#------------------------------------------------------------------------------
#$Date: 2016-03-26 03:58:05 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180204 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/98/7109826.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7109826
loop_
_publ_author_name
'Denis Prodius'
'Fliur Macaev'
'Yanhua Lan'
'Ghenadie Novitchi'
'Serghei Pogrebnoi'
'Eugenia Stingaci'
'Valeriu Mereacre'
'Christopher E. Anson'
'Annie K. Powell'
_publ_section_title
;
 Evidence of slow relaxation of magnetization in dysprosium-based ionic
 liquids
;
_journal_name_full               Chem.Commun.
_journal_page_first              9215
_journal_paper_doi               10.1039/c3cc45554h
_journal_volume                  49
_journal_year                    2013
_chemical_formula_moiety         'C18 H28 Dy N6 O8, 3(C2 F6 N O4 S2)'
_chemical_formula_sum            'C24 H28 Dy F18 N9 O20 S6'
_chemical_formula_weight         1459.41
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 100.593(9)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   19.517(7)
_cell_length_b                   27.899(9)
_cell_length_c                   9.294(3)
_cell_measurement_reflns_used    1750
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      29.87
_cell_measurement_theta_min      2.74
_cell_volume                     4974(3)
_computing_cell_refinement       'Apex2 (Bruker AXS Inc., 2005)'
_computing_data_collection       'Apex2 (Bruker AXS Inc., 2005)'
_computing_data_reduction        'Apex2 (Bruker AXS Inc., 2005)'
_computing_molecular_graphics    'Diamond 2.1 (Crystal Impact, 1998)'
_computing_publication_material  'SHELXTL 6.14 (BrukerAXS Inc., 2003)'
_computing_structure_refinement  'SHELXTL 6.14 (BrukerAXS Inc., 2003)'
_computing_structure_solution    'SHELXTL 6.14 (BrukerAXS Inc., 2003)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 8.333
_diffrn_measured_fraction_theta_full 0.585
_diffrn_measured_fraction_theta_max 0.566
_diffrn_measurement_device_type  'Bruker SMART Apex'
_diffrn_measurement_method       'CCD area detector'
_diffrn_radiation_monochromator  silicon
_diffrn_radiation_source         synchrotron
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     0.80000
_diffrn_reflns_av_R_equivalents  0.0302
_diffrn_reflns_av_unetI/netI     0.0520
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       1
_diffrn_reflns_limit_k_min       -34
_diffrn_reflns_limit_l_max       8
_diffrn_reflns_limit_l_min       -8
_diffrn_reflns_number            6594
_diffrn_reflns_theta_full        29.00
_diffrn_reflns_theta_max         30.05
_diffrn_reflns_theta_min         2.03
_exptl_absorpt_coefficient_mu    2.615
_exptl_absorpt_correction_T_max  0.9496
_exptl_absorpt_correction_T_min  0.4365
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS 2.10 (Bruker AXS Inc., 2005)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.949
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             2876
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.02
_refine_diff_density_max         2.293
_refine_diff_density_min         -2.876
_refine_diff_density_rms         0.184
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     687
_refine_ls_number_reflns         5790
_refine_ls_number_restraints     162
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.1180
_refine_ls_R_factor_gt           0.0849
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1818P)²+33.0857P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2238
_refine_ls_wR_factor_ref         0.2680
_reflns_number_gt                4168
_reflns_number_total             5790
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3cc45554h.txt
_cod_data_source_block           dytfsa
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7109826
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.32816(4) 0.256144(19) 0.48037(11) 0.0471(4) Uani 1 1 d . . .
O1 O 0.2157(7) 0.2678(3) 0.5312(18) 0.058(4) Uani 1 1 d . . .
O2 O 0.2591(5) 0.2709(3) 0.7654(15) 0.052(3) Uani 1 1 d . . .
C1 C 0.2090(7) 0.2665(4) 0.661(3) 0.045(6) Uani 1 1 d . . .
C2 C 0.1384(9) 0.2627(5) 0.704(2) 0.052(5) Uani 1 1 d . . .
H2A H 0.1413 0.2387 0.7831 0.063 Uiso 1 1 calc R . .
H2B H 0.1272 0.2939 0.7440 0.063 Uiso 1 1 calc R . .
N1 N 0.0802(7) 0.2492(3) 0.5856(18) 0.043(4) Uani 1 1 d . . .
C3 C 0.0327(8) 0.2786(5) 0.515(2) 0.051(5) Uani 1 1 d . . .
H3A H 0.0287 0.3117 0.5357 0.061 Uiso 1 1 calc R . .
N2 N -0.0085(7) 0.2548(4) 0.4097(19) 0.051(4) Uani 1 1 d . . .
C4 C 0.0151(9) 0.2072(5) 0.413(2) 0.061(6) Uani 1 1 d . . .
H4A H -0.0055 0.1817 0.3523 0.073 Uiso 1 1 calc R . .
C5 C 0.0731(9) 0.2044(5) 0.520(2) 0.056(5) Uani 1 1 d . . .
H5A H 0.1025 0.1773 0.5444 0.067 Uiso 1 1 calc R . .
C6 C -0.0666(9) 0.2756(6) 0.307(2) 0.068(6) Uani 1 1 d . . .
H6A H -0.0713 0.3095 0.3308 0.102 Uiso 1 1 calc R . .
H6B H -0.1097 0.2586 0.3152 0.102 Uiso 1 1 calc R . .
H6C H -0.0577 0.2726 0.2073 0.102 Uiso 1 1 calc R . .
O3 O 0.4418(5) 0.2745(3) 0.4369(17) 0.053(4) Uani 1 1 d . . .
O4 O 0.3921(6) 0.2649(3) 0.2111(15) 0.048(3) Uani 1 1 d . . .
C7 C 0.4470(8) 0.2686(4) 0.308(2) 0.039(5) Uani 1 1 d . . .
C8 C 0.5164(8) 0.2658(4) 0.2596(19) 0.042(5) Uani 1 1 d . . .
H8A H 0.5206 0.2342 0.2133 0.051 Uiso 1 1 calc R . .
H8B H 0.5185 0.2909 0.1851 0.051 Uiso 1 1 calc R . .
N3 N 0.5745(6) 0.2721(3) 0.3801(16) 0.043(4) Uani 1 1 d . . .
C9 C 0.6164(8) 0.2368(4) 0.449(2) 0.051(5) Uani 1 1 d . . .
H9A H 0.6148 0.2040 0.4221 0.061 Uiso 1 1 calc R . .
N4 N 0.6590(7) 0.2558(4) 0.559(2) 0.053(5) Uani 1 1 d . . .
C10 C 0.6449(8) 0.3048(5) 0.564(2) 0.060(6) Uani 1 1 d . . .
H10A H 0.6681 0.3271 0.6338 0.072 Uiso 1 1 calc R . .
C11 C 0.5934(8) 0.3145(4) 0.455(2) 0.046(5) Uani 1 1 d . . .
H11A H 0.5729 0.3450 0.4318 0.055 Uiso 1 1 calc R . .
C12 C 0.7150(9) 0.2297(5) 0.659(3) 0.065(6) Uani 1 1 d . . .
H12A H 0.7138 0.1957 0.6328 0.098 Uiso 1 1 calc R . .
H12B H 0.7076 0.2331 0.7604 0.098 Uiso 1 1 calc R . .
H12C H 0.7605 0.2433 0.6512 0.098 Uiso 1 1 calc R . .
O5 O 0.3751(5) 0.1780(3) 0.4205(14) 0.054(3) Uani 1 1 d . . .
O6 O 0.2920(5) 0.1730(3) 0.5536(14) 0.052(3) Uani 1 1 d . . .
C13 C 0.3350(7) 0.1541(5) 0.486(2) 0.057(6) Uani 1 1 d . . .
C14 C 0.3389(8) 0.0994(4) 0.472(2) 0.046(5) Uani 1 1 d . . .
H14A H 0.3103 0.0893 0.3778 0.055 Uiso 1 1 calc R . .
H14B H 0.3878 0.0900 0.4715 0.055 Uiso 1 1 calc R . .
N5 N 0.3142(8) 0.0739(3) 0.593(2) 0.059(5) Uani 1 1 d . . .
C15 C 0.3470(9) 0.0712(4) 0.730(3) 0.062(6) Uani 1 1 d . . .
H15A H 0.3898 0.0863 0.7705 0.074 Uiso 1 1 calc R . .
N6 N 0.3096(8) 0.0439(4) 0.800(2) 0.062(5) Uani 1 1 d . . .
C16 C 0.2519(11) 0.0289(6) 0.705(3) 0.083(8) Uani 1 1 d . . .
H16A H 0.2164 0.0088 0.7288 0.100 Uiso 1 1 calc R . .
C17 C 0.2531(10) 0.0468(6) 0.571(4) 0.103(11) Uani 1 1 d . . .
H17A H 0.2202 0.0422 0.4831 0.124 Uiso 1 1 calc R . .
C18 C 0.3255(11) 0.0346(6) 0.958(3) 0.090(9) Uani 1 1 d . . .
H18A H 0.3709 0.0486 0.9997 0.134 Uiso 1 1 calc R . .
H18B H 0.3268 0.0000 0.9756 0.134 Uiso 1 1 calc R . .
H18C H 0.2894 0.0491 1.0049 0.134 Uiso 1 1 calc R . .
O7 O 0.3516(6) 0.3285(3) 0.6239(16) 0.069(4) Uani 1 1 d . . .
O8 O 0.2942(6) 0.3269(3) 0.3373(18) 0.083(5) Uani 1 1 d . . .
S1 S 0.5493(2) 0.39827(11) 1.0933(6) 0.0543(14) Uani 1 1 d D . .
S2 S 0.5121(2) 0.39736(11) 0.7866(6) 0.0562(14) Uani 1 1 d D . .
N11 N 0.5104(7) 0.4184(4) 0.9469(19) 0.060(5) Uani 1 1 d . . .
O12 O 0.5019(8) 0.3970(4) 1.1940(19) 0.078(5) Uani 1 1 d . . .
O13 O 0.5925(6) 0.3574(3) 1.0939(16) 0.069(4) Uani 1 1 d . . .
O14 O 0.4465(6) 0.4070(3) 0.6921(17) 0.071(4) Uani 1 1 d . . .
O15 O 0.5412(7) 0.3506(3) 0.7802(17) 0.076(4) Uani 1 1 d . . .
C19 C 0.6079(10) 0.4474(6) 1.158(4) 0.081(8) Uani 1 1 d D . .
F1 F 0.6411(8) 0.4372(4) 1.297(2) 0.107(5) Uani 1 1 d . . .
F2 F 0.5765(8) 0.4880(4) 1.165(2) 0.142(7) Uani 1 1 d . . .
F3 F 0.6547(9) 0.4533(5) 1.081(2) 0.143(7) Uani 1 1 d . . .
C20 C 0.5704(12) 0.4368(6) 0.712(3) 0.068(7) Uani 1 1 d D . .
F4 F 0.6358(9) 0.4313(5) 0.781(2) 0.130(7) Uani 1 1 d . . .
F5 F 0.5553(7) 0.4822(3) 0.7207(17) 0.105(5) Uani 1 1 d . . .
F6 F 0.5711(9) 0.4269(4) 0.576(2) 0.125(7) Uani 1 1 d . . .
S3 S 0.1429(3) 0.41050(13) 0.6924(7) 0.0752(18) Uani 1 1 d . A .
S4 S 0.1229(3) 0.38198(12) 0.3981(7) 0.0689(17) Uani 1 1 d . . .
N16 N 0.1045(8) 0.3821(4) 0.560(2) 0.067(5) Uani 1 1 d . . .
O17 O 0.1980(8) 0.4415(5) 0.675(2) 0.107(6) Uani 1 1 d . . .
O18 O 0.1572(10) 0.3798(5) 0.820(2) 0.124(7) Uani 1 1 d . . .
O19 O 0.1948(7) 0.3932(4) 0.391(2) 0.088(6) Uani 1 1 d . . .
O20 O 0.0927(7) 0.3400(4) 0.3266(18) 0.078(5) Uani 1 1 d . . .
C21 C 0.0716(11) 0.4500(6) 0.7332(16) 0.110(11) Uani 1 1 d D . .
F7A F 0.0913(14) 0.4721(9) 0.864(2) 0.085(8) Uiso 0.50 1 d PD A 1
F8A F 0.0675(13) 0.4844(8) 0.625(2) 0.093(7) Uiso 0.50 1 d PD A 1
F9A F 0.0078(13) 0.4310(11) 0.726(3) 0.145(13) Uiso 0.50 1 d PD A 1
F7B F 0.1025(14) 0.4822(8) 0.830(2) 0.090(9) Uiso 0.50 1 d PD A 2
F8B F 0.0332(11) 0.4703(7) 0.616(2) 0.078(6) Uiso 0.50 1 d PD A 2
F9B F 0.0318(13) 0.4192(8) 0.797(3) 0.098(8) Uiso 0.50 1 d PD A 2
C22 C 0.0705(13) 0.4304(6) 0.293(4) 0.091(10) Uani 1 1 d . . .
F10 F 0.0956(7) 0.4726(3) 0.3476(18) 0.107(5) Uani 1 1 d . . .
F11 F 0.0057(7) 0.4270(4) 0.3070(19) 0.108(5) Uani 1 1 d . . .
F12 F 0.0762(9) 0.4268(4) 0.156(2) 0.121(6) Uani 1 1 d . . .
S5 S 0.1529(3) 0.65084(13) 0.3939(7) 0.0728(17) Uani 1 1 d D . .
S6 S 0.1849(3) 0.65615(14) 0.1093(7) 0.0749(17) Uani 1 1 d D . .
N21A N 0.1373(11) 0.6423(9) 0.2217(14) 0.079(9) Uiso 0.50 1 d PD B 1
O22A O 0.1972(12) 0.6910(7) 0.427(3) 0.071(7) Uiso 0.50 1 d PD B 1
O23A O 0.0843(9) 0.6523(8) 0.438(3) 0.071(7) Uiso 0.50 1 d PD B 1
O24A O 0.1475(13) 0.6915(7) 0.008(3) 0.070(7) Uiso 0.50 1 d PD B 1
O25A O 0.2558(8) 0.6593(10) 0.172(4) 0.092(9) Uiso 0.50 1 d PD B 1
N21B N 0.1965(12) 0.6388(10) 0.2742(16) 0.099(11) Uiso 0.50 1 d PD B 2
O22B O 0.1970(12) 0.6793(8) 0.508(2) 0.071(7) Uiso 0.50 1 d PD B 2
O23B O 0.0827(9) 0.6624(11) 0.334(4) 0.106(10) Uiso 0.50 1 d PD B 2
O24B O 0.1427(12) 0.6972(7) 0.088(3) 0.076(8) Uiso 0.50 1 d PD B 2
O25B O 0.2549(10) 0.6603(9) 0.074(3) 0.082(8) Uiso 0.50 1 d PD B 2
C23A C 0.1916(11) 0.5956(7) 0.466(3) 0.115(18) Uiso 0.50 1 d PD B 1
F13A F 0.1564(14) 0.5562(8) 0.427(4) 0.099(9) Uiso 0.50 1 d PD B 1
F14A F 0.2516(10) 0.5918(7) 0.424(3) 0.084(6) Uiso 0.50 1 d PD B 1
F15A F 0.2013(15) 0.5995(10) 0.607(3) 0.122(10) Uiso 0.50 1 d PD B 1
C23B C 0.1574(13) 0.5919(11) 0.480(3) 0.090(13) Uiso 0.50 1 d PD B 2
F13B F 0.1278(14) 0.5618(8) 0.379(3) 0.094(8) Uiso 0.50 1 d PD B 2
F14B F 0.2194(13) 0.5762(12) 0.535(4) 0.142(12) Uiso 0.50 1 d PD B 2
F15B F 0.1205(15) 0.5927(11) 0.585(3) 0.135(11) Uiso 0.50 1 d PD B 2
C24A C 0.1738(14) 0.6045(8) -0.010(3) 0.110(19) Uiso 0.50 1 d PD B 1
F16A F 0.2046(14) 0.5688(8) 0.065(3) 0.088(8) Uiso 0.50 1 d PD B 1
F17A F 0.1094(13) 0.5927(11) -0.057(4) 0.131(11) Uiso 0.50 1 d PD B 1
F18A F 0.2027(17) 0.6093(11) -0.125(4) 0.144(12) Uiso 0.50 1 d PD B 1
C24B C 0.1483(13) 0.6037(7) 0.015(3) 0.061(8) Uiso 0.50 1 d PD B 2
F16B F 0.1764(15) 0.5621(9) 0.037(4) 0.106(11) Uiso 0.50 1 d PD B 2
F17B F 0.0865(15) 0.6006(10) 0.047(4) 0.138(11) Uiso 0.50 1 d PD B 2
F18B F 0.1416(17) 0.6142(10) -0.122(3) 0.126(10) Uiso 0.50 1 d PD B 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0043 0.0021 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0082 0.0043 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0142 0.0079 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0225 0.0133 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1500 0.1576 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1899 5.4020 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 Dy1 O4 146.2(4) 4_565 4_566
O2 Dy1 O1 78.6(5) 4_565 .
O4 Dy1 O1 102.1(5) 4_566 .
O2 Dy1 O3 109.6(5) 4_565 .
O4 Dy1 O3 81.6(5) 4_566 .
O1 Dy1 O3 159.6(3) . .
O2 Dy1 O8 74.6(4) 4_565 .
O4 Dy1 O8 139.1(4) 4_566 .
O1 Dy1 O8 79.9(4) . .
O3 Dy1 O8 84.3(4) . .
O2 Dy1 O7 140.2(4) 4_565 .
O4 Dy1 O7 71.9(4) 4_566 .
O1 Dy1 O7 82.1(4) . .
O3 Dy1 O7 80.0(4) . .
O8 Dy1 O7 67.9(5) . .
O2 Dy1 O5 72.5(4) 4_565 .
O4 Dy1 O5 80.1(4) 4_566 .
O1 Dy1 O5 124.5(3) . .
O3 Dy1 O5 75.8(3) . .
O8 Dy1 O5 132.6(5) . .
O7 Dy1 O5 145.3(4) . .
O2 Dy1 O6 77.8(4) 4_565 .
O4 Dy1 O6 69.9(4) 4_566 .
O1 Dy1 O6 76.0(3) . .
O3 Dy1 O6 123.5(3) . .
O8 Dy1 O6 146.3(4) . .
O7 Dy1 O6 130.2(4) . .
O5 Dy1 O6 52.4(3) . .
C1 O1 Dy1 117.5(11) . .
C1 O2 Dy1 151.9(9) . 4_566
O1 C1 O2 122.9(15) . .
O1 C1 C2 121.6(18) . .
O2 C1 C2 115(2) . .
N1 C2 C1 116.1(18) . .
N1 C2 H2A 108.3 . .
C1 C2 H2A 108.3 . .
N1 C2 H2B 108.3 . .
C1 C2 H2B 108.3 . .
H2A C2 H2B 107.4 . .
C3 N1 C5 109.8(16) . .
C3 N1 C2 125.8(12) . .
C5 N1 C2 123.9(13) . .
N1 C3 N2 109.3(12) . .
N1 C3 H3A 125.4 . .
N2 C3 H3A 125.4 . .
C3 N2 C4 107.9(14) . .
C3 N2 C6 125.0(12) . .
C4 N2 C6 127.1(15) . .
C5 C4 N2 107.2(14) . .
C5 C4 H4A 126.4 . .
N2 C4 H4A 126.4 . .
C4 C5 N1 105.7(14) . .
C4 C5 H5A 127.2 . .
N1 C5 H5A 127.2 . .
N2 C6 H6A 109.5 . .
N2 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
N2 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
C7 O3 Dy1 112.6(10) . .
C7 O4 Dy1 154.8(11) . 4_565
O3 C7 O4 119.4(14) . .
O3 C7 C8 122.7(16) . .
O4 C7 C8 118.0(18) . .
N3 C8 C7 112.3(16) . .
N3 C8 H8A 109.1 . .
C7 C8 H8A 109.1 . .
N3 C8 H8B 109.1 . .
C7 C8 H8B 109.1 . .
H8A C8 H8B 107.9 . .
C9 N3 C11 107.3(15) . .
C9 N3 C8 126.4(11) . .
C11 N3 C8 126.1(12) . .
N4 C9 N3 108.4(11) . .
N4 C9 H9A 125.8 . .
N3 C9 H9A 125.8 . .
C9 N4 C10 108.9(14) . .
C9 N4 C12 125.5(12) . .
C10 N4 C12 125.6(15) . .
C11 C10 N4 107.5(14) . .
C11 C10 H10A 126.3 . .
N4 C10 H10A 126.3 . .
C10 C11 N3 107.8(13) . .
C10 C11 H11A 126.1 . .
N3 C11 H11A 126.1 . .
N4 C12 H12A 109.5 . .
N4 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
N4 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C13 O5 Dy1 93.9(9) . .
C13 O6 Dy1 90.3(8) . .
O6 C13 O5 123.4(12) . .
O6 C13 C14 120.5(13) . .
O5 C13 C14 116.1(14) . .
N5 C14 C13 112.9(13) . .
N5 C14 H14A 109.0 . .
C13 C14 H14A 109.0 . .
N5 C14 H14B 109.0 . .
C13 C14 H14B 109.0 . .
H14A C14 H14B 107.8 . .
C15 N5 C17 111.1(19) . .
C15 N5 C14 126.2(15) . .
C17 N5 C14 123(2) . .
N6 C15 N5 107.4(17) . .
N6 C15 H15A 126.3 . .
N5 C15 H15A 126.3 . .
C15 N6 C16 109(2) . .
C15 N6 C18 124.5(18) . .
C16 N6 C18 126.5(18) . .
C17 C16 N6 109.6(17) . .
C17 C16 H16A 125.2 . .
N6 C16 H16A 125.2 . .
C16 C17 N5 103(2) . .
C16 C17 H17A 128.5 . .
N5 C17 H17A 128.5 . .
N6 C18 H18A 109.5 . .
N6 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
N6 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
O13 S1 O12 115.6(8) . .
O13 S1 N11 119.6(8) . .
O12 S1 N11 108.4(8) . .
O13 S1 C19 105.5(8) . .
O12 S1 C19 104.1(11) . .
N11 S1 C19 101.3(11) . .
O15 S2 O14 117.5(8) . .
O15 S2 N11 116.6(8) . .
O14 S2 N11 109.3(8) . .
O15 S2 C20 104.8(9) . .
O14 S2 C20 101.8(10) . .
N11 S2 C20 104.7(9) . .
S1 N11 S2 126.6(8) . .
F3 C19 F2 108(2) . .
F3 C19 F1 107.4(19) . .
F2 C19 F1 107(2) . .
F3 C19 S1 112.4(18) . .
F2 C19 S1 113.6(15) . .
F1 C19 S1 108.5(15) . .
F6 C20 F5 108.1(18) . .
F6 C20 F4 105.4(19) . .
F5 C20 F4 106.8(17) . .
F6 C20 S2 111.4(14) . .
F5 C20 S2 113.6(14) . .
F4 C20 S2 111.2(16) . .
O17 S3 O18 114.8(12) . .
O17 S3 N16 119.5(11) . .
O18 S3 N16 110.0(9) . .
O17 S3 C21 105.9(8) . .
O18 S3 C21 102.8(10) . .
N16 S3 C21 101.2(7) . .
O20 S4 O19 118.6(8) . .
O20 S4 N16 107.1(8) . .
O19 S4 N16 115.1(10) . .
O20 S4 C22 102.3(11) . .
O19 S4 C22 105.4(10) . .
N16 S4 C22 107.0(12) . .
S3 N16 S4 126.1(10) . .
F8B C21 F7B 112.4(15) . .
F9A C21 F7A 109.4(16) . .
F8B C21 F9B 110.0(15) . .
F7B C21 F9B 110.8(16) . .
F9A C21 F8A 107.9(16) . .
F7A C21 F8A 107.8(14) . .
F8B C21 S3 114.6(16) . .
F7B C21 S3 105.9(18) . .
F9A C21 S3 118.4(19) . .
F7A C21 S3 110.6(17) . .
F9B C21 S3 102.9(16) . .
F8A C21 S3 102.0(16) . .
F11 C22 F10 108.9(18) . .
F11 C22 F12 111(3) . .
F10 C22 F12 110(2) . .
F11 C22 S4 110.3(19) . .
F10 C22 S4 108.2(19) . .
F12 C22 S4 108.6(14) . .
O23B S5 O22B 123.8(16) . .
O22A S5 O23A 117.9(14) . .
O23B S5 N21B 112.5(13) . .
O22B S5 N21B 108.0(12) . .
O22A S5 N21A 109.7(12) . .
O23A S5 N21A 105.7(11) . .
O22A S5 C23A 113.6(13) . .
O23A S5 C23A 105.1(12) . .
N21A S5 C23A 103.6(13) . .
O23B S5 C23B 110.1(16) . .
O22B S5 C23B 101.2(14) . .
N21B S5 C23B 97.5(13) . .
O25A S6 O24A 124.4(16) . .
O24B S6 O25B 116.7(15) . .
O25A S6 N21A 113.4(13) . .
O24A S6 N21A 107.9(11) . .
O24B S6 N21B 111.5(13) . .
O25B S6 N21B 105.4(12) . .
O24B S6 C24B 115.2(15) . .
O25B S6 C24B 105.1(14) . .
N21B S6 C24B 101.4(14) . .
O25A S6 C24A 107.6(15) . .
O24A S6 C24A 98.9(14) . .
N21A S6 C24A 101.2(13) . .
S6 N21A S5 127.3(14) . .
S5 N21B S6 128.7(15) . .
F15A C23A F14A 109.6(16) . .
F15A C23A F13A 108.8(16) . .
F14A C23A F13A 107.7(15) . .
F15A C23A S5 106(2) . .
F14A C23A S5 107.3(17) . .
F13A C23A S5 117(2) . .
F14B C23B F13B 108.8(19) . .
F14B C23B F15B 107.9(19) . .
F13B C23B F15B 108.2(19) . .
F14B C23B S5 116(2) . .
F13B C23B S5 107(2) . .
F15B C23B S5 109(2) . .
F17A C24A F16A 108.1(16) . .
F17A C24A F18A 107.1(16) . .
F16A C24A F18A 107.1(16) . .
F17A C24A S6 114(2) . .
F16A C24A S6 106.7(19) . .
F18A C24A S6 114(2) . .
F16B C24B F18B 108.8(16) . .
F16B C24B F17B 106.9(15) . .
F18B C24B F17B 108.1(17) . .
F16B C24B S6 123(2) . .
F18B C24B S6 105(2) . .
F17B C24B S6 104(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O2 2.321(12) 4_565
Dy1 O4 2.348(12) 4_566
Dy1 O1 2.351(13) .
Dy1 O3 2.381(10) .
Dy1 O8 2.405(11) .
Dy1 O7 2.416(10) .
Dy1 O5 2.469(9) .
Dy1 O6 2.552(9) .
O1 C1 1.24(2) .
O2 C1 1.25(2) .
O2 Dy1 2.321(12) 4_566
C1 C2 1.50(2) .
C2 N1 1.48(2) .
C2 H2A 0.9900 .
C2 H2B 0.9900 .
N1 C3 1.32(2) .
N1 C5 1.386(18) .
C3 N2 1.32(2) .
C3 H3A 0.9500 .
N2 C4 1.404(17) .
N2 C6 1.46(2) .
C4 C5 1.37(3) .
C4 H4A 0.9500 .
C5 H5A 0.9500 .
C6 H6A 0.9800 .
C6 H6B 0.9800 .
C6 H6C 0.9800 .
O3 C7 1.23(2) .
O4 C7 1.27(2) .
O4 Dy1 2.348(12) 4_565
C7 C8 1.51(2) .
C8 N3 1.45(2) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
N3 C9 1.36(2) .
N3 C11 1.388(17) .
C9 N4 1.30(2) .
C9 H9A 0.9500 .
N4 C10 1.397(16) .
N4 C12 1.49(2) .
C10 C11 1.32(2) .
C10 H10A 0.9500 .
C11 H11A 0.9500 .
C12 H12A 0.9800 .
C12 H12B 0.9800 .
C12 H12C 0.9800 .
O5 C13 1.264(18) .
O6 C13 1.255(18) .
C13 C14 1.534(17) .
C14 N5 1.48(2) .
C14 H14A 0.9900 .
C14 H14B 0.9900 .
N5 C15 1.32(2) .
N5 C17 1.39(2) .
C15 N6 1.31(2) .
C15 H15A 0.9500 .
N6 C16 1.37(3) .
N6 C18 1.47(3) .
C16 C17 1.34(4) .
C16 H16A 0.9500 .
C17 H17A 0.9500 .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
S1 O13 1.417(10) .
S1 O12 1.431(17) .
S1 N11 1.537(16) .
S1 C19 1.817(16) .
S2 O15 1.427(9) .
S2 O14 1.438(13) .
S2 N11 1.607(17) .
S2 C20 1.810(16) .
C19 F3 1.27(3) .
C19 F2 1.29(2) .
C19 F1 1.36(3) .
C20 F6 1.29(3) .
C20 F5 1.307(19) .
C20 F4 1.33(3) .
S3 O17 1.414(14) .
S3 O18 1.45(2) .
S3 N16 1.537(17) .
S3 C21 1.87(2) .
S4 O20 1.420(13) .
S4 O19 1.450(13) .
S4 N16 1.611(19) .
S4 C22 1.86(3) .
C21 F8B 1.328(16) .
C21 F7B 1.336(16) .
C21 F9A 1.344(17) .
C21 F7A 1.355(16) .
C21 F9B 1.363(16) .
C21 F8A 1.381(16) .
C22 F11 1.30(3) .
C22 F10 1.34(2) .
C22 F12 1.30(3) .
S5 O22A 1.413(14) .
S5 O23B 1.420(16) .
S5 O22B 1.471(14) .
S5 O23A 1.472(14) .
S5 N21B 1.558(13) .
S5 N21A 1.591(14) .
S5 C23A 1.792(19) .
S5 C23B 1.82(3) .
S6 O24B 1.403(14) .
S6 O25A 1.402(15) .
S6 O24A 1.462(14) .
S6 O25B 1.467(15) .
S6 N21A 1.569(13) .
S6 N21B 1.583(14) .
S6 C24B 1.785(18) .
S6 C24A 1.808(19) .
C23A F15A 1.298(18) .
C23A F14A 1.305(18) .
C23A F13A 1.310(18) .
C23B F14B 1.302(19) .
C23B F13B 1.313(19) .
C23B F15B 1.313(19) .
C24A F17A 1.295(18) .
C24A F16A 1.301(18) .
C24A F18A 1.299(18) .
C24B F16B 1.284(17) .
C24B F18B 1.291(18) .
C24B F17B 1.298(18) .
