 1
C16 C 0.7424(13) 1.0835(9) -0.0293(7) 0.229(13) Uani 0.61(2) 1 d PDU A 1
H16A H 0.7762 1.1169 -0.0219 0.344 Uiso 0.61(2) 1 calc PR A 1
H16B H 0.7076 1.0835 -0.0236 0.344 Uiso 0.61(2) 1 calc PR A 1
H16C H 0.7447 1.0854 -0.0481 0.344 Uiso 0.61(2) 1 calc PR A 1
X9 C 0.6160(12) 0.8635(12) -0.0332(7) 0.125(9) Uani 0.39(2) 1 d PDU A 2
X10 C 0.6606(13) 0.8632(11) -0.0198(7) 0.139(10) Uani 0.39(2) 1 d PDU A 2
H10A H 0.6562 0.8275 -0.0143 0.167 Uiso 0.39(2) 1 calc PR A 2
X11 C 0.7116(13) 0.9136(11) -0.0141(6) 0.140(8) Uani 0.39(2) 1 d PDU A 2
H11A H 0.7409 0.9111 -0.0049 0.168 Uiso 0.39(2) 1 calc PR A 2
X12 C 0.7206(13) 0.9662(10) -0.0213(7) 0.161(9) Uani 0.39(2) 1 d PDU A 2
X13 C 0.6782(15) 0.9678(12) -0.0351(9) 0.169(9) Uani 0.39(2) 1 d PDU A 2
H13A H 0.6834 1.0036 -0.0410 0.203 Uiso 0.39(2) 1 calc PR A 2
X14 C 0.6269(13) 0.9169(13) -0.0409(8) 0.155(9) Uani 0.39(2) 1 d PDU A 2
H14A H 0.5983 0.9197 -0.0505 0.186 Uiso 0.39(2) 1 calc PR A 2
N1X N 0.7740(13) 1.0180(10) -0.0146(7) 0.180(10) Uani 0.39(2) 1 d PDU A 2
X15 C 0.8219(16) 1.0150(18) -0.0024(7) 0.203(15) Uani 0.39(2) 1 d PDU A 2
H15D H 0.8543 1.0539 0.0001 0.305 Uiso 0.39(2) 1 calc PR A 2
H15E H 0.8339 0.9934 -0.0136 0.305 Uiso 0.39(2) 1 calc PR A 2
H15F H 0.8095 0.9956 0.0143 0.305 Uiso 0.39(2) 1 calc PR A 2
X16 C 0.785(2) 1.0759(11) -0.0215(8) 0.203(15) Uani 0.39(2) 1 d PDU A 2
H16D H 0.8238 1.1045 -0.0154 0.304 Uiso 0.39(2) 1 calc PR A 2
H16E H 0.7566 1.0829 -0.0135 0.304 Uiso 0.39(2) 1 calc PR A 2
H16F H 0.7836 1.0787 -0.0403 0.304 Uiso 0.39(2) 1 calc PR A 2
C17 C 0.5604(4) 0.7892(5) -0.0823(2) 0.140(4) Uani 1 1 d DU A .
C18 C 0.5178(5) 0.7764(5) -0.1006(2) 0.160(4) Uani 1 1 d DU . .
H18 H 0.4820 0.7723 -0.0953 0.192 Uiso 1 1 calc R A .
C19 C 0.5266(5) 0.7697(6) -0.1265(2) 0.202(7) Uani 1 1 d DU A .
H19 H 0.4972 0.7601 -0.1390 0.243 Uiso 1 1 calc R . .
C20 C 0.5798(5) 0.7775(8) -0.1334(2) 0.186(6) Uani 1 1 d DU . .
C21 C 0.6220(5) 0.7897(7) -0.1159(2) 0.161(4) Uani 1 1 d DU A .
H21 H 0.6579 0.7941 -0.1212 0.193 Uiso 1 1 calc R . .
C22 C 0.6118(5) 0.7955(6) -0.0898(2) 0.162(5) Uani 1 1 d DU . .
H22 H 0.6409 0.8040 -0.0773 0.195 Uiso 1 1 calc R A .
N2 N 0.5897(5) 0.7670(7) -0.1600(2) 0.205(5) Uani 1 1 d DU A .
C23 C 0.5448(7) 0.7551(12) -0.1793(3) 0.274(13) Uani 1 1 d DU . .
H23A H 0.5582 0.7513 -0.1964 0.411 Uiso 1 1 calc R A .
H23B H 0.5367 0.7869 -0.1795 0.411 Uiso 1 1 calc R . .
H23C H 0.5097 0.7193 -0.1748 0.411 Uiso 1 1 calc R . .
C24 C 0.6462(7) 0.7774(10) -0.1687(3) 0.229(8) Uani 1 1 d DU . .
H24A H 0.6448 0.7702 -0.1873 0.343 Uiso 1 1 calc R A .
H24B H 0.6560 0.7516 -0.1595 0.343 Uiso 1 1 calc R . .
H24C H 0.6754 0.8174 -0.1651 0.343 Uiso 1 1 calc R . .
C25 C 0.4434(8) 0.5773(8) -0.0975(3) 0.210(7) Uani 1 1 d DU . .
C26 C 0.4671(11) 0.6228(9) -0.1141(3) 0.314(12) Uani 1 1 d DU . .
H26 H 0.4871 0.6605 -0.1071 0.377 Uiso 1 1 calc R . .
C27 C 0.4632(11) 0.6159(10) -0.1411(3) 0.360(14) Uani 1 1 d DU . .
H27 H 0.4806 0.6483 -0.1522 0.432 Uiso 1 1 calc R . .
C28 C 0.4339(15) 0.5617(11) -0.1509(3) 0.361(14) Uani 1 1 d DU . .
C29 C 0.4084(15) 0.5143(10) -0.1352(3) 0.368(15) Uani 1 1 d DU . .
H29 H 0.3908 0.4765 -0.1421 0.441 Uiso 1 1 calc R . .
C30 C 0.4091(13) 0.5242(9) -0.1083(3) 0.353(14) Uani 1 1 d DU . .
H30 H 0.3851 0.4929 -0.0973 0.424 Uiso 1 1 calc R . .
N3 N 0.4318(14) 0.5541(12) -0.1789(3) 0.420(17) Uani 1 1 d DU . .
C31 C 0.454(2) 0.6049(15) -0.1950(5) 0.54(3) Uani 1 1 d DU . .
H31A H 0.4665 0.6389 -0.1841 0.812 Uiso 1 1 calc R . .
H31B H 0.4237 0.6012 -0.2068 0.812 Uiso 1 1 calc R . .
H31C H 0.4866 0.6088 -0.2051 0.812 Uiso 1 1 calc R . .
C32 C 0.403(2) 0.4967(14) -0.1900(5) 0.58(4) Uani 1 1 d DU . .
H32A H 0.3834 0.4683 -0.1764 0.863 Uiso 1 1 calc R . .
H32B H 0.4321 0.4895 -0.1982 0.863 Uiso 1 1 calc R . .
H32C H 0.3755 0.4938 -0.2031 0.863 Uiso 1 1 calc R . .
C33 C 0.4794(4) 0.5427(5) -0.0524(2) 0.136(3) Uani 1 1 d DU . .
C34 C 0.4511(5) 0.4977(5) -0.0356(3) 0.171(5) Uani 1 1 d DU . .
H34 H 0.4147 0.4901 -0.0293 0.205 Uiso 1 1 calc R . .
C35 C 0.4720(5) 0.4617(5) -0.0269(3) 0.202(6) Uani 1 1 d DU . .
H35 H 0.4497 0.4296 -0.0160 0.242 Uiso 1 1 calc R . .
C36 C 0.5256(6) 0.4753(7) -0.0347(4) 0.207(6) Uani 1 1 d DU . .
C37 C 0.5536(7) 0.5166(7) -0.0533(3) 0.188(5) Uani 1 1 d DU . .
H37 H 0.5879 0.5212 -0.0608 0.225 Uiso 1 1 calc R . .
C38 C 0.5319(5) 0.5524(5) -0.0614(2) 0.147(4) Uani 1 1 d DU . .
H38 H 0.5535 0.5831 -0.0730 0.176 Uiso 1 1 calc R . .
N4 N 0.5514(6) 0.4424(7) -0.0248(4) 0.247(7) Uani 1 1 d DU . .
C39 C 0.5126(11) 0.3893(11) -0.0113(7) 0.42(2) Uani 1 1 d DU . .
H39A H 0.4795 0.3915 -0.0048 0.623 Uiso 1 1 calc R . .
H39B H 0.5329 0.3840 0.0031 0.623 Uiso 1 1 calc R . .
H39C H 0.4993 0.3568 -0.0233 0.623 Uiso 1 1 calc R . .
C40 C 0.6027(9) 0.4485(10) -0.0374(5) 0.280(11) Uani 1 1 d DU . .
H40A H 0.6203 0.4834 -0.0479 0.420 Uiso 1 1 calc R . .
H40B H 0.5922 0.4150 -0.0484 0.420 Uiso 1 1 calc R . .
H40C H 0.6302 0.4512 -0.0242 0.420 Uiso 1 1 calc R . .
C41 C 0.6088(4) 0.7264(5) 0.0224(2) 0.139(4) Uani 1 1 d DU . .
C42 C 0.6539(4) 0.7313(6) 0.0074(3) 0.173(5) Uani 1 1 d DU . .
H42 H 0.6463 0.7009 -0.0042 0.208 Uiso 1 1 calc R . .
C43 C 0.7089(5) 0.7774(6) 0.0082(3) 0.200(6) Uani 1 1 d DU . .
H43 H 0.7386 0.7789 -0.0022 0.240 Uiso 1 1 calc R . .
C44 C 0.7187(4) 0.8207(7) 0.0245(3) 0.205(6) Uani 1 1 d DU . .
C45 C 0.6766(5) 0.8181(6) 0.0408(3) 0.174(5) Uani 1 1 d DU . .
H45 H 0.6850 0.8481 0.0527 0.209 Uiso 1 1 calc R . .
C46 C 0.6210(5) 0.7702(5) 0.0391(2) 0.148(4) Uani 1 1 d DU . .
H46 H 0.5914 0.7683 0.0498 0.178 Uiso 1 1 calc R . .
N5 N 0.7753(5) 0.8708(6) 0.0257(3) 0.241(7) Uani 1 1 d DU . .
C47 C 0.8203(7) 0.8776(13) 0.0079(5) 0.39(2) Uani 1 1 d DU . .
H47A H 0.8554 0.9142 0.0114 0.581 Uiso 1 1 calc R . .
H47B H 0.8077 0.8774 -0.0098 0.581 Uiso 1 1 calc R . .
H47C H 0.8279 0.8459 0.0103 0.581 Uiso 1 1 calc R . .
C48 C 0.7856(10) 0.9152(10) 0.0455(5) 0.323(17) Uani 1 1 d DU . .
H48A H 0.7488 0.9074 0.0529 0.484 Uiso 1 1 calc R . .
H48B H 0.8047 0.9532 0.0374 0.484 Uiso 1 1 calc R . .
H48C H 0.8102 0.9141 0.0592 0.484 Uiso 1 1 calc R . .
C49 C 0.5491(5) 0.6044(6) 0.0322(2) 0.150(4) Uani 1 1 d DU . .
C50 C 0.5302(5) 0.5830(5) 0.0562(3) 0.158(4) Uani 1 1 d DU . .
H50 H 0.5096 0.5969 0.0658 0.190 Uiso 1 1 calc R . .
C51 C 0.5399(6) 0.5416(5) 0.0671(3) 0.184(5) Uani 1 1 d DU . .
H51 H 0.5252 0.5270 0.0838 0.220 Uiso 1 1 calc R . .
C52 C 0.5704(8) 0.5215(8) 0.0542(3) 0.208(6) Uani 1 1 d DU . .
C53 C 0.5872(9) 0.5407(9) 0.0297(3) 0.230(7) Uani 1 1 d DU . .
H53 H 0.6048 0.5242 0.0196 0.276 Uiso 1 1 calc R . .
C54 C 0.5793(8) 0.5841(8) 0.0189(3) 0.210(6) Uani 1 1 d DU . .
H54 H 0.5950 0.5994 0.0024 0.252 Uiso 1 1 calc R . .
N6 N 0.5769(9) 0.4744(8) 0.0646(3) 0.265(7) Uani 1 1 d DU . .
C55 C 0.5585(12) 0.4521(12) 0.0909(4) 0.306(13) Uani 1 1 d DU . .
H55A H 0.5328 0.4651 0.0976 0.460 Uiso 1 1 calc R . .
H55B H 0.5923 0.4662 0.1021 0.460 Uiso 1 1 calc R . .
H55C H 0.5381 0.4100 0.0906 0.460 Uiso 1 1 calc R . .
C56 C 0.6137(12) 0.4565(12) 0.0510(5) 0.316(13) Uani 1 1 d DU . .
H56A H 0.6232 0.4739 0.0338 0.473 Uiso 1 1 calc R . .
H56B H 0.5933 0.4145 0.0494 0.473 Uiso 1 1 calc R . .
H56C H 0.6492 0.4691 0.0609 0.473 Uiso 1 1 calc R . .
C57 C 0.4518(3) 0.6098(4) 0.11332(18) 0.107(3) Uani 1 1 d DU . .
C58 C 0.4175(4) 0.5524(4) 0.1073(2) 0.129(3) Uani 1 1 d DU . .
H58 H 0.3871 0.5408 0.0952 0.155 Uiso 1 1 calc R . .
C59 C 0.4275(4) 0.5114(5) 0.1190(2) 0.147(4) Uani 1 1 d DU . .
H59 H 0.4016 0.4717 0.1160 0.177 Uiso 1 1 calc R . .
C60 C 0.4738(5) 0.5275(4) 0.1348(3) 0.161(4) Uani 1 1 d DU . .
C61 C 0.5058(6) 0.5840(5) 0.1416(3) 0.168(5) Uani 1 1 d DU . .
H61 H 0.5360 0.5955 0.1538 0.201 Uiso 1 1 calc R . .
C62 C 0.4945(5) 0.6252(5) 0.1308(3) 0.147(4) Uani 1 1 d DU . .
H62 H 0.5170 0.6643 0.1358 0.177 Uiso 1 1 calc R . .
N7 N 0.4827(6) 0.4869(4) 0.1494(3) 0.211(6) Uani 1 1 d DU . .
C63 C 0.4464(7) 0.4251(5) 0.1446(4) 0.225(9) Uani 1 1 d DU . .
H63A H 0.4576 0.4037 0.1563 0.338 Uiso 1 1 calc R . .
H63B H 0.4513 0.4166 0.1267 0.338 Uiso 1 1 calc R . .
H63C H 0.4061 0.4137 0.1476 0.338 Uiso 1 1 calc R . .
C64 C 0.5288(10) 0.5036(7) 0.1683(5) 0.298(14) Uani 1 1 d DU . .
H64A H 0.5257 0.4692 0.1762 0.447 Uiso 1 1 calc R . .
H64B H 0.5254 0.5277 0.1816 0.447 Uiso 1 1 calc R . .
H64C H 0.5660 0.5254 0.1596 0.447 Uiso 1 1 calc R . .
C65 C 0.4873(4) 0.7325(4) 0.1117(2) 0.121(3) Uani 1 1 d DU . .
C66 C 0.5254(4) 0.7757(4) 0.0957(2) 0.147(4) Uani 1 1 d DU . .
H66 H 0.5248 0.7678 0.0778 0.176 Uiso 1 1 calc R . .
C67 C 0.5640(5) 0.8295(5) 0.1043(3) 0.174(5) Uani 1 1 d DU . .
H67 H 0.5889 0.8592 0.0929 0.209 Uiso 1 1 calc R . .
C68 C 0.5648(6) 0.8380(5) 0.1298(3) 0.168(4) Uani 1 1 d DU . .
C69 C 0.5268(6) 0.7985(5) 0.1471(2) 0.166(5) Uani 1 1 d DU . .
H69 H 0.5275 0.8080 0.1648 0.199 Uiso 1 1 calc R . .
C70 C 0.4867(5) 0.7430(4) 0.1377(2) 0.142(3) Uani 1 1 d DU . .
H70 H 0.4602 0.7140 0.1490 0.171 Uiso 1 1 calc R . .
N8 N 0.6054(7) 0.8956(6) 0.1383(3) 0.234(7) Uani 1 1 d DU . .
C71 C 0.6468(10) 0.9381(9) 0.1199(4) 0.332(18) Uani 1 1 d DU . .
H71A H 0.6380 0.9221 0.1025 0.498 Uiso 1 1 calc R . .
H71B H 0.6858 0.9474 0.1246 0.498 Uiso 1 1 calc R . .
H71C H 0.6440 0.9731 0.1205 0.498 Uiso 1 1 calc R . .
C72 C 0.6045(10) 0.9045(8) 0.1657(3) 0.243(9) Uani 1 1 d DU . .
H72A H 0.6326 0.9445 0.1699 0.364 Uiso 1 1 calc R . .
H72B H 0.6143 0.8788 0.1750 0.364 Uiso 1 1 calc R . .
H72C H 0.5661 0.8964 0.1709 0.364 Uiso 1 1 calc R . .
Ag3 Ag 0.88103(4) 0.86006(4) 0.28518(2) 0.1344(4) Uani 1 1 d . . .
Ag4 Ag 1.02684(4) 0.87909(4) 0.181018(17) 0.1247(4) Uani 1 1 d . . .
P5 P 0.92881(15) 0.80731(14) 0.29525(6) 0.1251(9) Uani 1 1 d . . .
P6 P 1.14054(14) 0.93205(14) 0.28428(6) 0.1244(9) Uani 1 1 d D . .
P7 P 1.02362(12) 0.80730(12) 0.20986(6) 0.1138(8) Uani 1 1 d . . .
P8 P 1.03732(11) 0.91481(11) 0.13786(5) 0.0987(7) Uani 1 1 d . . .
C73 C 1.0028(5) 0.8371(5) 0.28911(19) 0.118(3) Uani 1 1 d U B .
H73A H 1.0229 0.8712 0.3004 0.141 Uiso 1 1 calc R . .
H73B H 1.0134 0.8088 0.2953 0.141 Uiso 1 1 calc R . .
C74 C 1.0981(5) 0.8792(5) 0.2628(3) 0.131(3) Uani 1 1 d U B .
H74A H 1.1135 0.8933 0.2453 0.157 Uiso 1 1 calc R . .
H74B H 1.1031 0.8457 0.2662 0.157 Uiso 1 1 calc R . .
C75 C 0.9995(6) 0.8023(5) 0.24366(19) 0.124(3) Uani 1 1 d U B .
H75A H 0.9580 0.7897 0.2432 0.149 Uiso 1 1 calc R . .
H75B H 1.0030 0.7710 0.2520 0.149 Uiso 1 1 calc R . .
C76 C 1.0292(5) 0.8560(5) 0.2621(2) 0.120(3) Uani 1 1 d U . .
C77 C 1.0189(5) 0.9024(4) 0.2510(2) 0.116(3) Uani 1 1 d U B .
H77A H 1.0368 0.9363 0.2622 0.174 Uiso 1 1 calc R . .
H77B H 0.9775 0.8880 0.2500 0.174 Uiso 1 1 calc R . .
H77C H 1.0357 0.9129 0.2337 0.174 Uiso 1 1 calc R . .
C78 C 1.0446(4) 0.9835(3) 0.13127(17) 0.090(2) Uani 1 1 d U . .
H78A H 1.0832 1.0130 0.1373 0.108 Uiso 1 1 calc R . .
H78B H 1.0444 0.9874 0.1123 0.108 Uiso 1 1 calc R . .
C79 C 1.0000 1.0000 0.1426(3) 0.095(4) Uani 1 3 d SU . .
C80 C 1.0000 1.0000 0.1730(3) 0.121(5) Uani 1 3 d SU . .
H80A H 1.0382 1.0286 0.1793 0.181 Uiso 0.33 1 calc PR . .
H80B H 0.9904 0.9618 0.1793 0.181 Uiso 0.33 1 calc PR . .
H80C H 0.9714 1.0096 0.1793 0.181 Uiso 0.33 1 calc PR . .
C81 C 0.9225(6) 0.7984(5) 0.3300(2) 0.157(4) Uani 1 1 d DU . .
C82 C 0.8757(7) 0.7960(6) 0.3425(2) 0.194(5) Uani 1 1 d DU . .
H82 H 0.8480 0.8000 0.3327 0.232 Uiso 1 1 calc R . .
C83 C 0.8681(7) 0.7879(6) 0.3691(2) 0.221(6) Uani 1 1 d DU . .
H83 H 0.8351 0.7852 0.3773 0.265 Uiso 1 1 calc R . .
C84 C 0.9093(8) 0.7841(7) 0.3831(2) 0.208(6) Uani 1 1 d DU . .
C85 C 0.9533(7) 0.7811(9) 0.3709(2) 0.222(7) Uani 1 1 d DU . .
H85 H 0.9780 0.7722 0.3804 0.266 Uiso 1 1 calc R . .
C86 C 0.9613(7) 0.7912(9) 0.3444(2) 0.207(6) Uani 1 1 d DU . .
H86 H 0.9939 0.7932 0.3363 0.248 Uiso 1 1 calc R . .
N9 N 0.9020(8) 0.7756(8) 0.4111(2) 0.274(8) Uani 1 1 d DU . .
C87 C 0.8502(10) 0.7700(7) 0.4229(4) 0.290(10) Uani 1 1 d DU . .
H87A H 0.8307 0.7821 0.4106 0.435 Uiso 1 1 calc R . .
H87B H 0.8606 0.7943 0.4383 0.435 Uiso 1 1 calc R . .
H87C H 0.8244 0.7298 0.4278 0.435 Uiso 1 1 calc R . .
C88 C 0.9431(12) 0.7656(16) 0.4256(4) 0.43(2) Uani 1 1 d DU . .
H88A H 0.9744 0.7709 0.4141 0.638 Uiso 1 1 calc R . .
H88B H 0.9235 0.7263 0.4324 0.638 Uiso 1 1 calc R . .
H88C H 0.9589 0.7930 0.4399 0.638 Uiso 1 1 calc R . .
C89 C 0.8888(5) 0.7338(5) 0.28168(19) 0.127(3) Uani 1 1 d DU . .
C90 C 0.8410(5) 0.7166(5) 0.26660(18) 0.152(4) Uani 1 1 d DU . .
H90 H 0.8284 0.7430 0.2626 0.182 Uiso 1 1 calc R . .
C91 C 0.8103(6) 0.6598(5) 0.2570(2) 0.180(5) Uani 1 1 d DU . .
H91 H 0.7775 0.6480 0.2464 0.216 Uiso 1 1 calc R . .
C92 C 0.8285(6) 0.6226(5) 0.2631(3) 0.178(5) Uani 1 1 d DU . .
C93 C 0.8771(6) 0.6401(5) 0.2781(3) 0.171(5) Uani 1 1 d DU . .
H93 H 0.8898 0.6137 0.2820 0.205 Uiso 1 1 calc R . .
C94 C 0.9075(6) 0.6962(4) 0.2877(2) 0.152(4) Uani 1 1 d DU . .
H94 H 0.9406 0.7081 0.2981 0.182 Uiso 1 1 calc R . .
N10 N 0.7987(7) 0.5647(5) 0.2524(3) 0.219(6) Uani 1 1 d DU . .
C95 C 0.7473(9) 0.5471(10) 0.2368(4) 0.273(10) Uani 1 1 d DU . .
H95A H 0.7416 0.5801 0.2341 0.409 Uiso 1 1 calc R . .
H95B H 0.7137 0.5165 0.2457 0.409 Uiso 1 1 calc R . .
H95C H 0.7519 0.5330 0.2200 0.409 Uiso 1 1 calc R . .
C96 C 0.8193(9) 0.5246(6) 0.2583(4) 0.244(8) Uani 1 1 d DU . .
H96A H 0.8545 0.5443 0.2687 0.366 Uiso 1 1 calc R . .
H96B H 0.8274 0.5109 0.2422 0.366 Uiso 1 1 calc R . .
H96C H 0.7898 0.4918 0.2680 0.366 Uiso 1 1 calc R . .
C97 C 1.1302(6) 0.9001(6) 0.3155(3) 0.175(5) Uani 1 1 d DU B .
C98 C 1.1338(7) 0.8529(6) 0.3209(3) 0.220(6) Uani 1 1 d DU . .
H98 H 1.1426 0.8344 0.3075 0.264 Uiso 1 1 calc R B .
C99 C 1.1245(8) 0.8309(8) 0.3460(3) 0.277(8) Uani 1 1 d DU B .
H99 H 1.1294 0.7989 0.3494 0.333 Uiso 1 1 calc R . .
C100 C 1.1088(12) 0.8533(10) 0.3656(3) 0.310(10) Uani 1 1 d DU . .
C101 C 1.1070(9) 0.9027(8) 0.3615(2) 0.261(8) Uani 1 1 d DU B .
H101 H 1.1010 0.9226 0.3753 0.314 Uiso 1 1 calc R . .
C102 C 1.1145(7) 0.9224(7) 0.3361(2) 0.186(5) Uani 1 1 d DU . .
H102 H 1.1084 0.9536 0.3326 0.223 Uiso 1 1 calc R B .
N11 N 1.1052(13) 0.8331(10) 0.3923(3) 0.395(14) Uani 1 1 d DU B .
C103 C 1.1091(17) 0.7817(13) 0.3966(5) 0.47(2) Uani 1 1 d DU . .
H10B H 1.1172 0.7689 0.3802 0.698 Uiso 1 1 calc R B .
H10C H 1.0727 0.7512 0.4036 0.698 Uiso 1 1 calc R . .
H10D H 1.1402 0.7903 0.4089 0.698 Uiso 1 1 calc R . .
C104 C 1.0927(16) 0.8617(13) 0.4133(4) 0.48(2) Uani 1 1 d DU . .
H10E H 1.0925 0.8957 0.4065 0.722 Uiso 1 1 calc R B .
H10F H 1.1222 0.8735 0.4267 0.722 Uiso 1 1 calc R . .
H10G H 1.0550 0.8351 0.4207 0.722 Uiso 1 1 calc R . .
C105 C 1.2119(6) 0.9500(8) 0.2745(4) 0.125(5) Uani 0.630(19) 1 d PDU B 1
C106 C 1.2596(8) 0.9835(9) 0.2893(4) 0.170(8) Uani 0.630(19) 1 d PDU B 1
H106 H 1.2536 0.9924 0.3064 0.204 Uiso 0.630(19) 1 calc PR B 1
C107 C 1.3156(8) 1.0052(11) 0.2811(4) 0.190(9) Uani 0.630(19) 1 d PDU B 1
H107 H 1.3458 1.0307 0.2922 0.228 Uiso 0.630(19) 1 calc PR B 1
C108 C 1.3295(8) 0.9919(14) 0.2581(5) 0.210(9) Uani 0.630(19) 1 d PDU B 1
C109 C 1.2836(8) 0.9633(15) 0.2419(5) 0.225(11) Uani 0.630(19) 1 d PDU B 1
H109 H 1.2902 0.9596 0.2242 0.270 Uiso 0.630(19) 1 calc PR B 1
C110 C 1.2272(8) 0.9392(13) 0.2509(4) 0.179(9) Uani 0.630(19) 1 d PDU B 1
H110 H 1.1972 0.9134 0.2398 0.214 Uiso 0.630(19) 1 calc PR B 1
N12 N 1.3893(8) 1.0211(14) 0.2489(5) 0.236(11) Uani 0.630(19) 1 d PDU B 1
C111 C 1.4365(11) 1.0543(17) 0.2670(7) 0.28(2) Uani 0.630(19) 1 d PDU B 1
H11B H 1.4208 1.0532 0.2842 0.422 Uiso 0.630(19) 1 calc PR B 1
H11C H 1.4587 1.0942 0.2611 0.422 Uiso 0.630(19) 1 calc PR B 1
H11D H 1.4616 1.0375 0.2678 0.422 Uiso 0.630(19) 1 calc PR B 1
C112 C 1.4012(15) 1.0095(19) 0.2226(6) 0.30(2) Uani 0.630(19) 1 d PDU B 1
H11E H 1.3648 0.9843 0.2137 0.450 Uiso 0.630(19) 1 calc PR B 1
H11F H 1.4243 0.9906 0.2233 0.450 Uiso 0.630(19) 1 calc PR B 1
H11G H 1.4223 1.0457 0.2131 0.450 Uiso 0.630(19) 1 calc PR B 1
X105 C 1.2017(11) 0.9229(17) 0.2844(8) 0.168(12) Uani 0.370(19) 1 d PDU B 2
X106 C 1.2455(13) 0.9540(18) 0.3014(7) 0.191(12) Uani 0.370(19) 1 d PDU B 2
H10H H 1.2374 0.9628 0.3181 0.229 Uiso 0.370(19) 1 calc PR B 2
X107 C 1.3020(12) 0.9726(16) 0.2941(6) 0.173(11) Uani 0.370(19) 1 d PDU B 2
H10I H 1.3314 0.9904 0.3067 0.208 Uiso 0.370(19) 1 calc PR B 2
X108 C 1.3169(11) 0.9664(18) 0.2697(7) 0.182(10) Uani 0.370(19) 1 d PDU B 2
X109 C 1.2732(12) 0.9262(19) 0.2546(6) 0.184(11) Uani 0.370(19) 1 d PDU B 2
H10J H 1.2814 0.9106 0.2399 0.220 Uiso 0.370(19) 1 calc PR B 2
X110 C 1.2162(12) 0.9088(19) 0.2612(7) 0.168(11) Uani 0.370(19) 1 d PDU B 2
H11H H 1.1866 0.8864 0.2493 0.202 Uiso 0.370(19) 1 calc PR B 2
N12X N 1.3755(11) 0.979(2) 0.2641(7) 0.215(12) Uani 0.370(19) 1 d PDU B 2
X111 C 1.4221(14) 1.016(3) 0.2820(10) 0.25(2) Uani 0.370(19) 1 d PDU B 2
H11I H 1.4056 1.0183 0.2985 0.382 Uiso 0.370(19) 1 calc PR B 2
H11J H 1.4446 1.0545 0.2746 0.382 Uiso 0.370(19) 1 calc PR B 2
H11K H 1.4471 0.9996 0.2848 0.382 Uiso 0.370(19) 1 calc PR B 2
X112 C 1.389(2) 0.970(3) 0.2374(9) 0.28(3) Uani 0.370(19) 1 d PDU B 2
H11L H 1.3535 0.9446 0.2283 0.419 Uiso 0.370(19) 1 calc PR B 2
H11M H 1.4139 0.9533 0.2378 0.419 Uiso 0.370(19) 1 calc PR B 2
H11N H 1.4090 1.0075 0.2285 0.419 Uiso 0.370(19) 1 calc PR B 2
C113 C 0.9736(4) 0.7380(4) 0.19744(19) 0.123(3) Uani 1 1 d DU . .
C114 C 0.9670(4) 0.7316(4) 0.1709(2) 0.132(3) Uani 1 1 d DU . .
H114 H 0.9890 0.7637 0.1599 0.158 Uiso 1 1 calc R . .
C115 C 0.9281(4) 0.6784(4) 0.1600(2) 0.135(3) Uani 1 1 d DU . .
H115 H 0.9242 0.6747 0.1418 0.162 Uiso 1 1 calc R . .
C116 C 0.8955(6) 0.6313(4) 0.1754(2) 0.159(4) Uani 1 1 d DU . .
C117 C 0.9011(9) 0.6393(6) 0.2015(2) 0.233(9) Uani 1 1 d DU . .
H117 H 0.8761 0.6087 0.2125 0.279 Uiso 1 1 calc R . .
C118 C 0.9423(8) 0.6911(5) 0.2124(2) 0.208(7) Uani 1 1 d DU . .
H118 H 0.9486 0.6935 0.2305 0.249 Uiso 1 1 calc R . .
N13 N 0.8580(5) 0.5763(4) 0.1633(2) 0.178(4) Uani 1 1 d DU . .
C119 C 0.8514(10) 0.5724(8) 0.1355(3) 0.270(13) Uani 1 1 d DU . .
H11O H 0.8792 0.6093 0.1277 0.405 Uiso 1 1 calc R . .
H11P H 0.8123 0.5633 0.1310 0.405 Uiso 1 1 calc R . .
H11Q H 0.8583 0.5422 0.1290 0.405 Uiso 1 1 calc R . .
C120 C 0.8224(11) 0.5281(7) 0.1800(4) 0.285(13) Uani 1 1 d DU . .
H12A H 0.8346 0.5386 0.1979 0.428 Uiso 1 1 calc R . .
H12B H 0.8263 0.4950 0.1751 0.428 Uiso 1 1 calc R . .
H12C H 0.7821 0.5182 0.1782 0.428 Uiso 1 1 calc R . .
C121 C 1.0914(4) 0.8095(4) 0.21053(18) 0.119(3) Uani 1 1 d DU . .
C122 C 1.1358(4) 0.8473(4) 0.1954(2) 0.143(4) Uani 1 1 d DU . .
H122 H 1.1298 0.8729 0.1849 0.172 Uiso 1 1 calc R . .
C123 C 1.1887(5) 0.8510(5) 0.1945(2) 0.159(4) Uani 1 1 d DU . .
H123 H 1.2186 0.8782 0.1837 0.191 Uiso 1 1 calc R . .
C124 C 1.1964(5) 0.8140(5) 0.2095(3) 0.153(4) Uani 1 1 d DU . .
C125 C 1.1538(5) 0.7743(6) 0.2250(2) 0.148(4) Uani 1 1 d DU . .
H125 H 1.1606 0.7493 0.2355 0.178 Uiso 1 1 calc R . .
C126 C 1.1001(5) 0.7709(5) 0.2253(2) 0.131(3) Uani 1 1 d DU . .
H126 H 1.0696 0.7425 0.2354 0.157 Uiso 1 1 calc R . .
N14 N 1.2520(5) 0.8174(6) 0.2094(3) 0.189(4) Uani 1 1 d DU . .
C127 C 1.2959(7) 0.8573(7) 0.1909(4) 0.204(7) Uani 1 1 d DU . .
H12D H 1.3313 0.8557 0.1931 0.305 Uiso 1 1 calc R . .
H12E H 1.3038 0.8965 0.1942 0.305 Uiso 1 1 calc R . .
H12F H 1.2815 0.8460 0.1733 0.305 Uiso 1 1 calc R . .
C128 C 1.2637(9) 0.7802(12) 0.2263(5) 0.307(14) Uani 1 1 d DU . .
H12G H 1.3034 0.7889 0.2237 0.461 Uiso 1 1 calc R . .
H12H H 1.2373 0.7398 0.2220 0.461 Uiso 1 1 calc R . .
H12I H 1.2582 0.7871 0.2443 0.461 Uiso 1 1 calc R . .
C129 C 0.9815(4) 0.8645(4) 0.11712(17) 0.103(2) Uani 1 1 d DU . .
C130 C 0.9810(4) 0.8719(5) 0.09090(18) 0.131(3) Uani 1 1 d DU . .
H130 H 1.0088 0.9065 0.0829 0.158 Uiso 1 1 calc R . .
C131 C 0.9377(4) 0.8264(5) 0.0762(2) 0.167(5) Uani 1 1 d DU . .
H131 H 0.9359 0.8313 0.0581 0.200 Uiso 1 1 calc R . .
C132 C 0.8978(5) 0.7747(5) 0.0876(2) 0.139(3) Uani 1 1 d DU . .
C133 C 0.8960(5) 0.7685(5) 0.1134(2) 0.145(4) Uani 1 1 d DU . .
H133 H 0.8669 0.7348 0.1216 0.174 Uiso 1 1 calc R . .
C134 C 0.9383(4) 0.8133(4) 0.1273(2) 0.123(3) Uani 1 1 d DU . .
H134 H 0.9378 0.8087 0.1455 0.147 Uiso 1 1 calc R . .
N15 N 0.8504(5) 0.7305(5) 0.0726(2) 0.186(4) Uani 1 1 d DU . .
C135 C 0.8527(8) 0.7336(10) 0.0447(2) 0.244(9) Uani 1 1 d DU . .
H13B H 0.8811 0.7727 0.0394 0.366 Uiso 1 1 calc R . .
H13C H 0.8149 0.7238 0.0379 0.366 Uiso 1 1 calc R . .
H13D H 0.8639 0.7065 0.0379 0.366 Uiso 1 1 calc R . .
C136 C 0.8115(6) 0.6755(5) 0.0852(3) 0.197(6) Uani 1 1 d DU . .
H13E H 0.8161 0.6801 0.1039 0.295 Uiso 1 1 calc R . .
H13F H 0.8209 0.6463 0.0795 0.295 Uiso 1 1 calc R . .
H13G H 0.7717 0.6634 0.0805 0.295 Uiso 1 1 calc R . .
C137 C 1.1049(4) 0.9258(4) 0.12431(19) 0.110(3) Uani 1 1 d DU . .
C138 C 1.1214(4) 0.8850(4) 0.12858(18) 0.127(3) Uani 1 1 d DU . .
H138 H 1.0970 0.8526 0.1389 0.152 Uiso 1 1 calc R . .
C139 C 1.1704(4) 0.8883(4) 0.11902(19) 0.128(3) Uani 1 1 d DU . .
H139 H 1.1791 0.8586 0.1221 0.154 Uiso 1 1 calc R . .
C140 C 1.2057(4) 0.9351(5) 0.1051(2) 0.141(3) Uani 1 1 d DU . .
C141 C 1.1906(5) 0.9747(5) 0.0986(3) 0.156(4) Uani 1 1 d DU . .
H141 H 1.2149 1.0059 0.0877 0.188 Uiso 1 1 calc R . .
C142 C 1.1397(4) 0.9704(4) 0.1078(2) 0.134(3) Uani 1 1 d DU . .
H142 H 1.1290 0.9978 0.1028 0.160 Uiso 1 1 calc R . .
N16 N 1.2590(4) 0.9426(4) 0.0946(2) 0.162(4) Uani 1 1 d DU . .
C143 C 1.2751(6) 0.9006(6) 0.1021(4) 0.194(7) Uani 1 1 d DU . .
H14B H 1.3115 0.9099 0.0939 0.291 Uiso 1 1 calc R . .
H14C H 1.2451 0.8622 0.0967 0.291 Uiso 1 1 calc R . .
H14D H 1.2795 0.9012 0.1209 0.291 Uiso 1 1 calc R . .
C144 C 1.2935(7) 0.9879(6) 0.0763(4) 0.224(9) Uani 1 1 d DU . .
H14E H 1.3272 0.9851 0.0714 0.337 Uiso 1 1 calc R . .
H14F H 1.3060 1.0254 0.0842 0.337 Uiso 1 1 calc R . .
H14G H 1.2705 0.9836 0.0609 0.337 Uiso 1 1 calc R . .
S1 S 0.47444(11) 0.81544(11) 0.02802(6) 0.1116(8) Uani 1 1 d DU A .
O1 O 0.4574(4) 0.8180(4) 0.00271(16) 0.162(3) Uani 1 1 d DU . .
O2 O 0.4998(4) 0.7798(4) 0.0299(2) 0.166(3) Uani 1 1 d DU . .
O3 O 0.4341(3) 0.8083(3) 0.04788(16) 0.142(2) Uani 1 1 d DU . .
C145 C 0.5333(5) 0.8851(5) 0.0342(2) 0.157(4) Uani 1 1 d DU . .
F1 F 0.5744(3) 0.9024(5) 0.0175(2) 0.249(5) Uani 1 1 d DU A .
F2 F 0.5198(4) 0.9250(3) 0.0327(2) 0.221(4) Uani 1 1 d DU A .
F3 F 0.5561(5) 0.8906(4) 0.0570(2) 0.236(4) Uani 1 1 d DU A .
S2 S 0.3333 0.6667 -0.07799(12) 0.1455(18) Uani 1 3 d SDU . .
O4 O 0.3822(5) 0.7211(6) -0.0736(3) 0.284(9) Uani 1 1 d DU . .
C146 C 0.3333 0.6667 -0.1135(4) 0.204(9) Uani 1 3 d SDU . .
F4 F 0.3822(6) 0.6783(11) -0.1224(2) 0.338(10) Uani 1 1 d DU A .
S3 S 0.87339(15) 0.84742(16) 0.20656(7) 0.1426(11) Uani 1 1 d DU . .
O5 O 0.8762(6) 0.8336(5) 0.23156(18) 0.226(5) Uani 1 1 d DU . .
O6 O 0.9224(4) 0.8613(6) 0.1904(3) 0.231(5) Uani 1 1 d DU . .
O7 O 0.8469(6) 0.8803(5) 0.2017(3) 0.224(5) Uani 1 1 d DU . .
C147 C 0.8227(5) 0.7781(6) 0.1919(2) 0.181(4) Uani 1 1 d DU . .
F5 F 0.8117(5) 0.7895(5) 0.1680(2) 0.242(5) Uani 1 1 d DU . .
F6 F 0.8483(7) 0.7464(5) 0.1934(2) 0.268(6) Uani 1 1 d DU . .
F7 F 0.7738(5) 0.7555(6) 0.2047(3) 0.288(6) Uani 1 1 d DU . .
S4 S 1.0000 1.0000 0.31375(11) 0.1378(16) Uani 1 3 d SDU . .
O8 O 0.9416(4) 0.9619(4) 0.3080(2) 0.178(3) Uani 1 1 d DU . .
C148 C 1.0000 1.0000 0.3494(3) 0.162(6) Uani 1 3 d SDU . .
F8 F 0.9828(6) 0.9464(5) 0.3567(2) 0.254(5) Uani 1 1 d DU . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P1 Ag1 P2 145.77(11) . 2_665
P1 Ag1 O1 96.9(2) . .
P1 Ag1 O4 105.1(4) . .
P2 Ag1 O1 102.8(2) 2_665 .
P2 Ag1 O4 87.2(5) 2_665 .
O1 Ag1 O4 123.2(3) . .
P3 Ag2 P4 147.14(10) . .
P3 Ag2 O2 89.3(2) . .
P3 Ag2 O3 106.69(19) . 3_565
P4 Ag2 O2 108.1(2) . .
P4 Ag2 O3 83.69(19) . 3_565
O2 Ag2 O3 129.9(2) . 3_565
Ag1 P1 C1 123.8(4) . .
Ag1 P1 C9 105.3(9) . .
Ag1 P1 X9 114.9(10) . .
Ag1 P1 C17 108.5(4) . .
C1 P1 C9 108.9(8) . .
C1 P1 X9 92.4(11) . .
C1 P1 C17 107.5(5) . .
C9 P1 X9 16.7(13) . .
C9 P1 C17 100.2(10) . .
X9 P1 C17 108.2(10) . .
Ag1 P2 C2 119.4(3) 3_565 .
Ag1 P2 C25 108.5(6) 3_565 .
Ag1 P2 C33 112.0(4) 3_565 .
C2 P2 C25 102.9(8) . .
C2 P2 C33 108.0(5) . .
C25 P2 C33 104.8(6) . .
Ag2 P3 C3 120.1(3) . .
Ag2 P3 C41 115.0(4) . .
Ag2 P3 C49 108.1(4) . .
C3 P3 C41 104.9(6) . .
C3 P3 C49 100.9(5) . .
C41 P3 C49 106.1(5) . .
Ag2 P4 C6 122.0(3) . .
Ag2 P4 C57 108.3(3) . .
Ag2 P4 C65 110.0(4) . .
C6 P4 C57 99.3(4) . .
C6 P4 C65 109.9(4) . .
C57 P4 C65 105.6(4) . .
P1 C1 H1A 107.8 . .
P1 C1 H1B 107.8 . .
P1 C1 C4 118.1(8) . .
H1A C1 H1B 107.1 . .
H1A C1 C4 107.8 . .
H1B C1 C4 107.8 . .
P2 C2 H2A 107.3 . .
P2 C2 H2B 107.3 . .
P2 C2 C4 120.0(8) . .
H2A C2 H2B 106.9 . .
H2A C2 C4 107.3 . .
H2B C2 C4 107.3 . .
P3 C3 H3A 106.1 . .
P3 C3 H3B 106.1 . .
P3 C3 C4 124.9(7) . .
H3A C3 H3B 106.3 . .
H3A C3 C4 106.1 . .
H3B C3 C4 106.1 . .
C1 C4 C2 110.1(9) . .
C1 C4 C3 105.9(8) . .
C1 C4 C5 109.7(8) . .
C2 C4 C3 110.8(9) . .
C2 C4 C5 111.9(8) . .
C3 C4 C5 108.4(9) . .
C4 C5 H5A 109.5 . .
C4 C5 H5B 109.5 . .
C4 C5 H5C 109.5 . .
H5A C5 H5B 109.5 . .
H5A C5 H5C 109.5 . .
H5B C5 H5C 109.5 . .
P4 C6 H6A 107.1 . .
P4 C6 H6B 107.1 . .
P4 C6 C7 121.0(7) . .
H6A C6 H6B 106.8 . .
H6A C6 C7 107.1 . .
H6B C6 C7 107.1 . .
C6 C7 C6 105.9(8) . 2_665
C6 C7 C6 105.9(8) . 3_565
C6 C7 C6 105.9(8) 2_665 3_565
C6 C7 C8 112.8(7) . .
C6 C7 C8 112.8(7) 2_665 .
C6 C7 C8 112.8(7) 3_565 .
C7 C8 H8A 109.5 . .
C7 C8 H8B 109.5 . .
C7 C8 H8C 109.5 . .
H8A C8 H8B 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
P1 C9 C10 121.1(14) . .
P1 C9 C14 124.2(13) . .
C10 C9 C14 114.5(13) . .
C9 C10 H10 118.2 . .
C9 C10 C11 123.7(14) . .
H10 C10 C11 118.2 . .
C10 C11 H11 119.4 . .
C10 C11 C12 121.2(14) . .
H11 C11 C12 119.4 . .
C11 C12 C13 116.4(13) . .
C11 C12 N1 121.4(13) . .
C13 C12 N1 122.0(14) . .
C12 C13 H13 118.8 . .
C12 C13 C14 122.4(14) . .
H13 C13 C14 118.8 . .
C9 C14 C13 121.5(14) . .
C9 C14 H14 119.2 . .
C13 C14 H14 119.2 . .
C12 N1 C15 121.6(15) . .
C12 N1 C16 121.0(15) . .
C15 N1 C16 117.3(16) . .
N1 C15 H15A 109.5 . .
N1 C15 H15B 109.5 . .
N1 C15 H15C 109.5 . .
H15A C15 H15B 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
N1 C16 H16A 109.5 . .
N1 C16 H16B 109.5 . .
N1 C16 H16C 109.5 . .
H16A C16 H16B 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
P1 X9 X10 129.5(19) . .
P1 X9 X14 115.0(19) . .
X10 X9 X14 114.5(16) . .
X9 X10 H10A 118.9 . .
X9 X10 X11 122.3(17) . .
H10A X10 X11 118.9 . .
X10 X11 H11A 119.1 . .
X10 X11 X12 121.8(17) . .
H11A X11 X12 119.1 . .
X11 X12 X13 117.3(15) . .
X11 X12 N1X 120.3(16) . .
X13 X12 N1X 122.4(16) . .
X12 X13 H13A 119.7 . .
X12 X13 X14 120.7(17) . .
H13A X13 X14 119.7 . .
X9 X14 X13 123.4(17) . .
X9 X14 H14A 118.3 . .
X13 X14 H14A 118.3 . .
X12 N1X X15 121.5(17) . .
X12 N1X X16 122.5(17) . .
X15 N1X X16 115.9(18) . .
N1X X15 H15D 109.5 . .
N1X X15 H15E 109.5 . .
N1X X15 H15F 109.5 . .
H15D X15 H15E 109.5 . .
H15D X15 H15F 109.5 . .
H15E X15 H15F 109.5 . .
N1X X16 H16D 109.5 . .
N1X X16 H16E 109.5 . .
N1X X16 H16F 109.5 . .
H16D X16 H16E 109.5 . .
H16D X16 H16F 109.5 . .
H16E X16 H16F 109.5 . .
P1 C17 C18 118.4(8) . .
P1 C17 C22 121.9(9) . .
C18 C17 C22 119.6(10) . .
C17 C18 H18 119.4 . .
C17 C18 C19 121.2(10) . .
H18 C18 C19 119.4 . .
C18 C19 H19 121.4 . .
C18 C19 C20 117.2(10) . .
H19 C19 C20 121.4 . .
C19 C20 C21 122.8(10) . .
C19 C20 N2 119.2(10) . .
C21 C20 N2 117.8(10) . .
C20 C21 H21 120.6 . .
C20 C21 C22 118.9(10) . .
H21 C21 C22 120.6 . .
C17 C22 C21 120.3(10) . .
C17 C22 H22 119.9 . .
C21 C22 H22 119.9 . .
C20 N2 C23 118.4(11) . .
C20 N2 C24 121.7(11) . .
C23 N2 C24 119.1(11) . .
N2 C23 H23A 109.5 . .
N2 C23 H23B 109.5 . .
N2 C23 H23C 109.5 . .
H23A C23 H23B 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
N2 C24 H24A 109.5 . .
N2 C24 H24B 109.5 . .
N2 C24 H24C 109.5 . .
H24A C24 H24B 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
P2 C25 C26 125.8(12) . .
P2 C25 C30 117.1(13) . .
C26 C25 C30 116.5(14) . .
C25 C26 H26 118.7 . .
C25 C26 C27 122.5(15) . .
H26 C26 C27 118.7 . .
C26 C27 H27 120.8 . .
C26 C27 C28 118.4(14) . .
H27 C27 C28 120.8 . .
C27 C28 C29 121.8(13) . .
C27 C28 N3 118.6(14) . .
C29 C28 N3 119.6(14) . .
C28 C29 H29 121.4 . .
C28 C29 C30 117.2(15) . .
H29 C29 C30 121.4 . .
C25 C30 C29 122.3(15) . .
C25 C30 H30 118.9 . .
C29 C30 H30 118.9 . .
C28 N3 C31 118.2(16) . .
C28 N3 C32 120.2(14) . .
C31 N3 C32 121.3(16) . .
N3 C31 H31A 109.5 . .
N3 C31 H31B 109.5 . .
N3 C31 H31C 109.5 . .
H31A C31 H31B 109.5 . .
H31A C31 H31C 109.5 . .
H31B C31 H31C 109.5 . .
N3 C32 H32A 109.5 . .
N3 C32 H32B 109.5 . .
N3 C32 H32C 109.5 . .
H32A C32 H32B 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
P2 C33 C34 118.8(8) . .
P2 C33 C38 124.7(10) . .
C34 C33 C38 116.4(10) . .
C33 C34 H34 117.6 . .
C33 C34 C35 124.8(11) . .
H34 C34 C35 117.6 . .
C34 C35 H35 121.5 . .
C34 C35 C36 116.9(11) . .
H35 C35 C36 121.5 . .
C35 C36 C37 120.2(11) . .
C35 C36 N4 119.6(11) . .
C37 C36 N4 120.0(11) . .
C36 C37 H37 119.6 . .
C36 C37 C38 120.7(11) . .
H37 C37 C38 119.6 . .
C33 C38 C37 120.1(11) . .
C33 C38 H38 120.0 . .
C37 C38 H38 120.0 . .
C36 N4 C39 115.9(13) . .
C36 N4 C40 119.0(13) . .
C39 N4 C40 119.8(16) . .
N4 C39 H39A 109.5 . .
N4 C39 H39B 109.5 . .
N4 C39 H39C 109.5 . .
H39A C39 H39B 109.5 . .
H39A C39 H39C 109.5 . .
H39B C39 H39C 109.5 . .
N4 C40 H40A 109.5 . .
N4 C40 H40B 109.5 . .
N4 C40 H40C 109.5 . .
H40A C40 H40B 109.5 . .
H40A C40 H40C 109.5 . .
H40B C40 H40C 109.5 . .
P3 C41 C42 123.0(8) . .
P3 C41 C46 119.9(8) . .
C42 C41 C46 116.9(10) . .
C41 C42 H42 118.0 . .
C41 C42 C43 124.1(11) . .
H42 C42 C43 118.0 . .
C42 C43 H43 121.5 . .
C42 C43 C44 117.1(11) . .
H43 C43 C44 121.5 . .
C43 C44 C45 122.3(10) . .
C43 C44 N5 119.4(11) . .
C45 C44 N5 118.3(10) . .
C44 C45 H45 120.8 . .
C44 C45 C46 118.4(10) . .
H45 C45 C46 120.8 . .
C41 C46 C45 121.1(10) . .
C41 C46 H46 119.4 . .
C45 C46 H46 119.4 . .
C44 N5 C47 120.7(12) . .
C44 N5 C48 117.8(12) . .
C47 N5 C48 121.6(13) . .
N5 C47 H47A 109.5 . .
N5 C47 H47B 109.5 . .
N5 C47 H47C 109.5 . .
H47A C47 H47B 109.5 . .
H47A C47 H47C 109.5 . .
H47B C47 H47C 109.5 . .
N5 C48 H48A 109.5 . .
N5 C48 H48B 109.5 . .
N5 C48 H48C 109.5 . .
H48A C48 H48B 109.5 . .
H48A C48 H48C 109.5 . .
H48B C48 H48C 109.5 . .
P3 C49 C50 115.8(8) . .
P3 C49 C54 126.1(10) . .
C50 C49 C54 117.6(11) . .
C49 C50 H50 118.9 . .
C49 C50 C51 122.1(11) . .
H50 C50 C51 118.9 . .
C50 C51 H51 119.6 . .
C50 C51 C52 120.7(12) . .
H51 C51 C52 119.6 . .
C51 C52 C53 117.4(11) . .
C51 C52 N6 121.1(12) . .
C53 C52 N6 120.7(12) . .
C52 C53 H53 119.1 . .
C52 C53 C54 121.9(12) . .
H53 C53 C54 119.1 . .
C49 C54 C53 119.9(12) . .
C49 C54 H54 120.1 . .
C53 C54 H54 120.1 . .
C52 N6 C55 122.2(13) . .
C52 N6 C56 119.7(13) . .
C55 N6 C56 116.8(13) . .
N6 C55 H55A 109.5 . .
N6 C55 H55B 109.5 . .
N6 C55 H55C 109.5 . .
H55A C55 H55B 109.5 . .
H55A C55 H55C 109.5 . .
H55B C55 H55C 109.5 . .
N6 C56 H56A 109.5 . .
N6 C56 H56B 109.5 . .
N6 C56 H56C 109.5 . .
H56A C56 H56B 109.5 . .
H56A C56 H56C 109.5 . .
H56B C56 H56C 109.5 . .
P4 C57 C58 118.8(6) . .
P4 C57 C62 122.2(7) . .
C58 C57 C62 118.9(9) . .
C57 C58 H58 120.0 . .
C57 C58 C59 119.9(9) . .
H58 C58 C59 120.0 . .
C58 C59 H59 119.5 . .
C58 C59 C60 121.0(9) . .
H59 C59 C60 119.5 . .
C59 C60 C61 118.4(9) . .
C59 C60 N7 123.0(9) . .
C61 C60 N7 116.9(9) . .
C60 C61 H61 119.7 . .
C60 C61 C62 120.6(10) . .
H61 C61 C62 119.7 . .
C57 C62 C61 120.7(9) . .
C57 C62 H62 119.6 . .
C61 C62 H62 119.6 . .
C60 N7 C63 119.8(10) . .
C60 N7 C64 123.6(10) . .
C63 N7 C64 116.5(10) . .
N7 C63 H63A 109.5 . .
N7 C63 H63B 109.5 . .
N7 C63 H63C 109.5 . .
H63A C63 H63B 109.5 . .
H63A C63 H63C 109.5 . .
H63B C63 H63C 109.5 . .
N7 C64 H64A 109.5 . .
N7 C64 H64B 109.5 . .
N7 C64 H64C 109.5 . .
H64A C64 H64B 109.5 . .
H64A C64 H64C 109.5 . .
H64B C64 H64C 109.5 . .
P4 C65 C66 115.1(8) . .
P4 C65 C70 125.2(8) . .
C66 C65 C70 119.8(10) . .
C65 C66 H66 118.4 . .
C65 C66 C67 123.1(11) . .
H66 C66 C67 118.4 . .
C66 C67 H67 121.9 . .
C66 C67 C68 116.2(11) . .
H67 C67 C68 121.9 . .
C67 C68 C69 124.7(10) . .
C67 C68 N8 115.0(10) . .
C69 C68 N8 120.0(10) . .
C68 C69 H69 121.0 . .
C68 C69 C70 118.1(10) . .
H69 C69 C70 121.0 . .
C65 C70 C69 117.9(10) . .
C65 C70 H70 121.1 . .
C69 C70 H70 121.1 . .
C68 N8 C71 120.3(11) . .
C68 N8 C72 114.4(11) . .
C71 N8 C72 125.1(13) . .
N8 C71 H71A 109.5 . .
N8 C71 H71B 109.5 . .
N8 C71 H71C 109.5 . .
H71A C71 H71B 109.5 . .
H71A C71 H71C 109.5 . .
H71B C71 H71C 109.5 . .
N8 C72 H72A 109.5 . .
N8 C72 H72B 109.5 . .
N8 C72 H72C 109.5 . .
H72A C72 H72B 109.5 . .
H72A C72 H72C 109.5 . .
H72B C72 H72C 109.5 . .
P5 Ag3 P6 146.31(12) . 3_675
P5 Ag3 O5 92.1(3) . .
P5 Ag3 O8 106.1(2) . .
P6 Ag3 O5 93.4(3) 3_675 .
P6 Ag3 O8 96.4(2) 3_675 .
O5 Ag3 O8 128.1(3) . .
P7 Ag4 P8 148.32(10) . .
P7 Ag4 O6 97.5(4) . .
P7 Ag4 O7 95.8(3) . 2_765
P8 Ag4 O6 98.4(4) . .
P8 Ag4 O7 98.7(4) . 2_765
O6 Ag4 O7 121.9(4) . 2_765
Ag3 P5 C73 120.5(4) . .
Ag3 P5 C81 104.6(4) . .
Ag3 P5 C89 110.5(4) . .
C73 P5 C81 104.4(6) . .
C73 P5 C89 109.8(5) . .
C81 P5 C89 105.7(5) . .
Ag3 P6 C74 120.3(4) 2_765 .
Ag3 P6 C97 112.7(5) 2_765 .
Ag3 P6 C105 106.0(6) 2_765 .
Ag3 P6 X105 127.2(13) 2_765 .
C74 P6 C97 108.1(6) . .
C74 P6 C105 102.4(7) . .
C74 P6 X105 99.5(13) . .
C97 P6 C105 105.8(8) . .
C97 P6 X105 82.1(14) . .
C105 P6 X105 26.4(12) . .
Ag4 P7 C75 121.2(4) . .
Ag4 P7 C113 108.6(3) . .
Ag4 P7 C121 110.9(3) . .
C75 P7 C113 102.2(5) . .
C75 P7 C121 107.3(5) . .
C113 P7 C121 105.3(5) . .
Ag4 P8 C78 121.5(3) . .
Ag4 P8 C129 111.8(3) . .
Ag4 P8 C137 109.4(3) . .
C78 P8 C129 106.4(4) . .
C78 P8 C137 100.0(4) . .
C129 P8 C137 106.3(4) . .
P5 C73 H73A 106.6 . .
P5 C73 H73B 106.6 . .
P5 C73 C76 123.1(7) . .
H73A C73 H73B 106.5 . .
H73A C73 C76 106.6 . .
H73B C73 C76 106.6 . .
P6 C74 H74A 107.5 . .
P6 C74 H74B 107.5 . .
P6 C74 C76 119.2(8) . .
H74A C74 H74B 107.0 . .
H74A C74 C76 107.5 . .
H74B C74 C76 107.5 . .
P7 C75 H75A 107.2 . .
P7 C75 H75B 107.2 . .
P7 C75 C76 120.5(8) . .
H75A C75 H75B 106.8 . .
H75A C75 C76 107.2 . .
H75B C75 C76 107.2 . .
C73 C76 C74 110.8(9) . .
C73 C76 C75 108.1(9) . .
C73 C76 C77 111.7(9) . .
C74 C76 C75 108.8(9) . .
C74 C76 C77 109.5(9) . .
C75 C76 C77 107.9(9) . .
C76 C77 H77A 109.5 . .
C76 C77 H77B 109.5 . .
C76 C77 H77C 109.5 . .
H77A C77 H77B 109.5 . .
H77A C77 H77C 109.5 . .
H77B C77 H77C 109.5 . .
P8 C78 H78A 107.2 . .
P8 C78 H78B 107.2 . .
P8 C78 C79 120.6(6) . .
H78A C78 H78B 106.8 . .
H78A C78 C79 107.2 . .
H78B C78 C79 107.2 . .
C78 C79 C78 107.0(6) 3_675 2_765
C78 C79 C78 107.0(6) . 3_675
C78 C79 C78 107.0(6) . 2_765
C78 C79 C80 111.8(6) . .
C78 C79 C80 111.8(6) 3_675 .
C78 C79 C80 111.8(6) 2_765 .
C79 C80 H80A 109.5 . .
C79 C80 H80B 109.5 . .
C79 C80 H80C 109.5 . .
H80A C80 H80B 109.5 . .
H80A C80 H80C 109.5 . .
H80B C80 H80C 109.5 . .
P5 C81 C82 119.6(9) . .
P5 C81 C86 122.2(9) . .
C82 C81 C86 118.1(11) . .
C81 C82 H82 119.0 . .
C81 C82 C83 122.0(12) . .
H82 C82 C83 119.0 . .
C82 C83 H83 120.8 . .
C82 C83 C84 118.4(12) . .
H83 C83 C84 120.8 . .
C83 C84 C85 120.5(11) . .
C83 C84 N9 119.1(12) . .
C85 C84 N9 119.9(12) . .
C84 C85 H85 120.2 . .
C84 C85 C86 119.7(12) . .
H85 C85 C86 120.2 . .
C81 C86 C85 120.6(12) . .
C81 C86 H86 119.7 . .
C85 C86 H86 119.7 . .
C84 N9 C87 118.5(13) . .
C84 N9 C88 118.7(12) . .
C87 N9 C88 122.4(13) . .
N9 C87 H87A 109.5 . .
N9 C87 H87B 109.5 . .
N9 C87 H87C 109.5 . .
H87A C87 H87B 109.5 . .
H87A C87 H87C 109.5 . .
H87B C87 H87C 109.5 . .
N9 C88 H88A 109.5 . .
N9 C88 H88B 109.5 . .
N9 C88 H88C 109.5 . .
H88A C88 H88B 109.5 . .
H88A C88 H88C 109.5 . .
H88B C88 H88C 109.5 . .
P5 C89 C90 121.5(8) . .
P5 C89 C94 118.0(8) . .
C90 C89 C94 120.5(10) . .
C89 C90 H90 119.8 . .
C89 C90 C91 120.4(11) . .
H90 C90 C91 119.8 . .
C90 C91 H91 120.5 . .
C90 C91 C92 119.0(11) . .
H91 C91 C92 120.5 . .
C91 C92 C93 120.6(11) . .
C91 C92 N10 119.5(11) . .
C93 C92 N10 119.8(11) . .
C92 C93 H93 119.7 . .
C92 C93 C94 120.5(11) . .
H93 C93 C94 119.7 . .
C89 C94 C93 118.9(11) . .
C89 C94 H94 120.6 . .
C93 C94 H94 120.6 . .
C92 N10 C95 118.8(13) . .
C92 N10 C96 119.7(11) . .
C95 N10 C96 121.4(13) . .
N10 C95 H95A 109.5 . .
N10 C95 H95B 109.5 . .
N10 C95 H95C 109.5 . .
H95A C95 H95B 109.5 . .
H95A C95 H95C 109.5 . .
H95B C95 H95C 109.5 . .
N10 C96 H96A 109.5 . .
N10 C96 H96B 109.5 . .
N10 C96 H96C 109.5 . .
H96A C96 H96B 109.5 . .
H96A C96 H96C 109.5 . .
H96B C96 H96C 109.5 . .
P6 C97 C98 125.0(11) . .
P6 C97 C102 119.7(9) . .
C98 C97 C102 115.2(12) . .
C97 C98 H98 119.7 . .
C97 C98 C99 120.7(13) . .
H98 C98 C99 119.7 . .
C98 C99 H99 118.7 . .
C98 C99 C100 122.6(14) . .
H99 C99 C100 118.7 . .
C99 C100 C101 119.2(13) . .
C99 C100 N11 121.4(14) . .
C101 C100 N11 118.3(13) . .
C100 C101 H101 121.8 . .
C100 C101 C102 116.3(13) . .
H101 C101 C102 121.8 . .
C97 C102 C101 125.4(13) . .
C97 C102 H102 117.3 . .
C101 C102 H102 117.3 . .
C100 N11 C103 118.1(14) . .
C100 N11 C104 119.7(14) . .
C103 N11 C104 122.0(14) . .
N11 C103 H10B 109.5 . .
N11 C103 H10C 109.5 . .
N11 C103 H10D 109.5 . .
H10B C103 H10C 109.5 . .
H10B C103 H10D 109.5 . .
H10C C103 H10D 109.5 . .
N11 C104 H10E 109.5 . .
N11 C104 H10F 109.5 . .
N11 C104 H10G 109.5 . .
H10E C104 H10F 109.5 . .
H10E C104 H10G 109.5 . .
H10F C104 H10G 109.5 . .
P6 C105 C106 122.4(12) . .
P6 C105 C110 126.0(12) . .
C106 C105 C110 111.0(13) . .
C105 C106 H106 117.7 . .
C105 C106 C107 124.5(15) . .
H106 C106 C107 117.7 . .
C106 C107 H107 118.4 . .
C106 C107 C108 123.2(15) . .
H107 C107 C108 118.4 . .
C107 C108 C109 113.6(14) . .
C107 C108 N12 121.1(15) . .
C109 C108 N12 122.7(15) . .
C108 C109 H109 119.3 . .
C108 C109 C110 121.3(15) . .
H109 C109 C110 119.3 . .
C105 C110 C109 124.9(15) . .
C105 C110 H110 117.5 . .
C109 C110 H110 117.5 . .
C108 N12 C111 120.1(15) . .
C108 N12 C112 118.7(15) . .
C111 N12 C112 120.6(17) . .
N12 C111 H11B 109.5 . .
N12 C111 H11C 109.5 . .
N12 C111 H11D 109.5 . .
H11B C111 H11C 109.5 . .
H11B C111 H11D 109.5 . .
H11C C111 H11D 109.5 . .
N12 C112 H11E 109.5 . .
N12 C112 H11F 109.5 . .
N12 C112 H11G 109.5 . .
H11E C112 H11F 109.5 . .
H11E C112 H11G 109.5 . .
H11F C112 H11G 109.5 . .
P6 X105 X106 119(2) . .
P6 X105 X110 116(2) . .
X106 X105 X110 117.1(16) . .
X105 X106 H10H 120.2 . .
X105 X106 X107 119.5(17) . .
H10H X106 X107 120.2 . .
X106 X107 H10I 118.5 . .
X106 X107 X108 123.1(17) . .
H10I X107 X108 118.5 . .
X107 X108 X109 115.8(16) . .
X107 X108 N12X 120.3(17) . .
X109 X108 N12X 117.9(18) . .
X108 X109 H10J 120.5 . .
X108 X109 X110 119.0(17) . .
H10J X109 X110 120.5 . .
X105 X110 X109 122.4(17) . .
X105 X110 H11H 118.8 . .
X109 X110 H11H 118.8 . .
X108 N12X X111 119.0(17) . .
X108 N12X X112 118.1(18) . .
X111 N12X X112 120.1(19) . .
N12X X111 H11I 109.5 . .
N12X X111 H11J 109.4 . .
N12X X111 H11K 109.5 . .
H11I X111 H11J 109.5 . .
H11I X111 H11K 109.5 . .
H11J X111 H11K 109.5 . .
N12X X112 H11L 109.5 . .
N12X X112 H11M 109.5 . .
N12X X112 H11N 109.5 . .
H11L X112 H11M 109.5 . .
H11L X112 H11N 109.5 . .
H11M X112 H11N 109.5 . .
P7 C113 C114 118.0(7) . .
P7 C113 C118 123.8(8) . .
C114 C113 C118 118.3(10) . .
C113 C114 H114 119.7 . .
C113 C114 C115 120.5(10) . .
H114 C114 C115 119.7 . .
C114 C115 H115 119.5 . .
C114 C115 C116 120.9(10) . .
H115 C115 C116 119.5 . .
C115 C116 C117 117.3(9) . .
C115 C116 N13 119.1(9) . .
C117 C116 N13 123.6(10) . .
C116 C117 H117 119.0 . .
C116 C117 C118 122.1(11) . .
H117 C117 C118 119.0 . .
C113 C118 C117 120.5(11) . .
C113 C118 H118 119.8 . .
C117 C118 H118 119.8 . .
C116 N13 C119 119.9(10) . .
C116 N13 C120 117.7(11) . .
C119 N13 C120 121.8(12) . .
N13 C119 H11O 109.5 . .
N13 C119 H11P 109.5 . .
N13 C119 H11Q 109.5 . .
H11O C119 H11P 109.5 . .
H11O C119 H11Q 109.5 . .
H11P C119 H11Q 109.5 . .
N13 C120 H12A 109.5 . .
N13 C120 H12B 109.5 . .
N13 C120 H12C 109.5 . .
H12A C120 H12B 109.5 . .
H12A C120 H12C 109.5 . .
H12B C120 H12C 109.5 . .
P7 C121 C122 120.5(7) . .
P7 C121 C126 122.0(7) . .
C122 C121 C126 117.4(9) . .
C121 C122 H122 117.9 . .
C121 C122 C123 124.1(10) . .
H122 C122 C123 117.9 . .
C122 C123 H123 121.4 . .
C122 C123 C124 117.2(10) . .
H123 C123 C124 121.4 . .
C123 C124 C125 122.2(10) . .
C123 C124 N14 118.6(10) . .
C125 C124 N14 119.2(10) . .
C124 C125 H125 120.3 . .
C124 C125 C126 119.4(10) . .
H125 C125 C126 120.3 . .
C121 C126 C125 119.7(10) . .
C121 C126 H126 120.1 . .
C125 C126 H126 120.1 . .
C124 N14 C127 118.2(10) . .
C124 N14 C128 121.0(11) . .
C127 N14 C128 120.8(11) . .
N14 C127 H12D 109.5 . .
N14 C127 H12E 109.5 . .
N14 C127 H12F 109.5 . .
H12D C127 H12E 109.5 . .
H12D C127 H12F 109.5 . .
H12E C127 H12F 109.5 . .
N14 C128 H12G 109.5 . .
N14 C128 H12H 109.5 . .
N14 C128 H12I 109.5 . .
H12G C128 H12H 109.5 . .
H12G C128 H12I 109.5 . .
H12H C128 H12I 109.5 . .
P8 C129 C130 123.4(7) . .
P8 C129 C134 119.4(7) . .
C130 C129 C134 117.1(9) . .
C129 C130 H130 120.9 . .
C129 C130 C131 118.2(9) . .
H130 C130 C131 120.9 . .
C130 C131 H131 119.3 . .
C130 C131 C132 121.5(10) . .
H131 C131 C132 119.3 . .
C131 C132 C133 120.5(9) . .
C131 C132 N15 120.7(10) . .
C133 C132 N15 117.8(9) . .
C132 C133 H133 121.6 . .
C132 C133 C134 116.8(10) . .
H133 C133 C134 121.6 . .
C129 C134 C133 125.7(10) . .
C129 C134 H134 117.2 . .
C133 C134 H134 117.2 . .
C132 N15 C135 119.3(11) . .
C132 N15 C136 118.3(10) . .
C135 N15 C136 119.5(12) . .
N15 C135 H13B 109.5 . .
N15 C135 H13C 109.5 . .
N15 C135 H13D 109.5 . .
H13B C135 H13C 109.5 . .
H13B C135 H13D 109.5 . .
H13C C135 H13D 109.5 . .
N15 C136 H13E 109.5 . .
N15 C136 H13F 109.5 . .
N15 C136 H13G 109.5 . .
H13E C136 H13F 109.5 . .
H13E C136 H13G 109.5 . .
H13F C136 H13G 109.5 . .
P8 C137 C138 119.7(7) . .
P8 C137 C142 124.2(7) . .
C138 C137 C142 115.9(8) . .
C137 C138 H138 117.7 . .
C137 C138 C139 124.6(9) . .
H138 C138 C139 117.7 . .
C138 C139 H139 121.2 . .
C138 C139 C140 117.5(9) . .
H139 C139 C140 121.2 . .
C139 C140 C141 121.1(9) . .
C139 C140 N16 121.3(9) . .
C141 C140 N16 117.4(9) . .
C140 C141 H141 119.5 . .
C140 C141 C142 121.0(9) . .
H141 C141 C142 119.5 . .
C137 C142 C141 119.4(9) . .
C137 C142 H142 120.3 . .
C141 C142 H142 120.3 . .
C140 N16 C143 116.7(9) . .
C140 N16 C144 122.3(9) . .
C143 N16 C144 120.8(10) . .
N16 C143 H14B 109.5 . .
N16 C143 H14C 109.5 . .
N16 C143 H14D 109.5 . .
H14B C143 H14C 109.5 . .
H14B C143 H14D 109.5 . .
H14C C143 H14D 109.5 . .
N16 C144 H14E 109.5 . .
N16 C144 H14F 109.5 . .
N16 C144 H14G 109.5 . .
H14E C144 H14F 109.5 . .
H14E C144 H14G 109.5 . .
H14F C144 H14G 109.5 . .
O1 S1 O2 111.8(6) . .
O1 S1 O3 115.8(6) . .
O1 S1 C145 105.0(5) . .
O2 S1 O3 116.2(6) . .
O2 S1 C145 102.8(5) . .
O3 S1 C145 103.1(4) . .
Ag1 O1 S1 153.5(7) . .
Ag2 O2 S1 138.2(6) . .
Ag2 O3 S1 137.8(5) 2_665 .
S1 C145 F1 114.2(8) . .
S1 C145 F2 113.1(8) . .
S1 C145 F3 113.8(8) . .
F1 C145 F2 101.8(11) . .
F1 C145 F3 107.2(12) . .
F2 C145 F3 105.7(11) . .
O4 S2 O4 117.5(3) . 3_565
O4 S2 O4 117.4(3) 3_565 2_665
O4 S2 O4 117.4(3) . 2_665
O4 S2 C146 99.3(6) . .
O4 S2 C146 99.3(6) 3_565 .
O4 S2 C146 99.3(6) 2_665 .
Ag1 O4 S2 157.9(9) . .
S2 C146 F4 111.2(11) . .
S2 C146 F4 111.2(11) . 2_665
S2 C146 F4 111.2(11) . 3_565
F4 C146 F4 107.7(12) 2_665 3_565
F4 C146 F4 107.7(12) . 2_665
F4 C146 F4 107.7(12) . 3_565
O5 S3 O6 117.1(10) . .
O5 S3 O7 117.2(11) . .
O5 S3 C147 103.3(6) . .
O6 S3 O7 114.6(10) . .
O6 S3 C147 98.1(6) . .
O7 S3 C147 102.2(6) . .
Ag3 O5 S3 149.4(9) . .
Ag4 O6 S3 154.4(10) . .
Ag4 O7 S3 148.9(9) 3_675 .
S3 C147 F5 106.6(9) . .
S3 C147 F6 105.5(9) . .
S3 C147 F7 108.8(10) . .
F5 C147 F6 116.2(13) . .
F5 C147 F7 106.6(13) . .
F6 C147 F7 112.9(14) . .
O8 S4 O8 115.7(4) . 3_675
O8 S4 O8 115.7(4) . 2_765
O8 S4 O8 115.7(4) 3_675 2_765
O8 S4 C148 102.1(5) . .
O8 S4 C148 102.1(5) 3_675 .
O8 S4 C148 102.1(5) 2_765 .
Ag3 O8 S4 136.5(6) . .
S4 C148 F8 106.6(9) . .
S4 C148 F8 106.6(9) . 2_765
S4 C148 F8 106.6(9) . 3_675
F8 C148 F8 112.2(8) . 2_765
F8 C148 F8 112.2(8) . 3_675
F8 C148 F8 112.2(8) 2_765 3_675
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 P1 2.415(3) .
Ag1 P2 2.407(3) 2_665
Ag1 O1 2.593(8) .
Ag1 O4 2.647(10) .
Ag2 P3 2.405(3) .
Ag2 P4 2.416(3) .
Ag2 O2 2.946(9) .
Ag2 O3 2.670(8) 3_565
P1 C1 1.827(13) .
P1 C9 1.670(18) .
P1 X9 1.98(3) .
P1 C17 1.859(11) .
P2 Ag1 2.407(3) 3_565
P2 C2 1.804(11) .
P2 C25 1.820(16) .
P2 C33 1.788(12) .
P3 C3 1.794(11) .
P3 C41 1.791(12) .
P3 C49 1.816(13) .
P4 C6 1.803(9) .
P4 C57 1.858(10) .
P4 C65 1.833(11) .
C1 H1A 0.990 .
C1 H1B 0.990 .
C1 C4 1.596(16) .
C2 H2A 0.990 .
C2 H2B 0.990 .
C2 C4 1.508(15) .
C3 H3A 0.990 .
C3 H3B 0.990 .
C3 C4 1.560(17) .
C4 C5 1.559(15) .
C5 H5A 0.980 .
C5 H5B 0.980 .
C5 H5C 0.980 .
C6 H6A 0.990 .
C6 H6B 0.990 .
C6 C7 1.560(11) .
C7 C6 1.560(11) 2_665
C7 C6 1.560(11) 3_565
C7 C8 1.43(2) .
C8 H8A 0.980 .
C8 H8B 0.980 .
C8 H8C 0.980 .
C9 C10 1.381(13) .
C9 C14 1.386(13) .
C10 H10 0.950 .
C10 C11 1.396(13) .
C11 H11 0.950 .
C11 C12 1.360(13) .
C12 C13 1.372(13) .
C12 N1 1.448(13) .
C13 H13 0.950 .
C13 C14 1.403(13) .
C14 H14 0.950 .
N1 C15 1.474(13) .
N1 C16 1.471(13) .
C15 H15A 0.980 .
C15 H15B 0.980 .
C15 H15C 0.980 .
C16 H16A 0.980 .
C16 H16B 0.980 .
C16 H16C 0.980 .
X9 X10 1.390(14) .
X9 X14 1.373(13) .
X10 H10A 0.950 .
X10 X11 1.394(13) .
X11 H11A 0.950 .
X11 X12 1.364(13) .
X12 X13 1.365(13) .
X12 N1X 1.455(13) .
X13 H13A 0.950 .
X13 X14 1.404(14) .
X14 H14A 0.950 .
N1X X15 1.472(14) .
N1X X16 1.472(14) .
X15 H15D 0.980 .
X15 H15E 0.980 .
X15 H15F 0.980 .
X16 H16D 0.980 .
X16 H16E 0.980 .
X16 H16F 0.980 .
C17 C18 1.395(11) .
C17 C22 1.361(11) .
C18 H18 0.950 .
C18 C19 1.390(11) .
C19 H19 0.950 .
C19 C20 1.384(11) .
C20 C21 1.359(11) .
C20 N2 1.458(11) .
C21 H21 0.950 .
C21 C22 1.404(11) .
C22 H22 0.950 .
N2 C23 1.475(12) .
N2 C24 1.471(12) .
C23 H23A 0.980 .
C23 H23B 0.980 .
C23 H23C 0.980 .
C24 H24A 0.980 .
C24 H24B 0.980 .
C24 H24C 0.980 .
C25 C26 1.361(13) .
C25 C30 1.374(13) .
C26 H26 0.950 .
C26 C27 1.411(13) .
C27 H27 0.950 .
C27 C28 1.360(13) .
C28 C29 1.370(13) .
C28 N3 1.465(13) .
C29 H29 0.950 .
C29 C30 1.417(13) .
C30 H30 0.950 .
N3 C31 1.448(14) .
N3 C32 1.455(13) .
C31 H31A 0.980 .
C31 H31B 0.980 .
C31 H31C 0.980 .
C32 H32A 0.980 .
C32 H32B 0.980 .
C32 H32C 0.980 .
C33 C34 1.372(11) .
C33 C38 1.383(11) .
C34 H34 0.950 .
C34 C35 1.413(12) .
C35 H35 0.950 .
C35 C36 1.358(12) .
C36 C37 1.378(12) .
C36 N4 1.460(12) .
C37 H37 0.950 .
C37 C38 1.413(11) .
C38 H38 0.950 .
N4 C39 1.457(13) .
N4 C40 1.458(13) .
C39 H39A 0.980 .
C39 H39B 0.980 .
C39 H39C 0.980 .
C40 H40A 0.980 .
C40 H40B 0.980 .
C40 H40C 0.980 .
C41 C42 1.390(11) .
C41 C46 1.363(11) .
C42 H42 0.950 .
C42 C43 1.374(11) .
C43 H43 0.950 .
C43 C44 1.351(11) .
C44 C45 1.384(11) .
C44 N5 1.443(12) .
C45 H45 0.950 .
C45 C46 1.404(11) .
C46 H46 0.950 .
N5 C47 1.458(13) .
N5 C48 1.488(12) .
C47 H47A 0.980 .
C47 H47B 0.980 .
C47 H47C 0.980 .
C48 H48A 0.980 .
C48 H48B 0.980 .
C48 H48C 0.980 .
C49 C50 1.360(11) .
C49 C54 1.368(11) .
C50 H50 0.950 .
C50 C51 1.385(12) .
C51 H51 0.950 .
C51 C52 1.361(12) .
C52 C53 1.359(12) .
C52 N6 1.462(12) .
C53 H53 0.950 .
C53 C54 1.402(12) .
C54 H54 0.950 .
N6 C55 1.475(13) .
N6 C56 1.479(13) .
C55 H55A 0.980 .
C55 H55B 0.980 .
C55 H55C 0.980 .
C56 H56A 0.980 .
C56 H56B 0.980 .
C56 H56C 0.980 .
C57 C58 1.380(10) .
C57 C62 1.355(10) .
C58 H58 0.950 .
C58 C59 1.397(11) .
C59 H59 0.950 .
C59 C60 1.365(11) .
C60 C61 1.365(11) .
C60 N7 1.446(11) .
C61 H61 0.950 .
C61 C62 1.404(11) .
C62 H62 0.950 .
N7 C63 1.466(11) .
N7 C64 1.459(12) .
C63 H63A 0.980 .
C63 H63B 0.980 .
C63 H63C 0.980 .
C64 H64A 0.980 .
C64 H64B 0.980 .
C64 H64C 0.980 .
C65 C66 1.376(11) .
C65 C70 1.382(11) .
C66 H66 0.950 .
C66 C67 1.365(11) .
C67 H67 0.950 .
C67 C68 1.339(11) .
C68 C69 1.373(11) .
C68 N8 1.447(12) .
C69 H69 0.950 .
C69 C70 1.418(11) .
C70 H70 0.950 .
N8 C71 1.477(12) .
N8 C72 1.444(12) .
C71 H71A 0.980 .
C71 H71B 0.980 .
C71 H71C 0.980 .
C72 H72A 0.980 .
C72 H72B 0.980 .
C72 H72C 0.980 .
Ag3 P5 2.398(3) .
Ag3 P6 2.398(3) 3_675
Ag3 O5 2.856(10) .
Ag3 O8 2.663(9) .
Ag4 P7 2.408(3) .
Ag4 P8 2.395(3) .
Ag4 O6 2.646(11) .
Ag4 O7 2.652(12) 2_765
P5 C73 1.761(12) .
P5 C81 1.811(13) .
P5 C89 1.852(12) .
P6 Ag3 2.398(3) 2_765
P6 C74 1.714(13) .
P6 C97 1.787(13) .
P6 C105 1.802(14) .
P6 X105 1.780(18) .
P7 C75 1.849(11) .
P7 C113 1.786(11) .
P7 C121 1.793(11) .
P8 C78 1.790(9) .
P8 C129 1.790(10) .
P8 C137 1.828(9) .
C73 H73A 0.990 .
C73 H73B 0.990 .
C73 C76 1.539(15) .
C74 H74A 0.990 .
C74 H74B 0.990 .
C74 C76 1.632(16) .
C75 H75A 0.990 .
C75 H75B 0.990 .
C75 C76 1.575(16) .
C76 C77 1.519(16) .
C77 H77A 0.980 .
C77 H77B 0.980 .
C77 H77C 0.980 .
C78 H78A 0.990 .
C78 H78B 0.990 .
C78 C79 1.584(10) .
C79 C78 1.584(10) 3_675
C79 C78 1.584(10) 2_765
C79 C80 1.58(2) .
C80 H80A 0.980 .
C80 H80B 0.980 .
C80 H80C 0.980 .
C81 C82 1.391(12) .
C81 C86 1.373(12) .
C82 H82 0.950 .
C82 C83 1.392(12) .
C83 H83 0.950 .
C83 C84 1.372(12) .
C84 C85 1.380(12) .
C84 N9 1.467(12) .
C85 H85 0.950 .
C85 C86 1.396(12) .
C86 H86 0.950 .
N9 C87 1.457(13) .
N9 C88 1.466(13) .
C87 H87A 0.980 .
C87 H87B 0.980 .
C87 H87C 0.980 .
C88 H88A 0.980 .
C88 H88B 0.980 .
C88 H88C 0.980 .
C89 C90 1.371(11) .
C89 C94 1.370(11) .
C90 H90 0.950 .
C90 C91 1.413(11) .
C91 H91 0.950 .
C91 C92 1.351(12) .
C92 C93 1.385(11) .
C92 N10 1.458(12) .
C93 H93 0.950 .
C93 C94 1.398(11) .
C94 H94 0.950 .
N10 C95 1.461(12) .
N10 C96 1.470(13) .
C95 H95A 0.980 .
C95 H95B 0.980 .
C95 H95C 0.980 .
C96 H96A 0.980 .
C96 H96B 0.980 .
C96 H96C 0.980 .
C97 C98 1.347(12) .
C97 C102 1.390(12) .
C98 H98 0.950 .
C98 C99 1.400(12) .
C99 H99 0.950 .
C99 C100 1.350(13) .
C100 C101 1.369(13) .
C100 N11 1.473(12) .
C101 H101 0.950 .
C101 C102 1.397(12) .
C102 H102 0.950 .
N11 C103 1.455(13) .
N11 C104 1.464(13) .
C103 H10B 0.980 .
C103 H10C 0.980 .
C103 H10D 0.980 .
C104 H10E 0.980 .
C104 H10F 0.980 .
C104 H10G 0.980 .
C105 C106 1.375(13) .
C105 C110 1.363(13) .
C106 H106 0.950 .
C106 C107 1.380(13) .
C107 H107 0.950 .
C107 C108 1.352(13) .
C108 C109 1.365(13) .
C108 N12 1.471(13) .
C109 H109 0.950 .
C109 C110 1.400(13) .
C110 H110 0.950 .
N12 C111 1.466(13) .
N12 C112 1.471(13) .
C111 H11B 0.980 .
C111 H11C 0.980 .
C111 H11D 0.980 .
C112 H11E 0.980 .
C112 H11F 0.980 .
C112 H11G 0.980 .
X105 X106 1.370(14) .
X105 X110 1.373(14) .
X106 H10H 0.950 .
X106 X107 1.392(14) .
X107 H10I 0.950 .
X107 X108 1.361(13) .
X108 X109 1.376(14) .
X108 N12X 1.464(14) .
X109 H10J 0.950 .
X109 X110 1.400(14) .
X110 H11H 0.950 .
N12X X111 1.470(14) .
N12X X112 1.478(14) .
X111 H11I 0.980 .
X111 H11J 0.980 .
X111 H11K 0.980 .
X112 H11L 0.980 .
X112 H11M 0.980 .
X112 H11N 0.980 .
C113 C114 1.388(10) .
C113 C118 1.355(11) .
C114 H114 0.950 .
C114 C115 1.399(10) .
C115 H115 0.950 .
C115 C116 1.376(11) .
C116 C117 1.365(11) .
C116 N13 1.451(11) .
C117 H117 0.950 .
C117 C118 1.395(12) .
C118 H118 0.950 .
N13 C119 1.450(12) .
N13 C120 1.449(12) .
C119 H11O 0.980 .
C119 H11P 0.980 .
C119 H11Q 0.980 .
C120 H12A 0.980 .
C120 H12B 0.980 .
C120 H12C 0.980 .
C121 C122 1.362(10) .
C121 C126 1.397(10) .
C122 H122 0.950 .
C122 C123 1.378(11) .
C123 H123 0.950 .
C123 C124 1.359(11) .
C124 C125 1.368(11) .
C124 N14 1.449(11) .
C125 H125 0.950 .
C125 C126 1.400(11) .
C126 H126 0.950 .
N14 C127 1.480(12) .
N14 C128 1.477(12) .
C127 H12D 0.980 .
C127 H12E 0.980 .
C127 H12F 0.980 .
C128 H12G 0.980 .
C128 H12H 0.980 .
C128 H12I 0.980 .
C129 C130 1.374(10) .
C129 C134 1.388(10) .
C130 H130 0.950 .
C130 C131 1.417(11) .
C131 H131 0.950 .
C131 C132 1.394(11) .
C132 C133 1.346(11) .
C132 N15 1.458(11) .
C133 H133 0.950 .
C133 C134 1.376(11) .
C134 H134 0.950 .
N15 C135 1.446(12) .
N15 C136 1.469(12) .
C135 H13B 0.980 .
C135 H13C 0.980 .
C135 H13D 0.980 .
C136 H13E 0.980 .
C136 H13F 0.980 .
C136 H13G 0.980 .
C137 C138 1.391(10) .
C137 C142 1.386(10) .
C138 H138 0.950 .
C138 C139 1.366(10) .
C139 H139 0.950 .
C139 C140 1.346(10) .
C140 C141 1.360(11) .
C140 N16 1.446(10) .
C141 H141 0.950 .
C141 C142 1.397(10) .
C142 H142 0.950 .
N16 C143 1.450(11) .
N16 C144 1.455(11) .
C143 H14B 0.980 .
C143 H14C 0.980 .
C143 H14D 0.980 .
C144 H14E 0.980 .
C144 H14F 0.980 .
C144 H14G 0.980 .
S1 O1 1.402(8) .
S1 O2 1.429(8) .
S1 O3 1.436(7) .
S1 C145 1.774(12) .
O3 Ag2 2.670(8) 2_665
C145 F1 1.292(10) .
C145 F2 1.294(11) .
C145 F3 1.304(11) .
S2 O4 1.413(10) .
S2 O4 1.412(10) 3_565
S2 O4 1.413(10) 2_665
S2 C146 1.84(2) .
C146 F4 1.274(10) .
C146 F4 1.274(10) 2_665
C146 F4 1.274(10) 3_565
S3 O5 1.360(9) .
S3 O6 1.443(9) .
S3 O7 1.408(9) .
S3 C147 1.834(14) .
O7 Ag4 2.652(11) 3_675
C147 F5 1.344(11) .
C147 F6 1.337(11) .
C147 F7 1.319(12) .
S4 O8 1.411(8) .
S4 O8 1.411(8) 3_675
S4 O8 1.411(8) 2_765
S4 C148 1.847(18) .
C148 F8 1.330(9) .
C148 F8 1.330(9) 2_765
C148 F8 1.330(9) 3_675
