#------------------------------------------------------------------------------
#$Date: 2016-03-26 16:32:09 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180341 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/10/7201067.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7201067
loop_
_publ_author_name
'Zhou, Xiao-Ping'
'Lin, Shi-Hong'
'Li, Dan'
'Yin, Ye-Gao'
_publ_section_title
;
 Two CuCN hybrid networks with unusual topology tuned by terpyridine
 ligands
;
_journal_issue                   9
_journal_name_full               CrystEngComm
_journal_page_first              1899
_journal_paper_doi               10.1039/b904512k
_journal_volume                  11
_journal_year                    2009
_chemical_formula_sum            'C27 H17 Cu5 N8'
_chemical_formula_weight         771.19
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                72.450(5)
_cell_angle_beta                 80.504(5)
_cell_angle_gamma                82.270(5)
_cell_formula_units_Z            2
_cell_length_a                   7.089(2)
_cell_length_b                   12.139(4)
_cell_length_c                   16.790(5)
_cell_measurement_reflns_used    2458
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      50
_cell_measurement_theta_min      2.5
_cell_volume                     1353.2(7)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0387
_diffrn_reflns_av_sigmaI/netI    0.0646
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            7039
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.28
_exptl_absorpt_coefficient_mu    3.898
_exptl_absorpt_correction_T_max  0.4675
_exptl_absorpt_correction_T_min  0.3778
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.893
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       stick-like
_exptl_crystal_F_000             760
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.27
_exptl_crystal_size_min          0.23
_refine_diff_density_max         1.612
_refine_diff_density_min         -0.893
_refine_diff_density_rms         0.204
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.979
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     360
_refine_ls_number_reflns         4690
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.979
_refine_ls_R_factor_all          0.0718
_refine_ls_R_factor_gt           0.0578
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1003P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1468
_refine_ls_wR_factor_ref         0.1586
_reflns_number_gt                3533
_reflns_number_total             4690
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b904512k.txt
_cod_data_source_block           1201bm
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7201067
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C6 C 0.9162(9) 0.9309(6) 0.3202(4) 0.0453(15) Uani 1 1 d . . .
H6 H 0.9689 0.8796 0.2893 0.054 Uiso 1 1 calc R . .
C7 C 0.8784(10) 1.0442(6) 0.2773(4) 0.0538(18) Uani 1 1 d . . .
H7 H 0.9054 1.0694 0.2189 0.065 Uiso 1 1 calc R . .
C8 C 0.7979(10) 1.1222(6) 0.3230(4) 0.0561(18) Uani 1 1 d . . .
H8 H 0.7724 1.2005 0.2956 0.067 Uiso 1 1 calc R . .
C9 C 0.7572(9) 1.0810(5) 0.4093(4) 0.0454(15) Uani 1 1 d . . .
H9 H 0.7009 1.1309 0.4408 0.054 Uiso 1 1 calc R . .
C10 C 0.8021(7) 0.9619(5) 0.4496(3) 0.0339(12) Uani 1 1 d . . .
C11 C 0.7615(7) 0.9111(5) 0.5424(3) 0.0318(12) Uani 1 1 d . . .
C12 C 0.7103(8) 0.9819(5) 0.5965(3) 0.0353(13) Uani 1 1 d . . .
H12 H 0.7017 1.0621 0.5741 0.042 Uiso 1 1 calc R . .
C13 C 0.6723(8) 0.9333(5) 0.6833(4) 0.0365(13) Uani 1 1 d . . .
C14 C 0.6081(8) 1.0056(5) 0.7411(4) 0.0380(13) Uani 1 1 d . . .
C15 C 0.5063(9) 1.1137(5) 0.7134(4) 0.0445(15) Uani 1 1 d . . .
H15 H 0.4811 1.1406 0.6578 0.053 Uiso 1 1 calc R . .
C16 C 0.4420(9) 1.1819(6) 0.7676(4) 0.0476(15) Uani 1 1 d . . .
H16 H 0.3756 1.2539 0.7473 0.057 Uiso 1 1 calc R . .
C17 C 0.4745(9) 1.1450(6) 0.8505(4) 0.0466(15) Uani 1 1 d . . .
C18 C 0.3984(12) 1.2210(7) 0.9092(5) 0.067(2) Uani 1 1 d . . .
H18A H 0.3089 1.1806 0.9545 0.101 Uiso 1 1 calc R . .
H18B H 0.3353 1.2922 0.8780 0.101 Uiso 1 1 calc R . .
H18C H 0.5036 1.2378 0.9318 0.101 Uiso 1 1 calc R . .
C19 C 0.5799(10) 1.0391(6) 0.8778(4) 0.0531(17) Uani 1 1 d . . .
H19 H 0.6090 1.0144 0.9328 0.064 Uiso 1 1 calc R . .
C20 C 0.6430(9) 0.9690(6) 0.8252(4) 0.0478(15) Uani 1 1 d . . .
H20 H 0.7091 0.8970 0.8460 0.057 Uiso 1 1 calc R . .
C21 C 0.6938(8) 0.8105(5) 0.7125(4) 0.0364(13) Uani 1 1 d . . .
H21 H 0.6708 0.7734 0.7699 0.044 Uiso 1 1 calc R . .
C22 C 0.7495(7) 0.7449(5) 0.6557(3) 0.0305(12) Uani 1 1 d . . .
C23 C 0.7691(7) 0.6162(5) 0.6881(3) 0.0322(12) Uani 1 1 d . . .
C24 C 0.8313(8) 0.5600(5) 0.7653(3) 0.0408(14) Uani 1 1 d . . .
H24 H 0.8692 0.6027 0.7966 0.049 Uiso 1 1 calc R . .
C25 C 0.8372(9) 0.4406(6) 0.7958(4) 0.0474(15) Uani 1 1 d . . .
H25 H 0.8780 0.4024 0.8478 0.057 Uiso 1 1 calc R . .
C26 C 0.7822(9) 0.3794(5) 0.7484(4) 0.0475(16) Uani 1 1 d . . .
H26 H 0.7838 0.2991 0.7681 0.057 Uiso 1 1 calc R . .
C27 C 0.7246(8) 0.4381(5) 0.6713(4) 0.0416(14) Uani 1 1 d . . .
H27 H 0.6900 0.3958 0.6389 0.050 Uiso 1 1 calc R . .
Cu1 Cu 1.0000 0.0000 0.0000 0.0778(5) Uani 1 2 d S . .
Cu2 Cu 0.0000 0.5000 0.0000 0.0739(5) Uani 1 2 d S . .
Cu3 Cu 0.63615(12) 0.32915(7) 0.08344(5) 0.0501(3) Uani 1 1 d . . .
Cu4 Cu 0.73961(12) 0.49464(8) 0.30686(5) 0.0539(3) Uani 1 1 d . . .
Cu5 Cu 0.93200(9) 0.71624(6) 0.47377(4) 0.0363(2) Uani 1 1 d . . .
Cu6 Cu 0.60688(10) 0.63795(7) 0.53410(5) 0.0420(2) Uani 1 1 d . . .
N1 N 0.8793(10) 0.1311(7) 0.0282(5) 0.081(2) Uani 1 1 d . . .
C1 C 0.7948(10) 0.2119(6) 0.0450(5) 0.0546(17) Uani 1 1 d . . .
C2 C 0.2310(10) 0.4226(7) 0.0319(4) 0.0561(12) Uani 1 1 d . . .
N2 N 0.3752(8) 0.3798(5) 0.0512(3) 0.0561(12) Uani 1 1 d . . .
N3 N 0.6808(8) 0.3929(5) 0.1724(4) 0.0535(14) Uani 1 1 d . . .
C3 C 0.7007(8) 0.4313(5) 0.2251(4) 0.0398(14) Uani 1 1 d . . .
N4 N 0.7861(7) 0.5736(4) 0.3788(3) 0.0435(12) Uani 1 1 d . . .
C4 C 0.8143(8) 0.6210(5) 0.4254(3) 0.0348(13) Uani 1 1 d . . .
N5 N 1.2004(7) 0.6931(4) 0.4943(3) 0.0404(12) Uani 1 1 d . . .
C5 C 1.3528(8) 0.6781(5) 0.5076(3) 0.0338(12) Uani 1 1 d . . .
N6 N 0.7162(6) 0.5561(4) 0.6405(3) 0.0324(10) Uani 1 1 d . . .
N7 N 0.7804(6) 0.7939(4) 0.5713(3) 0.0306(10) Uani 1 1 d . . .
N8 N 0.8820(6) 0.8884(4) 0.4046(3) 0.0360(11) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N8 C6 C7 124.1(6) . . ?
N8 C6 H6 118.0 . . ?
C7 C6 H6 118.0 . . ?
C6 C7 C8 118.5(6) . . ?
C6 C7 H7 120.7 . . ?
C8 C7 H7 120.7 . . ?
C9 C8 C7 118.8(6) . . ?
C9 C8 H8 120.6 . . ?
C7 C8 H8 120.6 . . ?
C8 C9 C10 119.4(6) . . ?
C8 C9 H9 120.3 . . ?
C10 C9 H9 120.3 . . ?
N8 C10 C9 120.9(5) . . ?
N8 C10 C11 116.7(5) . . ?
C9 C10 C11 122.4(5) . . ?
N7 C11 C12 122.4(5) . . ?
N7 C11 C10 116.2(5) . . ?
C12 C11 C10 121.3(5) . . ?
C13 C12 C11 120.8(5) . . ?
C13 C12 H12 119.6 . . ?
C11 C12 H12 119.6 . . ?
C12 C13 C21 116.0(5) . . ?
C12 C13 C14 121.8(5) . . ?
C21 C13 C14 122.1(5) . . ?
C15 C14 C20 117.4(5) . . ?
C15 C14 C13 120.4(5) . . ?
C20 C14 C13 122.2(5) . . ?
C14 C15 C16 121.1(6) . . ?
C14 C15 H15 119.5 . . ?
C16 C15 H15 119.5 . . ?
C17 C16 C15 121.5(6) . . ?
C17 C16 H16 119.3 . . ?
C15 C16 H16 119.3 . . ?
C16 C17 C19 117.7(6) . . ?
C16 C17 C18 120.3(6) . . ?
C19 C17 C18 122.0(6) . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C17 C19 C20 121.8(6) . . ?
C17 C19 H19 119.1 . . ?
C20 C19 H19 119.1 . . ?
C19 C20 C14 120.6(6) . . ?
C19 C20 H20 119.7 . . ?
C14 C20 H20 119.7 . . ?
C22 C21 C13 120.5(5) . . ?
C22 C21 H21 119.7 . . ?
C13 C21 H21 119.7 . . ?
N7 C22 C21 122.4(5) . . ?
N7 C22 C23 118.2(5) . . ?
C21 C22 C23 119.3(5) . . ?
N6 C23 C24 121.2(5) . . ?
N6 C23 C22 117.3(5) . . ?
C24 C23 C22 121.4(5) . . ?
C25 C24 C23 120.0(6) . . ?
C25 C24 H24 120.0 . . ?
C23 C24 H24 120.0 . . ?
C26 C25 C24 119.1(6) . . ?
C26 C25 H25 120.5 . . ?
C24 C25 H25 120.5 . . ?
C25 C26 C27 119.3(6) . . ?
C25 C26 H26 120.4 . . ?
C27 C26 H26 120.4 . . ?
N6 C27 C26 122.4(6) . . ?
N6 C27 H27 118.8 . . ?
C26 C27 H27 118.8 . . ?
N1 Cu1 N1 180.0(7) . 2_755 ?
C2 Cu2 C2 180.0(7) 2_565 . ?
C1 Cu3 N3 126.3(3) . . ?
C1 Cu3 N2 121.3(3) . . ?
N3 Cu3 N2 111.4(2) . . ?
C3 Cu4 N4 173.2(3) . . ?
C4 Cu5 N5 124.8(2) . . ?
C4 Cu5 N8 108.2(2) . . ?
N5 Cu5 N8 106.93(19) . . ?
C4 Cu5 N7 123.6(2) . . ?
N5 Cu5 N7 104.18(19) . . ?
N8 Cu5 N7 78.44(17) . . ?
C4 Cu5 Cu6 56.57(16) . . ?
N5 Cu5 Cu6 141.92(15) . . ?
N8 Cu5 Cu6 107.55(13) . . ?
N7 Cu5 Cu6 67.87(11) . . ?
C5 Cu6 N6 133.2(2) 1_455 . ?
C5 Cu6 C4 112.7(2) 1_455 . ?
N6 Cu6 C4 110.1(2) . . ?
C5 Cu6 Cu5 135.98(17) 1_455 . ?
N6 Cu6 Cu5 87.87(12) . . ?
C4 Cu6 Cu5 47.49(15) . . ?
C1 N1 Cu1 176.4(7) . . ?
N1 C1 Cu3 172.2(8) . . ?
N2 C2 Cu2 176.9(7) . . ?
C2 N2 Cu3 171.3(7) . . ?
C3 N3 Cu3 177.7(6) . . ?
N3 C3 Cu4 178.1(6) . . ?
C4 N4 Cu4 178.5(5) . . ?
N4 C4 Cu5 160.7(5) . . ?
N4 C4 Cu6 123.0(4) . . ?
Cu5 C4 Cu6 75.9(2) . . ?
C5 N5 Cu5 178.5(5) . . ?
N5 C5 Cu6 174.7(5) . 1_655 ?
C23 N6 C27 118.0(5) . . ?
C23 N6 Cu6 120.9(4) . . ?
C27 N6 Cu6 120.9(4) . . ?
C11 N7 C22 117.8(5) . . ?
C11 N7 Cu5 111.4(3) . . ?
C22 N7 Cu5 128.6(4) . . ?
C6 N8 C10 118.2(5) . . ?
C6 N8 Cu5 126.1(4) . . ?
C10 N8 Cu5 115.7(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C6 N8 1.346(7) . ?
C6 C7 1.360(9) . ?
C6 H6 0.9300 . ?
C7 C8 1.400(10) . ?
C7 H7 0.9300 . ?
C8 C9 1.376(9) . ?
C8 H8 0.9300 . ?
C9 C10 1.417(8) . ?
C9 H9 0.9300 . ?
C10 N8 1.348(7) . ?
C10 C11 1.488(7) . ?
C11 N7 1.354(7) . ?
C11 C12 1.405(7) . ?
C12 C13 1.392(8) . ?
C12 H12 0.9300 . ?
C13 C21 1.417(8) . ?
C13 C14 1.476(8) . ?
C14 C15 1.395(8) . ?
C14 C20 1.400(8) . ?
C15 C16 1.391(8) . ?
C15 H15 0.9300 . ?
C16 C17 1.376(9) . ?
C16 H16 0.9300 . ?
C17 C19 1.386(9) . ?
C17 C18 1.533(8) . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C19 C20 1.387(9) . ?
C19 H19 0.9300 . ?
C20 H20 0.9300 . ?
C21 C22 1.396(7) . ?
C21 H21 0.9300 . ?
C22 N7 1.354(7) . ?
C22 C23 1.487(8) . ?
C23 N6 1.355(7) . ?
C23 C24 1.383(7) . ?
C24 C25 1.381(9) . ?
C24 H24 0.9300 . ?
C25 C26 1.370(9) . ?
C25 H25 0.9300 . ?
C26 C27 1.375(9) . ?
C26 H26 0.9300 . ?
C27 N6 1.365(7) . ?
C27 H27 0.9300 . ?
Cu1 N1 1.856(8) . ?
Cu1 N1 1.856(8) 2_755 ?
Cu2 C2 1.851(7) 2_565 ?
Cu2 C2 1.851(7) . ?
Cu3 C1 1.895(7) . ?
Cu3 N3 1.963(6) . ?
Cu3 N2 1.979(6) . ?
Cu4 C3 1.836(6) . ?
Cu4 N4 1.844(5) . ?
Cu5 C4 1.935(6) . ?
Cu5 N5 1.958(5) . ?
Cu5 N8 2.077(5) . ?
Cu5 N7 2.191(4) . ?
Cu5 Cu6 2.5456(11) . ?
Cu6 C5 1.891(6) 1_455 ?
Cu6 N6 1.989(5) . ?
Cu6 C4 2.190(5) . ?
N1 C1 1.163(10) . ?
C2 N2 1.133(9) . ?
N3 C3 1.151(8) . ?
N4 C4 1.156(7) . ?
N5 C5 1.119(7) . ?
C5 Cu6 1.891(6) 1_655 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N8 C6 C7 C8 -0.4(10) . . . . ?
C6 C7 C8 C9 -1.1(10) . . . . ?
C7 C8 C9 C10 1.6(10) . . . . ?
C8 C9 C10 N8 -0.7(9) . . . . ?
C8 C9 C10 C11 -179.7(5) . . . . ?
N8 C10 C11 N7 -10.0(7) . . . . ?
C9 C10 C11 N7 169.0(5) . . . . ?
N8 C10 C11 C12 168.7(5) . . . . ?
C9 C10 C11 C12 -12.2(8) . . . . ?
N7 C11 C12 C13 -1.5(8) . . . . ?
C10 C11 C12 C13 179.9(5) . . . . ?
C11 C12 C13 C21 1.7(8) . . . . ?
C11 C12 C13 C14 -176.6(5) . . . . ?
C12 C13 C14 C15 27.7(8) . . . . ?
C21 C13 C14 C15 -150.5(6) . . . . ?
C12 C13 C14 C20 -153.3(6) . . . . ?
C21 C13 C14 C20 28.4(8) . . . . ?
C20 C14 C15 C16 -0.2(9) . . . . ?
C13 C14 C15 C16 178.9(5) . . . . ?
C14 C15 C16 C17 -0.6(10) . . . . ?
C15 C16 C17 C19 2.3(10) . . . . ?
C15 C16 C17 C18 -178.8(6) . . . . ?
C16 C17 C19 C20 -3.2(10) . . . . ?
C18 C17 C19 C20 177.9(6) . . . . ?
C17 C19 C20 C14 2.5(10) . . . . ?
C15 C14 C20 C19 -0.7(9) . . . . ?
C13 C14 C20 C19 -179.7(6) . . . . ?
C12 C13 C21 C22 -0.2(8) . . . . ?
C14 C13 C21 C22 178.1(5) . . . . ?
C13 C21 C22 N7 -1.7(8) . . . . ?
C13 C21 C22 C23 -179.4(5) . . . . ?
N7 C22 C23 N6 -34.1(7) . . . . ?
C21 C22 C23 N6 143.7(5) . . . . ?
N7 C22 C23 C24 148.5(5) . . . . ?
C21 C22 C23 C24 -33.7(7) . . . . ?
N6 C23 C24 C25 -1.1(8) . . . . ?
C22 C23 C24 C25 176.2(5) . . . . ?
C23 C24 C25 C26 0.5(9) . . . . ?
C24 C25 C26 C27 0.7(9) . . . . ?
C25 C26 C27 N6 -1.3(9) . . . . ?
C4 Cu5 Cu6 C5 -78.7(3) . . . 1_455 ?
N5 Cu5 Cu6 C5 175.9(3) . . . 1_455 ?
N8 Cu5 Cu6 C5 21.8(3) . . . 1_455 ?
N7 Cu5 Cu6 C5 91.0(3) . . . 1_455 ?
C4 Cu5 Cu6 N6 120.1(2) . . . . ?
N5 Cu5 Cu6 N6 14.7(3) . . . . ?
N8 Cu5 Cu6 N6 -139.35(19) . . . . ?
N7 Cu5 Cu6 N6 -70.17(18) . . . . ?
N5 Cu5 Cu6 C4 -105.4(3) . . . . ?
N8 Cu5 Cu6 C4 100.6(2) . . . . ?
N7 Cu5 Cu6 C4 169.7(2) . . . . ?
N1 Cu1 N1 C1 -8(12) 2_755 . . . ?
Cu1 N1 C1 Cu3 60(16) . . . . ?
N3 Cu3 C1 N1 91(5) . . . . ?
N2 Cu3 C1 N1 -77(5) . . . . ?
C2 Cu2 C2 N2 169(100) 2_565 . . . ?
Cu2 C2 N2 Cu3 1(15) . . . . ?
C1 Cu3 N2 C2 -141(4) . . . . ?
N3 Cu3 N2 C2 50(4) . . . . ?
C1 Cu3 N3 C3 -155(14) . . . . ?
N2 Cu3 N3 C3 13(14) . . . . ?
Cu3 N3 C3 Cu4 -140(13) . . . . ?
N4 Cu4 C3 N3 42(19) . . . . ?
C3 Cu4 N4 C4 179(100) . . . . ?
Cu4 N4 C4 Cu5 140(19) . . . . ?
Cu4 N4 C4 Cu6 -51(21) . . . . ?
N5 Cu5 C4 N4 -56.1(16) . . . . ?
N8 Cu5 C4 N4 70.9(16) . . . . ?
N7 Cu5 C4 N4 158.9(15) . . . . ?
Cu6 Cu5 C4 N4 170.3(17) . . . . ?
N5 Cu5 C4 Cu6 133.6(2) . . . . ?
N8 Cu5 C4 Cu6 -99.41(17) . . . . ?
N7 Cu5 C4 Cu6 -11.4(3) . . . . ?
C5 Cu6 C4 N4 -43.8(6) 1_455 . . . ?
N6 Cu6 C4 N4 116.7(5) . . . . ?
Cu5 Cu6 C4 N4 -176.2(7) . . . . ?
C5 Cu6 C4 Cu5 132.4(2) 1_455 . . . ?
N6 Cu6 C4 Cu5 -67.1(2) . . . . ?
C4 Cu5 N5 C5 -83(21) . . . . ?
N8 Cu5 N5 C5 149(21) . . . . ?
N7 Cu5 N5 C5 67(21) . . . . ?
Cu6 Cu5 N5 C5 -5(21) . . . . ?
Cu5 N5 C5 Cu6 40(25) . . . 1_655 ?
C24 C23 N6 C27 0.5(7) . . . . ?
C22 C23 N6 C27 -176.9(4) . . . . ?
C24 C23 N6 Cu6 175.0(4) . . . . ?
C22 C23 N6 Cu6 -2.5(6) . . . . ?
C26 C27 N6 C23 0.7(8) . . . . ?
C26 C27 N6 Cu6 -173.7(4) . . . . ?
C5 Cu6 N6 C23 -96.1(5) 1_455 . . . ?
C4 Cu6 N6 C23 108.8(4) . . . . ?
Cu5 Cu6 N6 C23 66.0(4) . . . . ?
C5 Cu6 N6 C27 78.1(5) 1_455 . . . ?
C4 Cu6 N6 C27 -77.0(4) . . . . ?
Cu5 Cu6 N6 C27 -119.7(4) . . . . ?
C12 C11 N7 C22 -0.5(7) . . . . ?
C10 C11 N7 C22 178.3(4) . . . . ?
C12 C11 N7 Cu5 -165.1(4) . . . . ?
C10 C11 N7 Cu5 13.6(5) . . . . ?
C21 C22 N7 C11 2.0(7) . . . . ?
C23 C22 N7 C11 179.7(4) . . . . ?
C21 C22 N7 Cu5 163.6(4) . . . . ?
C23 C22 N7 Cu5 -18.7(7) . . . . ?
C4 Cu5 N7 C11 -114.5(4) . . . . ?
N5 Cu5 N7 C11 94.5(4) . . . . ?
N8 Cu5 N7 C11 -10.3(3) . . . . ?
Cu6 Cu5 N7 C11 -124.8(4) . . . . ?
C4 Cu5 N7 C22 82.9(5) . . . . ?
N5 Cu5 N7 C22 -68.0(5) . . . . ?
N8 Cu5 N7 C22 -172.8(4) . . . . ?
Cu6 Cu5 N7 C22 72.6(4) . . . . ?
C7 C6 N8 C10 1.3(9) . . . . ?
C7 C6 N8 Cu5 178.9(5) . . . . ?
C9 C10 N8 C6 -0.7(8) . . . . ?
C11 C10 N8 C6 178.4(5) . . . . ?
C9 C10 N8 Cu5 -178.6(4) . . . . ?
C11 C10 N8 Cu5 0.5(6) . . . . ?
C4 Cu5 N8 C6 -50.8(5) . . . . ?
N5 Cu5 N8 C6 85.9(5) . . . . ?
N7 Cu5 N8 C6 -172.6(5) . . . . ?
Cu6 Cu5 N8 C6 -110.5(4) . . . . ?
C4 Cu5 N8 C10 126.9(4) . . . . ?
N5 Cu5 N8 C10 -96.4(4) . . . . ?
N7 Cu5 N8 C10 5.1(4) . . . . ?
Cu6 Cu5 N8 C10 67.2(4) . . . . ?
