#------------------------------------------------------------------------------
#$Date: 2022-06-16 00:53:53 +0300 (Thu, 16 Jun 2022) $
#$Revision: 276050 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/13/02/7130227.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7130227
loop_
_publ_author_name
'Tanioka, Masaru'
'Kuromiya, Ayako'
'Ueda, Rina'
'Obata, Tohru'
'Muranaka, Atsuya'
'Uchiyama, Masanobu'
'Kamino, Shinichiro'
_publ_section_title
;
 Bridged eosin Y: A visible and near-infrared photoredox catalyst
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/D2CC02907C
_journal_year                    2022
_chemical_formula_moiety         'C20 H7 Br3 O5'
_chemical_formula_sum            'C20 H7 Br3 O5'
_chemical_formula_weight         566.99
_chemical_name_common            'bridged eosin Y'
_chemical_name_systematic        'bridged eosin Y'
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2020-10-30
_audit_creation_method
;
Olex2 1.3-ac4
(compiled 2019.04.23 svn.r3594 for Rigaku Oxford Diffraction, GUI svn.r5739)
;
_audit_update_record
;
2022-04-07 deposited with the CCDC.	2022-06-15 downloaded from the CCDC.
;
_cell_angle_alpha                68.286(5)
_cell_angle_beta                 76.020(4)
_cell_angle_gamma                83.671(4)
_cell_formula_units_Z            2
_cell_length_a                   7.9825(4)
_cell_length_b                   9.6307(5)
_cell_length_c                   12.1546(6)
_cell_measurement_reflns_used    4026
_cell_measurement_temperature    103.15
_cell_measurement_theta_max      68.0090
_cell_measurement_theta_min      4.9440
_cell_volume                     842.17(8)
_computing_cell_refinement       'CrysAlisPro 1.171.40.84a (Rigaku OD, 2020)'
_computing_data_collection       'CrysAlisPro 1.171.40.84a (Rigaku OD, 2020)'
_computing_data_reduction        'CrysAlisPro 1.171.40.84a (Rigaku OD, 2020)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      103.15
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix3000
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     -9.00  42.00   0.50    0.24    --   41.13 -37.00  60.00  102
  2  ω     12.00  62.00   0.50    0.24    --   41.13 -63.00 120.00  100
  3  ω     41.00  72.00   0.50    0.24    --   41.13-104.00  90.00   62
  4  ω     31.00  57.00   0.50    0.95    --   95.43 -50.00 120.00   52
  5  ω     72.00 101.00   0.50    0.95    --   95.43 -77.00  90.00   58
  6  ω     38.00  68.00   0.50    0.24    --   41.13 -91.00 -30.00   60
  7  ω     39.00  76.00   0.50    0.95    --   95.43 -80.00-137.00   74
  8  ω     41.00  67.00   0.50    0.95    --   95.43 -59.00-120.00   52
  9  ω     29.00  55.00   0.50    0.95    --   95.43 -50.00-150.00   52
 10  ω     29.00  54.00   0.50    0.95    --   95.43 -50.00 -90.00   50
 11  ω     36.00  94.00   0.50    0.95    --   95.43-117.00 -60.00  116
 12  ω     69.00  94.00   0.50    0.24    --   41.13-138.00-150.00   50
 13  ω     21.00  46.00   0.50    0.24    --   41.13-138.00-150.00   50
 14  ω    -26.00  33.00   0.50    0.24    --   41.13 -91.00 -30.00  118
 15  ω     30.00  73.00   0.50    0.95    --   95.43 -77.00  60.00   86
 16  ω     11.00  37.00   0.50    0.24    --   41.13-104.00  90.00   52
 17  ω    -20.00  29.00   0.50    0.24    --  -41.44  12.00  90.00   98
 18  ω    -18.00  12.00   0.50    0.24    --  -41.44  80.00 -13.00   60
 19  ω    -51.00 -26.00   0.50    0.24    --  -41.44  80.00 -13.00   50
 20  ω    -66.00 -41.00   0.50    0.95    --  -95.75  59.00 -30.00   50
 21  ω    -57.00 -32.00   0.50    0.95    --  -95.75  50.00   0.00   50
 22  ω    -61.00 -35.00   0.50    0.95    --  -95.75 117.00  60.00   52
 23  ω    -57.00 -31.00   0.50    0.95    --  -95.75  50.00 120.00   52
 24  ω    -22.00  13.00   0.50    0.24    --  -41.44  37.00 120.00   70
 25  ω     49.00  87.00   0.50    0.24    --   41.13  80.00 -13.00   76
 26  ω     79.00 142.00   0.50    0.95    --   95.43  42.00 -30.00  126
 27  ω    128.00 161.00   0.50    0.95    --   95.43  68.00  60.00   66
 28  ω    123.00 148.00   0.50    0.95    --   95.43  77.00 120.00   50
 29  ω     94.00 120.00   0.50    0.95    --   95.43  68.00  60.00   52
 30  ω     82.00 117.00   0.50    0.95    --   95.43  80.00 -13.00   70
 31  ω     69.00 106.00   0.50    0.95    --   95.43  77.00 120.00   74
 32  ω    -28.00  39.00   0.50    0.24    --   41.13 -80.00-137.00  134
 33  ω    -18.00  26.00   0.50    0.24    --   41.13 -25.00-150.00   88
 34  ω     82.00 163.00   0.50    0.95    --   95.43  33.00-180.00  162
 35  ω    -57.00 -32.00   0.50    0.95    --  -95.75  50.00-180.00   50
 36  ω    -83.00 -29.00   0.50    0.95    --  -95.75  68.00-180.00  108
 37  ω    -97.00 -30.00   0.50    0.95    --  -95.75 117.00 -30.00  134
 38  ω    -97.00 -65.00   0.50    0.95    --  -95.75 117.00  60.00   64
 39  ω    -92.00 -67.00   0.50    0.95    --  -95.75  80.00 -13.00   50
 40  ω   -104.00 -32.00   0.50    0.95    --  -95.75 117.00 -60.00  144
 41  ω   -125.00 -35.00   0.50    0.95    --  -95.75 141.00 -30.15  180
 42  ω   -106.00 -29.00   0.50    0.95    --  -95.75 117.00 150.00  154
 43  ω   -125.00 -27.00   0.50    0.95    --  -95.75 145.00 150.00  196
 44  ω    -96.00 -71.00   0.50    0.95    --  -95.75 -17.00 120.00   50
 45  ω   -110.00 -79.00   0.50    0.95    --  -95.75 -42.00  90.00   62
 46  ω    -56.00 -29.00   0.50    0.24    --  -41.44 -50.00 120.00   54
 47  ω   -104.00 -76.00   0.50    0.24    --  -41.44 -50.00 120.00   56
 48  ω    -96.00 -71.00   0.50    0.24    --  -41.44-138.00 120.00   50
 49  ω   -156.00-113.00   0.50    0.95    --  -95.75 -42.00  90.00   86
 50  ω   -161.00-116.00   0.50    0.95    --  -95.75 -17.00 120.00   90
 51  ω   -145.00 -84.00   0.50    0.95    --  -95.75 -96.00 -90.00  122
 52  ω   -112.00 -84.00   0.50    0.95    --  -95.75 -80.00-137.00   56
 53  ω   -110.00 -73.00   0.50    0.24    --  -41.44 -80.00-137.00   74
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type
'XtaLAB Synergy, Single source at home/near, HyPix3000'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.1740421000
_diffrn_orient_matrix_UB_12      -0.0753729000
_diffrn_orient_matrix_UB_13      0.0297260000
_diffrn_orient_matrix_UB_21      -0.0449559000
_diffrn_orient_matrix_UB_22      0.1169180000
_diffrn_orient_matrix_UB_23      -0.1163081000
_diffrn_orient_matrix_UB_31      0.0852317000
_diffrn_orient_matrix_UB_32      -0.1015431000
_diffrn_orient_matrix_UB_33      -0.0715902000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0353
_diffrn_reflns_av_unetI/netI     0.0403
_diffrn_reflns_Laue_measured_fraction_full 0.993
_diffrn_reflns_Laue_measured_fraction_max 0.986
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            6805
_diffrn_reflns_point_group_measured_fraction_full 0.993
_diffrn_reflns_point_group_measured_fraction_max 0.986
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         68.408
_diffrn_reflns_theta_min         4.011
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'PhotonJet (Cu) X-ray Source'
_exptl_absorpt_coefficient_mu    9.196
_exptl_absorpt_correction_T_max  0.895
_exptl_absorpt_correction_T_min  0.447
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.40.84a (Rigaku Oxford Diffraction, 2020)
Numerical absorption correction based on gaussian integration over
a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'metallic dark black'
_exptl_crystal_colour_lustre     metallic
_exptl_crystal_colour_modifier   dark
_exptl_crystal_colour_primary    black
_exptl_crystal_density_diffrn    2.236
_exptl_crystal_description       plate
_exptl_crystal_F_000             544
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: CHCl3/Et2O'
_exptl_crystal_size_max          0.129
_exptl_crystal_size_mid          0.099
_exptl_crystal_size_min          0.033
_refine_diff_density_max         0.685
_refine_diff_density_min         -1.012
_refine_diff_density_rms         0.132
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.105
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     255
_refine_ls_number_reflns         3051
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.105
_refine_ls_R_factor_all          0.0401
_refine_ls_R_factor_gt           0.0376
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0651P)²+0.2908P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1034
_refine_ls_wR_factor_ref         0.1055
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2788
_reflns_number_total             3051
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2cc02907c2.cif
_cod_data_source_block           bey_1030
_cod_database_code               7130227
_shelx_shelxl_version_number     2018/3
_chemical_oxdiff_formula         'C40 H10 Br6 O10 '
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_diffrn_oxdiff_digest_frames
;
014c042441cbf784b05a58b8aa6e2b3b76042949a36
;
_diffrn_oxdiff_digest_hkl
;
01907412a1eb38ad94eff3f063f7698015342f
;
_reflns_odcompleteness_completeness 99.70
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C18(H18), C16(H16), C15(H15), C17(H17), C5(H5A)
2.b Idealised tetrahedral OH refined as rotating group:
 O5(H5), O2(H2)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.530
_oxdiff_exptl_absorpt_empirical_full_min 0.769
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Br3 Br 1.00770(5) -0.05855(4) 0.22157(4) 0.02644(15) Uani 1 1 d . . . . .
Br1 Br 0.93879(5) 0.32816(4) -0.09052(3) 0.02651(15) Uani 1 1 d . . . . .
Br2 Br 0.56195(6) 0.85190(4) -0.05115(4) 0.03007(15) Uani 1 1 d . . . . .
O1 O 0.7917(4) 0.2166(3) 0.1725(2) 0.0230(6) Uani 1 1 d . . . . .
O3 O 0.7159(4) -0.0702(3) 0.6601(2) 0.0262(6) Uani 1 1 d . . . . .
O5 O 0.5028(4) 0.1297(3) 0.7005(2) 0.0260(6) Uani 1 1 d . . . . .
H5 H 0.565684 0.052128 0.716937 0.039 Uiso 1 1 calc GR . . . .
O2 O 0.8054(4) 0.6437(3) -0.1781(2) 0.0276(6) Uani 1 1 d . . . . .
H2 H 0.767055 0.732020 -0.203184 0.041 Uiso 1 1 calc GR . . . .
O4 O 0.9458(4) -0.1734(3) 0.5020(3) 0.0274(6) Uani 1 1 d . . . . .
C3 C 0.7416(5) 0.5807(4) -0.0587(3) 0.0225(8) Uani 1 1 d . . . . .
C18 C 0.2914(5) 0.3735(4) 0.6194(4) 0.0216(7) Uani 1 1 d . . . . .
H18 H 0.283143 0.324345 0.704102 0.026 Uiso 1 1 calc R . . . .
C16 C 0.1900(5) 0.5593(4) 0.4539(4) 0.0226(8) Uani 1 1 d . . . . .
H16 H 0.114746 0.641548 0.425012 0.027 Uiso 1 1 calc R . . . .
C15 C 0.3008(5) 0.5053(4) 0.3724(4) 0.0222(7) Uani 1 1 d . . . . .
H15 H 0.294065 0.545321 0.289475 0.027 Uiso 1 1 calc R . . . .
C19 C 0.4110(5) 0.3212(4) 0.5371(3) 0.0211(7) Uani 1 1 d . . . . .
C7 C 0.5598(5) 0.3429(4) 0.3258(3) 0.0213(8) Uani 1 1 d . . . . .
C9 C 0.6295(5) 0.1331(4) 0.5020(3) 0.0201(7) Uani 1 1 d . . . . .
C14 C 0.4246(5) 0.3912(4) 0.4098(3) 0.0193(7) Uani 1 1 d . . . . .
C13 C 0.7704(5) 0.1477(4) 0.2939(3) 0.0220(8) Uani 1 1 d . . . . .
C17 C 0.1857(5) 0.4962(4) 0.5777(4) 0.0227(8) Uani 1 1 d . . . . .
H17 H 0.111211 0.536873 0.632617 0.027 Uiso 1 1 calc R . . . .
C20 C 0.5179(5) 0.1908(4) 0.5812(3) 0.0224(8) Uani 1 1 d . . . . .
C8 C 0.6508(5) 0.2108(4) 0.3739(4) 0.0212(7) Uani 1 1 d . . . . .
C1 C 0.7281(5) 0.3592(4) 0.1250(3) 0.0203(7) Uani 1 1 d . . . . .
C12 C 0.8621(5) 0.0177(4) 0.3338(3) 0.0216(7) Uani 1 1 d . . . . .
C5 C 0.5725(5) 0.5788(4) 0.1381(3) 0.0207(7) Uani 1 1 d . . . . .
H5A H 0.501375 0.632789 0.184194 0.025 Uiso 1 1 calc R . . . .
C10 C 0.7289(5) -0.0019(4) 0.5491(4) 0.0229(8) Uani 1 1 d . . . . .
C11 C 0.8564(5) -0.0634(4) 0.4608(4) 0.0232(8) Uani 1 1 d . . . . .
C2 C 0.7893(5) 0.4316(4) 0.0003(3) 0.0218(8) Uani 1 1 d . . . . .
C4 C 0.6321(5) 0.6503(4) 0.0157(3) 0.0230(8) Uani 1 1 d . . . . .
C6 C 0.6142(5) 0.4279(4) 0.1969(3) 0.0205(7) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.6763 1.2805 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
3 -3 4 0.0825
2 -5 -5 0.0632
-1 -3 -8 0.0497
-3 4 -1 0.0528
-1 5 6 0.0403
4 4 0 0.0038
-2 4 5 0.0422
4 -4 0 0.0672
2 3 8 0.0431
-1 -4 4 0.0571
-4 -3 1 0.0229
-4 -5 -5 0.0323
-5 0 0 0.0340
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C13 O1 C1 120.2(3) . . ?
O2 C3 C2 118.2(3) . . ?
O2 C3 C4 126.3(4) . . ?
C4 C3 C2 115.6(3) . . ?
C17 C18 C19 120.3(4) . . ?
C15 C16 C17 121.5(4) . . ?
C16 C15 C14 121.2(4) . . ?
C18 C19 C14 121.1(3) . . ?
C18 C19 C20 120.0(4) . . ?
C14 C19 C20 118.8(3) . . ?
C8 C7 C14 117.6(3) . . ?
C8 C7 C6 117.6(3) . . ?
C6 C7 C14 124.7(3) . . ?
C20 C9 C8 119.6(3) . . ?
C20 C9 C10 119.6(3) . . ?
C8 C9 C10 120.7(3) . . ?
C15 C14 C19 116.3(3) . . ?
C15 C14 C7 123.6(3) . . ?
C19 C14 C7 120.0(3) . . ?
O1 C13 C8 119.6(3) . . ?
O1 C13 C12 116.8(3) . . ?
C12 C13 C8 123.5(4) . . ?
C18 C17 C16 118.9(3) . . ?
O5 C20 C19 117.0(3) . . ?
O5 C20 C9 122.2(3) . . ?
C9 C20 C19 120.8(3) . . ?
C7 C8 C9 122.1(3) . . ?
C7 C8 C13 120.0(4) . . ?
C9 C8 C13 117.9(3) . . ?
O1 C1 C2 115.3(3) . . ?
O1 C1 C6 122.1(3) . . ?
C6 C1 C2 122.6(3) . . ?
C13 C12 Br3 120.0(3) . . ?
C13 C12 C11 122.3(3) . . ?
C11 C12 Br3 117.7(3) . . ?
C4 C5 C6 121.6(3) . . ?
O3 C10 C9 122.2(3) . . ?
O3 C10 C11 118.3(3) . . ?
C9 C10 C11 119.5(3) . . ?
O4 C11 C12 125.5(3) . . ?
O4 C11 C10 118.7(4) . . ?
C12 C11 C10 115.8(3) . . ?
C3 C2 Br1 119.2(3) . . ?
C1 C2 Br1 119.7(3) . . ?
C1 C2 C3 121.1(3) . . ?
C3 C4 Br2 120.0(3) . . ?
C5 C4 Br2 116.9(3) . . ?
C5 C4 C3 123.1(4) . . ?
C1 C6 C7 118.1(3) . . ?
C1 C6 C5 115.8(3) . . ?
C5 C6 C7 125.9(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Br3 C12 1.881(4) . ?
Br1 C2 1.884(4) . ?
Br2 C4 1.886(4) . ?
O1 C13 1.351(5) . ?
O1 C1 1.371(5) . ?
O3 C10 1.247(5) . ?
O5 C20 1.328(5) . ?
O2 C3 1.339(4) . ?
O4 C11 1.223(5) . ?
C3 C2 1.404(5) . ?
C3 C4 1.404(5) . ?
C18 C19 1.405(5) . ?
C18 C17 1.382(6) . ?
C16 C15 1.375(5) . ?
C16 C17 1.392(6) . ?
C15 C14 1.414(5) . ?
C19 C14 1.422(5) . ?
C19 C20 1.442(5) . ?
C7 C14 1.460(5) . ?
C7 C8 1.392(5) . ?
C7 C6 1.454(5) . ?
C9 C20 1.379(6) . ?
C9 C8 1.432(5) . ?
C9 C10 1.445(5) . ?
C13 C8 1.445(5) . ?
C13 C12 1.364(5) . ?
C1 C2 1.399(6) . ?
C1 C6 1.393(5) . ?
C12 C11 1.441(6) . ?
C5 C4 1.373(5) . ?
C5 C6 1.405(5) . ?
C10 C11 1.532(5) . ?
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
3.1847 -2.7668 4.0562 -0.2252 -0.9384 0.2620
1.5327 -5.1165 -4.7994 -0.0238 -0.1089 0.9938
-1.1928 -2.5315 -7.8834 0.1641 0.6746 0.7198
-3.0829 4.2700 -1.0875 0.1824 0.7643 -0.6185
-0.7487 4.6944 6.2599 -0.0374 -0.1456 -0.9886
4.0549 3.5199 -0.0401 -0.9722 0.2339 -0.0089
-1.7844 4.4147 5.4367 0.1394 -0.0360 -0.9896
3.7715 -3.7387 0.0048 -0.3745 -0.6072 0.7008
2.2180 3.0427 7.6601 -0.3877 -0.6349 -0.6683
-0.9605 -3.8769 3.5511 0.5649 -0.8231 0.0576
-4.1614 -3.0034 0.5903 0.9682 -0.2327 -0.0920
-3.7995 -4.5711 -4.5025 0.8720 0.1600 0.4627
-4.9394 -0.0127 0.4960 0.8754 0.1629 -0.4552
