#------------------------------------------------------------------------------
#$Date: 2021-01-07 06:46:17 +0200 (Thu, 07 Jan 2021) $
#$Revision: 260659 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/12/74/7127423.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7127423
loop_
_publ_author_name
'Cabeza, Javier A.'
'García-Álvarez, Pablo'
'Laglera-Gándara, Carlos J'
'Pérez-Carreño, Enrique'
_publ_section_title
;
 A Z-type PGeP pincer germylene ligand in a T-shaped palladium(0) complex.
;
_journal_issue                   90
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              14095
_journal_page_last               14097
_journal_paper_doi               10.1039/d0cc06614a
_journal_volume                  56
_journal_year                    2020
_chemical_formula_moiety         'C37 H52 Ge N2 P2 Pd S2'
_chemical_formula_sum            'C37 H52 Ge N2 P2 Pd S2'
_chemical_formula_weight         829.85
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014
_audit_update_record
;
2020-10-02 deposited with the CCDC.	2020-10-19 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 114.6700(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   17.5001(4)
_cell_length_b                   12.1142(2)
_cell_length_c                   18.9450(4)
_cell_measurement_reflns_used    9882
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      74.6585
_cell_measurement_theta_min      2.8905
_cell_volume                     3649.75(13)
_computing_cell_refinement       'BRUKER APEX3'
_computing_data_collection       'BRUKER APEX3'
_computing_data_reduction        'BRUKER APEX3'
_computing_molecular_graphics
'MERCURY (Cambridge Crystallographic Data Centre: Cambridge, UK, 2020)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_structure_solution    'SIR-97 (Giacovazzo, 1999)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker D8 VENTURE PHOTON III-14'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0396
_diffrn_reflns_av_unetI/netI     0.0115
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            176781
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         74.487
_diffrn_reflns_theta_min         2.890
_exptl_absorpt_coefficient_mu    7.101
_exptl_absorpt_correction_T_max  0.6308
_exptl_absorpt_correction_T_min  0.4706
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
; 
SADABS-2016/2 - Bruker AXS area detector scaling and absorption correction 

Reference: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D., J. Appl. Cryst. 48 (2015) 3-10.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.510
_exptl_crystal_description       prism
_exptl_crystal_F_000             1712
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.422
_refine_diff_density_min         -0.317
_refine_diff_density_rms         0.051
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.068
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     416
_refine_ls_number_reflns         7461
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.068
_refine_ls_R_factor_all          0.0190
_refine_ls_R_factor_gt           0.0178
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0156P)²+3.1910P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0410
_refine_ls_wR_factor_ref         0.0418
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7173
_reflns_number_total             7461
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0cc06614a2.cif
_cod_data_source_block           4
_cod_depositor_comments
'Adding full bibliography for 7127422--7127423.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7127423
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelxl_version_number           2014-3
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.88562(11) 0.28198(14) 0.47118(10) 0.0217(4) Uani 1 1 d . . . . .
H1A H 0.8638 0.3427 0.4339 0.033 Uiso 1 1 calc R U . . .
H1B H 0.8424 0.2583 0.4881 0.033 Uiso 1 1 calc R U . . .
H1C H 0.9009 0.2199 0.4465 0.033 Uiso 1 1 calc R U . . .
C2 C 1.03370(11) 0.35347(14) 0.51724(11) 0.0212(4) Uani 1 1 d . . . . .
H2A H 1.0501 0.2888 0.4957 0.032 Uiso 1 1 calc R U . . .
H2B H 1.0824 0.3805 0.5626 0.032 Uiso 1 1 calc R U . . .
H2C H 1.0134 0.4117 0.4778 0.032 Uiso 1 1 calc R U . . .
C3 C 0.96353(10) 0.32115(13) 0.54170(9) 0.0151(3) Uani 1 1 d . . . . .
H3 H 0.9473 0.3891 0.5621 0.018 Uiso 1 1 calc R U . . .
C4 C 1.12841(10) 0.19511(15) 0.76839(9) 0.0196(3) Uani 1 1 d . . . . .
H4A H 1.1831 0.2223 0.8058 0.029 Uiso 1 1 calc R U . . .
H4B H 1.1342 0.1186 0.7545 0.029 Uiso 1 1 calc R U . . .
H4C H 1.0879 0.1984 0.7917 0.029 Uiso 1 1 calc R U . . .
C5 C 1.09109(10) 0.38816(14) 0.71652(11) 0.0208(3) Uani 1 1 d . . . . .
H5A H 1.0476 0.3952 0.7361 0.031 Uiso 1 1 calc R U . . .
H5B H 1.0764 0.4345 0.6703 0.031 Uiso 1 1 calc R U . . .
H5C H 1.1453 0.4120 0.7567 0.031 Uiso 1 1 calc R U . . .
C6 C 1.09727(10) 0.26706(13) 0.69527(9) 0.0154(3) Uani 1 1 d . . . . .
H6 H 1.1402 0.2630 0.6733 0.019 Uiso 1 1 calc R U . . .
C7 C 1.02784(10) 0.10050(12) 0.57404(9) 0.0134(3) Uani 1 1 d . . . . .
H7A H 0.9767 0.0679 0.5330 0.016 Uiso 1 1 calc R U . . .
H7B H 1.0628 0.1301 0.5487 0.016 Uiso 1 1 calc R U . . .
C8 C 1.07564(10) 0.01143(12) 0.62892(9) 0.0127(3) Uani 1 1 d . . . . .
C9 C 1.15855(10) -0.01783(13) 0.65531(10) 0.0164(3) Uani 1 1 d . . . . .
H9 H 1.1987 0.0133 0.6395 0.020 Uiso 1 1 calc R U . . .
C10 C 1.17338(10) -0.10344(13) 0.71084(10) 0.0162(3) Uani 1 1 d . . . . .
H10 H 1.2254 -0.1400 0.7388 0.019 Uiso 1 1 calc R U . . .
C11 C 1.09916(9) -0.12380(12) 0.71690(9) 0.0123(3) Uani 1 1 d . . . . .
C12 C 1.07634(9) -0.21276(12) 0.76070(9) 0.0129(3) Uani 1 1 d . . . . .
C13 C 1.02850(10) -0.30602(13) 0.70346(9) 0.0161(3) Uani 1 1 d . . . . .
H13A H 0.9765 -0.2764 0.6632 0.024 Uiso 1 1 calc R U . . .
H13B H 1.0149 -0.3650 0.7317 0.024 Uiso 1 1 calc R U . . .
H13C H 1.0639 -0.3357 0.6792 0.024 Uiso 1 1 calc R U . . .
C14 C 1.15645(10) -0.26318(14) 0.82348(9) 0.0182(3) Uani 1 1 d . . . . .
H14A H 1.1907 -0.2955 0.7990 0.027 Uiso 1 1 calc R U . . .
H14B H 1.1410 -0.3207 0.8515 0.027 Uiso 1 1 calc R U . . .
H14C H 1.1887 -0.2054 0.8600 0.027 Uiso 1 1 calc R U . . .
C15 C 1.02045(9) -0.16716(12) 0.79695(9) 0.0118(3) Uani 1 1 d . . . . .
C16 C 1.02107(10) -0.18650(13) 0.86839(9) 0.0147(3) Uani 1 1 d . . . . .
H16 H 1.0624 -0.2271 0.9095 0.018 Uiso 1 1 calc R U . . .
C17 C 0.94876(10) -0.13506(13) 0.87014(9) 0.0146(3) Uani 1 1 d . . . . .
H17 H 0.9330 -0.1350 0.9125 0.017 Uiso 1 1 calc R U . . .
C18 C 0.90615(9) -0.08571(12) 0.79951(9) 0.0120(3) Uani 1 1 d . . . . .
C19 C 0.82330(9) -0.02661(12) 0.76685(9) 0.0121(3) Uani 1 1 d . . . . .
H19A H 0.7962 -0.0360 0.8031 0.015 Uiso 1 1 calc R U . . .
H19B H 0.7865 -0.0618 0.7170 0.015 Uiso 1 1 calc R U . . .
C20 C 0.88300(10) 0.18498(13) 0.84806(9) 0.0143(3) Uani 1 1 d . . . . .
H20 H 0.8583 0.2601 0.8453 0.017 Uiso 1 1 calc R U . . .
C21 C 0.97709(10) 0.20000(15) 0.87099(10) 0.0207(3) Uani 1 1 d . . . . .
H21A H 1.0037 0.2314 0.9234 0.031 Uiso 1 1 calc R U . . .
H21B H 0.9854 0.2500 0.8341 0.031 Uiso 1 1 calc R U . . .
H21C H 1.0026 0.1282 0.8702 0.031 Uiso 1 1 calc R U . . .
C22 C 0.87043(10) 0.12120(13) 0.91238(9) 0.0171(3) Uani 1 1 d . . . . .
H22A H 0.8999 0.0503 0.9209 0.026 Uiso 1 1 calc R U . . .
H22B H 0.8103 0.1082 0.8968 0.026 Uiso 1 1 calc R U . . .
H22C H 0.8931 0.1644 0.9605 0.026 Uiso 1 1 calc R U . . .
C23 C 0.72059(9) 0.17069(12) 0.71055(9) 0.0124(3) Uani 1 1 d . . . . .
H23 H 0.7208 0.2499 0.6958 0.015 Uiso 1 1 calc R U . . .
C24 C 0.66711(10) 0.10742(14) 0.63623(9) 0.0168(3) Uani 1 1 d . . . . .
H24A H 0.6565 0.0326 0.6497 0.025 Uiso 1 1 calc R U . . .
H24B H 0.6971 0.1034 0.6027 0.025 Uiso 1 1 calc R U . . .
H24C H 0.6135 0.1458 0.6087 0.025 Uiso 1 1 calc R U . . .
C25 C 0.67868(10) 0.16528(13) 0.76711(9) 0.0162(3) Uani 1 1 d . . . . .
H25A H 0.6200 0.1891 0.7405 0.024 Uiso 1 1 calc R U . . .
H25B H 0.7086 0.2140 0.8114 0.024 Uiso 1 1 calc R U . . .
H25C H 0.6807 0.0893 0.7856 0.024 Uiso 1 1 calc R U . . .
C26 C 0.75153(9) -0.06014(13) 0.51964(8) 0.0126(3) Uani 1 1 d . . . . .
C27 C 0.68397(10) -0.11435(13) 0.52506(10) 0.0181(3) Uani 1 1 d . . . . .
H27 H 0.6933 -0.1797 0.5553 0.022 Uiso 1 1 calc R U . . .
C28 C 0.60291(11) -0.07305(15) 0.48637(11) 0.0262(4) Uani 1 1 d . . . . .
H28 H 0.5571 -0.1100 0.4905 0.031 Uiso 1 1 calc R U . . .
C29 C 0.58875(11) 0.02152(17) 0.44197(11) 0.0294(4) Uani 1 1 d . . . . .
H29 H 0.5332 0.0487 0.4147 0.035 Uiso 1 1 calc R U . . .
C30 C 0.65573(12) 0.07637(15) 0.43740(10) 0.0273(4) Uani 1 1 d . . . . .
H30 H 0.6460 0.1420 0.4074 0.033 Uiso 1 1 calc R U . . .
C31 C 0.73723(11) 0.03647(14) 0.47621(9) 0.0191(3) Uani 1 1 d . . . . .
H31 H 0.7830 0.0750 0.4731 0.023 Uiso 1 1 calc R U . . .
C32 C 0.81230(9) 0.40928(12) 0.60245(9) 0.0129(3) Uani 1 1 d . . . . .
C33 C 0.74202(10) 0.35116(14) 0.55139(10) 0.0181(3) Uani 1 1 d . . . . .
H33 H 0.7282 0.2820 0.5667 0.022 Uiso 1 1 calc R U . . .
C34 C 0.69218(11) 0.39368(15) 0.47843(10) 0.0230(4) Uani 1 1 d . . . . .
H34 H 0.6451 0.3526 0.4440 0.028 Uiso 1 1 calc R U . . .
C35 C 0.71010(11) 0.49525(15) 0.45509(10) 0.0221(4) Uani 1 1 d . . . . .
H35 H 0.6756 0.5239 0.4052 0.027 Uiso 1 1 calc R U . . .
C36 C 0.77915(11) 0.55433(14) 0.50571(10) 0.0188(3) Uani 1 1 d . . . . .
H36 H 0.7917 0.6244 0.4906 0.023 Uiso 1 1 calc R U . . .
C37 C 0.83018(10) 0.51183(13) 0.57839(9) 0.0150(3) Uani 1 1 d . . . . .
H37 H 0.8777 0.5527 0.6122 0.018 Uiso 1 1 calc R U . . .
Ge1 Ge 0.93261(2) -0.01924(2) 0.66515(2) 0.00892(4) Uani 1 1 d . . . . .
N1 N 1.03827(8) -0.05333(10) 0.66615(7) 0.0114(2) Uani 1 1 d . . . . .
N2 N 0.94967(8) -0.10454(10) 0.75382(7) 0.0110(2) Uani 1 1 d . . . . .
P1 P 0.99614(2) 0.21623(3) 0.61970(2) 0.01063(7) Uani 1 1 d . . . . .
P2 P 0.83044(2) 0.12210(3) 0.74997(2) 0.00975(7) Uani 1 1 d . . . . .
Pd1 Pd 0.90287(2) 0.16935(2) 0.67508(2) 0.00859(3) Uani 1 1 d . . . . .
S1 S 0.85243(2) -0.12333(3) 0.56101(2) 0.01662(8) Uani 1 1 d . . . . .
S2 S 0.87647(2) 0.35817(3) 0.69626(2) 0.01283(7) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge -1.0885 0.8855 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd 0.1215 3.9337 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 C3 C2 110.43(14) . . ?
C1 C3 P1 110.45(11) . . ?
C2 C3 P1 113.45(11) . . ?
C4 C6 C5 110.11(13) . . ?
C4 C6 P1 111.93(11) . . ?
C5 C6 P1 111.71(11) . . ?
C8 C7 P1 114.40(11) . . ?
C9 C8 N1 108.69(13) . . ?
C9 C8 C7 130.02(14) . . ?
N1 C8 C7 121.18(13) . . ?
C8 C9 C10 107.29(14) . . ?
C11 C10 C9 107.82(14) . . ?
C10 C11 N1 108.08(13) . . ?
C10 C11 C12 130.51(14) . . ?
N1 C11 C12 121.03(13) . . ?
C11 C12 C15 110.94(12) . . ?
C11 C12 C14 110.09(13) . . ?
C15 C12 C14 110.32(12) . . ?
C11 C12 C13 108.98(12) . . ?
C15 C12 C13 108.73(12) . . ?
C14 C12 C13 107.70(13) . . ?
C16 C15 N2 108.17(13) . . ?
C16 C15 C12 130.21(14) . . ?
N2 C15 C12 121.20(13) . . ?
C15 C16 C17 107.93(13) . . ?
C18 C17 C16 107.19(13) . . ?
C17 C18 N2 108.71(13) . . ?
C17 C18 C19 130.59(14) . . ?
N2 C18 C19 120.55(13) . . ?
C18 C19 P2 114.48(10) . . ?
C21 C20 C22 109.19(13) . . ?
C21 C20 P2 110.98(11) . . ?
C22 C20 P2 114.37(11) . . ?
C24 C23 C25 109.53(13) . . ?
C24 C23 P2 110.26(10) . . ?
C25 C23 P2 115.18(11) . . ?
C31 C26 C27 119.42(15) . . ?
C31 C26 S1 121.53(12) . . ?
C27 C26 S1 118.79(12) . . ?
C28 C27 C26 120.15(16) . . ?
C29 C28 C27 120.26(17) . . ?
C28 C29 C30 119.74(16) . . ?
C29 C30 C31 120.63(17) . . ?
C30 C31 C26 119.78(16) . . ?
C33 C32 C37 118.20(14) . . ?
C33 C32 S2 121.67(12) . . ?
C37 C32 S2 120.11(12) . . ?
C34 C33 C32 120.52(15) . . ?
C35 C34 C33 120.97(16) . . ?
C34 C35 C36 119.01(16) . . ?
C35 C36 C37 120.51(15) . . ?
C36 C37 C32 120.78(15) . . ?
N2 Ge1 N1 94.64(5) . . ?
N2 Ge1 S1 106.30(4) . . ?
N1 Ge1 S1 97.76(4) . . ?
N2 Ge1 Pd1 114.58(4) . . ?
N1 Ge1 Pd1 117.21(4) . . ?
S1 Ge1 Pd1 121.936(12) . . ?
C8 N1 C11 108.11(12) . . ?
C8 N1 Ge1 122.61(10) . . ?
C11 N1 Ge1 127.31(10) . . ?
C18 N2 C15 108.00(12) . . ?
C18 N2 Ge1 122.71(10) . . ?
C15 N2 Ge1 126.38(10) . . ?
C3 P1 C7 101.53(7) . . ?
C3 P1 C6 105.38(7) . . ?
C7 P1 C6 103.69(7) . . ?
C3 P1 Pd1 118.87(5) . . ?
C7 P1 Pd1 115.19(5) . . ?
C6 P1 Pd1 110.63(5) . . ?
C19 P2 C23 104.34(7) . . ?
C19 P2 C20 105.56(7) . . ?
C23 P2 C20 105.75(7) . . ?
C19 P2 Pd1 116.01(5) . . ?
C23 P2 Pd1 114.47(5) . . ?
C20 P2 Pd1 109.85(5) . . ?
P2 Pd1 P1 170.293(14) . . ?
P2 Pd1 Ge1 90.275(10) . . ?
P1 Pd1 Ge1 88.915(10) . . ?
P2 Pd1 S2 86.606(13) . . ?
P1 Pd1 S2 93.578(13) . . ?
Ge1 Pd1 S2 175.348(10) . . ?
C26 S1 Ge1 106.50(5) . . ?
C32 S2 Pd1 104.54(5) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C3 1.532(2) . ?
C2 C3 1.533(2) . ?
C3 P1 1.8496(16) . ?
C4 C6 1.531(2) . ?
C5 C6 1.537(2) . ?
C6 P1 1.8563(16) . ?
C7 C8 1.490(2) . ?
C7 P1 1.8500(15) . ?
C8 C9 1.369(2) . ?
C8 N1 1.3877(19) . ?
C9 C10 1.422(2) . ?
C10 C11 1.373(2) . ?
C11 N1 1.3904(19) . ?
C11 C12 1.512(2) . ?
C12 C15 1.515(2) . ?
C12 C14 1.537(2) . ?
C12 C13 1.548(2) . ?
C15 C16 1.369(2) . ?
C15 N2 1.3901(19) . ?
C16 C17 1.423(2) . ?
C17 C18 1.368(2) . ?
C18 N2 1.3897(19) . ?
C18 C19 1.500(2) . ?
C19 P2 1.8429(15) . ?
C20 C21 1.528(2) . ?
C20 C22 1.534(2) . ?
C20 P2 1.8581(16) . ?
C23 C24 1.532(2) . ?
C23 C25 1.532(2) . ?
C23 P2 1.8442(15) . ?
C26 C31 1.392(2) . ?
C26 C27 1.393(2) . ?
C26 S1 1.7785(15) . ?
C27 C28 1.390(2) . ?
C28 C29 1.381(3) . ?
C29 C30 1.381(3) . ?
C30 C31 1.390(2) . ?
C32 C33 1.397(2) . ?
C32 C37 1.403(2) . ?
C32 S2 1.7710(16) . ?
C33 C34 1.389(2) . ?
C34 C35 1.387(3) . ?
C35 C36 1.387(2) . ?
C36 C37 1.390(2) . ?
Ge1 N2 1.8869(12) . ?
Ge1 N1 1.8870(12) . ?
Ge1 S1 2.2673(4) . ?
Ge1 Pd1 2.36801(19) . ?
P1 Pd1 2.3488(4) . ?
P2 Pd1 2.3343(4) . ?
Pd1 S2 2.4003(4) . ?
