#------------------------------------------------------------------------------
#$Date: 2016-03-26 17:15:50 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180384 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/53/7205312.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7205312
loop_
_publ_author_name
'Cheng, Xian'
'Liu, Tao'
'Duan, Xianying'
'Wang, Fangming'
'Meng, Qingjin'
'Lu, Changsheng'
_publ_section_title
;
 A novel 2D coordination polymer with unprecedented [Ag]7 chains and
 two 3D silver--organic frameworks constructed by
 methylenediisophthalic acid (H4MDIP) with strong Ag--Ag interactions
;
_journal_issue                   5
_journal_name_full               CrystEngComm
_journal_page_first              1314
_journal_paper_doi               10.1039/c0ce00360c
_journal_volume                  13
_journal_year                    2011
_chemical_formula_moiety
'C17 H8 Ag O8, 3(C14 H14 Ag N4), 0.4(H2 O), 0.3(H2 O), 0.3(H2 O)'
_chemical_formula_sum            'C59 H52 Ag4 N12 O9'
_chemical_formula_weight         1504.61
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 107.933(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   14.5138(11)
_cell_length_b                   17.2793(13)
_cell_length_c                   25.1262(16)
_cell_measurement_reflns_used    3207
_cell_measurement_temperature    291(2)
_cell_measurement_theta_max      23.49
_cell_measurement_theta_min      2.21
_cell_volume                     5995.2(8)
_computing_cell_refinement       SMART
_computing_data_collection       'SMART (Bruker, 2000)'
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL (Bruker, 2000)'
_diffrn_ambient_temperature      291(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker Smart Aepex CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0459
_diffrn_reflns_av_sigmaI/netI    0.0922
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            31983
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.70
_exptl_absorpt_coefficient_mu    1.353
_exptl_absorpt_correction_T_max  0.76
_exptl_absorpt_correction_T_min  0.71
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.667
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       pin
_exptl_crystal_F_000             3000
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.935
_refine_diff_density_min         -0.651
_refine_diff_density_rms         0.099
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     775
_refine_ls_number_reflns         11740
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.050
_refine_ls_R_factor_all          0.0944
_refine_ls_R_factor_gt           0.0508
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0300P)²+1.2200P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0818
_refine_ls_wR_factor_ref         0.0879
_reflns_number_gt                7847
_reflns_number_total             11740
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            C0CE00360C.TXT
_cod_data_source_block           81125cm
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 
;
_cod_original_cell_volume        5995.2(7)
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7205312
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.24430(3) 0.55016(2) 0.773190(16) 0.03403(10) Uani 1 1 d . . .
Ag2 Ag 0.24502(3) 0.71294(2) 1.103190(16) 0.03382(10) Uani 1 1 d . . .
Ag3 Ag 0.17623(3) 0.77951(2) 0.976000(16) 0.03450(10) Uani 1 1 d . . .
Ag4 Ag 0.08451(3) 0.82650(2) 0.843630(17) 0.03598(10) Uani 1 1 d . . .
C1 C 0.4314(4) 0.5849(3) 0.7797(3) 0.0439(14) Uani 1 1 d . . .
C2 C 0.5376(4) 0.5979(3) 0.7916(2) 0.0366(12) Uani 1 1 d . . .
C3 C 0.6032(4) 0.5638(3) 0.8395(2) 0.0359(12) Uani 1 1 d . . .
H3 H 0.5779 0.5348 0.8629 0.043 Uiso 1 1 calc R . .
C4 C 0.7006(4) 0.5708(3) 0.8533(2) 0.0428(13) Uani 1 1 d . . .
C5 C 0.7357(4) 0.6150(3) 0.8153(2) 0.0408(13) Uani 1 1 d . . .
H5 H 0.8023 0.6211 0.8237 0.049 Uiso 1 1 calc R . .
C6 C 0.6794(4) 0.6479(3) 0.7688(2) 0.0364(12) Uani 1 1 d . . .
C7 C 0.5798(4) 0.6410(3) 0.7568(3) 0.0442(14) Uani 1 1 d . . .
H7 H 0.5395 0.6652 0.7251 0.053 Uiso 1 1 calc R . .
C8 C 0.7674(4) 0.5340(3) 0.9050(2) 0.0418(13) Uani 1 1 d . . .
C9 C 0.7220(4) 0.6902(3) 0.7308(2) 0.0441(14) Uani 1 1 d . . .
H9A H 0.6703 0.7144 0.7015 0.053 Uiso 1 1 calc R . .
H9B H 0.7636 0.7310 0.7517 0.053 Uiso 1 1 calc R . .
C10 C 0.7784(4) 0.6409(3) 0.7050(2) 0.0393(13) Uani 1 1 d . . .
C11 C 0.8788(4) 0.6365(3) 0.7317(2) 0.0395(13) Uani 1 1 d . . .
H11 H 0.9068 0.6669 0.7630 0.047 Uiso 1 1 calc R . .
C12 C 0.9384(4) 0.5861(3) 0.7115(2) 0.0426(13) Uani 1 1 d . . .
C13 C 0.8962(4) 0.5389(3) 0.6661(2) 0.0425(13) Uani 1 1 d . . .
H13 H 0.9349 0.5063 0.6526 0.051 Uiso 1 1 calc R . .
C14 C 0.7949(4) 0.5397(3) 0.6400(2) 0.0415(13) Uani 1 1 d . . .
C15 C 0.7350(4) 0.5909(3) 0.6619(2) 0.0391(13) Uani 1 1 d . . .
H15 H 0.6679 0.5897 0.6468 0.047 Uiso 1 1 calc R . .
C16 C 1.0466(4) 0.5814(3) 0.7411(2) 0.0418(13) Uani 1 1 d . . .
C17 C 0.7460(4) 0.4868(3) 0.5917(2) 0.0412(13) Uani 1 1 d . . .
C18 C 0.4479(4) 0.7513(3) 1.0861(2) 0.0424(13) Uani 1 1 d . . .
H18 H 0.4406 0.8042 1.0901 0.051 Uiso 1 1 calc R . .
C19 C 0.5241(4) 0.7218(3) 1.0749(2) 0.0397(13) Uani 1 1 d . . .
H19 H 0.5766 0.7474 1.0691 0.048 Uiso 1 1 calc R . .
C20 C 0.4206(4) 0.6351(3) 1.0827(2) 0.0412(13) Uani 1 1 d . . .
H20 H 0.3905 0.5876 1.0827 0.049 Uiso 1 1 calc R . .
C21 C 0.5630(4) 0.5813(3) 1.0617(2) 0.0427(14) Uani 1 1 d . . .
H21A H 0.5572 0.5836 1.0222 0.051 Uiso 1 1 calc R . .
H21B H 0.5359 0.5323 1.0683 0.051 Uiso 1 1 calc R . .
C22 C 0.6685(4) 0.5823(3) 1.0946(2) 0.0426(13) Uani 1 1 d . . .
C23 C 0.7372(4) 0.5558(3) 1.0726(2) 0.0411(13) Uani 1 1 d . . .
H23 H 0.7185 0.5382 1.0358 0.049 Uiso 1 1 calc R . .
C24 C 0.8327(4) 0.5543(3) 1.1030(2) 0.0413(13) Uani 1 1 d . . .
H24 H 0.8779 0.5352 1.0869 0.050 Uiso 1 1 calc R . .
C25 C 0.8628(5) 0.5805(3) 1.1568(3) 0.0433(14) Uani 1 1 d . . .
C26 C 0.7954(4) 0.6045(3) 1.1794(3) 0.0471(14) Uani 1 1 d . . .
H26 H 0.8150 0.6193 1.2168 0.056 Uiso 1 1 calc R . .
C27 C 0.6988(4) 0.6082(3) 1.1499(2) 0.0426(13) Uani 1 1 d . . .
H27 H 0.6544 0.6276 1.1664 0.051 Uiso 1 1 calc R . .
C28 C 0.9688(5) 0.5759(3) 1.1868(3) 0.0491(15) Uani 1 1 d . . .
H28A H 0.9787 0.5770 1.2268 0.059 Uiso 1 1 calc R . .
H28B H 0.9931 0.5268 1.1781 0.059 Uiso 1 1 calc R . .
C29 C 0.0873(4) 0.7484(4) 1.1617(3) 0.0486(15) Uani 1 1 d . . .
H29 H 0.0999 0.8013 1.1631 0.058 Uiso 1 1 calc R . .
C30 C 0.0264(5) 0.7132(3) 1.1837(2) 0.0471(14) Uani 1 1 d . . .
H30 H -0.0097 0.7373 1.2038 0.057 Uiso 1 1 calc R . .
C31 C 0.0902(4) 0.6288(3) 1.1427(2) 0.0435(14) Uani 1 1 d . . .
H31 H 0.1043 0.5818 1.1290 0.052 Uiso 1 1 calc R . .
C32 C 0.0306(4) 0.8927(3) 1.0118(2) 0.0419(14) Uani 1 1 d . . .
H32 H 0.0606 0.9372 1.0044 0.050 Uiso 1 1 calc R . .
C33 C -0.0410(4) 0.8937(3) 1.0298(2) 0.0420(13) Uani 1 1 d . . .
H33 H -0.0742 0.9369 1.0363 0.050 Uiso 1 1 calc R . .
C34 C 0.0024(4) 0.7707(3) 1.0197(2) 0.0394(13) Uani 1 1 d . . .
H34 H 0.0032 0.7169 1.0186 0.047 Uiso 1 1 calc R . .
C35 C -0.1340(4) 0.7827(3) 1.0597(2) 0.0458(14) Uani 1 1 d . . .
H35A H -0.1381 0.8141 1.0909 0.055 Uiso 1 1 calc R . .
H35B H -0.1147 0.7309 1.0737 0.055 Uiso 1 1 calc R . .
C36 C -0.2328(4) 0.7789(3) 1.0165(2) 0.0448(14) Uani 1 1 d . . .
C37 C -0.2903(5) 0.8427(4) 1.0050(3) 0.0544(16) Uani 1 1 d . . .
H37 H -0.2684 0.8890 1.0235 0.065 Uiso 1 1 calc R . .
C38 C -0.3828(5) 0.8390(3) 0.9653(3) 0.0496(15) Uani 1 1 d . . .
H38 H -0.4231 0.8821 0.9593 0.059 Uiso 1 1 calc R . .
C39 C -0.4136(4) 0.7738(3) 0.9359(2) 0.0403(13) Uani 1 1 d . . .
C40 C -0.3530(4) 0.7090(3) 0.9474(2) 0.0410(13) Uani 1 1 d . . .
H40 H -0.3743 0.6631 0.9282 0.049 Uiso 1 1 calc R . .
C41 C -0.2627(4) 0.7114(3) 0.9864(2) 0.0455(14) Uani 1 1 d . . .
H41 H -0.2223 0.6684 0.9925 0.055 Uiso 1 1 calc R . .
C42 C -0.5113(4) 0.7691(3) 0.8925(2) 0.0416(13) Uani 1 1 d . . .
H42A H -0.5282 0.8200 0.8762 0.050 Uiso 1 1 calc R . .
H42B H -0.5068 0.7346 0.8629 0.050 Uiso 1 1 calc R . .
C43 C 0.3855(4) 0.6655(3) 0.9162(2) 0.0443(14) Uani 1 1 d . . .
H43A H 0.4140 0.6219 0.9062 0.053 Uiso 1 1 calc R . .
C44 C 0.3097(4) 0.6672(3) 0.9372(2) 0.0414(13) Uani 1 1 d . . .
H44A H 0.2770 0.6237 0.9437 0.050 Uiso 1 1 calc R . .
C45 C 0.3515(4) 0.7853(3) 0.9313(2) 0.0451(14) Uani 1 1 d . . .
H45A H 0.3530 0.8391 0.9329 0.054 Uiso 1 1 calc R . .
C46 C 0.2415(4) 0.7575(4) 0.7967(2) 0.0455(14) Uani 1 1 d . . .
H46 H 0.2317 0.7083 0.8089 0.055 Uiso 1 1 calc R . .
C47 C 0.2994(4) 0.7720(3) 0.7677(2) 0.0404(13) Uani 1 1 d . . .
H47 H 0.3357 0.7366 0.7547 0.049 Uiso 1 1 calc R . .
C48 C 0.2308(4) 0.8777(4) 0.7840(2) 0.0443(14) Uani 1 1 d . . .
H48 H 0.2119 0.9291 0.7841 0.053 Uiso 1 1 calc R . .
C49 C 0.3517(4) 0.8956(3) 0.7309(3) 0.0454(14) Uani 1 1 d . . .
H49A H 0.3213 0.9453 0.7189 0.054 Uiso 1 1 calc R . .
H49B H 0.3522 0.8670 0.6978 0.054 Uiso 1 1 calc R . .
C50 C 0.4540(4) 0.9083(3) 0.7673(2) 0.0393(13) Uani 1 1 d . . .
C51 C 0.5288(4) 0.8700(3) 0.7531(2) 0.0403(13) Uani 1 1 d . . .
H51 H 0.5146 0.8388 0.7215 0.048 Uiso 1 1 calc R . .
C52 C 0.6234(4) 0.8792(3) 0.7865(2) 0.0443(14) Uani 1 1 d . . .
H52 H 0.6724 0.8525 0.7776 0.053 Uiso 1 1 calc R . .
C53 C 0.6472(4) 0.9271(3) 0.8328(2) 0.0407(13) Uani 1 1 d . . .
C54 C 0.5700(5) 0.9648(3) 0.8471(3) 0.0476(15) Uani 1 1 d . . .
H54 H 0.5833 0.9961 0.8787 0.057 Uiso 1 1 calc R . .
C55 C 0.4758(4) 0.9543(3) 0.8136(2) 0.0462(14) Uani 1 1 d . . .
H55 H 0.4260 0.9792 0.8228 0.055 Uiso 1 1 calc R . .
C56 C 0.7471(4) 0.9428(3) 0.8673(3) 0.0490(15) Uani 1 1 d . . .
H56A H 0.7677 0.9909 0.8546 0.059 Uiso 1 1 calc R . .
H56B H 0.7473 0.9507 0.9056 0.059 Uiso 1 1 calc R . .
C57 C -0.1007(4) 0.7775(3) 0.8759(2) 0.0445(14) Uani 1 1 d . . .
H57 H -0.0824 0.7259 0.8826 0.053 Uiso 1 1 calc R . .
C58 C -0.1792(4) 0.8089(3) 0.8829(3) 0.0480(15) Uani 1 1 d . . .
H58 H -0.2246 0.7840 0.8961 0.058 Uiso 1 1 calc R . .
C59 C -0.1013(4) 0.8970(3) 0.8523(2) 0.0435(14) Uani 1 1 d . . .
H59 H -0.0852 0.9446 0.8403 0.052 Uiso 1 1 calc R . .
N1 N 0.3833(3) 0.7009(3) 1.09121(18) 0.0388(11) Uani 1 1 d . . .
N2 N 0.5057(4) 0.6427(3) 1.0740(2) 0.0502(13) Uani 1 1 d . . .
N3 N 0.1283(4) 0.6942(3) 1.1367(2) 0.0436(11) Uani 1 1 d . . .
N4 N 0.0251(4) 0.6385(3) 1.1726(2) 0.0491(13) Uani 1 1 d . . .
N5 N 0.0612(3) 0.8166(2) 1.00388(17) 0.0337(10) Uani 1 1 d . . .
N6 N -0.0606(4) 0.8147(3) 1.03820(19) 0.0437(11) Uani 1 1 d . . .
N7 N 0.2883(3) 0.7414(2) 0.94741(17) 0.0337(10) Uani 1 1 d . . .
N8 N 0.4118(3) 0.7424(3) 0.91280(19) 0.0447(11) Uani 1 1 d . . .
N9 N 0.1966(3) 0.8220(3) 0.8074(2) 0.0437(11) Uani 1 1 d . . .
N10 N 0.2957(3) 0.8535(2) 0.75992(18) 0.0376(10) Uani 1 1 d . . .
N11 N -0.0497(3) 0.8338(3) 0.8570(2) 0.0427(11) Uani 1 1 d . . .
N12 N -0.1812(3) 0.8832(3) 0.8674(2) 0.0457(12) Uani 1 1 d . . .
O1 O 0.3997(3) 0.5521(2) 0.81330(16) 0.0439(9) Uani 1 1 d . . .
O2 O 0.3799(3) 0.6139(2) 0.73389(16) 0.0412(9) Uani 1 1 d . . .
O3 O 0.7322(3) 0.5027(2) 0.93706(17) 0.0499(10) Uani 1 1 d . . .
O4 O 0.8580(3) 0.5355(2) 0.91122(16) 0.0429(9) Uani 1 1 d . . .
O5 O 1.0785(3) 0.6156(2) 0.78650(17) 0.0449(9) Uani 1 1 d . . .
O6 O 0.0952(3) 0.5420(2) 0.71720(15) 0.0423(9) Uani 1 1 d . . .
O7 O 0.8055(3) 0.4536(2) 0.57115(17) 0.0476(10) Uani 1 1 d . . .
O8 O 0.6576(3) 0.4821(2) 0.57676(16) 0.0437(9) Uani 1 1 d . . .
O10 O 0.1483(7) 0.6116(5) -0.0006(4) 0.041(2) Uani 0.40 1 d P . .
H10B H 0.1226 0.5669 -0.0065 0.061 Uiso 0.40 1 d PR . .
H10D H 0.1967 0.6105 0.0289 0.061 Uiso 0.40 1 d PR . .
O11 O 0.5198(9) 0.0568(7) 0.9617(5) 0.043(3) Uani 0.30 1 d P . .
H11A H 0.5084 0.0095 0.9664 0.064 Uiso 0.30 1 d PR . .
H11B H 0.5761 0.0611 0.9583 0.064 Uiso 0.30 1 d PR . .
O19 O 0.2912(9) 0.9260(6) 0.0365(5) 0.035(3) Uani 0.30 1 d P . .
H9C H 0.2912 0.8870 0.0159 0.052 Uiso 0.30 1 d PR . .
H9D H 0.3190 0.9638 0.0260 0.052 Uiso 0.30 1 d PR . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Ag1 O6 168.20(15) . . ?
N1 Ag2 N3 159.62(17) . . ?
N1 Ag2 Ag3 85.02(12) . . ?
N3 Ag2 Ag3 113.60(13) . . ?
N7 Ag3 N5 178.94(16) . . ?
N7 Ag3 Ag2 101.05(11) . . ?
N5 Ag3 Ag2 79.35(11) . . ?
N7 Ag3 Ag4 81.05(11) . . ?
N5 Ag3 Ag4 98.42(11) . . ?
Ag2 Ag3 Ag4 171.867(17) . . ?
N11 Ag4 N9 164.39(18) . . ?
N11 Ag4 Ag3 87.66(12) . . ?
N9 Ag4 Ag3 107.71(13) . . ?
O1 C1 O2 124.8(6) . . ?
O1 C1 C2 121.2(5) . . ?
O2 C1 C2 114.0(5) . . ?
C3 C2 C7 115.9(5) . . ?
C3 C2 C1 119.4(5) . . ?
C7 C2 C1 124.7(5) . . ?
C4 C3 C2 123.9(5) . . ?
C4 C3 H3 118.1 . . ?
C2 C3 H3 118.1 . . ?
C3 C4 C5 115.8(5) . . ?
C3 C4 C8 121.9(5) . . ?
C5 C4 C8 122.3(5) . . ?
C6 C5 C4 124.4(6) . . ?
C6 C5 H5 117.8 . . ?
C4 C5 H5 117.8 . . ?
C5 C6 C7 118.1(5) . . ?
C5 C6 C9 120.8(5) . . ?
C7 C6 C9 121.1(5) . . ?
C6 C7 C2 121.9(5) . . ?
C6 C7 H7 119.1 . . ?
C2 C7 H7 119.1 . . ?
O3 C8 O4 124.1(5) . . ?
O3 C8 C4 118.3(5) . . ?
O4 C8 C4 117.6(5) . . ?
C10 C9 C6 113.6(4) . . ?
C10 C9 H9A 108.9 . . ?
C6 C9 H9A 108.9 . . ?
C10 C9 H9B 108.9 . . ?
C6 C9 H9B 108.9 . . ?
H9A C9 H9B 107.7 . . ?
C15 C10 C11 119.8(5) . . ?
C15 C10 C9 122.1(5) . . ?
C11 C10 C9 117.3(5) . . ?
C10 C11 C12 121.1(5) . . ?
C10 C11 H11 119.5 . . ?
C12 C11 H11 119.5 . . ?
C13 C12 C11 119.4(6) . . ?
C13 C12 C16 120.1(5) . . ?
C11 C12 C16 120.5(5) . . ?
C12 C13 C14 120.7(5) . . ?
C12 C13 H13 119.7 . . ?
C14 C13 H13 119.7 . . ?
C13 C14 C15 119.0(5) . . ?
C13 C14 C17 122.1(5) . . ?
C15 C14 C17 118.8(5) . . ?
C10 C15 C14 119.7(5) . . ?
C10 C15 H15 120.2 . . ?
C14 C15 H15 120.2 . . ?
O5 C16 O6 126.2(6) . 1_655 ?
O5 C16 C12 117.5(5) . . ?
O6 C16 C12 116.3(5) 1_655 . ?
O8 C17 O7 128.7(5) . . ?
O8 C17 C14 118.4(5) . . ?
O7 C17 C14 112.9(5) . . ?
N1 C18 C19 115.7(5) . . ?
N1 C18 H18 122.2 . . ?
C19 C18 H18 122.2 . . ?
C18 C19 N2 102.3(5) . . ?
C18 C19 H19 128.9 . . ?
N2 C19 H19 128.9 . . ?
N1 C20 N2 113.3(5) . . ?
N1 C20 H20 123.4 . . ?
N2 C20 H20 123.4 . . ?
N2 C21 C22 115.6(5) . . ?
N2 C21 H21A 108.4 . . ?
C22 C21 H21A 108.4 . . ?
N2 C21 H21B 108.4 . . ?
C22 C21 H21B 108.4 . . ?
H21A C21 H21B 107.4 . . ?
C23 C22 C27 117.8(6) . . ?
C23 C22 C21 121.6(5) . . ?
C27 C22 C21 120.5(5) . . ?
C22 C23 C24 121.7(6) . . ?
C22 C23 H23 119.1 . . ?
C24 C23 H23 119.1 . . ?
C23 C24 C25 120.7(5) . . ?
C23 C24 H24 119.7 . . ?
C25 C24 H24 119.7 . . ?
C26 C25 C24 118.1(6) . . ?
C26 C25 C28 125.2(6) . . ?
C24 C25 C28 116.7(5) . . ?
C25 C26 C27 123.0(6) . . ?
C25 C26 H26 118.5 . . ?
C27 C26 H26 118.5 . . ?
C26 C27 C22 118.7(5) . . ?
C26 C27 H27 120.7 . . ?
C22 C27 H27 120.7 . . ?
N4 C28 C25 113.8(5) 1_655 . ?
N4 C28 H28A 108.8 1_655 . ?
C25 C28 H28A 108.8 . . ?
N4 C28 H28B 108.8 1_655 . ?
C25 C28 H28B 108.8 . . ?
H28A C28 H28B 107.7 . . ?
C30 C29 N3 108.6(5) . . ?
C30 C29 H29 125.7 . . ?
N3 C29 H29 125.7 . . ?
N4 C30 C29 109.2(5) . . ?
N4 C30 H30 125.4 . . ?
C29 C30 H30 125.4 . . ?
N3 C31 N4 110.3(5) . . ?
N3 C31 H31 124.9 . . ?
N4 C31 H31 124.9 . . ?
C33 C32 N5 113.1(5) . . ?
C33 C32 H32 123.5 . . ?
N5 C32 H32 123.5 . . ?
C32 C33 N6 105.4(5) . . ?
C32 C33 H33 127.3 . . ?
N6 C33 H33 127.3 . . ?
N5 C34 N6 109.3(5) . . ?
N5 C34 H34 125.4 . . ?
N6 C34 H34 125.4 . . ?
N6 C35 C36 113.2(5) . . ?
N6 C35 H35A 108.9 . . ?
C36 C35 H35A 108.9 . . ?
N6 C35 H35B 108.9 . . ?
C36 C35 H35B 108.9 . . ?
H35A C35 H35B 107.7 . . ?
C37 C36 C41 119.9(6) . . ?
C37 C36 C35 120.2(6) . . ?
C41 C36 C35 119.8(5) . . ?
C36 C37 C38 120.2(6) . . ?
C36 C37 H37 119.9 . . ?
C38 C37 H37 119.9 . . ?
C39 C38 C37 120.7(6) . . ?
C39 C38 H38 119.6 . . ?
C37 C38 H38 119.6 . . ?
C38 C39 C40 118.4(6) . . ?
C38 C39 C42 121.6(5) . . ?
C40 C39 C42 120.0(5) . . ?
C41 C40 C39 121.6(6) . . ?
C41 C40 H40 119.2 . . ?
C39 C40 H40 119.2 . . ?
C40 C41 C36 119.0(6) . . ?
C40 C41 H41 120.5 . . ?
C36 C41 H41 120.5 . . ?
N8 C42 C39 115.0(4) 1_455 . ?
N8 C42 H42A 108.5 1_455 . ?
C39 C42 H42A 108.5 . . ?
N8 C42 H42B 108.5 1_455 . ?
C39 C42 H42B 108.5 . . ?
H42A C42 H42B 107.5 . . ?
C44 C43 N8 105.9(5) . . ?
C44 C43 H43A 127.1 . . ?
N8 C43 H43A 127.1 . . ?
C43 C44 N7 110.6(5) . . ?
C43 C44 H44A 124.7 . . ?
N7 C44 H44A 124.7 . . ?
N8 C45 N7 111.9(5) . . ?
N8 C45 H45A 124.1 . . ?
N7 C45 H45A 124.1 . . ?
C47 C46 N9 112.7(5) . . ?
C47 C46 H46 123.6 . . ?
N9 C46 H46 123.6 . . ?
C46 C47 N10 105.4(5) . . ?
C46 C47 H47 127.3 . . ?
N10 C47 H47 127.3 . . ?
N9 C48 N10 113.2(5) . . ?
N9 C48 H48 123.4 . . ?
N10 C48 H48 123.4 . . ?
N10 C49 C50 111.8(5) . . ?
N10 C49 H49A 109.3 . . ?
C50 C49 H49A 109.3 . . ?
N10 C49 H49B 109.3 . . ?
C50 C49 H49B 109.3 . . ?
H49A C49 H49B 107.9 . . ?
C55 C50 C51 119.7(6) . . ?
C55 C50 C49 122.1(5) . . ?
C51 C50 C49 118.2(5) . . ?
C52 C51 C50 119.5(5) . . ?
C52 C51 H51 120.3 . . ?
C50 C51 H51 120.3 . . ?
C51 C52 C53 121.7(5) . . ?
C51 C52 H52 119.2 . . ?
C53 C52 H52 119.2 . . ?
C52 C53 C54 118.1(6) . . ?
C52 C53 C56 123.6(5) . . ?
C54 C53 C56 118.3(5) . . ?
C55 C54 C53 119.4(6) . . ?
C55 C54 H54 120.3 . . ?
C53 C54 H54 120.3 . . ?
C50 C55 C54 121.6(6) . . ?
C50 C55 H55 119.2 . . ?
C54 C55 H55 119.2 . . ?
N12 C56 C53 116.3(5) 1_655 . ?
N12 C56 H56A 108.2 1_655 . ?
C53 C56 H56A 108.2 . . ?
N12 C56 H56B 108.2 1_655 . ?
C53 C56 H56B 108.2 . . ?
H56A C56 H56B 107.4 . . ?
C58 C57 N11 109.2(5) . . ?
C58 C57 H57 125.4 . . ?
N11 C57 H57 125.4 . . ?
C57 C58 N12 107.3(5) . . ?
C57 C58 H58 126.4 . . ?
N12 C58 H58 126.4 . . ?
N11 C59 N12 110.2(5) . . ?
N11 C59 H59 124.9 . . ?
N12 C59 H59 124.9 . . ?
C20 N1 C18 102.5(5) . . ?
C20 N1 Ag2 124.4(4) . . ?
C18 N1 Ag2 132.9(4) . . ?
C20 N2 C19 106.2(5) . . ?
C20 N2 C21 126.3(5) . . ?
C19 N2 C21 127.4(5) . . ?
C31 N3 C29 106.6(5) . . ?
C31 N3 Ag2 126.9(4) . . ?
C29 N3 Ag2 126.1(4) . . ?
C30 N4 C31 105.4(5) . . ?
C30 N4 C28 130.1(5) . 1_455 ?
C31 N4 C28 124.6(5) . 1_455 ?
C34 N5 C32 104.9(4) . . ?
C34 N5 Ag3 125.0(3) . . ?
C32 N5 Ag3 130.1(4) . . ?
C34 N6 C33 107.2(4) . . ?
C34 N6 C35 123.9(5) . . ?
C33 N6 C35 128.8(5) . . ?
C45 N7 C44 105.0(4) . . ?
C45 N7 Ag3 127.2(4) . . ?
C44 N7 Ag3 127.7(4) . . ?
C45 N8 C43 106.7(5) . . ?
C45 N8 C42 127.5(5) . 1_655 ?
C43 N8 C42 125.8(5) . 1_655 ?
C48 N9 C46 104.1(5) . . ?
C48 N9 Ag4 128.5(4) . . ?
C46 N9 Ag4 126.9(4) . . ?
C48 N10 C47 104.5(5) . . ?
C48 N10 C49 131.1(5) . . ?
C47 N10 C49 124.4(4) . . ?
C59 N11 C57 105.3(5) . . ?
C59 N11 Ag4 125.1(4) . . ?
C57 N11 Ag4 129.5(4) . . ?
C58 N12 C59 107.9(5) . . ?
C58 N12 C56 128.8(5) . 1_455 ?
C59 N12 C56 123.2(5) . 1_455 ?
C1 O1 Ag1 104.2(4) . . ?
C16 O6 Ag1 104.3(4) 1_455 . ?
H10B O10 H10D 109.4 . . ?
H11A O11 H11B 109.4 . . ?
H9C O19 H9D 109.3 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O1 2.169(4) . ?
Ag1 O6 2.193(4) . ?
Ag2 N1 2.129(4) . ?
Ag2 N3 2.136(5) . ?
Ag2 Ag3 3.2509(6) . ?
Ag3 N7 2.077(4) . ?
Ag3 N5 2.100(4) . ?
Ag3 Ag4 3.2813(6) . ?
Ag4 N11 2.080(5) . ?
Ag4 N9 2.096(5) . ?
C1 O1 1.219(7) . ?
C1 O2 1.267(7) . ?
C1 C2 1.494(8) . ?
C2 C3 1.413(7) . ?
C2 C7 1.423(7) . ?
C3 C4 1.353(8) . ?
C3 H3 0.9300 . ?
C4 C5 1.433(8) . ?
C4 C8 1.502(8) . ?
C5 C6 1.330(8) . ?
C5 H5 0.9300 . ?
C6 C7 1.388(8) . ?
C6 C9 1.480(7) . ?
C7 H7 0.9300 . ?
C8 O3 1.207(6) . ?
C8 O4 1.276(7) . ?
C9 C10 1.464(8) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 C15 1.377(7) . ?
C10 C11 1.406(8) . ?
C11 C12 1.426(8) . ?
C11 H11 0.9300 . ?
C12 C13 1.383(8) . ?
C12 C16 1.519(8) . ?
C13 C14 1.414(8) . ?
C13 H13 0.9300 . ?
C14 C15 1.461(8) . ?
C14 C17 1.511(8) . ?
C15 H15 0.9300 . ?
C16 O5 1.241(6) . ?
C16 O6 1.258(7) 1_655 ?
C17 O8 1.224(7) . ?
C17 O7 1.271(6) . ?
C18 N1 1.314(7) . ?
C18 C19 1.324(8) . ?
C18 H18 0.9300 . ?
C19 N2 1.391(7) . ?
C19 H19 0.9300 . ?
C20 N1 1.305(7) . ?
C20 N2 1.325(7) . ?
C20 H20 0.9300 . ?
C21 N2 1.439(7) . ?
C21 C22 1.500(8) . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C22 C23 1.360(7) . ?
C22 C27 1.396(8) . ?
C23 C24 1.361(8) . ?
C23 H23 0.9300 . ?
C24 C25 1.364(8) . ?
C24 H24 0.9300 . ?
C25 C26 1.339(8) . ?
C25 C28 1.492(9) . ?
C26 C27 1.371(8) . ?
C26 H26 0.9300 . ?
C27 H27 0.9300 . ?
C28 N4 1.464(7) 1_655 ?
C28 H28A 0.9700 . ?
C28 H28B 0.9700 . ?
C29 C30 1.326(8) . ?
C29 N3 1.362(7) . ?
C29 H29 0.9300 . ?
C30 N4 1.319(7) . ?
C30 H30 0.9300 . ?
C31 N3 1.287(7) . ?
C31 N4 1.386(7) . ?
C31 H31 0.9300 . ?
C32 C33 1.255(7) . ?
C32 N5 1.421(6) . ?
C32 H32 0.9300 . ?
C33 N6 1.423(7) . ?
C33 H33 0.9300 . ?
C34 N5 1.313(7) . ?
C34 N6 1.375(7) . ?
C34 H34 0.9300 . ?
C35 N6 1.445(7) . ?
C35 C36 1.510(8) . ?
C35 H35A 0.9700 . ?
C35 H35B 0.9700 . ?
C36 C37 1.359(8) . ?
C36 C41 1.385(8) . ?
C37 C38 1.406(9) . ?
C37 H37 0.9300 . ?
C38 C39 1.346(8) . ?
C38 H38 0.9300 . ?
C39 C40 1.398(7) . ?
C39 C42 1.501(8) . ?
C40 C41 1.374(8) . ?
C40 H40 0.9300 . ?
C41 H41 0.9300 . ?
C42 N8 1.439(7) 1_455 ?
C42 H42A 0.9700 . ?
C42 H42B 0.9700 . ?
C43 C44 1.359(7) . ?
C43 N8 1.392(7) . ?
C43 H43A 0.9300 . ?
C44 N7 1.362(6) . ?
C44 H44A 0.9300 . ?
C45 N8 1.335(7) . ?
C45 N7 1.345(7) . ?
C45 H45A 0.9300 . ?
C46 C47 1.295(7) . ?
C46 N9 1.359(7) . ?
C46 H46 0.9300 . ?
C47 N10 1.421(7) . ?
C47 H47 0.9300 . ?
C48 N9 1.303(7) . ?
C48 N10 1.334(7) . ?
C48 H48 0.9300 . ?
C49 N10 1.444(7) . ?
C49 C50 1.501(8) . ?
C49 H49A 0.9700 . ?
C49 H49B 0.9700 . ?
C50 C55 1.363(8) . ?
C50 C51 1.408(7) . ?
C51 C52 1.380(8) . ?
C51 H51 0.9300 . ?
C52 C53 1.382(8) . ?
C52 H52 0.9300 . ?
C53 C54 1.434(8) . ?
C53 C56 1.467(8) . ?
C54 C55 1.379(8) . ?
C54 H54 0.9300 . ?
C55 H55 0.9300 . ?
C56 N12 1.464(7) 1_655 ?
C56 H56A 0.9700 . ?
C56 H56B 0.9700 . ?
C57 C58 1.322(8) . ?
C57 N11 1.391(7) . ?
C57 H57 0.9300 . ?
C58 N12 1.339(7) . ?
C58 H58 0.9300 . ?
C59 N11 1.309(7) . ?
C59 N12 1.348(7) . ?
C59 H59 0.9300 . ?
N4 C28 1.464(7) 1_455 ?
N8 C42 1.439(7) 1_655 ?
N12 C56 1.464(7) 1_455 ?
O6 C16 1.258(7) 1_455 ?
O10 H10B 0.8507 . ?
O10 H10D 0.8501 . ?
O11 H11A 0.8493 . ?
O11 H11B 0.8506 . ?
O19 H9C 0.8497 . ?
O19 H9D 0.8512 . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O10 H10D O3 0.85 2.25 2.785(10) 120.6 3_666
O11 H11A O8 0.85 2.37 2.774(14) 110.1 2_646
O11 H11B O19 0.85 1.90 2.746(18) 170.6 3_666
O19 H9D O11 0.85 2.29 2.746(17) 113.6 3_666
O11 H11A O11 0.85 2.28 2.93(2) 133.1 3_657
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Ag2 Ag3 N7 16.86(17) . . . . ?
N3 Ag2 Ag3 N7 -154.55(18) . . . . ?
N1 Ag2 Ag3 N5 -164.15(17) . . . . ?
N3 Ag2 Ag3 N5 24.44(18) . . . . ?
N1 Ag2 Ag3 Ag4 121.08(17) . . . . ?
N3 Ag2 Ag3 Ag4 -50.33(18) . . . . ?
N7 Ag3 Ag4 N11 162.39(18) . . . . ?
N5 Ag3 Ag4 N11 -16.68(17) . . . . ?
Ag2 Ag3 Ag4 N11 56.78(18) . . . . ?
N7 Ag3 Ag4 N9 -14.81(19) . . . . ?
N5 Ag3 Ag4 N9 166.12(19) . . . . ?
Ag2 Ag3 Ag4 N9 -120.42(18) . . . . ?
O1 C1 C2 C3 7.5(8) . . . . ?
O2 C1 C2 C3 -175.6(4) . . . . ?
O1 C1 C2 C7 -174.7(5) . . . . ?
O2 C1 C2 C7 2.2(8) . . . . ?
C7 C2 C3 C4 0.6(7) . . . . ?
C1 C2 C3 C4 178.6(5) . . . . ?
C2 C3 C4 C5 -1.0(8) . . . . ?
C2 C3 C4 C8 179.4(5) . . . . ?
C3 C4 C5 C6 -0.3(8) . . . . ?
C8 C4 C5 C6 179.3(5) . . . . ?
C4 C5 C6 C7 1.9(8) . . . . ?
C4 C5 C6 C9 -177.7(5) . . . . ?
C5 C6 C7 C2 -2.2(8) . . . . ?
C9 C6 C7 C2 177.4(5) . . . . ?
C3 C2 C7 C6 1.1(7) . . . . ?
C1 C2 C7 C6 -176.9(5) . . . . ?
C3 C4 C8 O3 -6.0(8) . . . . ?
C5 C4 C8 O3 174.5(5) . . . . ?
C3 C4 C8 O4 171.6(5) . . . . ?
C5 C4 C8 O4 -7.9(8) . . . . ?
C5 C6 C9 C10 64.4(7) . . . . ?
C7 C6 C9 C10 -115.2(6) . . . . ?
C6 C9 C10 C15 75.4(7) . . . . ?
C6 C9 C10 C11 -94.2(6) . . . . ?
C15 C10 C11 C12 6.1(7) . . . . ?
C9 C10 C11 C12 176.0(5) . . . . ?
C10 C11 C12 C13 -2.2(8) . . . . ?
C10 C11 C12 C16 -179.4(5) . . . . ?
C11 C12 C13 C14 -0.6(8) . . . . ?
C16 C12 C13 C14 176.6(5) . . . . ?
C12 C13 C14 C15 -0.4(8) . . . . ?
C12 C13 C14 C17 -177.7(5) . . . . ?
C11 C10 C15 C14 -7.0(7) . . . . ?
C9 C10 C15 C14 -176.3(5) . . . . ?
C13 C14 C15 C10 4.2(7) . . . . ?
C17 C14 C15 C10 -178.4(5) . . . . ?
C13 C12 C16 O5 -168.9(5) . . . . ?
C11 C12 C16 O5 8.2(7) . . . . ?
C13 C12 C16 O6 10.2(7) . . . 1_655 ?
C11 C12 C16 O6 -172.6(5) . . . 1_655 ?
C13 C14 C17 O8 169.0(5) . . . . ?
C15 C14 C17 O8 -8.3(7) . . . . ?
C13 C14 C17 O7 -12.3(7) . . . . ?
C15 C14 C17 O7 170.4(5) . . . . ?
N1 C18 C19 N2 -1.3(7) . . . . ?
N2 C21 C22 C23 -148.3(5) . . . . ?
N2 C21 C22 C27 34.0(8) . . . . ?
C27 C22 C23 C24 -0.1(8) . . . . ?
C21 C22 C23 C24 -177.8(5) . . . . ?
C22 C23 C24 C25 -0.8(9) . . . . ?
C23 C24 C25 C26 2.8(8) . . . . ?
C23 C24 C25 C28 179.5(5) . . . . ?
C24 C25 C26 C27 -4.0(9) . . . . ?
C28 C25 C26 C27 179.5(6) . . . . ?
C25 C26 C27 C22 3.2(9) . . . . ?
C23 C22 C27 C26 -1.1(8) . . . . ?
C21 C22 C27 C26 176.7(5) . . . . ?
C26 C25 C28 N4 -103.7(7) . . . 1_655 ?
C24 C25 C28 N4 79.8(6) . . . 1_655 ?
N3 C29 C30 N4 -1.4(7) . . . . ?
N5 C32 C33 N6 3.1(7) . . . . ?
N6 C35 C36 C37 -81.8(7) . . . . ?
N6 C35 C36 C41 94.7(6) . . . . ?
C41 C36 C37 C38 4.3(9) . . . . ?
C35 C36 C37 C38 -179.2(6) . . . . ?
C36 C37 C38 C39 -3.8(10) . . . . ?
C37 C38 C39 C40 2.5(9) . . . . ?
C37 C38 C39 C42 -178.8(5) . . . . ?
C38 C39 C40 C41 -2.0(8) . . . . ?
C42 C39 C40 C41 179.3(5) . . . . ?
C39 C40 C41 C36 2.5(8) . . . . ?
C37 C36 C41 C40 -3.7(9) . . . . ?
C35 C36 C41 C40 179.8(5) . . . . ?
C38 C39 C42 N8 -91.2(6) . . . 1_455 ?
C40 C39 C42 N8 87.5(6) . . . 1_455 ?
N8 C43 C44 N7 -0.5(7) . . . . ?
N9 C46 C47 N10 2.2(7) . . . . ?
N10 C49 C50 C55 -66.4(7) . . . . ?
N10 C49 C50 C51 112.5(5) . . . . ?
C55 C50 C51 C52 0.4(8) . . . . ?
C49 C50 C51 C52 -178.6(5) . . . . ?
C50 C51 C52 C53 -2.0(8) . . . . ?
C51 C52 C53 C54 2.9(8) . . . . ?
C51 C52 C53 C56 -175.7(5) . . . . ?
C52 C53 C54 C55 -2.1(8) . . . . ?
C56 C53 C54 C55 176.5(5) . . . . ?
C51 C50 C55 C54 0.3(8) . . . . ?
C49 C50 C55 C54 179.2(5) . . . . ?
C53 C54 C55 C50 0.6(9) . . . . ?
C52 C53 C56 N12 -25.8(8) . . . 1_655 ?
C54 C53 C56 N12 155.6(5) . . . 1_655 ?
N11 C57 C58 N12 1.8(7) . . . . ?
N2 C20 N1 C18 1.5(7) . . . . ?
N2 C20 N1 Ag2 177.2(4) . . . . ?
C19 C18 N1 C20 0.0(7) . . . . ?
C19 C18 N1 Ag2 -175.2(4) . . . . ?
N3 Ag2 N1 C20 51.8(7) . . . . ?
Ag3 Ag2 N1 C20 -105.1(4) . . . . ?
N3 Ag2 N1 C18 -133.9(6) . . . . ?
Ag3 Ag2 N1 C18 69.2(5) . . . . ?
N1 C20 N2 C19 -2.4(7) . . . . ?
N1 C20 N2 C21 -177.9(5) . . . . ?
C18 C19 N2 C20 2.1(6) . . . . ?
C18 C19 N2 C21 177.5(6) . . . . ?
C22 C21 N2 C20 -133.4(6) . . . . ?
C22 C21 N2 C19 52.0(8) . . . . ?
N4 C31 N3 C29 -1.2(7) . . . . ?
N4 C31 N3 Ag2 172.1(4) . . . . ?
C30 C29 N3 C31 1.6(7) . . . . ?
C30 C29 N3 Ag2 -171.7(4) . . . . ?
N1 Ag2 N3 C31 -51.1(8) . . . . ?
Ag3 Ag2 N3 C31 103.6(5) . . . . ?
N1 Ag2 N3 C29 120.8(6) . . . . ?
Ag3 Ag2 N3 C29 -84.5(5) . . . . ?
C29 C30 N4 C31 0.7(7) . . . . ?
C29 C30 N4 C28 -178.8(6) . . . 1_455 ?
N3 C31 N4 C30 0.3(7) . . . . ?
N3 C31 N4 C28 179.9(6) . . . 1_455 ?
N6 C34 N5 C32 -1.6(6) . . . . ?
N6 C34 N5 Ag3 176.7(3) . . . . ?
C33 C32 N5 C34 -1.1(7) . . . . ?
C33 C32 N5 Ag3 -179.2(4) . . . . ?
N7 Ag3 N5 C34 49(10) . . . . ?
Ag2 Ag3 N5 C34 -62.3(4) . . . . ?
Ag4 Ag3 N5 C34 109.7(4) . . . . ?
N7 Ag3 N5 C32 -133(9) . . . . ?
Ag2 Ag3 N5 C32 115.5(4) . . . . ?
Ag4 Ag3 N5 C32 -72.5(4) . . . . ?
N5 C34 N6 C33 3.4(6) . . . . ?
N5 C34 N6 C35 -178.8(5) . . . . ?
C32 C33 N6 C34 -3.9(6) . . . . ?
C32 C33 N6 C35 178.4(6) . . . . ?
C36 C35 N6 C34 -97.2(6) . . . . ?
C36 C35 N6 C33 80.1(7) . . . . ?
N8 C45 N7 C44 -1.2(6) . . . . ?
N8 C45 N7 Ag3 -177.2(4) . . . . ?
C43 C44 N7 C45 1.1(6) . . . . ?
C43 C44 N7 Ag3 176.9(4) . . . . ?
N5 Ag3 N7 C45 132(9) . . . . ?
Ag2 Ag3 N7 C45 -116.4(4) . . . . ?
Ag4 Ag3 N7 C45 71.5(4) . . . . ?
N5 Ag3 N7 C44 -43(10) . . . . ?
Ag2 Ag3 N7 C44 68.5(4) . . . . ?
Ag4 Ag3 N7 C44 -103.5(4) . . . . ?
N7 C45 N8 C43 0.9(7) . . . . ?
N7 C45 N8 C42 -179.7(5) . . . 1_655 ?
C44 C43 N8 C45 -0.3(7) . . . . ?
C44 C43 N8 C42 -179.6(5) . . . 1_655 ?
N10 C48 N9 C46 -1.1(7) . . . . ?
N10 C48 N9 Ag4 -173.5(4) . . . . ?
C47 C46 N9 C48 -0.8(7) . . . . ?
C47 C46 N9 Ag4 171.8(4) . . . . ?
N11 Ag4 N9 C48 71.7(9) . . . . ?
Ag3 Ag4 N9 C48 -118.8(5) . . . . ?
N11 Ag4 N9 C46 -99.1(8) . . . . ?
Ag3 Ag4 N9 C46 70.5(5) . . . . ?
N9 C48 N10 C47 2.4(7) . . . . ?
N9 C48 N10 C49 -178.6(5) . . . . ?
C46 C47 N10 C48 -2.7(6) . . . . ?
C46 C47 N10 C49 178.2(5) . . . . ?
C50 C49 N10 C48 101.4(7) . . . . ?
C50 C49 N10 C47 -79.7(7) . . . . ?
N12 C59 N11 C57 0.2(7) . . . . ?
N12 C59 N11 Ag4 -175.9(4) . . . . ?
C58 C57 N11 C59 -1.3(7) . . . . ?
C58 C57 N11 Ag4 174.6(4) . . . . ?
N9 Ag4 N11 C59 -73.6(9) . . . . ?
Ag3 Ag4 N11 C59 116.4(5) . . . . ?
N9 Ag4 N11 C57 111.3(7) . . . . ?
Ag3 Ag4 N11 C57 -58.7(5) . . . . ?
C57 C58 N12 C59 -1.6(7) . . . . ?
C57 C58 N12 C56 -179.9(6) . . . 1_455 ?
N11 C59 N12 C58 0.9(7) . . . . ?
N11 C59 N12 C56 179.2(5) . . . 1_455 ?
O2 C1 O1 Ag1 3.7(7) . . . . ?
C2 C1 O1 Ag1 -179.8(4) . . . . ?
O6 Ag1 O1 C1 42.3(9) . . . . ?
O1 Ag1 O6 C16 -158.3(6) . . . 1_455 ?
