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#$Date: 2024-02-04 13:15:10 +0200 (Sun, 04 Feb 2024) $
#$Revision: 289361 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/13/24/7132466.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7132466
loop_
_publ_author_name
'Titov, Aleksei A.'
'Smol'yakov, Alexander F.'
'Chernyadyev, Andrey Yu'
'Godovikov, Ivan A.'
'Filippov, Oleg A.'
'Shubina, Elena S.'
_publ_section_title
;
 Pyrazolate vs. phenylethynide: direct exchange of the anionic
 bridging ligand in a cyclic trinuclear silver complex.
;
_journal_issue                   7
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              847
_journal_page_last               850
_journal_paper_doi               10.1039/d3cc05659g
_journal_volume                  60
_journal_year                    2024
_chemical_formula_moiety         'C18 H7 Ag3 F12 N4'
_chemical_formula_sum            'C18 H7 Ag3 F12 N4'
_chemical_formula_weight         830.89
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2023-09-05
_audit_creation_method
;
Olex2 1.5
(compiled 2023.03.06 svn.rbb2c1857 for OlexSys, GUI svn.r6748)
;
_audit_update_record
;
2023-09-22 deposited with the CCDC.	2023-12-11 downloaded from the CCDC.
;
_cell_angle_alpha                116.4550(10)
_cell_angle_beta                 95.181(2)
_cell_angle_gamma                102.301(2)
_cell_formula_units_Z            2
_cell_length_a                   8.2213(5)
_cell_length_b                   12.3633(8)
_cell_length_c                   12.5168(8)
_cell_measurement_reflns_used    6408
_cell_measurement_temperature    100
_cell_measurement_theta_max      30.62
_cell_measurement_theta_min      2.59
_cell_volume                     1087.63(12)
_computing_cell_refinement       'SAINT v8.34A (Bruker, 2013)'
_computing_data_reduction        'SAINT v8.34A (Bruker, 2013)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_diffrn_ambient_temperature      100
_diffrn_detector_area_resol_mean 8
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0169
_diffrn_reflns_av_unetI/netI     0.0264
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            11538
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.000
_diffrn_reflns_theta_min         1.859
_diffrn_source                   'sealed tube'
_diffrn_source_current           30.0
_diffrn_source_power             1.5
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.793
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.6678
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2008/1 (Bruker,2008) was used for absorption correction.
wR2(int) was 0.0427 before and 0.0299 after correction.
The Ratio of minimum to maximum transmission is 0.8951.
The λ/2 correction factor is 0.0015.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    2.537
_exptl_crystal_description       prism
_exptl_crystal_F_000             784
_exptl_crystal_size_max          0.27
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.14
_refine_diff_density_max         1.815
_refine_diff_density_min         -1.041
_refine_diff_density_rms         0.119
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     361
_refine_ls_number_reflns         5780
_refine_ls_number_restraints     36
_refine_ls_restrained_S_all      1.114
_refine_ls_R_factor_all          0.0336
_refine_ls_R_factor_gt           0.0281
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0256P)²+2.5106P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0628
_refine_ls_wR_factor_ref         0.0660
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5048
_reflns_number_total             5780
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d3cc05659g2.cif
_cod_data_source_block           a
_cod_depositor_comments
'Adding full bibliography for 7132466--7132467.cif.'
_cod_database_code               7132466
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.696
_shelx_estimated_absorpt_t_min   0.519
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(F11R) \\sim Ueq, Uanis(F10R) \\sim Ueq, Uanis(F12R) \\sim Ueq: with sigma
of 0.001 and sigma for terminal atoms of 0.002
Uanis(F12) \\sim Ueq, Uanis(F10) \\sim Ueq, Uanis(F11) \\sim Ueq: with sigma of
0.001 and sigma for terminal atoms of 0.002
3. Others
 Fixed Sof: F10(0.25) F10R(0.75) F11(0.25) F11R(0.75) F12(0.25) F12R(0.75)
4.a Aromatic/amide H refined with riding coordinates:
 C4(H4), C5(H5), C6(H6), C7(H7), C8(H8), C10(H10), C13(H13)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.16229(3) 0.42617(2) 0.46246(2) 0.02078(6) Uani 1 1 d . . . . .
Ag2 Ag 0.33967(3) 0.68031(2) 0.60794(2) 0.01983(6) Uani 1 1 d . . . . .
Ag3 Ag 0.49294(3) 0.53005(2) 0.35492(2) 0.02355(6) Uani 1 1 d . . . . .
F1 F -0.0312(3) 0.1499(2) 0.34883(18) 0.0325(5) Uani 1 1 d . . . . .
F2 F -0.1607(2) 0.1097(2) 0.17266(19) 0.0302(4) Uani 1 1 d . . . . .
F3 F -0.0289(3) -0.01720(19) 0.1865(2) 0.0330(5) Uani 1 1 d . . . . .
F4 F 0.5894(3) 0.1921(2) 0.0708(2) 0.0332(5) Uani 1 1 d . . . . .
F5 F 0.3985(3) 0.2051(2) -0.04843(17) 0.0339(5) Uani 1 1 d . . . . .
F6 F 0.5599(3) 0.37380(19) 0.10768(19) 0.0305(4) Uani 1 1 d . . . . .
F7 F 0.9474(3) 0.7543(3) 0.3911(2) 0.0507(7) Uani 1 1 d . . . . .
F8 F 0.7226(4) 0.6770(3) 0.2542(2) 0.0707(11) Uani 1 1 d . . . . .
F9 F 0.8654(3) 0.8712(3) 0.3304(3) 0.0512(7) Uani 1 1 d . . . . .
F10 F 0.586(2) 1.0040(16) 0.8061(15) 0.080(4) Uani 0.25 1 d . U P A 2
F10R F 0.4945(5) 0.9602(3) 0.7901(3) 0.0397(7) Uani 0.75 1 d . U P A 1
F11 F 0.3770(10) 0.9993(8) 0.6839(7) 0.0236(16) Uani 0.25 1 d . U P A 2
F11R F 0.4517(7) 1.0623(5) 0.6955(4) 0.0735(13) Uani 0.75 1 d . U P A 1
F12 F 0.6008(16) 1.1202(11) 0.7198(11) 0.056(3) Uani 0.25 1 d . U P A 2
F12R F 0.6930(5) 1.1009(3) 0.7968(3) 0.0562(9) Uani 0.75 1 d . U P A 1
N1 N 0.2177(3) 0.2960(2) 0.2968(2) 0.0172(5) Uani 1 1 d . . . . .
N2 N 0.3490(3) 0.3376(2) 0.2532(2) 0.0181(5) Uani 1 1 d . . . . .
N3 N 0.5883(3) 0.7291(2) 0.4621(2) 0.0198(5) Uani 1 1 d . . . . .
N4 N 0.5216(3) 0.7908(2) 0.5598(2) 0.0196(5) Uani 1 1 d . . . . .
C1 C 0.1548(4) 0.5613(3) 0.6411(3) 0.0213(6) Uani 1 1 d . . . . .
C2 C 0.0730(4) 0.5499(3) 0.7138(3) 0.0201(6) Uani 1 1 d . . . . .
C3 C -0.0275(4) 0.5398(3) 0.7993(3) 0.0193(6) Uani 1 1 d . . . . .
C4 C 0.0036(4) 0.6416(3) 0.9167(3) 0.0236(6) Uani 1 1 d . . . . .
H4 H 0.093829 0.715673 0.941207 0.028 Uiso 1 1 calc R U . . .
C5 C -0.0980(5) 0.6338(4) 0.9973(3) 0.0291(7) Uani 1 1 d . . . . .
H5 H -0.078324 0.703456 1.076599 0.035 Uiso 1 1 calc R U . . .
C6 C -0.2273(5) 0.5257(4) 0.9630(3) 0.0308(8) Uani 1 1 d . . . . .
H6 H -0.295566 0.520952 1.018958 0.037 Uiso 1 1 calc R U . . .
C7 C -0.2581(4) 0.4243(4) 0.8476(4) 0.0289(7) Uani 1 1 d . . . . .
H7 H -0.347088 0.349980 0.824925 0.035 Uiso 1 1 calc R U . . .
C8 C -0.1600(4) 0.4300(3) 0.7645(3) 0.0242(6) Uani 1 1 d . . . . .
H8 H -0.182198 0.360361 0.684980 0.029 Uiso 1 1 calc R U . . .
C9 C 0.1385(4) 0.1754(3) 0.2151(3) 0.0181(6) Uani 1 1 d . . . . .
C10 C 0.2153(4) 0.1357(3) 0.1162(3) 0.0212(6) Uani 1 1 d . . . . .
H10 H 0.185221 0.055137 0.045836 0.025 Uiso 1 1 calc R U . . .
C11 C 0.3463(4) 0.2408(3) 0.1439(3) 0.0183(6) Uani 1 1 d . . . . .
C12 C 0.7059(4) 0.8168(3) 0.4526(3) 0.0200(6) Uani 1 1 d . . . . .
C13 C 0.7190(4) 0.9361(3) 0.5443(3) 0.0251(7) Uani 1 1 d . . . . .
H13 H 0.791750 1.014413 0.559142 0.030 Uiso 1 1 calc R U . . .
C14 C 0.6006(4) 0.9139(3) 0.6092(3) 0.0225(6) Uani 1 1 d . . . . .
C15 C -0.0190(4) 0.1049(3) 0.2320(3) 0.0230(6) Uani 1 1 d . . . . .
C16 C 0.4732(4) 0.2541(3) 0.0690(3) 0.0214(6) Uani 1 1 d . . . . .
C17 C 0.8075(4) 0.7794(3) 0.3563(3) 0.0261(7) Uani 1 1 d . . . . .
C18 C 0.5542(5) 1.0089(3) 0.7184(4) 0.0307(8) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag2 Ag1 Ag3 67.196(9) . 2_666 ?
N1 Ag1 Ag2 126.55(7) . . ?
N1 Ag1 Ag3 96.77(7) . 2_666 ?
C1 Ag1 Ag2 47.89(9) . . ?
C1 Ag1 Ag3 72.91(9) . 2_666 ?
C1 Ag1 N1 169.45(11) . . ?
Ag1 Ag2 Ag3 63.067(9) . 2_666 ?
N4 Ag2 Ag1 126.52(7) . . ?
N4 Ag2 Ag3 108.92(7) . 2_666 ?
C1 Ag2 Ag1 49.23(8) . . ?
C1 Ag2 Ag3 70.77(9) . 2_666 ?
C1 Ag2 N4 175.58(11) . . ?
Ag1 Ag3 Ag2 49.738(8) 2_666 2_666 ?
N2 Ag3 Ag1 112.76(7) . 2_666 ?
N2 Ag3 Ag2 63.13(7) . 2_666 ?
N2 Ag3 N3 168.41(10) . . ?
N3 Ag3 Ag1 75.70(7) . 2_666 ?
N3 Ag3 Ag2 125.29(8) . 2_666 ?
N2 N1 Ag1 119.24(19) . . ?
C9 N1 Ag1 132.7(2) . . ?
C9 N1 N2 107.8(2) . . ?
N1 N2 Ag3 117.87(18) . . ?
C11 N2 Ag3 134.8(2) . . ?
C11 N2 N1 107.1(2) . . ?
N4 N3 Ag3 119.72(19) . . ?
C12 N3 Ag3 133.0(2) . . ?
C12 N3 N4 107.2(2) . . ?
N3 N4 Ag2 117.56(19) . . ?
C14 N4 Ag2 134.5(2) . . ?
C14 N4 N3 107.7(3) . . ?
Ag2 C1 Ag1 82.88(11) . . ?
C2 C1 Ag1 130.4(3) . . ?
C2 C1 Ag2 146.7(3) . . ?
C1 C2 C3 177.7(4) . . ?
C4 C3 C2 119.7(3) . . ?
C4 C3 C8 119.7(3) . . ?
C8 C3 C2 120.6(3) . . ?
C3 C4 H4 120.2 . . ?
C5 C4 C3 119.7(3) . . ?
C5 C4 H4 120.2 . . ?
C4 C5 H5 119.8 . . ?
C6 C5 C4 120.4(3) . . ?
C6 C5 H5 119.8 . . ?
C5 C6 H6 119.8 . . ?
C5 C6 C7 120.3(3) . . ?
C7 C6 H6 119.8 . . ?
C6 C7 H7 119.8 . . ?
C6 C7 C8 120.5(3) . . ?
C8 C7 H7 119.8 . . ?
C3 C8 H8 120.3 . . ?
C7 C8 C3 119.4(3) . . ?
C7 C8 H8 120.3 . . ?
N1 C9 C10 110.9(3) . . ?
N1 C9 C15 121.1(3) . . ?
C10 C9 C15 127.9(3) . . ?
C9 C10 H10 128.3 . . ?
C9 C10 C11 103.5(3) . . ?
C11 C10 H10 128.3 . . ?
N2 C11 C10 110.8(3) . . ?
N2 C11 C16 121.5(3) . . ?
C10 C11 C16 127.7(3) . . ?
N3 C12 C13 110.9(3) . . ?
N3 C12 C17 120.7(3) . . ?
C13 C12 C17 128.3(3) . . ?
C12 C13 H13 128.4 . . ?
C12 C13 C14 103.2(3) . . ?
C14 C13 H13 128.4 . . ?
N4 C14 C13 111.0(3) . . ?
N4 C14 C18 121.2(3) . . ?
C13 C14 C18 127.9(3) . . ?
F1 C15 F2 106.3(3) . . ?
F1 C15 C9 113.0(3) . . ?
F2 C15 C9 111.6(3) . . ?
F3 C15 F1 108.2(3) . . ?
F3 C15 F2 105.9(3) . . ?
F3 C15 C9 111.4(3) . . ?
F4 C16 C11 111.6(3) . . ?
F5 C16 F4 106.1(3) . . ?
F5 C16 C11 111.6(3) . . ?
F6 C16 F4 106.7(3) . . ?
F6 C16 F5 107.6(3) . . ?
F6 C16 C11 112.9(3) . . ?
F7 C17 C12 112.5(3) . . ?
F8 C17 F7 105.5(3) . . ?
F8 C17 C12 113.3(3) . . ?
F9 C17 F7 104.5(3) . . ?
F9 C17 F8 108.7(3) . . ?
F9 C17 C12 111.7(3) . . ?
F10 C18 F11 113.7(10) . . ?
F10 C18 F12 119.4(11) . . ?
F10 C18 C14 115.3(9) . . ?
F10R C18 C14 112.2(3) . . ?
F11 C18 C14 107.2(4) . . ?
F11R C18 F10R 109.3(4) . . ?
F11R C18 F12R 106.7(4) . . ?
F11R C18 C14 115.4(4) . . ?
F12 C18 F11 90.2(7) . . ?
F12 C18 C14 107.8(6) . . ?
F12R C18 F10R 100.7(4) . . ?
F12R C18 C14 111.4(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag2 2.7901(4) . ?
Ag1 Ag3 3.2598(4) 2_666 ?
Ag1 N1 2.147(2) . ?
Ag1 C1 2.129(3) . ?
Ag2 Ag3 3.3706(4) 2_666 ?
Ag2 N4 2.120(3) . ?
Ag2 C1 2.086(3) . ?
Ag3 N2 2.124(3) . ?
Ag3 N3 2.126(3) . ?
F1 C15 1.335(4) . ?
F2 C15 1.351(4) . ?
F3 C15 1.335(4) . ?
F4 C16 1.351(4) . ?
F5 C16 1.338(4) . ?
F6 C16 1.335(4) . ?
F7 C17 1.338(4) . ?
F8 C17 1.321(4) . ?
F9 C17 1.320(4) . ?
F10 C18 1.136(17) . ?
F10R C18 1.358(5) . ?
F11 C18 1.446(9) . ?
F11R C18 1.262(5) . ?
F12 C18 1.339(12) . ?
F12R C18 1.345(5) . ?
N1 N2 1.359(3) . ?
N1 C9 1.342(4) . ?
N2 C11 1.352(4) . ?
N3 N4 1.358(3) . ?
N3 C12 1.347(4) . ?
N4 C14 1.337(4) . ?
C1 C2 1.218(4) . ?
C2 C3 1.442(4) . ?
C3 C4 1.398(4) . ?
C3 C8 1.406(5) . ?
C4 H4 0.9500 . ?
C4 C5 1.389(4) . ?
C5 H5 0.9500 . ?
C5 C6 1.379(5) . ?
C6 H6 0.9500 . ?
C6 C7 1.381(5) . ?
C7 H7 0.9500 . ?
C7 C8 1.389(5) . ?
C8 H8 0.9500 . ?
C9 C10 1.380(4) . ?
C9 C15 1.489(4) . ?
C10 H10 0.9500 . ?
C10 C11 1.380(4) . ?
C11 C16 1.495(4) . ?
C12 C13 1.380(4) . ?
C12 C17 1.489(4) . ?
C13 H13 0.9500 . ?
C13 C14 1.382(5) . ?
C14 C18 1.499(5) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 N1 N2 Ag3 0.8(3) . . . . ?
Ag1 N1 N2 C11 -174.66(19) . . . . ?
Ag1 N1 C9 C10 174.0(2) . . . . ?
Ag1 N1 C9 C15 -1.4(5) . . . . ?
Ag2 N4 C14 C13 175.7(2) . . . . ?
Ag2 N4 C14 C18 -6.0(5) . . . . ?
Ag3 N2 C11 C10 -175.0(2) . . . . ?
Ag3 N2 C11 C16 5.0(5) . . . . ?
Ag3 N3 N4 Ag2 5.5(3) . . . . ?
Ag3 N3 N4 C14 -178.7(2) . . . . ?
Ag3 N3 C12 C13 178.0(2) . . . . ?
Ag3 N3 C12 C17 -4.8(5) . . . . ?
N1 N2 C11 C10 -0.7(4) . . . . ?
N1 N2 C11 C16 179.3(3) . . . . ?
N1 C9 C10 C11 -0.1(4) . . . . ?
N1 C9 C15 F1 -25.5(4) . . . . ?
N1 C9 C15 F2 94.2(3) . . . . ?
N1 C9 C15 F3 -147.6(3) . . . . ?
N2 N1 C9 C10 -0.3(4) . . . . ?
N2 N1 C9 C15 -175.7(3) . . . . ?
N2 C11 C16 F4 106.7(3) . . . . ?
N2 C11 C16 F5 -134.8(3) . . . . ?
N2 C11 C16 F6 -13.5(4) . . . . ?
N3 N4 C14 C13 0.9(4) . . . . ?
N3 N4 C14 C18 179.1(3) . . . . ?
N3 C12 C13 C14 -0.3(4) . . . . ?
N3 C12 C17 F7 -86.6(4) . . . . ?
N3 C12 C17 F8 32.9(5) . . . . ?
N3 C12 C17 F9 156.2(3) . . . . ?
N4 N3 C12 C13 0.8(4) . . . . ?
N4 N3 C12 C17 178.0(3) . . . . ?
N4 C14 C18 F10 66.8(12) . . . . ?
N4 C14 C18 F10R 28.8(5) . . . . ?
N4 C14 C18 F11 -60.9(6) . . . . ?
N4 C14 C18 F11R -97.3(5) . . . . ?
N4 C14 C18 F12 -156.9(7) . . . . ?
N4 C14 C18 F12R 140.9(4) . . . . ?
C2 C3 C4 C5 177.2(3) . . . . ?
C2 C3 C8 C7 -178.1(3) . . . . ?
C3 C4 C5 C6 1.1(5) . . . . ?
C4 C3 C8 C7 0.0(5) . . . . ?
C4 C5 C6 C7 -0.5(6) . . . . ?
C5 C6 C7 C8 -0.3(6) . . . . ?
C6 C7 C8 C3 0.6(5) . . . . ?
C8 C3 C4 C5 -0.8(5) . . . . ?
C9 N1 N2 Ag3 176.03(19) . . . . ?
C9 N1 N2 C11 0.6(3) . . . . ?
C9 C10 C11 N2 0.4(4) . . . . ?
C9 C10 C11 C16 -179.5(3) . . . . ?
C10 C9 C15 F1 159.9(3) . . . . ?
C10 C9 C15 F2 -80.4(4) . . . . ?
C10 C9 C15 F3 37.9(5) . . . . ?
C10 C11 C16 F4 -73.3(4) . . . . ?
C10 C11 C16 F5 45.2(5) . . . . ?
C10 C11 C16 F6 166.5(3) . . . . ?
C12 N3 N4 Ag2 -176.9(2) . . . . ?
C12 N3 N4 C14 -1.0(3) . . . . ?
C12 C13 C14 N4 -0.4(4) . . . . ?
C12 C13 C14 C18 -178.5(3) . . . . ?
C13 C12 C17 F7 90.0(4) . . . . ?
C13 C12 C17 F8 -150.4(4) . . . . ?
C13 C12 C17 F9 -27.2(5) . . . . ?
C13 C14 C18 F10 -115.3(11) . . . . ?
C13 C14 C18 F10R -153.2(4) . . . . ?
C13 C14 C18 F11 117.0(5) . . . . ?
C13 C14 C18 F11R 80.7(6) . . . . ?
C13 C14 C18 F12 21.0(8) . . . . ?
C13 C14 C18 F12R -41.1(5) . . . . ?
C15 C9 C10 C11 174.9(3) . . . . ?
C17 C12 C13 C14 -177.2(3) . . . . ?
