#------------------------------------------------------------------------------
#$Date: 2021-10-06 16:42:06 +0300 (Wed, 06 Oct 2021) $
#$Revision: 269604 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/12/89/7128937.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7128937
loop_
_publ_author_name
'He, Fengkai'
'Gourlaouen, Christophe'
'Pang, Huan'
'Braunstein, Pierre'
_publ_section_title
;
 Imidazolium salts and [Pt(cod)₂]: from NHC hydrido complexes
 to the unprecedented olefinic tetrahedral cluster
 [Pt₄(μ-H)(cod)₄]BF₄.
;
_journal_issue                   78
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              10039
_journal_page_last               10042
_journal_paper_doi               10.1039/d1cc03673d
_journal_volume                  57
_journal_year                    2021
_chemical_formula_moiety         'C22 H35 Cl N4 Pt'
_chemical_formula_sum            'C22 H35 Cl N4 Pt'
_chemical_formula_weight         586.08
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2021-06-29 deposited with the CCDC.	2021-09-03 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 112.646(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   14.6958(8)
_cell_length_b                   13.8722(7)
_cell_length_c                   12.7246(6)
_cell_measurement_reflns_used    9725
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      31.02
_cell_measurement_theta_min      2.27
_cell_volume                     2394.1(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX3'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker PHOTON-III CPAD'
_diffrn_measurement_method       'φ and ω shuterless scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0458
_diffrn_reflns_av_unetI/netI     0.0230
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            77110
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         31.058
_diffrn_reflns_theta_min         2.100
_diffrn_source                   'Mo-ImuS 3.0 microfocus tube'
_exptl_absorpt_coefficient_mu    5.987
_exptl_absorpt_correction_T_max  0.7462
_exptl_absorpt_correction_T_min  0.6041
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.626
_exptl_crystal_description       needle
_exptl_crystal_F_000             1160
_exptl_crystal_size_max          0.240
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.060
_refine_diff_density_max         0.598
_refine_diff_density_min         -0.894
_refine_diff_density_rms         0.113
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.069
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     264
_refine_ls_number_reflns         7659
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.069
_refine_ls_R_factor_all          0.0276
_refine_ls_R_factor_gt           0.0204
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0081P)²+2.9579P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0358
_refine_ls_wR_factor_ref         0.0386
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6696
_reflns_number_total             7659
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1cc03673d2.cif
_cod_data_source_block           dafh200302
_cod_depositor_comments
'Adding full bibliography for 7128934--7128937.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7128937
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.328
_shelx_estimated_absorpt_t_max   0.715
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.59204(15) 0.76574(15) 0.73142(18) 0.0161(4) Uani 1 1 d . . . . .
C2 C 0.59716(17) 0.89098(16) 0.61660(18) 0.0194(4) Uani 1 1 d . . . . .
H2 H 0.6173 0.9316 0.5694 0.023 Uiso 1 1 calc R U . . .
C3 C 0.51864(17) 0.90309(16) 0.64499(19) 0.0207(4) Uani 1 1 d . . . . .
H3 H 0.4724 0.9544 0.6210 0.025 Uiso 1 1 calc R U . . .
C4 C 0.72688(16) 0.75960(16) 0.67123(17) 0.0162(4) Uani 1 1 d . . . . .
C5 C 0.83017(15) 0.62446(15) 0.72827(17) 0.0151(4) Uani 1 1 d . . . . .
C6 C 0.81865(17) 0.56707(16) 0.63248(18) 0.0187(4) Uani 1 1 d . . . . .
C7 C 0.90135(18) 0.51596(17) 0.6355(2) 0.0246(5) Uani 1 1 d . . . . .
H7 H 0.8967 0.4765 0.5726 0.030 Uiso 1 1 calc R U . . .
C8 C 0.99001(19) 0.52159(17) 0.7282(2) 0.0260(5) Uani 1 1 d . . . . .
H8 H 1.0456 0.4871 0.7276 0.031 Uiso 1 1 calc R U . . .
C9 C 0.99834(17) 0.57706(16) 0.8217(2) 0.0213(5) Uani 1 1 d . . . . .
H9 H 1.0594 0.5793 0.8853 0.026 Uiso 1 1 calc R U . . .
C10 C 0.91826(16) 0.62971(15) 0.82384(18) 0.0172(4) Uani 1 1 d . . . . .
C11 C 0.78108(17) 0.80509(17) 0.6071(2) 0.0221(5) Uani 1 1 d . . . . .
H11A H 0.8431 0.7705 0.6229 0.033 Uiso 1 1 calc R U . . .
H11B H 0.7952 0.8725 0.6306 0.033 Uiso 1 1 calc R U . . .
H11C H 0.7407 0.8023 0.5253 0.033 Uiso 1 1 calc R U . . .
C12 C 0.72017(18) 0.55954(18) 0.53199(19) 0.0233(5) Uani 1 1 d . . . . .
H12 H 0.6883 0.6245 0.5212 0.028 Uiso 1 1 calc R U . . .
C13 C 0.6516(2) 0.4888(2) 0.5570(2) 0.0381(7) Uani 1 1 d . . . . .
H13A H 0.6810 0.4242 0.5688 0.057 Uiso 1 1 calc R U . . .
H13B H 0.5879 0.4874 0.4925 0.057 Uiso 1 1 calc R U . . .
H13C H 0.6421 0.5092 0.6257 0.057 Uiso 1 1 calc R U . . .
C14 C 0.7305(2) 0.5333(2) 0.4207(2) 0.0401(7) Uani 1 1 d . . . . .
H14A H 0.7748 0.5793 0.4059 0.060 Uiso 1 1 calc R U . . .
H14B H 0.6656 0.5356 0.3581 0.060 Uiso 1 1 calc R U . . .
H14C H 0.7577 0.4681 0.4265 0.060 Uiso 1 1 calc R U . . .
C15 C 0.92744(16) 0.69322(16) 0.92482(18) 0.0192(4) Uani 1 1 d . . . . .
H15 H 0.8600 0.7003 0.9255 0.023 Uiso 1 1 calc R U . . .
C16 C 0.9931(2) 0.6494(2) 1.0384(2) 0.0340(6) Uani 1 1 d . . . . .
H16A H 0.9681 0.5854 1.0462 0.051 Uiso 1 1 calc R U . . .
H16B H 0.9929 0.6910 1.1006 0.051 Uiso 1 1 calc R U . . .
H16C H 1.0605 0.6435 1.0415 0.051 Uiso 1 1 calc R U . . .
C17 C 0.9635(2) 0.79417(19) 0.9117(2) 0.0343(6) Uani 1 1 d . . . . .
H17A H 1.0291 0.7897 0.9089 0.051 Uiso 1 1 calc R U . . .
H17B H 0.9670 0.8341 0.9766 0.051 Uiso 1 1 calc R U . . .
H17C H 0.9176 0.8234 0.8411 0.051 Uiso 1 1 calc R U . . .
C18 C 0.43839(16) 0.81152(17) 0.7582(2) 0.0212(4) Uani 1 1 d . . . . .
H18A H 0.4112 0.8746 0.7681 0.025 Uiso 1 1 calc R U . . .
H18B H 0.4656 0.7792 0.8334 0.025 Uiso 1 1 calc R U . . .
C19 C 0.35661(18) 0.74992(19) 0.6751(2) 0.0251(5) Uani 1 1 d . . . . .
H19A H 0.3418 0.7727 0.5965 0.030 Uiso 1 1 calc R U . . .
H19B H 0.3793 0.6823 0.6803 0.030 Uiso 1 1 calc R U . . .
C20 C 0.26317(17) 0.75412(19) 0.6995(2) 0.0263(5) Uani 1 1 d . . . . .
H20A H 0.2356 0.8201 0.6834 0.032 Uiso 1 1 calc R U . . .
H20B H 0.2139 0.7095 0.6473 0.032 Uiso 1 1 calc R U . . .
C21 C 0.18910(19) 0.7494(2) 0.8361(2) 0.0332(6) Uani 1 1 d . . . . .
H21A H 0.1346 0.7109 0.7835 0.050 Uiso 1 1 calc R U . . .
H21B H 0.1731 0.8180 0.8228 0.050 Uiso 1 1 calc R U . . .
H21C H 0.1993 0.7330 0.9147 0.050 Uiso 1 1 calc R U . . .
C22 C 0.3056(2) 0.62814(18) 0.8407(2) 0.0315(6) Uani 1 1 d . . . . .
H22A H 0.2544 0.5875 0.7864 0.047 Uiso 1 1 calc R U . . .
H22B H 0.3118 0.6127 0.9183 0.047 Uiso 1 1 calc R U . . .
H22C H 0.3687 0.6162 0.8335 0.047 Uiso 1 1 calc R U . . .
N1 N 0.64272(14) 0.80658(13) 0.67076(15) 0.0169(4) Uani 1 1 d . . . . .
N2 N 0.51735(14) 0.82663(13) 0.71606(16) 0.0186(4) Uani 1 1 d . . . . .
N3 N 0.74717(13) 0.68021(13) 0.72783(14) 0.0140(3) Uani 1 1 d . . . . .
N4 N 0.27885(15) 0.72890(15) 0.81689(18) 0.0238(4) Uani 1 1 d . . . . .
Cl1 Cl 0.72388(4) 0.50604(4) 0.90289(4) 0.01920(10) Uani 1 1 d . . . . .
Pt1 Pt 0.64576(2) 0.64729(2) 0.80927(2) 0.01399(2) Uani 1 1 d . . . . .
H1 H 0.5612(19) 0.6322(19) 0.862(2) 0.025(7) Uiso 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 C1 N1 104.33(18) . . ?
N2 C1 Pt1 139.90(16) . . ?
N1 C1 Pt1 115.76(15) . . ?
C3 C2 N1 105.70(19) . . ?
C3 C2 H2 127.2 . . ?
N1 C2 H2 127.2 . . ?
C2 C3 N2 107.78(19) . . ?
C2 C3 H3 126.1 . . ?
N2 C3 H3 126.1 . . ?
N3 C4 N1 114.58(18) . . ?
N3 C4 C11 127.9(2) . . ?
N1 C4 C11 117.50(19) . . ?
C10 C5 C6 123.02(19) . . ?
C10 C5 N3 118.33(18) . . ?
C6 C5 N3 118.65(19) . . ?
C7 C6 C5 116.7(2) . . ?
C7 C6 C12 121.7(2) . . ?
C5 C6 C12 121.6(2) . . ?
C8 C7 C6 121.3(2) . . ?
C8 C7 H7 119.3 . . ?
C6 C7 H7 119.3 . . ?
C9 C8 C7 120.5(2) . . ?
C9 C8 H8 119.7 . . ?
C7 C8 H8 119.7 . . ?
C8 C9 C10 120.9(2) . . ?
C8 C9 H9 119.6 . . ?
C10 C9 H9 119.6 . . ?
C9 C10 C5 117.5(2) . . ?
C9 C10 C15 121.3(2) . . ?
C5 C10 C15 121.15(19) . . ?
C4 C11 H11A 109.5 . . ?
C4 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C4 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C6 C12 C13 111.1(2) . . ?
C6 C12 C14 113.2(2) . . ?
C13 C12 C14 110.5(2) . . ?
C6 C12 H12 107.3 . . ?
C13 C12 H12 107.3 . . ?
C14 C12 H12 107.3 . . ?
C12 C13 H13A 109.5 . . ?
C12 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C12 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C12 C14 H14A 109.5 . . ?
C12 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C12 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C10 C15 C16 112.9(2) . . ?
C10 C15 C17 111.09(18) . . ?
C16 C15 C17 110.5(2) . . ?
C10 C15 H15 107.4 . . ?
C16 C15 H15 107.4 . . ?
C17 C15 H15 107.4 . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
N2 C18 C19 110.49(18) . . ?
N2 C18 H18A 109.6 . . ?
C19 C18 H18A 109.6 . . ?
N2 C18 H18B 109.6 . . ?
C19 C18 H18B 109.6 . . ?
H18A C18 H18B 108.1 . . ?
C20 C19 C18 111.7(2) . . ?
C20 C19 H19A 109.3 . . ?
C18 C19 H19A 109.3 . . ?
C20 C19 H19B 109.3 . . ?
C18 C19 H19B 109.3 . . ?
H19A C19 H19B 107.9 . . ?
N4 C20 C19 113.55(19) . . ?
N4 C20 H20A 108.9 . . ?
C19 C20 H20A 108.9 . . ?
N4 C20 H20B 108.9 . . ?
C19 C20 H20B 108.9 . . ?
H20A C20 H20B 107.7 . . ?
N4 C21 H21A 109.5 . . ?
N4 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
N4 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
N4 C22 H22A 109.5 . . ?
N4 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
N4 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C1 N1 C2 111.16(18) . . ?
C1 N1 C4 118.22(18) . . ?
C2 N1 C4 130.61(18) . . ?
C1 N2 C3 111.01(18) . . ?
C1 N2 C18 125.13(19) . . ?
C3 N2 C18 123.61(19) . . ?
C4 N3 C5 118.32(17) . . ?
C4 N3 Pt1 113.24(14) . . ?
C5 N3 Pt1 128.43(13) . . ?
C22 N4 C21 110.0(2) . . ?
C22 N4 C20 111.5(2) . . ?
C21 N4 C20 109.1(2) . . ?
C1 Pt1 N3 78.18(8) . . ?
C1 Pt1 Cl1 175.18(6) . . ?
N3 Pt1 Cl1 97.27(5) . . ?
C1 Pt1 H1 95.4(9) . . ?
N3 Pt1 H1 173.4(9) . . ?
Cl1 Pt1 H1 89.2(9) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N2 1.338(3) . ?
C1 N1 1.383(3) . ?
C1 Pt1 1.924(2) . ?
C2 C3 1.346(3) . ?
C2 N1 1.392(3) . ?
C2 H2 0.9500 . ?
C3 N2 1.399(3) . ?
C3 H3 0.9500 . ?
C4 N3 1.286(3) . ?
C4 N1 1.396(3) . ?
C4 C11 1.483(3) . ?
C5 C10 1.396(3) . ?
C5 C6 1.410(3) . ?
C5 N3 1.443(3) . ?
C6 C7 1.395(3) . ?
C6 C12 1.522(3) . ?
C7 C8 1.383(4) . ?
C7 H7 0.9500 . ?
C8 C9 1.382(3) . ?
C8 H8 0.9500 . ?
C9 C10 1.394(3) . ?
C9 H9 0.9500 . ?
C10 C15 1.521(3) . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 C13 1.525(4) . ?
C12 C14 1.525(3) . ?
C12 H12 1.0000 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 C16 1.522(3) . ?
C15 C17 1.529(3) . ?
C15 H15 1.0000 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 N2 1.469(3) . ?
C18 C19 1.521(3) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C19 C20 1.521(3) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C20 N4 1.463(3) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C21 N4 1.459(3) . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 N4 1.452(3) . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
N3 Pt1 2.1662(16) . ?
Cl1 Pt1 2.3502(5) . ?
Pt1 H1 1.63(3) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C2 C3 N2 0.2(2) . . . . ?
C10 C5 C6 C7 -1.5(3) . . . . ?
N3 C5 C6 C7 178.68(19) . . . . ?
C10 C5 C6 C12 177.2(2) . . . . ?
N3 C5 C6 C12 -2.7(3) . . . . ?
C5 C6 C7 C8 0.0(3) . . . . ?
C12 C6 C7 C8 -178.6(2) . . . . ?
C6 C7 C8 C9 1.2(4) . . . . ?
C7 C8 C9 C10 -1.1(4) . . . . ?
C8 C9 C10 C5 -0.3(3) . . . . ?
C8 C9 C10 C15 -178.2(2) . . . . ?
C6 C5 C10 C9 1.6(3) . . . . ?
N3 C5 C10 C9 -178.57(18) . . . . ?
C6 C5 C10 C15 179.53(19) . . . . ?
N3 C5 C10 C15 -0.6(3) . . . . ?
C7 C6 C12 C13 98.4(3) . . . . ?
C5 C6 C12 C13 -80.1(3) . . . . ?
C7 C6 C12 C14 -26.5(3) . . . . ?
C5 C6 C12 C14 154.9(2) . . . . ?
C9 C10 C15 C16 -37.6(3) . . . . ?
C5 C10 C15 C16 144.5(2) . . . . ?
C9 C10 C15 C17 87.1(3) . . . . ?
C5 C10 C15 C17 -90.8(3) . . . . ?
N2 C18 C19 C20 -165.31(19) . . . . ?
C18 C19 C20 N4 -54.5(3) . . . . ?
N2 C1 N1 C2 -1.4(2) . . . . ?
Pt1 C1 N1 C2 179.19(15) . . . . ?
N2 C1 N1 C4 179.28(18) . . . . ?
Pt1 C1 N1 C4 -0.1(2) . . . . ?
C3 C2 N1 C1 0.7(3) . . . . ?
C3 C2 N1 C4 179.9(2) . . . . ?
N3 C4 N1 C1 1.4(3) . . . . ?
C11 C4 N1 C1 -179.18(19) . . . . ?
N3 C4 N1 C2 -177.7(2) . . . . ?
C11 C4 N1 C2 1.7(3) . . . . ?
N1 C1 N2 C3 1.5(2) . . . . ?
Pt1 C1 N2 C3 -179.3(2) . . . . ?
N1 C1 N2 C18 175.95(19) . . . . ?
Pt1 C1 N2 C18 -4.9(4) . . . . ?
C2 C3 N2 C1 -1.1(3) . . . . ?
C2 C3 N2 C18 -175.7(2) . . . . ?
C19 C18 N2 C1 -84.7(3) . . . . ?
C19 C18 N2 C3 89.0(3) . . . . ?
N1 C4 N3 C5 177.02(18) . . . . ?
C11 C4 N3 C5 -2.3(3) . . . . ?
N1 C4 N3 Pt1 -1.9(2) . . . . ?
C11 C4 N3 Pt1 178.80(18) . . . . ?
C10 C5 N3 C4 101.6(2) . . . . ?
C6 C5 N3 C4 -78.6(3) . . . . ?
C10 C5 N3 Pt1 -79.8(2) . . . . ?
C6 C5 N3 Pt1 100.1(2) . . . . ?
C19 C20 N4 C22 -66.9(3) . . . . ?
C19 C20 N4 C21 171.3(2) . . . . ?
