#------------------------------------------------------------------------------
#$Date: 2016-03-26 16:23:36 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180336 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/05/7200592.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7200592
loop_
_publ_author_name
'Niu, Cao-Yuan'
'Wu, Ben-Lai'
'Zheng, Xian-Fu'
'Wan, Xin-Sheng'
'Zhang, Hong-Yun'
'Niu, Yun-Yin'
'Meng, Lu-Yan'
_publ_section_title
;
 Counteranion's effects on the structures of supramolecular silver
 coordination compounds of one asymmetric and one biting organic
 ligands
;
_journal_issue                   7
_journal_name_full               CrystEngComm
_journal_page_first              1373
_journal_paper_doi               10.1039/b818745b
_journal_volume                  11
_journal_year                    2009
_chemical_formula_sum            'C25 H22 Ag B F4 N6 O3'
_chemical_formula_weight         649.17
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                103.3460(10)
_cell_angle_beta                 91.1900(10)
_cell_angle_gamma                97.5140(10)
_cell_formula_units_Z            2
_cell_length_a                   9.9336(7)
_cell_length_b                   10.1696(7)
_cell_length_c                   13.7544(9)
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      25.50
_cell_measurement_theta_min      2.27
_cell_volume                     1338.47(16)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0109
_diffrn_reflns_av_sigmaI/netI    0.0182
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            7441
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         2.27
_exptl_absorpt_coefficient_mu    0.820
_exptl_absorpt_correction_T_max  0.8466
_exptl_absorpt_correction_T_min  0.6750
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.611
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             652
_exptl_crystal_size_max          0.52
_exptl_crystal_size_mid          0.41
_exptl_crystal_size_min          0.21
_refine_diff_density_max         0.933
_refine_diff_density_min         -0.638
_refine_diff_density_rms         0.072
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.962
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     373
_refine_ls_number_reflns         4901
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      0.962
_refine_ls_R_factor_all          0.0409
_refine_ls_R_factor_gt           0.0379
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0513P)²+2.3268P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0996
_refine_ls_wR_factor_ref         0.1022
_reflns_number_gt                4486
_reflns_number_total             4901
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b818745b.txt
_cod_data_source_block           4
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7200592
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.10553(3) 0.17943(3) 0.09987(2) 0.05002(12) Uani 1 1 d . . .
N1 N 0.2226(3) 0.2637(3) -0.0053(2) 0.0435(6) Uani 1 1 d . . .
N2 N 0.5325(3) 0.5583(3) -0.3276(2) 0.0434(6) Uani 1 1 d D . .
N3 N 0.9653(3) 0.4537(5) -0.2404(4) 0.0837(12) Uani 1 1 d . . .
N4 N 0.0013(3) 0.0929(3) 0.2095(2) 0.0455(6) Uani 1 1 d . . .
N5 N -0.3355(3) -0.2434(3) 0.4952(2) 0.0435(6) Uani 1 1 d D . .
N6 N -0.7615(3) -0.1325(4) 0.3967(3) 0.0714(10) Uani 1 1 d . . .
O1 O 0.7465(2) 0.6097(3) -0.3758(2) 0.0657(8) Uani 1 1 d . . .
O2 O -0.5535(2) -0.3002(3) 0.5338(2) 0.0585(7) Uani 1 1 d . . .
O3 O 0.5292(6) 0.1043(8) 0.2177(5) 0.160(2) Uani 1 1 d . . .
H3 H 0.5655 0.1240 0.1673 0.241 Uiso 1 1 calc R . .
B1 B 0.7746(5) 0.1962(5) 0.0083(4) 0.0594(11) Uani 1 1 d . . .
F1 F 0.8273(3) 0.0757(2) -0.0041(2) 0.0762(7) Uani 1 1 d . . .
F2 F 0.8715(4) 0.2956(3) 0.0651(4) 0.1406(17) Uani 1 1 d . . .
F3 F 0.7527(4) 0.2293(4) -0.0775(3) 0.1153(12) Uani 1 1 d . . .
F4 F 0.6637(4) 0.1992(5) 0.0592(4) 0.1564(19) Uani 1 1 d . . .
C1 C 0.2004(3) 0.3802(3) -0.0287(3) 0.0466(8) Uani 1 1 d . . .
H1 H 0.1265 0.4234 -0.0003 0.056 Uiso 1 1 calc R . .
C2 C 0.2793(3) 0.4401(3) -0.0916(3) 0.0446(8) Uani 1 1 d . . .
H2 H 0.2598 0.5232 -0.1053 0.053 Uiso 1 1 calc R . .
C3 C 0.3881(3) 0.3795(3) -0.1354(2) 0.0348(6) Uani 1 1 d . . .
C4 C 0.4092(3) 0.2576(3) -0.1118(2) 0.0415(7) Uani 1 1 d . . .
H4 H 0.4814 0.2112 -0.1399 0.050 Uiso 1 1 calc R . .
C5 C 0.3259(3) 0.2042(3) -0.0478(3) 0.0459(8) Uani 1 1 d . . .
H5 H 0.3426 0.1208 -0.0330 0.055 Uiso 1 1 calc R . .
C6 C 0.4807(3) 0.4396(3) -0.2014(2) 0.0347(6) Uani 1 1 d . . .
C7 C 0.6202(3) 0.4270(3) -0.1953(2) 0.0390(7) Uani 1 1 d . . .
H7 H 0.6511 0.3792 -0.1493 0.047 Uiso 1 1 calc R . .
C8 C 0.7124(3) 0.4806(3) -0.2526(2) 0.0415(7) Uani 1 1 d . . .
C9 C 0.6700(3) 0.5536(4) -0.3232(3) 0.0457(8) Uani 1 1 d . . .
C10 C 0.2959(3) 0.5278(4) -0.2935(3) 0.0483(8) Uani 1 1 d . . .
H10A H 0.2768 0.6139 -0.2505 0.072 Uiso 1 1 calc R . .
H10B H 0.2323 0.4521 -0.2810 0.072 Uiso 1 1 calc R . .
H10C H 0.2852 0.5312 -0.3638 0.072 Uiso 1 1 calc R . .
C11 C 0.4392(3) 0.5066(3) -0.2708(2) 0.0366(6) Uani 1 1 d . . .
C12 C 0.8539(4) 0.4663(4) -0.2461(3) 0.0538(9) Uani 1 1 d . . .
C13 C 0.0064(3) -0.0369(4) 0.2127(3) 0.0477(8) Uani 1 1 d . . .
H13 H 0.0715 -0.0841 0.1746 0.057 Uiso 1 1 calc R . .
C14 C -0.0777(3) -0.1053(4) 0.2682(3) 0.0451(7) Uani 1 1 d . . .
H14 H -0.0702 -0.1975 0.2682 0.054 Uiso 1 1 calc R . .
C15 C -0.1741(3) -0.0383(3) 0.3245(2) 0.0368(6) Uani 1 1 d . . .
C16 C -0.1772(3) 0.0967(3) 0.3228(3) 0.0439(7) Uani 1 1 d . . .
H16 H -0.2403 0.1468 0.3611 0.053 Uiso 1 1 calc R . .
C17 C -0.0887(3) 0.1587(4) 0.2654(3) 0.0486(8) Uani 1 1 d . . .
H17 H -0.0920 0.2518 0.2657 0.058 Uiso 1 1 calc R . .
C18 C -0.2735(3) -0.1085(3) 0.3808(2) 0.0371(6) Uani 1 1 d . . .
C19 C -0.2371(3) -0.1821(3) 0.4471(2) 0.0398(7) Uani 1 1 d . . .
C20 C -0.4122(3) -0.0973(3) 0.3692(2) 0.0390(7) Uani 1 1 d . . .
H20 H -0.4391 -0.0443 0.3256 0.047 Uiso 1 1 calc R . .
C21 C -0.5100(3) -0.1602(3) 0.4185(2) 0.0385(7) Uani 1 1 d . . .
C22 C -0.4735(3) -0.2395(3) 0.4861(2) 0.0417(7) Uani 1 1 d . . .
C23 C -0.0948(3) -0.1983(5) 0.4760(3) 0.0589(10) Uani 1 1 d . . .
H23A H -0.0839 -0.1819 0.5490 0.088 Uiso 1 1 calc R . .
H23B H -0.0302 -0.1323 0.4527 0.088 Uiso 1 1 calc R . .
H23C H -0.0775 -0.2910 0.4453 0.088 Uiso 1 1 calc R . .
C24 C -0.6501(3) -0.1462(4) 0.4064(3) 0.0463(8) Uani 1 1 d . . .
C25 C 0.3997(6) 0.0986(8) 0.2072(6) 0.133(3) Uani 1 1 d . . .
H25A H 0.3591 0.0962 0.2712 0.200 Uiso 1 1 calc R . .
H25B H 0.3628 0.0161 0.1568 0.200 Uiso 1 1 calc R . .
H25C H 0.3783 0.1792 0.1857 0.200 Uiso 1 1 calc R . .
H26 H 0.504(4) 0.601(4) -0.373(2) 0.059(11) Uiso 1 1 d D . .
H27 H -0.310(4) -0.293(3) 0.537(2) 0.059(11) Uiso 1 1 d D . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N4 Ag1 N1 176.05(10) . . ?
C5 N1 C1 116.9(3) . . ?
C5 N1 Ag1 120.7(2) . . ?
C1 N1 Ag1 122.3(2) . . ?
C11 N2 C9 126.6(3) . . ?
C11 N2 H26 119(3) . . ?
C9 N2 H26 115(3) . . ?
C17 N4 C13 117.4(3) . . ?
C17 N4 Ag1 120.6(2) . . ?
C13 N4 Ag1 121.0(2) . . ?
C19 N5 C22 126.7(3) . . ?
C19 N5 H27 118(3) . . ?
C22 N5 H27 115(3) . . ?
C25 O3 H3 109.5 . . ?
F4 B1 F3 110.0(4) . . ?
F4 B1 F1 113.6(4) . . ?
F3 B1 F1 112.5(4) . . ?
F4 B1 F2 106.1(5) . . ?
F3 B1 F2 108.0(4) . . ?
F1 B1 F2 106.2(4) . . ?
N1 C1 C2 123.2(3) . . ?
N1 C1 H1 118.4 . . ?
C2 C1 H1 118.4 . . ?
C1 C2 C3 120.2(3) . . ?
C1 C2 H2 119.9 . . ?
C3 C2 H2 119.9 . . ?
C4 C3 C2 116.2(3) . . ?
C4 C3 C6 120.2(3) . . ?
C2 C3 C6 123.6(3) . . ?
C5 C4 C3 120.1(3) . . ?
C5 C4 H4 119.9 . . ?
C3 C4 H4 119.9 . . ?
N1 C5 C4 123.3(3) . . ?
N1 C5 H5 118.3 . . ?
C4 C5 H5 118.3 . . ?
C11 C6 C7 117.0(3) . . ?
C11 C6 C3 124.0(3) . . ?
C7 C6 C3 118.9(3) . . ?
C8 C7 C6 122.6(3) . . ?
C8 C7 H7 118.7 . . ?
C6 C7 H7 118.7 . . ?
C7 C8 C12 122.1(3) . . ?
C7 C8 C9 120.5(3) . . ?
C12 C8 C9 117.4(3) . . ?
O1 C9 N2 120.9(3) . . ?
O1 C9 C8 125.2(3) . . ?
N2 C9 C8 113.9(3) . . ?
C11 C10 H10A 109.5 . . ?
C11 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C11 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
N2 C11 C6 119.4(3) . . ?
N2 C11 C10 114.0(3) . . ?
C6 C11 C10 126.6(3) . . ?
N3 C12 C8 179.2(4) . . ?
N4 C13 C14 123.4(3) . . ?
N4 C13 H13 118.3 . . ?
C14 C13 H13 118.3 . . ?
C13 C14 C15 119.4(3) . . ?
C13 C14 H14 120.3 . . ?
C15 C14 H14 120.3 . . ?
C16 C15 C14 117.2(3) . . ?
C16 C15 C18 120.6(3) . . ?
C14 C15 C18 122.1(3) . . ?
C17 C16 C15 120.0(3) . . ?
C17 C16 H16 120.0 . . ?
C15 C16 H16 120.0 . . ?
N4 C17 C16 122.6(3) . . ?
N4 C17 H17 118.7 . . ?
C16 C17 H17 118.7 . . ?
C19 C18 C20 117.5(3) . . ?
C19 C18 C15 123.3(3) . . ?
C20 C18 C15 119.2(3) . . ?
N5 C19 C18 119.1(3) . . ?
N5 C19 C23 114.8(3) . . ?
C18 C19 C23 126.1(3) . . ?
C21 C20 C18 122.4(3) . . ?
C21 C20 H20 118.8 . . ?
C18 C20 H20 118.8 . . ?
C20 C21 C24 121.4(3) . . ?
C20 C21 C22 120.5(3) . . ?
C24 C21 C22 118.0(3) . . ?
O2 C22 N5 120.7(3) . . ?
O2 C22 C21 125.6(3) . . ?
N5 C22 C21 113.7(3) . . ?
C19 C23 H23A 109.5 . . ?
C19 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C19 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
N6 C24 C21 178.7(4) . . ?
O3 C25 H25A 109.5 . . ?
O3 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
O3 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N4 2.134(3) . ?
Ag1 N1 2.135(2) . ?
N1 C5 1.336(4) . ?
N1 C1 1.341(4) . ?
N2 C11 1.356(4) . ?
N2 C9 1.373(4) . ?
N2 H26 0.894(10) . ?
N3 C12 1.133(5) . ?
N4 C17 1.337(4) . ?
N4 C13 1.339(4) . ?
N5 C19 1.356(4) . ?
N5 C22 1.380(4) . ?
N5 H27 0.899(10) . ?
N6 C24 1.142(5) . ?
O1 C9 1.236(4) . ?
O2 C22 1.235(4) . ?
O3 C25 1.284(7) . ?
O3 H3 0.8400 . ?
B1 F4 1.317(6) . ?
B1 F3 1.320(6) . ?
B1 F1 1.371(5) . ?
B1 F2 1.382(6) . ?
C1 C2 1.371(4) . ?
C1 H1 0.9500 . ?
C2 C3 1.393(4) . ?
C2 H2 0.9500 . ?
C3 C4 1.392(4) . ?
C3 C6 1.480(4) . ?
C4 C5 1.374(4) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C11 1.379(4) . ?
C6 C7 1.411(4) . ?
C7 C8 1.362(4) . ?
C7 H7 0.9500 . ?
C8 C12 1.435(5) . ?
C8 C9 1.438(4) . ?
C10 C11 1.504(4) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C13 C14 1.373(4) . ?
C13 H13 0.9500 . ?
C14 C15 1.392(4) . ?
C14 H14 0.9500 . ?
C15 C16 1.383(4) . ?
C15 C18 1.479(4) . ?
C16 C17 1.381(4) . ?
C16 H16 0.9500 . ?
C17 H17 0.9500 . ?
C18 C19 1.377(4) . ?
C18 C20 1.406(4) . ?
C19 C23 1.499(4) . ?
C20 C21 1.370(4) . ?
C20 H20 0.9500 . ?
C21 C24 1.427(5) . ?
C21 C22 1.434(4) . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N5 H27 O1 0.899(10) 1.845(11) 2.743(4) 178(4) 1_446
N2 H26 O2 0.894(10) 1.927(11) 2.820(4) 177(4) 1_664
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N4 Ag1 N1 C5 42.7(17) . . . . ?
N4 Ag1 N1 C1 -134.5(15) . . . . ?
N1 Ag1 N4 C17 128.6(15) . . . . ?
N1 Ag1 N4 C13 -62.8(17) . . . . ?
C5 N1 C1 C2 -1.1(5) . . . . ?
Ag1 N1 C1 C2 176.2(3) . . . . ?
N1 C1 C2 C3 0.5(6) . . . . ?
C1 C2 C3 C4 0.4(5) . . . . ?
C1 C2 C3 C6 -178.0(3) . . . . ?
C2 C3 C4 C5 -0.6(5) . . . . ?
C6 C3 C4 C5 177.8(3) . . . . ?
C1 N1 C5 C4 0.9(5) . . . . ?
Ag1 N1 C5 C4 -176.4(3) . . . . ?
C3 C4 C5 N1 -0.1(6) . . . . ?
C4 C3 C6 C11 143.4(3) . . . . ?
C2 C3 C6 C11 -38.3(5) . . . . ?
C4 C3 C6 C7 -35.6(4) . . . . ?
C2 C3 C6 C7 142.6(3) . . . . ?
C11 C6 C7 C8 1.6(5) . . . . ?
C3 C6 C7 C8 -179.3(3) . . . . ?
C6 C7 C8 C12 -179.6(3) . . . . ?
C6 C7 C8 C9 0.0(5) . . . . ?
C11 N2 C9 O1 -176.8(4) . . . . ?
C11 N2 C9 C8 2.6(5) . . . . ?
C7 C8 C9 O1 177.4(4) . . . . ?
C12 C8 C9 O1 -3.0(6) . . . . ?
C7 C8 C9 N2 -2.0(5) . . . . ?
C12 C8 C9 N2 177.6(3) . . . . ?
C9 N2 C11 C6 -1.1(5) . . . . ?
C9 N2 C11 C10 -179.9(3) . . . . ?
C7 C6 C11 N2 -1.1(5) . . . . ?
C3 C6 C11 N2 179.9(3) . . . . ?
C7 C6 C11 C10 177.5(3) . . . . ?
C3 C6 C11 C10 -1.5(5) . . . . ?
C7 C8 C12 N3 18(40) . . . . ?
C9 C8 C12 N3 -162(40) . . . . ?
C17 N4 C13 C14 1.6(5) . . . . ?
Ag1 N4 C13 C14 -167.4(3) . . . . ?
N4 C13 C14 C15 0.1(6) . . . . ?
C13 C14 C15 C16 -1.4(5) . . . . ?
C13 C14 C15 C18 176.0(3) . . . . ?
C14 C15 C16 C17 1.1(5) . . . . ?
C18 C15 C16 C17 -176.4(3) . . . . ?
C13 N4 C17 C16 -1.9(5) . . . . ?
Ag1 N4 C17 C16 167.1(3) . . . . ?
C15 C16 C17 N4 0.6(5) . . . . ?
C16 C15 C18 C19 -130.5(4) . . . . ?
C14 C15 C18 C19 52.1(5) . . . . ?
C16 C15 C18 C20 47.6(4) . . . . ?
C14 C15 C18 C20 -129.8(3) . . . . ?
C22 N5 C19 C18 -0.7(5) . . . . ?
C22 N5 C19 C23 177.0(3) . . . . ?
C20 C18 C19 N5 2.1(5) . . . . ?
C15 C18 C19 N5 -179.8(3) . . . . ?
C20 C18 C19 C23 -175.4(3) . . . . ?
C15 C18 C19 C23 2.8(6) . . . . ?
C19 C18 C20 C21 -2.2(5) . . . . ?
C15 C18 C20 C21 179.6(3) . . . . ?
C18 C20 C21 C24 179.3(3) . . . . ?
C18 C20 C21 C22 0.9(5) . . . . ?
C19 N5 C22 O2 179.7(3) . . . . ?
C19 N5 C22 C21 -0.5(5) . . . . ?
C20 C21 C22 O2 -179.8(3) . . . . ?
C24 C21 C22 O2 1.7(5) . . . . ?
C20 C21 C22 N5 0.5(5) . . . . ?
C24 C21 C22 N5 -178.0(3) . . . . ?
C20 C21 C24 N6 -42(18) . . . . ?
C22 C21 C24 N6 136(18) . . . . ?
