#------------------------------------------------------------------------------
#$Date: 2016-03-26 13:35:34 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180228 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/14/7111436.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_7111436
loop_
_publ_author_name
'Youm, Kyoung-Tae'
'Huh, Seong'
'Park, Young Jun'
'Park, Sangwoo'
'Choi, Moon-Gun'
'Jun, Moo-Jin'
_publ_section_title
;
 Non-interpenetrating honeycomb-like 2D [6,3] network built by a novel
 trigonal metalloligand
;
_journal_issue                   21
_journal_name_full               'Chemical Communications'
_journal_page_first              2384
_journal_page_last               2385
_journal_paper_doi               10.1039/b409596k
_journal_year                    2004
_chemical_formula_sum            'C60 H64 Ag B N9 O12 P Rh3'
_chemical_formula_weight         1561.58
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 107.750(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   18.4633(15)
_cell_length_b                   36.227(3)
_cell_length_c                   21.1806(18)
_cell_measurement_temperature    233(2)
_cell_volume                     13492.7(19)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      233(2)
_diffrn_measured_fraction_theta_full 0.983
_diffrn_measured_fraction_theta_max 0.983
_diffrn_measurement_device_type  'Bruker SMART Area Detector'
_diffrn_measurement_method       'ω-rotation with narrow frames (0.3 °)'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1870
_diffrn_reflns_av_sigmaI/netI    0.3576
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       47
_diffrn_reflns_limit_k_min       -47
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            122313
_diffrn_reflns_theta_full        28.12
_diffrn_reflns_theta_max         28.12
_diffrn_reflns_theta_min         1.12
_diffrn_standards_decay_%        none
_exptl_absorpt_coefficient_mu    0.547
_exptl_absorpt_correction_T_max  0.9225
_exptl_absorpt_correction_T_min  0.8317
_exptl_absorpt_correction_type   ' Empirical, pseudo-azimuthal scan (SADABS)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    0.769
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       flat
_exptl_crystal_F_000             3140
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.467
_refine_diff_density_min         -2.228
_refine_diff_density_rms         0.184
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.778
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     796
_refine_ls_number_reflns         32406
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      0.794
_refine_ls_R_factor_all          0.2364
_refine_ls_R_factor_gt           0.0981
_refine_ls_shift/su_max          2.321
_refine_ls_shift/su_mean         0.048
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1132P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2281
_refine_ls_wR_factor_ref         0.2592
_reflns_number_gt                8892
_reflns_number_total             32406
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b409596ksup1.cif
_cod_data_source_block           ag-rh
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_refine_ls_weighting_scheme' value 'Calc' changed to
'calc' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        13492.5(19)
_cod_original_sg_symbol_H-M      'P 2(1)/n '
_cod_database_code               7111436
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.88141(3) 0.013673(18) 0.63735(3) 0.0391(2) Uani 1 1 d .
B1 B 0.6973(6) 0.0097(3) 0.5476(4) 0.036(2) Uani 1 1 d .
H1 H 0.6433 0.0080 0.5204 0.043 Uiso 1 1 calc R
N1 N 0.8090(4) 0.05340(19) 0.5561(3) 0.047(2) Uani 1 1 d .
N2 N 0.7330(4) 0.04757(19) 0.5289(3) 0.0415(18) Uani 1 1 d .
N3 N 0.7465(6) 0.1901(2) 0.3519(5) 0.084(3) Uani 1 1 d .
C1 C 0.8251(5) 0.0834(3) 0.5280(4) 0.053(3) Uani 1 1 d .
C2 C 0.7637(6) 0.0974(2) 0.4846(5) 0.050(3) Uani 1 1 d .
C3 C 0.7015(6) 0.0737(3) 0.4834(4) 0.053(3) Uani 1 1 d .
C4 C 0.9044(7) 0.0974(3) 0.5434(7) 0.113(5) Uani 1 1 d .
H4A H 0.9352 0.0872 0.5852 0.169 Uiso 1 1 calc R
H4B H 0.9043 0.1242 0.5465 0.169 Uiso 1 1 calc R
H4C H 0.9253 0.0902 0.5084 0.169 Uiso 1 1 calc R
C5 C 0.6185(5) 0.0744(3) 0.4488(5) 0.069(3) Uani 1 1 d .
H5A H 0.6054 0.0543 0.4171 0.104 Uiso 1 1 calc R
H5B H 0.6049 0.0977 0.4257 0.104 Uiso 1 1 calc R
H5C H 0.5910 0.0716 0.4809 0.104 Uiso 1 1 calc R
C6 C 0.7544(6) 0.1294(3) 0.4408(5) 0.055(3) Uani 1 1 d .
C7 C 0.7118(6) 0.1289(3) 0.3731(6) 0.069(3) Uani 1 1 d .
H7 H 0.6866 0.1070 0.3552 0.083 Uiso 1 1 calc R
C8 C 0.7053(7) 0.1590(4) 0.3320(6) 0.089(4) Uani 1 1 d .
H8 H 0.6713 0.1579 0.2888 0.107 Uiso 1 1 calc R
C9 C 0.7897(9) 0.1926(3) 0.4160(7) 0.116(5) Uani 1 1 d .
H9 H 0.8162 0.2147 0.4312 0.139 Uiso 1 1 calc R
C10 C 0.7961(6) 0.1616(3) 0.4631(5) 0.075(3) Uani 1 1 d .
H10 H 0.8277 0.1635 0.5071 0.090 Uiso 1 1 calc R
N4 N 0.7716(4) 0.01256(19) 0.6689(4) 0.048(2) Uani 1 1 d .
N5 N 0.7014(4) 0.01080(17) 0.6203(3) 0.0348(16) Uani 1 1 d .
N6 N 0.5787(5) 0.0086(3) 0.8731(4) 0.065(2) Uani 1 1 d .
C11 C 0.7594(6) 0.0127(3) 0.7292(4) 0.054(3) Uani 1 1 d .
C12 C 0.6826(5) 0.0111(2) 0.7180(5) 0.045(2) Uani 1 1 d .
C13 C 0.6473(5) 0.0097(2) 0.6515(4) 0.040(2) Uani 1 1 d .
C14 C 0.8262(5) 0.0139(3) 0.7928(4) 0.074(3) Uani 1 1 d .
H14A H 0.8365 -0.0108 0.8111 0.111 Uiso 1 1 calc R
H14B H 0.8138 0.0299 0.8247 0.111 Uiso 1 1 calc R
H14C H 0.8708 0.0233 0.7831 0.111 Uiso 1 1 calc R
C15 C 0.5665(5) 0.0068(3) 0.6130(5) 0.073(3) Uani 1 1 d .
H15A H 0.5564 -0.0175 0.5932 0.109 Uiso 1 1 calc R
H15B H 0.5542 0.0254 0.5782 0.109 Uiso 1 1 calc R
H15C H 0.5355 0.0108 0.6420 0.109 Uiso 1 1 calc R
C16 C 0.6448(5) 0.0083(3) 0.7714(4) 0.046(2) Uani 1 1 d .
C17 C 0.6713(6) -0.0152(3) 0.8222(5) 0.067(3) Uani 1 1 d .
H17 H 0.7122 -0.0311 0.8238 0.081 Uiso 1 1 calc R
C18 C 0.6371(6) -0.0159(3) 0.8728(5) 0.079(4) Uani 1 1 d .
H18 H 0.6537 -0.0332 0.9073 0.095 Uiso 1 1 calc R
C19 C 0.5580(5) 0.0322(3) 0.8270(6) 0.071(3) Uani 1 1 d .
H19 H 0.5213 0.0499 0.8287 0.085 Uiso 1 1 calc R
C20 C 0.5884(5) 0.0332(3) 0.7723(4) 0.060(3) Uani 1 1 d .
H20 H 0.5704 0.0503 0.7378 0.072 Uiso 1 1 calc R
N7 N 0.8139(4) -0.0308(2) 0.5647(3) 0.0433(19) Uani 1 1 d .
N8 N 0.7402(4) -0.02275(16) 0.5317(3) 0.0309(17) Uani 1 1 d .
N9 N 0.7687(5) -0.1651(2) 0.3590(4) 0.055(2) Uani 1 1 d .
C21 C 0.8336(6) -0.0612(3) 0.5365(5) 0.053(3) Uani 1 1 d .
C22 C 0.7705(5) -0.0725(2) 0.4842(4) 0.039(2) Uani 1 1 d .
C23 C 0.7145(5) -0.0472(3) 0.4815(5) 0.048(3) Uani 1 1 d .
C24 C 0.9129(6) -0.0757(3) 0.5634(5) 0.085(4) Uani 1 1 d .
H24A H 0.9428 -0.0674 0.5356 0.127 Uiso 1 1 calc R
H24B H 0.9118 -0.1025 0.5640 0.127 Uiso 1 1 calc R
H24C H 0.9356 -0.0666 0.6082 0.127 Uiso 1 1 calc R
C25 C 0.6373(5) -0.0462(3) 0.4352(5) 0.067(3) Uani 1 1 d .
H25A H 0.6008 -0.0493 0.4595 0.101 Uiso 1 1 calc R
H25B H 0.6310 -0.0659 0.4031 0.101 Uiso 1 1 calc R
H25C H 0.6288 -0.0226 0.4123 0.101 Uiso 1 1 calc R
C26 C 0.7701(7) -0.1043(2) 0.4387(5) 0.062(3) Uani 1 1 d .
C27 C 0.7164(6) -0.1304(3) 0.4306(5) 0.076(4) Uani 1 1 d .
H27 H 0.6789 -0.1282 0.4521 0.091 Uiso 1 1 calc R
C28 C 0.7163(7) -0.1602(3) 0.3909(6) 0.089(4) Uani 1 1 d .
H28 H 0.6780 -0.1781 0.3856 0.107 Uiso 1 1 calc R
C29 C 0.8247(6) -0.1408(3) 0.3720(5) 0.072(3) Uani 1 1 d .
H29 H 0.8657 -0.1453 0.3555 0.086 Uiso 1 1 calc R
C30 C 0.8260(6) -0.1086(3) 0.4094(5) 0.071(3) Uani 1 1 d .
H30 H 0.8640 -0.0906 0.4140 0.086 Uiso 1 1 calc R
Rh1 Rh 0.52758(4) 0.00326(2) 0.95601(4) 0.0550(3) Uani 1 1 d .
O1 O 0.4193(4) 0.0093(2) 0.8935(3) 0.074(2) Uani 1 1 d .
C61 C 0.3654(5) 0.0069(3) 0.9165(6) 0.067(3) Uani 1 1 d .
C62 C 0.2872(6) 0.0109(4) 0.8637(5) 0.100(4) Uani 1 1 d .
H62A H 0.2846 0.0345 0.8413 0.151 Uiso 1 1 calc R
H62B H 0.2475 0.0098 0.8849 0.151 Uiso 1 1 calc R
H62C H 0.2802 -0.0089 0.8317 0.151 Uiso 1 1 calc R
O2 O 0.6323(3) -0.0027(2) 1.0242(3) 0.077(2) Uani 1 1 d .
O3 O 0.5214(4) -0.0522(2) 0.9450(3) 0.072(2) Uani 1 1 d .
C63 C 0.4962(6) -0.0716(4) 0.9856(6) 0.077(3) Uani 1 1 d .
C64 C 0.4962(8) -0.1129(3) 0.9767(5) 0.110(5) Uani 1 1 d .
H64A H 0.4862 -0.1186 0.9300 0.166 Uiso 1 1 calc R
H64B H 0.4571 -0.1238 0.9925 0.166 Uiso 1 1 calc R
H64C H 0.5455 -0.1227 1.0016 0.166 Uiso 1 1 calc R
O4 O 0.5288(4) 0.0591(2) 0.9702(3) 0.074(2) Uani 1 1 d .
Rh2 Rh 0.76294(5) -0.21227(2) 0.28900(4) 0.0626(3) Uani 1 1 d .
Rh3 Rh 0.75831(5) -0.26260(2) 0.21455(4) 0.0699(3) Uani 1 1 d .
O5 O 0.7856(5) -0.2506(2) 0.3634(3) 0.097(3) Uani 1 1 d .
O6 O 0.7819(5) -0.29741(19) 0.2960(4) 0.098(3) Uani 1 1 d .
C65 C 0.7943(9) -0.2837(3) 0.3509(6) 0.101(5) Uani 1 1 d .
C66 C 0.8206(15) -0.3077(4) 0.4070(7) 0.277(16) Uani 1 1 d .
H66A H 0.8468 -0.2933 0.4459 0.416 Uiso 1 1 calc R
H66B H 0.8553 -0.3258 0.3985 0.416 Uiso 1 1 calc R
H66C H 0.7776 -0.3203 0.4145 0.416 Uiso 1 1 calc R
O7 O 0.6490(5) -0.2172(2) 0.2744(5) 0.106(4) Uani 1 1 d .
O8 O 0.6453(4) -0.2667(2) 0.2043(4) 0.083(2) Uani 1 1 d .
C67 C 0.6233(8) -0.2393(4) 0.2388(8) 0.092(5) Uani 1 1 d .
C68 C 0.5265(9) -0.2469(4) 0.2178(9) 0.158(7) Uani 1 1 d .
H68A H 0.5042 -0.2298 0.2419 0.237 Uiso 1 1 calc R
H68B H 0.5172 -0.2720 0.2292 0.237 Uiso 1 1 calc R
H68C H 0.5036 -0.2432 0.1706 0.237 Uiso 1 1 calc R
O9 O 0.7391(4) -0.17796(17) 0.2098(3) 0.067(2) Uani 1 1 d .
O10 O 0.7358(5) -0.22680(19) 0.1393(3) 0.082(2) Uani 1 1 d .
C69 C 0.7330(7) -0.1918(4) 0.1550(6) 0.085(4) Uani 1 1 d .
C70 C 0.7102(9) -0.1653(4) 0.0908(6) 0.137(6) Uani 1 1 d .
H70A H 0.6831 -0.1439 0.0995 0.205 Uiso 1 1 calc R
H70B H 0.6779 -0.1787 0.0531 0.205 Uiso 1 1 calc R
H70C H 0.7559 -0.1573 0.0813 0.205 Uiso 1 1 calc R
O11 O 0.8764(4) -0.2095(2) 0.3005(4) 0.086(2) Uani 1 1 d .
O12 O 0.8716(4) -0.2555(2) 0.2311(4) 0.089(3) Uani 1 1 d .
C71 C 0.9059(8) -0.2302(3) 0.2682(8) 0.103(5) Uani 1 1 d .
C72 C 0.9934(8) -0.2238(5) 0.2782(11) 0.211(10) Uani 1 1 d .
H72A H 1.0190 -0.2475 0.2825 0.317 Uiso 1 1 calc R
H72B H 1.0153 -0.2094 0.3180 0.317 Uiso 1 1 calc R
H72C H 0.9996 -0.2107 0.2402 0.317 Uiso 1 1 calc R
P1 P 1.00698(13) 0.01460(7) 0.70344(11) 0.0421(6) Uani 1 1 d .
C31 C 1.0451(5) 0.0600(3) 0.7340(5) 0.053(3) Uani 1 1 d .
C32 C 0.9936(8) 0.0826(4) 0.7471(9) 0.135(7) Uani 1 1 d .
H32 H 0.9442 0.0734 0.7401 0.162 Uiso 1 1 calc R
C33 C 1.0082(8) 0.1172(7) 0.7695(10) 0.197(11) Uani 1 1 d .
H33 H 0.9704 0.1327 0.7761 0.236 Uiso 1 1 calc R
C34 C 1.0799(13) 0.1280(4) 0.7817(8) 0.148(7) Uani 1 1 d .
H34 H 1.0924 0.1523 0.7968 0.178 Uiso 1 1 calc R
C35 C 1.1379(8) 0.1056(5) 0.7734(7) 0.118(5) Uani 1 1 d .
H35 H 1.1888 0.1134 0.7848 0.141 Uiso 1 1 calc R
C36 C 1.1136(6) 0.0693(3) 0.7458(5) 0.062(3) Uani 1 1 d .
H36 H 1.1487 0.0529 0.7367 0.075 Uiso 1 1 calc R
C41 C 1.0763(5) -0.0012(2) 0.6641(5) 0.048(2) Uani 1 1 d .
C42 C 1.0645(6) 0.0066(3) 0.5976(5) 0.069(3) Uani 1 1 d U
H42 H 1.0203 0.0196 0.5745 0.082 Uiso 1 1 calc R
C43 C 1.1112(6) -0.0030(4) 0.5655(6) 0.088(3) Uani 1 1 d U
H43 H 1.0992 0.0018 0.5198 0.106 Uiso 1 1 calc R
C44 C 1.1694(10) -0.0178(5) 0.5943(8) 0.123(6) Uani 1 1 d .
H44 H 1.2037 -0.0222 0.5702 0.148 Uiso 1 1 calc R
C45 C 1.1931(7) -0.0299(4) 0.6646(10) 0.131(6) Uani 1 1 d .
H45 H 1.2391 -0.0422 0.6852 0.158 Uiso 1 1 calc R
C46 C 1.1398(7) -0.0212(3) 0.6967(6) 0.082(4) Uani 1 1 d .
H46 H 1.1473 -0.0289 0.7406 0.098 Uiso 1 1 calc R
C51 C 1.0251(5) -0.0134(3) 0.7783(5) 0.051(3) Uani 1 1 d .
C52 C 0.9905(9) -0.0483(3) 0.7716(6) 0.111(5) Uani 1 1 d .
H52 H 0.9558 -0.0552 0.7308 0.133 Uiso 1 1 calc R
C53 C 1.0073(11) -0.0728(4) 0.8253(9) 0.139(7) Uani 1 1 d .
H53 H 0.9927 -0.0978 0.8197 0.167 Uiso 1 1 calc R
C54 C 1.0467(11) -0.0586(7) 0.8874(10) 0.174(10) Uani 1 1 d .
H54 H 1.0522 -0.0730 0.9256 0.208 Uiso 1 1 calc R
C55 C 1.0753(12) -0.0264(7) 0.8929(7) 0.226(14) Uani 1 1 d .
H55 H 1.1083 -0.0194 0.9345 0.271 Uiso 1 1 calc R
C56 C 1.0608(11) -0.0006(5) 0.8411(8) 0.179(8) Uani 1 1 d .
H56 H 1.0748 0.0243 0.8490 0.215 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N7 Ag1 P1 130.52(18) . .
N7 Ag1 N4 80.7(2) . .
P1 Ag1 N4 128.9(2) . .
N7 Ag1 N1 82.4(2) . .
P1 Ag1 N1 133.00(18) . .
N4 Ag1 N1 82.4(3) . .
N8 B1 N5 112.2(7) . .
N8 B1 N2 108.8(6) . .
N5 B1 N2 109.1(7) . .
C1 N1 N2 106.4(7) . .
C1 N1 Ag1 133.4(6) . .
N2 N1 Ag1 120.2(5) . .
C3 N2 N1 110.9(7) . .
C3 N2 B1 130.4(8) . .
N1 N2 B1 118.1(7) . .
C9 N3 C8 118.2(9) . .
C9 N3 Rh3 119.1(7) . 2_655
C8 N3 Rh3 122.6(8) . 2_655
N1 C1 C2 111.5(8) . .
N1 C1 C4 121.7(8) . .
C2 C1 C4 126.7(9) . .
C1 C2 C3 107.2(8) . .
C1 C2 C6 130.9(9) . .
C3 C2 C6 121.8(9) . .
N2 C3 C2 103.9(8) . .
N2 C3 C5 121.3(9) . .
C2 C3 C5 134.6(8) . .
C10 C6 C7 115.7(9) . .
C10 C6 C2 120.1(9) . .
C7 C6 C2 123.8(9) . .
C8 C7 C6 123.2(10) . .
N3 C8 C7 122.0(11) . .
N3 C9 C10 121.7(10) . .
C6 C10 C9 118.9(10) . .
C11 N4 N5 108.2(7) . .
C11 N4 Ag1 132.7(6) . .
N5 N4 Ag1 119.1(5) . .
C13 N5 N4 107.4(6) . .
C13 N5 B1 132.6(7) . .
N4 N5 B1 120.1(6) . .
C19 N6 C18 118.4(8) . .
C19 N6 Rh1 124.2(7) . .
C18 N6 Rh1 117.3(7) . .
N4 C11 C12 107.2(8) . .
N4 C11 C14 120.5(8) . .
C12 C11 C14 132.2(8) . .
C13 C12 C11 109.0(8) . .
C13 C12 C16 126.3(8) . .
C11 C12 C16 124.6(8) . .
N5 C13 C12 108.2(7) . .
N5 C13 C15 120.4(8) . .
C12 C13 C15 131.4(8) . .
C17 C16 C20 119.6(8) . .
C17 C16 C12 120.4(8) . .
C20 C16 C12 119.5(8) . .
C16 C17 C18 119.0(9) . .
N6 C18 C17 121.5(9) . .
N6 C19 C20 122.6(9) . .
C16 C20 C19 118.6(8) . .
C21 N7 N8 107.9(7) . .
C21 N7 Ag1 134.3(6) . .
N8 N7 Ag1 116.4(5) . .
C23 N8 N7 108.7(6) . .
C23 N8 B1 127.0(8) . .
N7 N8 B1 124.2(7) . .
C29 N9 C28 116.3(9) . .
C29 N9 Rh2 121.5(7) . .
C28 N9 Rh2 122.2(8) . .
N7 C21 C22 108.5(8) . .
N7 C21 C24 118.7(9) . .
C22 C21 C24 132.8(8) . .
C23 C22 C21 105.8(8) . .
C23 C22 C26 129.1(9) . .
C21 C22 C26 124.9(8) . .
N8 C23 C22 109.0(7) . .
N8 C23 C25 123.0(9) . .
C22 C23 C25 128.0(9) . .
C27 C26 C30 119.5(10) . .
C27 C26 C22 118.7(11) . .
C30 C26 C22 121.6(9) . .
C26 C27 C28 119.8(11) . .
N9 C28 C27 122.9(10) . .
N9 C29 C30 123.3(10) . .
C26 C30 C29 117.7(9) . .
O3 Rh1 O2 89.1(3) . .
O3 Rh1 O4 176.4(3) . .
O2 Rh1 O4 92.0(3) . .
O3 Rh1 O1 91.2(3) . .
O2 Rh1 O1 175.7(3) . .
O4 Rh1 O1 87.4(3) . .
O3 Rh1 N6 91.0(3) . .
O2 Rh1 N6 91.7(3) . .
O4 Rh1 N6 92.4(3) . .
O1 Rh1 N6 92.6(3) . .
O3 Rh1 Rh1 88.24(18) . 3_657
O2 Rh1 Rh1 88.53(19) . 3_657
O4 Rh1 Rh1 88.36(19) . 3_657
O1 Rh1 Rh1 87.17(19) . 3_657
N6 Rh1 Rh1 179.2(3) . 3_657
C61 O1 Rh1 118.9(6) . .
O1 C61 O2 128.1(9) . 3_657
O1 C61 C62 113.4(10) . .
O2 C61 C62 118.5(9) 3_657 .
C61 O2 Rh1 117.2(6) 3_657 .
C63 O3 Rh1 118.7(7) . .
O4 C63 O3 126.0(12) 3_657 .
O4 C63 C64 118.0(12) 3_657 .
O3 C63 C64 116.0(12) . .
C63 O4 Rh1 118.7(8) 3_657 .
O9 Rh2 O11 91.4(3) . .
O9 Rh2 O7 88.5(4) . .
O11 Rh2 O7 177.2(3) . .
O9 Rh2 O5 175.1(3) . .
O11 Rh2 O5 88.9(3) . .
O7 Rh2 O5 90.9(4) . .
O9 Rh2 N9 92.0(3) . .
O11 Rh2 N9 92.5(3) . .
O7 Rh2 N9 90.3(3) . .
O5 Rh2 N9 92.9(3) . .
O9 Rh2 Rh3 88.10(19) . .
O11 Rh2 Rh3 86.9(2) . .
O7 Rh2 Rh3 90.3(2) . .
O5 Rh2 Rh3 87.0(2) . .
N9 Rh2 Rh3 179.3(2) . .
O10 Rh3 O12 90.5(3) . .
O10 Rh3 O8 90.3(3) . .
O12 Rh3 O8 175.2(3) . .
O10 Rh3 O6 176.9(3) . .
O12 Rh3 O6 89.4(3) . .
O8 Rh3 O6 89.6(3) . .
O10 Rh3 N3 92.1(3) . 2_645
O12 Rh3 N3 92.7(3) . 2_645
O8 Rh3 N3 92.0(3) . 2_645
O6 Rh3 N3 90.9(3) . 2_645
O10 Rh3 Rh2 89.3(2) . .
O12 Rh3 Rh2 87.8(2) . .
O8 Rh3 Rh2 87.5(2) . .
O6 Rh3 Rh2 87.6(2) . .
N3 Rh3 Rh2 178.5(3) 2_645 .
C65 O5 Rh2 119.9(7) . .
C65 O6 Rh3 118.4(7) . .
O6 C65 O5 126.5(11) . .
O6 C65 C66 117.3(11) . .
O5 C65 C66 116.2(12) . .
C67 O7 Rh2 112.2(10) . .
C67 O8 Rh3 110.6(8) . .
O7 C67 O8 139.2(14) . .
O7 C67 C68 119.3(13) . .
O8 C67 C68 101.5(13) . .
C69 O9 Rh2 117.6(7) . .
C69 O10 Rh3 116.0(7) . .
O9 C69 O10 128.9(10) . .
O9 C69 C70 118.4(12) . .
O10 C69 C70 112.4(11) . .
C71 O11 Rh2 120.6(9) . .
C71 O12 Rh3 119.9(8) . .
O11 C71 O12 124.6(13) . .
O11 C71 C72 116.0(13) . .
O12 C71 C72 119.5(12) . .
C41 P1 C51 104.8(4) . .
C41 P1 C31 101.3(4) . .
C51 P1 C31 104.1(5) . .
C41 P1 Ag1 115.7(3) . .
C51 P1 Ag1 113.7(3) . .
C31 P1 Ag1 115.7(3) . .
C36 C31 C32 121.9(10) . .
C36 C31 P1 124.4(8) . .
C32 C31 P1 113.6(8) . .
C33 C32 C31 124.4(12) . .
C34 C33 C32 115.2(17) . .
C33 C34 C35 124.0(16) . .
C34 C35 C36 115.0(13) . .
C31 C36 C35 119.3(11) . .
C46 C41 C42 117.7(8) . .
C46 C41 P1 123.2(8) . .
C42 C41 P1 119.2(7) . .
C43 C42 C41 123.7(10) . .
C44 C43 C42 119.5(13) . .
C43 C44 C45 126.3(13) . .
C46 C45 C44 112.7(11) . .
C41 C46 C45 119.8(11) . .
C56 C51 C52 118.2(11) . .
C56 C51 P1 124.0(11) . .
C52 C51 P1 117.1(8) . .
C53 C52 C51 120.4(14) . .
C54 C53 C52 117.1(16) . .
C55 C54 C53 120.6(14) . .
C54 C55 C56 124.4(16) . .
C51 C56 C55 116.8(17) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N7 2.312(7) .
Ag1 P1 2.314(2) .
Ag1 N4 2.321(7) .
Ag1 N1 2.327(7) .
B1 N8 1.513(11) .
B1 N5 1.517(10) .
B1 N2 1.622(11) .
N1 C1 1.317(10) .
N1 N2 1.362(8) .
N2 C3 1.350(10) .
N3 C9 1.352(13) .
N3 C8 1.354(13) .
N3 Rh3 2.202(8) 2_655
C1 C2 1.323(11) .
C1 C4 1.488(13) .
C2 C3 1.429(12) .
C2 C6 1.462(12) .
C3 C5 1.483(12) .
C6 C10 1.397(12) .
C6 C7 1.410(13) .
C7 C8 1.377(13) .
C9 C10 1.483(13) .
N4 C11 1.363(10) .
N4 N5 1.389(9) .
N5 C13 1.357(9) .
N6 C19 1.268(11) .
N6 C18 1.397(12) .
N6 Rh1 2.241(7) .
C11 C12 1.366(11) .
C11 C14 1.524(12) .
C12 C13 1.362(11) .
C12 C16 1.501(12) .
C13 C15 1.471(12) .
C16 C17 1.344(12) .
C16 C20 1.381(12) .
C17 C18 1.400(12) .
C19 C20 1.433(12) .
N7 C21 1.354(10) .
N7 N8 1.359(8) .
N8 C23 1.355(10) .
N9 C29 1.320(11) .
N9 C28 1.351(12) .
N9 Rh2 2.243(7) .
C21 C22 1.402(12) .
C21 C24 1.496(12) .
C22 C23 1.369(11) .
C22 C26 1.499(12) .
C23 C25 1.463(11) .
C26 C27 1.344(13) .
C26 C30 1.366(13) .
C27 C28 1.370(14) .
C29 C30 1.407(12) .
Rh1 O3 2.021(8) .
Rh1 O2 2.042(6) .
Rh1 O4 2.043(8) .
Rh1 O1 2.045(6) .
Rh1 Rh1 2.3922(14) 3_657
O1 C61 1.238(11) .
C61 O2 1.252(12) 3_657
C61 C62 1.540(13) .
O2 C61 1.252(12) 3_657
O3 C63 1.302(13) .
C63 O4 1.248(13) 3_657
C63 C64 1.507(15) .
O4 C63 1.248(13) 3_657
Rh2 O9 2.025(7) .
Rh2 O11 2.037(7) .
Rh2 O7 2.039(10) .
Rh2 O5 2.045(7) .
Rh2 Rh3 2.3951(11) .
Rh3 O10 1.998(7) .
Rh3 O12 2.030(7) .
Rh3 O8 2.037(8) .
Rh3 O6 2.074(8) .
Rh3 N3 2.202(8) 2_645
O5 C65 1.247(11) .
O6 C65 1.221(12) .
C65 C66 1.433(15) .
O7 C67 1.102(18) .
O8 C67 1.368(16) .
C67 C68 1.727(19) .
O9 C69 1.237(13) .
O10 C69 1.317(14) .
C69 C70 1.613(15) .
O11 C71 1.246(12) .
O12 C71 1.248(13) .
C71 C72 1.581(18) .
P1 C41 1.819(8) .
P1 C51 1.826(9) .
P1 C31 1.828(9) .
C31 C36 1.259(11) .
C31 C32 1.344(15) .
C32 C33 1.34(2) .
C33 C34 1.33(2) .
C34 C35 1.398(19) .
C35 C36 1.453(16) .
C41 C46 1.373(13) .
C41 C42 1.386(13) .
C42 C43 1.298(12) .
C43 C44 1.188(18) .
C44 C45 1.486(19) .
C45 C46 1.392(17) .
C51 C56 1.373(17) .
C51 C52 1.403(14) .
C52 C53 1.403(17) .
C53 C54 1.39(2) .
C54 C55 1.27(2) .
C55 C56 1.41(2) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N7 Ag1 N1 C1 -135.7(9) . .
P1 Ag1 N1 C1 4.8(10) . .
N4 Ag1 N1 C1 142.7(9) . .
N7 Ag1 N1 N2 45.6(6) . .
P1 Ag1 N1 N2 -174.0(4) . .
N4 Ag1 N1 N2 -36.0(6) . .
C1 N1 N2 C3 0.4(10) . .
Ag1 N1 N2 C3 179.5(5) . .
C1 N1 N2 B1 173.2(7) . .
Ag1 N1 N2 B1 -7.8(9) . .
N8 B1 N2 C3 116.2(9) . .
N5 B1 N2 C3 -121.1(9) . .
N8 B1 N2 N1 -54.9(9) . .
N5 B1 N2 N1 67.8(9) . .
N2 N1 C1 C2 0.5(11) . .
Ag1 N1 C1 C2 -178.4(6) . .
N2 N1 C1 C4 -177.2(10) . .
Ag1 N1 C1 C4 3.9(16) . .
N1 C1 C2 C3 -1.1(12) . .
C4 C1 C2 C3 176.4(11) . .
N1 C1 C2 C6 -178.1(9) . .
C4 C1 C2 C6 -0.6(19) . .
N1 N2 C3 C2 -1.1(9) . .
B1 N2 C3 C2 -172.6(7) . .
N1 N2 C3 C5 -177.4(8) . .
B1 N2 C3 C5 11.1(13) . .
C1 C2 C3 N2 1.3(10) . .
C6 C2 C3 N2 178.6(8) . .
C1 C2 C3 C5 176.8(10) . .
C6 C2 C3 C5 -5.8(17) . .
C1 C2 C6 C10 -38.7(16) . .
C3 C2 C6 C10 144.7(10) . .
C1 C2 C6 C7 133.5(12) . .
C3 C2 C6 C7 -43.2(14) . .
C10 C6 C7 C8 -5.6(16) . .
C2 C6 C7 C8 -178.1(10) . .
C9 N3 C8 C7 -6.2(19) . .
Rh3 N3 C8 C7 176.6(8) 2_655 .
C6 C7 C8 N3 7.5(18) . .
C8 N3 C9 C10 4(2) . .
Rh3 N3 C9 C10 -179.1(9) 2_655 .
C7 C6 C10 C9 2.9(16) . .
C2 C6 C10 C9 175.7(10) . .
N3 C9 C10 C6 -2(2) . .
N7 Ag1 N4 C11 136.4(8) . .
P1 Ag1 N4 C11 0.8(9) . .
N1 Ag1 N4 C11 -140.1(8) . .
N7 Ag1 N4 N5 -42.2(5) . .
P1 Ag1 N4 N5 -177.8(4) . .
N1 Ag1 N4 N5 41.2(5) . .
C11 N4 N5 C13 -0.1(9) . .
Ag1 N4 N5 C13 178.8(5) . .
C11 N4 N5 B1 -179.1(7) . .
Ag1 N4 N5 B1 -0.2(9) . .
N8 B1 N5 C13 -120.4(9) . .
N2 B1 N5 C13 118.9(9) . .
N8 B1 N5 N4 58.2(10) . .
N2 B1 N5 N4 -62.5(9) . .
N5 N4 C11 C12 -0.2(10) . .
Ag1 N4 C11 C12 -178.9(6) . .
N5 N4 C11 C14 179.1(8) . .
Ag1 N4 C11 C14 0.4(13) . .
N4 C11 C12 C13 0.4(10) . .
C14 C11 C12 C13 -178.7(10) . .
N4 C11 C12 C16 176.2(8) . .
C14 C11 C12 C16 -3.0(17) . .
N4 N5 C13 C12 0.4(9) . .
B1 N5 C13 C12 179.2(8) . .
N4 N5 C13 C15 -178.5(8) . .
B1 N5 C13 C15 0.3(13) . .
C11 C12 C13 N5 -0.5(10) . .
C16 C12 C13 N5 -176.2(8) . .
C11 C12 C13 C15 178.2(10) . .
C16 C12 C13 C15 2.5(16) . .
C13 C12 C16 C17 130.4(10) . .
C11 C12 C16 C17 -44.6(14) . .
C13 C12 C16 C20 -57.4(13) . .
C11 C12 C16 C20 127.6(10) . .
C20 C16 C17 C18 4.7(16) . .
C12 C16 C17 C18 177.0(9) . .
C19 N6 C18 C17 -1.4(17) . .
Rh1 N6 C18 C17 178.5(8) . .
C16 C17 C18 N6 -3.2(17) . .
C18 N6 C19 C20 4.3(17) . .
Rh1 N6 C19 C20 -175.5(7) . .
C17 C16 C20 C19 -2.0(15) . .
C12 C16 C20 C19 -174.3(9) . .
N6 C19 C20 C16 -2.8(17) . .
P1 Ag1 N7 C21 -13.9(9) . .
N4 Ag1 N7 C21 -148.1(8) . .
N1 Ag1 N7 C21 128.4(8) . .
P1 Ag1 N7 N8 -178.7(4) . .
N4 Ag1 N7 N8 47.1(5) . .
N1 Ag1 N7 N8 -36.4(5) . .
C21 N7 N8 C23 -2.1(9) . .
Ag1 N7 N8 C23 166.5(5) . .
C21 N7 N8 B1 -179.2(7) . .
Ag1 N7 N8 B1 -10.6(9) . .
N5 B1 N8 C23 130.7(8) . .
N2 B1 N8 C23 -108.5(9) . .
N5 B1 N8 N7 -52.8(10) . .
N2 B1 N8 N7 68.1(9) . .
N8 N7 C21 C22 0.2(10) . .
Ag1 N7 C21 C22 -165.5(6) . .
N8 N7 C21 C24 179.2(8) . .
Ag1 N7 C21 C24 13.5(13) . .
N7 C21 C22 C23 1.7(10) . .
C24 C21 C22 C23 -177.1(10) . .
N7 C21 C22 C26 177.3(8) . .
C24 C21 C22 C26 -1.6(17) . .
N7 N8 C23 C22 3.3(9) . .
B1 N8 C23 C22 -179.8(7) . .
N7 N8 C23 C25 -179.1(8) . .
B1 N8 C23 C25 -2.1(12) . .
C21 C22 C23 N8 -3.0(10) . .
C26 C22 C23 N8 -178.3(9) . .
C21 C22 C23 C25 179.5(9) . .
C26 C22 C23 C25 4.2(16) . .
C23 C22 C26 C27 -58.4(14) . .
C21 C22 C26 C27 127.1(11) . .
C23 C22 C26 C30 126.4(11) . .
C21 C22 C26 C30 -48.0(14) . .
C30 C26 C27 C28 -2.7(17) . .
C22 C26 C27 C28 -178.0(10) . .
C29 N9 C28 C27 5.1(17) . .
Rh2 N9 C28 C27 -175.9(9) . .
C26 C27 C28 N9 0.4(19) . .
C28 N9 C29 C30 -8.6(16) . .
Rh2 N9 C29 C30 172.4(8) . .
C27 C26 C30 C29 -0.5(16) . .
C22 C26 C30 C29 174.6(9) . .
N9 C29 C30 C26 6.5(17) . .
C19 N6 Rh1 O3 134.4(9) . .
C18 N6 Rh1 O3 -45.4(8) . .
C19 N6 Rh1 O2 -136.4(9) . .
C18 N6 Rh1 O2 43.7(8) . .
C19 N6 Rh1 O4 -44.3(9) . .
C18 N6 Rh1 O4 135.8(8) . .
C19 N6 Rh1 O1 43.2(9) . .
C18 N6 Rh1 O1 -136.7(8) . .
C19 N6 Rh1 Rh1 118(19) . 3_657
C18 N6 Rh1 Rh1 -62(19) . 3_657
O3 Rh1 O1 C61 86.3(8) . .
O2 Rh1 O1 C61 -8(5) . .
O4 Rh1 O1 C61 -90.3(8) . .
N6 Rh1 O1 C61 177.4(8) . .
Rh1 Rh1 O1 C61 -1.8(8) 3_657 .
Rh1 O1 C61 O2 3.3(17) . 3_657
Rh1 O1 C61 C62 -178.4(7) . .
O3 Rh1 O2 C61 -89.0(8) . 3_657
O4 Rh1 O2 C61 87.5(8) . 3_657
O1 Rh1 O2 C61 5(5) . 3_657
N6 Rh1 O2 C61 180.0(8) . 3_657
Rh1 Rh1 O2 C61 -0.8(8) 3_657 3_657
O2 Rh1 O3 C63 85.7(7) . .
O4 Rh1 O3 C63 -23(5) . .
O1 Rh1 O3 C63 -90.0(7) . .
N6 Rh1 O3 C63 177.3(7) . .
Rh1 Rh1 O3 C63 -2.9(7) 3_657 .
Rh1 O3 C63 O4 4.0(14) . 3_657
Rh1 O3 C63 C64 -177.4(7) . .
O3 Rh1 O4 C63 20(5) . 3_657
O2 Rh1 O4 C63 -88.5(8) . 3_657
O1 Rh1 O4 C63 87.2(8) . 3_657
N6 Rh1 O4 C63 179.7(8) . 3_657
Rh1 Rh1 O4 C63 -0.1(8) 3_657 3_657
C29 N9 Rh2 O9 -69.7(8) . .
C28 N9 Rh2 O9 111.3(8) . .
C29 N9 Rh2 O11 21.8(8) . .
C28 N9 Rh2 O11 -157.2(8) . .
C29 N9 Rh2 O7 -158.3(8) . .
C28 N9 Rh2 O7 22.8(9) . .
C29 N9 Rh2 O5 110.8(8) . .
C28 N9 Rh2 O5 -68.2(8) . .
C29 N9 Rh2 Rh3 28(18) . .
C28 N9 Rh2 Rh3 -151(17) . .
O9 Rh2 Rh3 O10 0.4(3) . .
O11 Rh2 Rh3 O10 -91.1(3) . .
O7 Rh2 Rh3 O10 89.0(4) . .
O5 Rh2 Rh3 O10 179.9(3) . .
N9 Rh2 Rh3 O10 -97(18) . .
O9 Rh2 Rh3 O12 91.0(3) . .
O11 Rh2 Rh3 O12 -0.5(3) . .
O7 Rh2 Rh3 O12 179.5(4) . .
O5 Rh2 Rh3 O12 -89.6(4) . .
N9 Rh2 Rh3 O12 -7(18) . .
O9 Rh2 Rh3 O8 -89.9(3) . .
O11 Rh2 Rh3 O8 178.6(3) . .
O7 Rh2 Rh3 O8 -1.4(4) . .
O5 Rh2 Rh3 O8 89.6(3) . .
N9 Rh2 Rh3 O8 172(100) . .
O9 Rh2 Rh3 O6 -179.6(3) . .
O11 Rh2 Rh3 O6 88.9(3) . .
O7 Rh2 Rh3 O6 -91.0(4) . .
O5 Rh2 Rh3 O6 -0.1(4) . .
N9 Rh2 Rh3 O6 83(18) . .
O9 Rh2 Rh3 N3 -159(10) . 2_645
O11 Rh2 Rh3 N3 109(10) . 2_645
O7 Rh2 Rh3 N3 -70(10) . 2_645
O5 Rh2 Rh3 N3 20(10) . 2_645
N9 Rh2 Rh3 N3 103(20) . 2_645
O9 Rh2 O5 C65 11(4) . .
O11 Rh2 O5 C65 -82.7(11) . .
O7 Rh2 O5 C65 94.5(11) . .
N9 Rh2 O5 C65 -175.1(11) . .
Rh3 Rh2 O5 C65 4.3(10) . .
O10 Rh3 O6 C65 -4(7) . .
O12 Rh3 O6 C65 83.8(11) . .
O8 Rh3 O6 C65 -91.5(11) . .
N3 Rh3 O6 C65 176.5(11) 2_645 .
Rh2 Rh3 O6 C65 -4.0(11) . .
Rh3 O6 C65 O5 9(2) . .
Rh3 O6 C65 C66 -171.6(14) . .
Rh2 O5 C65 O6 -9(2) . .
Rh2 O5 C65 C66 171.3(14) . .
O9 Rh2 O7 C67 86.8(10) . .
O11 Rh2 O7 C67 -2(8) . .
O5 Rh2 O7 C67 -88.3(10) . .
N9 Rh2 O7 C67 178.8(10) . .
Rh3 Rh2 O7 C67 -1.3(10) . .
O10 Rh3 O8 C67 -85.6(7) . .
O12 Rh3 O8 C67 14(4) . .
O6 Rh3 O8 C67 91.3(7) . .
N3 Rh3 O8 C67 -177.8(7) 2_645 .
Rh2 Rh3 O8 C67 3.7(6) . .
Rh2 O7 C67 O8 7(2) . .
Rh2 O7 C67 C68 -178.1(8) . .
Rh3 O8 C67 O7 -7.9(19) . .
Rh3 O8 C67 C68 176.1(7) . .
O11 Rh2 O9 C69 84.7(9) . .
O7 Rh2 O9 C69 -92.5(9) . .
O5 Rh2 O9 C69 -8(4) . .
N9 Rh2 O9 C69 177.2(9) . .
Rh3 Rh2 O9 C69 -2.2(8) . .
O12 Rh3 O10 C69 -86.8(8) . .
O8 Rh3 O10 C69 88.5(8) . .
O6 Rh3 O10 C69 1(7) . .
N3 Rh3 O10 C69 -179.5(8) 2_645 .
Rh2 Rh3 O10 C69 1.0(8) . .
Rh2 O9 C69 O10 4.0(17) . .
Rh2 O9 C69 C70 177.2(8) . .
Rh3 O10 C69 O9 -3.4(17) . .
Rh3 O10 C69 C70 -177.0(8) . .
O9 Rh2 O11 C71 -84.9(10) . .
O7 Rh2 O11 C71 4(8) . .
O5 Rh2 O11 C71 90.2(10) . .
N9 Rh2 O11 C71 -176.9(10) . .
Rh3 Rh2 O11 C71 3.1(10) . .
O10 Rh3 O12 C71 87.5(10) . .
O8 Rh3 O12 C71 -12(5) . .
O6 Rh3 O12 C71 -89.4(10) . .
N3 Rh3 O12 C71 179.6(10) 2_645 .
Rh2 Rh3 O12 C71 -1.8(10) . .
Rh2 O11 C71 O12 -6(2) . .
Rh2 O11 C71 C72 176.5(10) . .
Rh3 O12 C71 O11 5(2) . .
Rh3 O12 C71 C72 -177.3(11) . .
N7 Ag1 P1 C41 43.9(4) . .
N4 Ag1 P1 C41 158.6(4) . .
N1 Ag1 P1 C41 -80.0(4) . .
N7 Ag1 P1 C51 -77.4(4) . .
N4 Ag1 P1 C51 37.2(5) . .
N1 Ag1 P1 C51 158.6(5) . .
N7 Ag1 P1 C31 162.2(4) . .
N4 Ag1 P1 C31 -83.2(4) . .
N1 Ag1 P1 C31 38.2(5) . .
C41 P1 C31 C36 -23.4(11) . .
C51 P1 C31 C36 85.2(10) . .
Ag1 P1 C31 C36 -149.3(9) . .
C41 P1 C31 C32 160.4(11) . .
C51 P1 C31 C32 -91.0(11) . .
Ag1 P1 C31 C32 34.5(12) . .
C36 C31 C32 C33 4(3) . .
P1 C31 C32 C33 -179.5(17) . .
C31 C32 C33 C34 -3(3) . .
C32 C33 C34 C35 -1(3) . .
C33 C34 C35 C36 4(3) . .
C32 C31 C36 C35 -0.9(19) . .
P1 C31 C36 C35 -176.7(9) . .
C34 C35 C36 C31 -2.9(18) . .
C51 P1 C41 C46 -17.2(10) . .
C31 P1 C41 C46 90.8(9) . .
Ag1 P1 C41 C46 -143.3(8) . .
C51 P1 C41 C42 161.6(8) . .
C31 P1 C41 C42 -90.3(9) . .
Ag1 P1 C41 C42 35.6(9) . .
C46 C41 C42 C43 -2.1(17) . .
P1 C41 C42 C43 179.0(10) . .
C41 C42 C43 C44 -4(2) . .
C42 C43 C44 C45 6(3) . .
C43 C44 C45 C46 -2(2) . .
C42 C41 C46 C45 5.8(17) . .
P1 C41 C46 C45 -175.3(10) . .
C44 C45 C46 C41 -4.0(18) . .
C41 P1 C51 C56 105.2(13) . .
C31 P1 C51 C56 -0.8(14) . .
Ag1 P1 C51 C56 -127.5(12) . .
C41 P1 C51 C52 -84.5(9) . .
C31 P1 C51 C52 169.5(8) . .
Ag1 P1 C51 C52 42.8(9) . .
C56 C51 C52 C53 -15(2) . .
P1 C51 C52 C53 173.9(10) . .
C51 C52 C53 C54 12(2) . .
C52 C53 C54 C55 -10(3) . .
C53 C54 C55 C56 10(4) . .
C52 C51 C56 C55 14(3) . .
P1 C51 C56 C55 -175.5(15) . .
C54 C55 C56 C51 -13(4) . .
