#------------------------------------------------------------------------------
#$Date: 2017-07-11 15:10:40 +0300 (Tue, 11 Jul 2017) $
#$Revision: 198633 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/20/58/7205852.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7205852
loop_
_publ_author_name
'Liu, Hai-Yang'
'Yuan, Yong-Jun'
'Yu, Zhen-Tao'
'Zou, Zhi-Gang'
_publ_section_title
;
 Direct assembly of new cobalt(iii)-lanthanide(iii) heterometallic
 frameworks with NaCl-like topology
;
_journal_issue                   7
_journal_name_full               CrystEngComm
_journal_page_first              2391
_journal_paper_doi               10.1039/c0ce00881h
_journal_volume                  13
_journal_year                    2011
_chemical_formula_sum            'C72 H74 Co2 Eu4 N18 O61'
_chemical_formula_weight         2893.19
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                101.9860(10)
_cell_angle_beta                 103.319(2)
_cell_angle_gamma                95.5480(10)
_cell_formula_units_Z            1
_cell_length_a                   11.1668(11)
_cell_length_b                   12.4554(12)
_cell_length_c                   22.2593(15)
_cell_measurement_reflns_used    2816
_cell_measurement_temperature    291(2)
_cell_measurement_theta_max      23.60
_cell_measurement_theta_min      2.25
_cell_volume                     2912.9(4)
_computing_cell_refinement       SMART
_computing_data_collection       'SMART (Bruker, 2000)'
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL (Bruker, 2000)'
_diffrn_ambient_temperature      291(2)
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'Bruker Smart Apex CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0231
_diffrn_reflns_av_sigmaI/netI    0.0492
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            16170
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.74
_exptl_absorpt_coefficient_mu    2.500
_exptl_absorpt_correction_T_max  0.6092
_exptl_absorpt_correction_T_min  0.5209
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.649
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1426
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.22
_refine_diff_density_max         1.096
_refine_diff_density_min         -1.261
_refine_diff_density_rms         0.108
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.088
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           fullcycle
_refine_ls_number_parameters     739
_refine_ls_number_reflns         11257
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.088
_refine_ls_R_factor_all          0.0629
_refine_ls_R_factor_gt           0.0438
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.06P)²+0.55P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1045
_refine_ls_wR_factor_ref         0.1095
_reflns_number_gt                8280
_reflns_number_total             11257
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c0ce00881h.txt
_cod_data_source_block           5
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 

The following automatic conversions were performed:

'_refine_ls_hydrogen_treatment' value 'const' was replaced with the
value 'constr' as specified in the replacement file
'src/cod-tools/trunk/data/replacement-values/replacement_values.lst'.

Automatic conversion script
Id: cif_fix_values 5376 2017-05-30 11:51:03Z andrius 
;
_cod_original_sg_symbol_H-M      'P-1 '
_cod_database_code               7205852
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.6988(5) 0.8272(4) 0.3712(3) 0.0442(13) Uani 1 1 d . . .
H1A H 0.7747 0.8736 0.3884 0.053 Uiso 1 1 calc R . .
C2 C 0.6541(6) 0.7589(5) 0.4087(3) 0.0530(15) Uani 1 1 d . . .
H2A H 0.6978 0.7638 0.4504 0.064 Uiso 1 1 calc R . .
C3 C 0.5457(5) 0.6870(4) 0.3814(2) 0.0361(11) Uani 1 1 d . . .
C4 C 0.4773(5) 0.6884(4) 0.3168(2) 0.0373(11) Uani 1 1 d . . .
H4A H 0.4032 0.6402 0.2970 0.045 Uiso 1 1 calc R . .
C5 C 0.5222(5) 0.7597(4) 0.2862(2) 0.0384(11) Uani 1 1 d . . .
C6 C 0.4644(5) 0.7684(4) 0.2213(2) 0.0371(11) Uani 1 1 d . . .
C7 C 0.3583(5) 0.6940(4) 0.1794(3) 0.0397(11) Uani 1 1 d . . .
H7A H 0.3238 0.6349 0.1926 0.048 Uiso 1 1 calc R . .
C8 C 0.3050(5) 0.7095(4) 0.1177(2) 0.0371(11) Uani 1 1 d . . .
C9 C 0.3537(5) 0.7998(5) 0.1037(2) 0.0402(11) Uani 1 1 d . . .
H9A H 0.3154 0.8183 0.0663 0.048 Uiso 1 1 calc R . .
C10 C 0.4614(5) 0.8678(4) 0.1441(3) 0.0406(12) Uani 1 1 d . . .
H10E H 0.4978 0.9253 0.1303 0.049 Uiso 1 1 calc R . .
C11 C 0.4937(5) 0.6097(4) 0.4158(2) 0.0372(11) Uani 1 1 d . . .
C12 C 0.1946(5) 0.6312(5) 0.0742(3) 0.0482(14) Uani 1 1 d . . .
C13 C 0.7173(5) 1.1087(4) 0.1974(3) 0.0390(11) Uani 1 1 d . . .
H13E H 0.6833 1.1522 0.2265 0.047 Uiso 1 1 calc R . .
C14 C 0.7617(4) 1.1526(4) 0.1567(3) 0.0405(12) Uani 1 1 d . . .
H14E H 0.7597 1.2275 0.1580 0.049 Uiso 1 1 calc R . .
C15 C 0.8125(5) 1.0893(4) 0.1110(2) 0.0377(11) Uani 1 1 d . . .
C16 C 0.8184(5) 0.9812(4) 0.1101(2) 0.0404(12) Uani 1 1 d . . .
H16E H 0.8518 0.9380 0.0805 0.048 Uiso 1 1 calc R . .
C17 C 0.7736(5) 0.9353(4) 0.1544(3) 0.0386(11) Uani 1 1 d . . .
C18 C 0.7705(5) 0.8178(4) 0.1560(3) 0.0400(11) Uani 1 1 d . . .
C19 C 0.8160(5) 0.7395(5) 0.1159(3) 0.0425(12) Uani 1 1 d . . .
H19E H 0.8419 0.7580 0.0821 0.051 Uiso 1 1 calc R . .
C20 C 0.8225(5) 0.6350(4) 0.1263(3) 0.0398(11) Uani 1 1 d . . .
C21 C 0.7934(5) 0.6111(4) 0.1774(3) 0.0410(12) Uani 1 1 d . . .
H21D H 0.8014 0.5425 0.1870 0.049 Uiso 1 1 calc R . .
C22 C 0.7505(4) 0.6934(4) 0.2154(2) 0.0344(10) Uani 1 1 d . . .
H22C H 0.7293 0.6744 0.2503 0.041 Uiso 1 1 calc R . .
C23 C 0.8658(6) 1.1416(5) 0.0680(3) 0.0490(13) Uani 1 1 d . . .
C24 C 0.8785(5) 0.5602(4) 0.0843(2) 0.0390(11) Uani 1 1 d . . .
C25 C 0.9505(4) 0.9375(4) 0.3083(2) 0.0349(10) Uani 1 1 d . . .
H25E H 0.9467 0.8696 0.2804 0.042 Uiso 1 1 calc R . .
C26 C 1.0663(6) 0.9931(5) 0.3466(3) 0.0498(14) Uani 1 1 d . . .
H26A H 1.1377 0.9599 0.3484 0.060 Uiso 1 1 calc R . .
C27 C 1.0704(5) 1.0977(4) 0.3812(3) 0.0391(11) Uani 1 1 d . . .
C28 C 0.9558(4) 1.1459(4) 0.3861(2) 0.0341(10) Uani 1 1 d . . .
H28A H 0.9580 1.2147 0.4128 0.041 Uiso 1 1 calc R . .
C29 C 0.8474(4) 1.0832(4) 0.3492(2) 0.0324(10) Uani 1 1 d . . .
C30 C 0.7249(4) 1.1148(5) 0.3501(2) 0.0384(11) Uani 1 1 d . . .
C31 C 0.7037(5) 1.2045(5) 0.3889(3) 0.0438(12) Uani 1 1 d . . .
H31A H 0.7700 1.2533 0.4180 0.053 Uiso 1 1 calc R . .
C32 C 0.5778(5) 1.2251(5) 0.3855(3) 0.0420(11) Uani 1 1 d . . .
C33 C 0.4833(5) 1.1523(4) 0.3386(2) 0.0397(11) Uani 1 1 d . . .
H33A H 0.4017 1.1660 0.3345 0.048 Uiso 1 1 calc R . .
C34 C 0.5051(5) 1.0623(5) 0.2988(3) 0.0439(12) Uani 1 1 d . . .
H34A H 0.4400 1.0157 0.2676 0.053 Uiso 1 1 calc R . .
C35 C 1.1935(5) 1.1708(4) 0.4173(3) 0.0430(12) Uani 1 1 d . . .
C36 C 0.5447(5) 1.3223(5) 0.4277(3) 0.0492(14) Uani 1 1 d . . .
Co1 Co 0.67778(6) 0.91394(5) 0.25723(3) 0.03368(15) Uani 1 1 d . . .
Eu1 Eu 0.69870(2) 0.55354(2) 0.548601(12) 0.03476(8) Uani 1 1 d . . .
Eu2 Eu 0.04045(2) 0.36846(2) 0.050600(12) 0.03672(8) Uani 1 1 d . . .
N1 N 0.6314(4) 0.8259(4) 0.3093(2) 0.0397(10) Uani 1 1 d . . .
N2 N 0.5147(4) 0.8536(3) 0.2025(2) 0.0381(9) Uani 1 1 d . . .
N3 N 0.7212(4) 0.9935(3) 0.19702(19) 0.0338(9) Uani 1 1 d . . .
N4 N 0.7356(4) 0.7924(3) 0.20962(19) 0.0355(9) Uani 1 1 d . . .
N5 N 0.8445(4) 0.9791(4) 0.3105(2) 0.0392(9) Uani 1 1 d . . .
N6 N 0.6253(4) 1.0416(3) 0.30555(19) 0.0321(8) Uani 1 1 d . . .
N7 N 0.1377(5) 0.9639(4) 0.2003(2) 0.0480(11) Uani 1 1 d . . .
N8 N 0.8757(6) 0.3944(4) 0.2911(2) 0.0556(13) Uani 1 1 d . . .
N9 N 0.7883(4) 0.1514(4) 0.5386(2) 0.0475(11) Uani 1 1 d . . .
O1 O 0.5700(3) 0.5904(3) 0.46235(17) 0.0407(8) Uani 1 1 d . . .
O2 O 0.3790(3) 0.5675(3) 0.39925(17) 0.0388(8) Uani 1 1 d . . .
O3 O 0.1599(3) 0.5489(3) 0.09087(17) 0.0392(8) Uani 1 1 d . . .
O4 O 0.1440(3) 0.6593(3) 0.02801(17) 0.0428(8) Uani 1 1 d . . .
O5 O 0.9084(3) 1.2441(3) 0.08138(17) 0.0383(8) Uani 1 1 d . . .
O6 O 0.8711(4) 1.0764(3) 0.01695(18) 0.0471(9) Uani 1 1 d . . .
O7 O 0.9045(3) 0.5841(3) 0.03714(16) 0.0367(7) Uani 1 1 d . . .
O8 O 0.9085(3) 0.4722(3) 0.10335(17) 0.0400(8) Uani 1 1 d . . .
O9 O 1.2866(3) 1.1257(3) 0.42811(18) 0.0419(8) Uani 1 1 d . . .
O10 O 1.1954(3) 1.2728(3) 0.43839(16) 0.0373(7) Uani 1 1 d . . .
O11 O 0.6365(3) 1.3774(3) 0.47096(17) 0.0396(8) Uani 1 1 d . . .
O12 O 0.4450(3) 1.3536(3) 0.41301(16) 0.0377(8) Uani 1 1 d . . .
O71 O 0.0983(4) 1.0522(3) 0.2031(2) 0.0542(11) Uani 1 1 d . . .
O72 O 0.0907(4) 0.8830(4) 0.1557(2) 0.0599(11) Uani 1 1 d . . .
O73 O 0.2245(4) 0.9535(3) 0.24147(18) 0.0463(9) Uani 1 1 d . . .
O81 O 0.9616(4) 0.3765(4) 0.26508(19) 0.0525(10) Uani 1 1 d . . .
O82 O 0.7877(4) 0.4291(3) 0.26143(18) 0.0467(9) Uani 1 1 d . . .
O83 O 0.8749(4) 0.3707(4) 0.3416(2) 0.0546(10) Uani 1 1 d . . .
O91 O 0.6836(4) 0.1029(3) 0.5225(2) 0.0534(10) Uani 1 1 d . . .
O92 O 0.8104(3) 0.2519(3) 0.56206(19) 0.0443(9) Uani 1 1 d . . .
O93 O 0.8759(4) 0.1011(3) 0.53123(17) 0.0447(9) Uani 1 1 d . . .
O1W O 0.7988(4) 0.6335(3) 0.66283(17) 0.0450(9) Uani 1 1 d . . .
H1X H 0.7429 0.6746 0.6820 0.054 Uiso 1 1 d R . .
H1Y H 0.8740 0.6825 0.6673 0.054 Uiso 1 1 d R . .
O2W O 0.8681(4) 0.4588(3) 0.5845(2) 0.0508(9) Uani 1 1 d . . .
H2X H 0.8390 0.3984 0.6009 0.061 Uiso 1 1 d R . .
H2Y H 0.9311 0.5102 0.6177 0.061 Uiso 1 1 d R . .
O3W O 0.8267(4) 0.5446(3) 0.47357(19) 0.0479(9) Uani 1 1 d . . .
H3X H 0.8821 0.6136 0.4837 0.058 Uiso 1 1 d R . .
H3Y H 0.7739 0.5324 0.4311 0.058 Uiso 1 1 d R . .
O4W O 0.1199(4) 0.3713(3) 0.16279(18) 0.0456(9) Uani 1 1 d . . .
H4X H 0.0514 0.3559 0.1806 0.055 Uiso 1 1 d R . .
H4Y H 0.1661 0.4434 0.1852 0.055 Uiso 1 1 d R . .
O5W O 0.2463(3) 0.3227(3) 0.0696(2) 0.0487(9) Uani 1 1 d . . .
H5X H 0.2566 0.2762 0.0314 0.058 Uiso 1 1 d R . .
H5Y H 0.3058 0.3895 0.0822 0.058 Uiso 1 1 d R . .
O6W O 0.0212(4) 0.1899(3) -0.02524(19) 0.0485(9) Uani 1 1 d . . .
H6X H -0.0180 0.1994 -0.0651 0.058 Uiso 1 1 d R . .
H6Y H -0.0170 0.1381 -0.0226 0.058 Uiso 1 1 d R . .
O7W O 0.1292(9) 0.5168(7) 0.2756(4) 0.059(2) Uani 0.50 1 d P . .
H7X H 0.1292 0.5865 0.2872 0.071 Uiso 0.50 1 d PR . .
H7Y H 0.1942 0.5026 0.2996 0.071 Uiso 0.50 1 d PR . .
O8W O 0.6439(8) 0.6474(6) 0.7543(4) 0.0458(18) Uani 0.50 1 d P . .
H8X H 0.5971 0.6146 0.7723 0.055 Uiso 0.50 1 d PR . .
H8Y H 0.6634 0.7157 0.7736 0.055 Uiso 0.50 1 d PR . .
O9W O 0.0943(8) 0.7154(7) 0.2189(4) 0.057(2) Uani 0.50 1 d P . .
H9X H 0.0161 0.7132 0.2052 0.069 Uiso 0.50 1 d PR . .
H9Y H 0.1287 0.7825 0.2351 0.069 Uiso 0.50 1 d PR . .
O10W O 0.9138(8) 0.6226(8) 0.3831(4) 0.060(2) Uani 0.50 1 d P . .
H10X H 0.8512 0.5931 0.3518 0.072 Uiso 0.50 1 d PR . .
H10Y H 0.9163 0.6928 0.3921 0.072 Uiso 0.50 1 d PR . .
O11W O 0.5068(8) 0.5154(6) 0.9173(3) 0.0447(18) Uani 0.50 1 d P . .
H11X H 0.4613 0.4749 0.8822 0.054 Uiso 0.50 1 d PR . .
H11Y H 0.5459 0.4746 0.9390 0.054 Uiso 0.50 1 d PR . .
O12W O 0.3562(8) 0.6893(7) 0.9540(4) 0.0471(18) Uani 0.50 1 d P . .
H12X H 0.3970 0.7331 0.9892 0.057 Uiso 0.50 1 d PR . .
H12Y H 0.2877 0.6597 0.9583 0.057 Uiso 0.50 1 d PR . .
O13W O 0.3960(8) 0.1577(7) 0.0748(4) 0.055(2) Uani 0.50 1 d P . .
H13X H 0.4078 0.1631 0.0390 0.066 Uiso 0.50 1 d PR . .
H13Y H 0.4340 0.1070 0.0874 0.066 Uiso 0.50 1 d PR . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 C2 122.2(4) . . ?
N1 C1 H1A 118.9 . . ?
C2 C1 H1A 118.9 . . ?
C3 C2 C1 118.0(5) . . ?
C3 C2 H2A 121.0 . . ?
C1 C2 H2A 121.0 . . ?
C2 C3 C4 118.2(5) . . ?
C2 C3 C11 122.1(5) . . ?
C4 C3 C11 119.7(5) . . ?
C5 C4 C3 119.9(5) . . ?
C5 C4 H4A 120.0 . . ?
C3 C4 H4A 120.0 . . ?
N1 C5 C4 123.8(5) . . ?
N1 C5 C6 110.5(4) . . ?
C4 C5 C6 125.5(5) . . ?
N2 C6 C7 119.8(4) . . ?
N2 C6 C5 116.2(4) . . ?
C7 C6 C5 123.9(4) . . ?
C8 C7 C6 120.9(4) . . ?
C8 C7 H7A 119.6 . . ?
C6 C7 H7A 119.6 . . ?
C9 C8 C7 116.3(5) . . ?
C9 C8 C12 123.1(5) . . ?
C7 C8 C12 120.5(4) . . ?
C8 C9 C10 121.4(5) . . ?
C8 C9 H9A 119.3 . . ?
C10 C9 H9A 119.3 . . ?
N2 C10 C9 122.8(4) . . ?
N2 C10 H10E 118.6 . . ?
C9 C10 H10E 118.6 . . ?
O1 C11 O2 122.3(4) . . ?
O1 C11 C3 116.0(4) . . ?
O2 C11 C3 121.7(4) . . ?
O1 C11 Eu1 83.8(2) . 2_666 ?
C3 C11 Eu1 160.2(4) . 2_666 ?
O4 C12 O3 126.0(5) . . ?
O4 C12 C8 116.1(4) . . ?
O3 C12 C8 117.7(5) . . ?
C14 C13 N3 120.2(4) . . ?
C14 C13 H13E 119.9 . . ?
N3 C13 H13E 119.9 . . ?
C13 C14 C15 121.9(5) . . ?
C13 C14 H14E 119.1 . . ?
C15 C14 H14E 119.1 . . ?
C16 C15 C14 119.1(5) . . ?
C16 C15 C23 120.2(5) . . ?
C14 C15 C23 120.6(4) . . ?
C15 C16 C17 118.8(5) . . ?
C15 C16 H16E 120.6 . . ?
C17 C16 H16E 120.6 . . ?
N3 C17 C16 122.9(4) . . ?
N3 C17 C18 113.6(4) . . ?
C16 C17 C18 123.4(5) . . ?
C19 C18 N4 120.6(4) . . ?
C19 C18 C17 124.9(5) . . ?
N4 C18 C17 113.7(4) . . ?
C20 C19 C18 120.2(5) . . ?
C20 C19 H19E 119.9 . . ?
C18 C19 H19E 119.9 . . ?
C21 C20 C19 119.7(5) . . ?
C21 C20 C24 123.2(5) . . ?
C19 C20 C24 116.5(5) . . ?
C20 C21 C22 116.7(5) . . ?
C20 C21 H21D 121.7 . . ?
C22 C21 H21D 121.7 . . ?
N4 C22 C21 129.6(5) . . ?
N4 C22 H22C 115.2 . . ?
C21 C22 H22C 115.2 . . ?
O5 C23 O6 121.7(5) . . ?
O5 C23 C15 122.9(5) . . ?
O6 C23 C15 115.4(5) . . ?
O7 C24 O8 122.5(4) . . ?
O7 C24 C20 122.1(4) . . ?
O8 C24 C20 115.1(4) . . ?
O7 C24 Eu2 80.8(2) . 1_655 ?
C20 C24 Eu2 154.8(4) . 1_655 ?
N5 C25 C26 122.1(5) . . ?
N5 C25 H25E 119.0 . . ?
C26 C25 H25E 119.0 . . ?
C27 C26 C25 117.3(6) . . ?
C27 C26 H26A 121.3 . . ?
C25 C26 H26A 121.3 . . ?
C26 C27 C28 122.0(5) . . ?
C26 C27 C35 121.4(5) . . ?
C28 C27 C35 116.6(5) . . ?
C29 C28 C27 115.6(4) . . ?
C29 C28 H28A 122.2 . . ?
C27 C28 H28A 122.2 . . ?
C28 C29 N5 121.9(4) . . ?
C28 C29 C30 123.4(4) . . ?
N5 C29 C30 114.6(4) . . ?
C31 C30 N6 120.4(4) . . ?
C31 C30 C29 125.4(5) . . ?
N6 C30 C29 114.2(4) . . ?
C30 C31 C32 119.8(5) . . ?
C30 C31 H31A 120.1 . . ?
C32 C31 H31A 120.1 . . ?
C33 C32 C31 117.3(5) . . ?
C33 C32 C36 119.0(5) . . ?
C31 C32 C36 123.6(5) . . ?
C34 C33 C32 122.8(5) . . ?
C34 C33 H33A 118.6 . . ?
C32 C33 H33A 118.6 . . ?
C33 C34 N6 118.5(5) . . ?
C33 C34 H34A 120.8 . . ?
N6 C34 H34A 120.8 . . ?
O9 C35 O10 122.5(4) . . ?
O9 C35 C27 117.9(4) . . ?
O10 C35 C27 119.4(5) . . ?
O12 C36 O11 124.4(4) . . ?
O12 C36 C32 121.1(5) . . ?
O11 C36 C32 113.2(4) . . ?
N1 Co1 N4 91.38(18) . . ?
N1 Co1 N2 84.14(19) . . ?
N4 Co1 N2 86.55(18) . . ?
N1 Co1 N3 174.89(18) . . ?
N4 Co1 N3 84.50(18) . . ?
N2 Co1 N3 92.59(18) . . ?
N1 Co1 N6 90.46(17) . . ?
N4 Co1 N6 177.53(17) . . ?
N2 Co1 N6 95.28(18) . . ?
N3 Co1 N6 93.76(16) . . ?
N1 Co1 N5 98.22(19) . . ?
N4 Co1 N5 93.53(19) . . ?
N2 Co1 N5 177.64(18) . . ?
N3 Co1 N5 85.07(18) . . ?
N6 Co1 N5 84.58(18) . . ?
O1 Eu1 O12 74.60(12) . 2_676 ?
O1 Eu1 O10 85.18(13) . 2_776 ?
O12 Eu1 O10 84.78(13) 2_676 2_776 ?
O1 Eu1 O2 119.14(13) . 2_666 ?
O12 Eu1 O2 78.05(13) 2_676 2_666 ?
O10 Eu1 O2 144.29(13) 2_776 2_666 ?
O1 Eu1 O2W 145.39(14) . . ?
O12 Eu1 O2W 139.65(13) 2_676 . ?
O10 Eu1 O2W 100.26(14) 2_776 . ?
O2 Eu1 O2W 74.97(13) 2_666 . ?
O1 Eu1 O11 74.79(13) . 1_545 ?
O12 Eu1 O11 121.13(12) 2_676 1_545 ?
O10 Eu1 O11 139.96(12) 2_776 1_545 ?
O2 Eu1 O11 74.96(12) 2_666 1_545 ?
O2W Eu1 O11 79.69(14) . 1_545 ?
O1 Eu1 O3W 77.30(13) . . ?
O12 Eu1 O3W 144.24(13) 2_676 . ?
O10 Eu1 O3W 71.16(13) 2_776 . ?
O2 Eu1 O3W 135.96(13) 2_666 . ?
O2W Eu1 O3W 72.41(14) . . ?
O11 Eu1 O3W 70.80(12) 1_545 . ?
O1 Eu1 O1W 142.14(13) . . ?
O12 Eu1 O1W 74.70(13) 2_676 . ?
O10 Eu1 O1W 70.48(12) 2_776 . ?
O2 Eu1 O1W 74.85(13) 2_666 . ?
O2W Eu1 O1W 69.67(14) . . ?
O11 Eu1 O1W 141.41(12) 1_545 . ?
O3W Eu1 O1W 118.70(14) . . ?
O1 Eu1 C11 99.01(10) . 2_666 ?
O12 Eu1 C11 69.05(9) 2_676 2_666 ?
O10 Eu1 C11 151.04(9) 2_776 2_666 ?
O2 Eu1 C11 20.16(10) 2_666 2_666 ?
O2W Eu1 C11 92.43(10) . 2_666 ?
O11 Eu1 C11 67.76(9) 1_545 2_666 ?
O3W Eu1 C11 137.78(9) . 2_666 ?
O1W Eu1 C11 90.16(9) . 2_666 ?
O1 Eu1 Eu1 46.30(9) . 2_666 ?
O12 Eu1 Eu1 61.20(9) 2_676 2_666 ?
O10 Eu1 Eu1 124.70(9) 2_776 2_666 ?
O2 Eu1 Eu1 72.87(9) 2_666 2_666 ?
O2W Eu1 Eu1 134.26(10) . 2_666 ?
O11 Eu1 Eu1 61.17(8) 1_545 2_666 ?
O3W Eu1 Eu1 111.69(10) . 2_666 ?
O1W Eu1 Eu1 129.34(10) . 2_666 ?
C11 Eu1 Eu1 52.72(10) 2_666 2_666 ?
O4 Eu2 O7 74.21(12) 2_565 2_665 ?
O4 Eu2 O5 76.89(12) 2_565 1_445 ?
O7 Eu2 O5 144.04(12) 2_665 1_445 ?
O4 Eu2 O3 119.97(12) 2_565 . ?
O7 Eu2 O3 74.82(12) 2_665 . ?
O5 Eu2 O3 139.54(12) 1_445 . ?
O4 Eu2 O5W 142.11(14) 2_565 . ?
O7 Eu2 O5W 81.36(13) 2_665 . ?
O5 Eu2 O5W 110.43(13) 1_445 . ?
O3 Eu2 O5W 79.44(13) . . ?
O4 Eu2 O8 76.91(13) 2_565 1_455 ?
O7 Eu2 O8 120.74(12) 2_665 1_455 ?
O5 Eu2 O8 71.72(12) 1_445 1_455 ?
O3 Eu2 O8 76.84(12) . 1_455 ?
O5W Eu2 O8 140.98(14) . 1_455 ?
O4 Eu2 O4W 141.62(13) 2_565 . ?
O7 Eu2 O4W 143.60(13) 2_665 . ?
O5 Eu2 O4W 69.65(13) 1_445 . ?
O3 Eu2 O4W 78.26(12) . . ?
O5W Eu2 O4W 69.91(14) . . ?
O8 Eu2 O4W 75.21(13) 1_455 . ?
O4 Eu2 O6W 70.51(13) 2_565 . ?
O7 Eu2 O6W 75.50(13) 2_665 . ?
O5 Eu2 O6W 75.01(13) 1_445 . ?
O3 Eu2 O6W 143.57(13) . . ?
O5W Eu2 O6W 75.65(14) . . ?
O8 Eu2 O6W 137.61(13) 1_455 . ?
O4W Eu2 O6W 116.36(13) . . ?
O4 Eu2 C24 69.90(10) 2_565 1_455 ?
O7 Eu2 C24 99.56(10) 2_665 1_455 ?
O5 Eu2 C24 90.04(10) 1_445 1_455 ?
O3 Eu2 C24 66.32(10) . 1_455 ?
O5W Eu2 C24 143.91(10) . 1_455 ?
O8 Eu2 C24 21.27(10) 1_455 1_455 ?
O4W Eu2 C24 91.46(9) . 1_455 ?
O6W Eu2 C24 139.89(9) . 1_455 ?
O4 Eu2 Eu2 61.34(9) 2_565 2_565 ?
O7 Eu2 Eu2 46.06(8) 2_665 2_565 ?
O5 Eu2 Eu2 130.99(8) 1_445 2_565 ?
O3 Eu2 Eu2 59.99(8) . 2_565 ?
O5W Eu2 Eu2 118.18(10) . 2_565 ?
O8 Eu2 Eu2 74.69(8) 1_455 2_565 ?
O4W Eu2 Eu2 132.78(9) . 2_565 ?
O6W Eu2 Eu2 110.46(10) . 2_565 ?
C24 Eu2 Eu2 53.50(10) 1_455 2_565 ?
C5 N1 C1 117.6(3) . . ?
C5 N1 Co1 116.5(3) . . ?
C1 N1 Co1 125.9(3) . . ?
C6 N2 C10 118.4(3) . . ?
C6 N2 Co1 110.4(3) . . ?
C10 N2 Co1 129.4(3) . . ?
C17 N3 C13 117.1(3) . . ?
C17 N3 Co1 114.7(2) . . ?
C13 N3 Co1 127.8(3) . . ?
C22 N4 C18 113.1(3) . . ?
C22 N4 Co1 134.5(3) . . ?
C18 N4 Co1 112.5(2) . . ?
C25 N5 C29 120.5(3) . . ?
C25 N5 Co1 126.4(3) . . ?
C29 N5 Co1 112.8(3) . . ?
C34 N6 C30 121.2(3) . . ?
C34 N6 Co1 125.8(3) . . ?
C30 N6 Co1 113.1(2) . . ?
O73 N7 O71 120.6(5) . . ?
O73 N7 O72 118.1(5) . . ?
O71 N7 O72 121.2(5) . . ?
O82 N8 O83 121.4(6) . . ?
O82 N8 O81 116.7(5) . . ?
O83 N8 O81 121.7(6) . . ?
O91 N9 O92 120.9(5) . . ?
O91 N9 O93 120.4(5) . . ?
O92 N9 O93 118.7(5) . . ?
C11 O1 Eu1 176.9(3) . . ?
C11 O2 Eu1 121.3(2) . 2_666 ?
C12 O3 Eu2 142.0(3) . . ?
C12 O4 Eu2 143.9(2) . 2_565 ?
C23 O5 Eu2 140.2(3) . 1_665 ?
C24 O7 Eu2 178.4(3) . 2_665 ?
C24 O8 Eu2 116.7(2) . 1_655 ?
C35 O10 Eu1 144.5(3) . 2_776 ?
C36 O11 Eu1 141.1(2) . 1_565 ?
C36 O12 Eu1 144.4(3) . 2_676 ?
Eu1 O1W H1X 109.6 . . ?
Eu1 O1W H1Y 109.4 . . ?
H1X O1W H1Y 109.4 . . ?
Eu1 O2W H2X 109.8 . . ?
Eu1 O2W H2Y 109.0 . . ?
H2X O2W H2Y 109.3 . . ?
Eu1 O3W H3X 109.1 . . ?
Eu1 O3W H3Y 109.4 . . ?
H3X O3W H3Y 109.5 . . ?
Eu2 O4W H4X 109.5 . . ?
Eu2 O4W H4Y 109.6 . . ?
H4X O4W H4Y 109.4 . . ?
Eu2 O5W H5X 109.3 . . ?
Eu2 O5W H5Y 109.6 . . ?
H5X O5W H5Y 109.6 . . ?
Eu2 O6W H6X 106.7 . . ?
Eu2 O6W H6Y 121.1 . . ?
H6X O6W H6Y 103.6 . . ?
H7X O7W H7Y 106.5 . . ?
H8X O8W H8Y 109.4 . . ?
H9X O9W H9Y 109.4 . . ?
H10X O10W H10Y 109.4 . . ?
H11X O11W H11Y 109.6 . . ?
H12X O12W H12Y 109.4 . . ?
H13X O13W H13Y 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.404(5) . ?
C1 C2 1.441(8) . ?
C1 H1A 0.9300 . ?
C2 C3 1.365(8) . ?
C2 H2A 0.9300 . ?
C3 C4 1.469(7) . ?
C3 C11 1.502(7) . ?
C4 C5 1.352(7) . ?
C4 H4A 0.9300 . ?
C5 N1 1.331(5) . ?
C5 C6 1.471(7) . ?
C6 N2 1.339(4) . ?
C6 C7 1.432(7) . ?
C7 C8 1.424(7) . ?
C7 H7A 0.9300 . ?
C8 C9 1.329(7) . ?
C8 C12 1.494(7) . ?
C9 C10 1.400(8) . ?
C9 H9A 0.9300 . ?
C10 N2 1.353(5) . ?
C10 H10E 0.9300 . ?
C11 O1 1.262(5) . ?
C11 O2 1.274(5) . ?
C11 Eu1 3.160(5) 2_666 ?
C12 O4 1.191(6) . ?
C12 O3 1.220(5) . ?
C13 C14 1.313(7) . ?
C13 N3 1.438(5) . ?
C13 H13E 0.9300 . ?
C14 C15 1.414(7) . ?
C14 H14E 0.9300 . ?
C15 C16 1.350(7) . ?
C15 C23 1.463(8) . ?
C16 C17 1.400(7) . ?
C16 H16E 0.9300 . ?
C17 N3 1.349(5) . ?
C17 C18 1.468(7) . ?
C18 C19 1.396(7) . ?
C18 N4 1.422(5) . ?
C19 C20 1.374(7) . ?
C19 H19E 0.9300 . ?
C20 C21 1.333(7) . ?
C20 C24 1.467(7) . ?
C21 C22 1.385(7) . ?
C21 H21D 0.9300 . ?
C22 N4 1.288(5) . ?
C22 H22C 0.9300 . ?
C23 O5 1.267(6) . ?
C23 O6 1.270(6) . ?
C24 O7 1.237(5) . ?
C24 O8 1.301(5) . ?
C24 Eu2 3.202(5) 1_655 ?
C25 N5 1.344(5) . ?
C25 C26 1.397(7) . ?
C25 H25E 0.9300 . ?
C26 C27 1.359(8) . ?
C26 H26A 0.9300 . ?
C27 C28 1.482(7) . ?
C27 C35 1.520(7) . ?
C28 C29 1.357(7) . ?
C28 H28A 0.9300 . ?
C29 N5 1.394(5) . ?
C29 C30 1.463(6) . ?
C30 C31 1.340(8) . ?
C30 N6 1.404(5) . ?
C31 C32 1.440(7) . ?
C31 H31A 0.9300 . ?
C32 C33 1.392(8) . ?
C32 C36 1.504(7) . ?
C33 C34 1.358(8) . ?
C33 H33A 0.9300 . ?
C34 N6 1.372(6) . ?
C34 H34A 0.9300 . ?
C35 O9 1.227(6) . ?
C35 O10 1.256(5) . ?
C36 O12 1.211(5) . ?
C36 O11 1.258(6) . ?
Co1 N1 1.874(4) . ?
Co1 N4 1.916(4) . ?
Co1 N2 1.924(4) . ?
Co1 N3 1.942(4) . ?
Co1 N6 1.947(4) . ?
Co1 N5 1.954(4) . ?
Eu1 O1 2.277(3) . ?
Eu1 O12 2.286(3) 2_676 ?
Eu1 O10 2.291(3) 2_776 ?
Eu1 O2 2.305(3) 2_666 ?
Eu1 O2W 2.396(4) . ?
Eu1 O11 2.421(4) 1_545 ?
Eu1 O3W 2.429(4) . ?
Eu1 O1W 2.476(4) . ?
Eu1 C11 3.160(5) 2_666 ?
Eu2 O4 2.319(4) 2_565 ?
Eu2 O7 2.346(3) 2_665 ?
Eu2 O5 2.347(4) 1_445 ?
Eu2 O3 2.380(4) . ?
Eu2 O5W 2.386(4) . ?
Eu2 O8 2.399(4) 1_455 ?
Eu2 O4W 2.441(4) . ?
Eu2 O6W 2.454(4) . ?
Eu2 C24 3.202(5) 1_455 ?
N7 O73 1.208(6) . ?
N7 O71 1.219(6) . ?
N7 O72 1.232(6) . ?
N8 O82 1.220(7) . ?
N8 O83 1.222(6) . ?
N8 O81 1.245(7) . ?
N9 O91 1.200(6) . ?
N9 O92 1.228(6) . ?
N9 O93 1.236(6) . ?
O2 Eu1 2.305(3) 2_666 ?
O4 Eu2 2.319(4) 2_565 ?
O5 Eu2 2.347(4) 1_665 ?
O7 Eu2 2.346(3) 2_665 ?
O8 Eu2 2.399(4) 1_655 ?
O10 Eu1 2.291(3) 2_776 ?
O11 Eu1 2.421(4) 1_565 ?
O12 Eu1 2.286(3) 2_676 ?
O1W H1X 0.9625 . ?
O1W H1Y 0.9610 . ?
O2W H2X 0.9615 . ?
O2W H2Y 0.9632 . ?
O3W H3X 0.9614 . ?
O3W H3Y 0.9645 . ?
O4W H4X 0.9610 . ?
O4W H4Y 0.9623 . ?
O5W H5X 0.9633 . ?
O5W H5Y 0.9616 . ?
O6W H6X 0.9318 . ?
O6W H6Y 0.7592 . ?
O7W H7X 0.8522 . ?
O7W H7Y 0.8537 . ?
O8W H8X 0.8511 . ?
O8W H8Y 0.8522 . ?
O9W H9X 0.8525 . ?
O9W H9Y 0.8519 . ?
O10W H10X 0.8534 . ?
O10W H10Y 0.8522 . ?
O11W H11X 0.8533 . ?
O11W H11Y 0.8536 . ?
O12W H12X 0.8534 . ?
O12W H12Y 0.8509 . ?
O13W H13X 0.8524 . ?
O13W H13Y 0.8533 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C1 C2 C3 3.4(9) . . . . ?
C1 C2 C3 C4 -3.7(8) . . . . ?
C1 C2 C3 C11 178.0(5) . . . . ?
C2 C3 C4 C5 0.0(7) . . . . ?
C11 C3 C4 C5 178.3(4) . . . . ?
C3 C4 C5 N1 4.7(7) . . . . ?
C3 C4 C5 C6 178.9(5) . . . . ?
N1 C5 C6 N2 -13.3(6) . . . . ?
C4 C5 C6 N2 171.9(4) . . . . ?
N1 C5 C6 C7 168.4(4) . . . . ?
C4 C5 C6 C7 -6.4(8) . . . . ?
N2 C6 C7 C8 -0.2(8) . . . . ?
C5 C6 C7 C8 178.1(5) . . . . ?
C6 C7 C8 C9 -4.5(8) . . . . ?
C6 C7 C8 C12 179.7(5) . . . . ?
C7 C8 C9 C10 8.0(8) . . . . ?
C12 C8 C9 C10 -176.3(5) . . . . ?
C8 C9 C10 N2 -7.4(8) . . . . ?
C2 C3 C11 O1 -20.3(7) . . . . ?
C4 C3 C11 O1 161.4(4) . . . . ?
C2 C3 C11 O2 158.9(5) . . . . ?
C4 C3 C11 O2 -19.4(7) . . . . ?
C2 C3 C11 Eu1 161.1(8) . . . 2_666 ?
C4 C3 C11 Eu1 -17.1(12) . . . 2_666 ?
C9 C8 C12 O4 -6.9(8) . . . . ?
C7 C8 C12 O4 168.6(5) . . . . ?
C9 C8 C12 O3 177.8(5) . . . . ?
C7 C8 C12 O3 -6.7(8) . . . . ?
N3 C13 C14 C15 1.0(8) . . . . ?
C13 C14 C15 C16 -1.7(8) . . . . ?
C13 C14 C15 C23 -177.5(5) . . . . ?
C14 C15 C16 C17 0.2(8) . . . . ?
C23 C15 C16 C17 176.1(5) . . . . ?
C15 C16 C17 N3 2.0(8) . . . . ?
C15 C16 C17 C18 177.3(5) . . . . ?
N3 C17 C18 C19 178.5(5) . . . . ?
C16 C17 C18 C19 2.8(9) . . . . ?
N3 C17 C18 N4 -11.6(6) . . . . ?
C16 C17 C18 N4 172.7(5) . . . . ?
N4 C18 C19 C20 2.8(8) . . . . ?
C17 C18 C19 C20 172.1(5) . . . . ?
C18 C19 C20 C21 -4.6(8) . . . . ?
C18 C19 C20 C24 -176.4(5) . . . . ?
C19 C20 C21 C22 3.7(8) . . . . ?
C24 C20 C21 C22 174.9(5) . . . . ?
C20 C21 C22 N4 -1.1(8) . . . . ?
C16 C15 C23 O5 -151.0(5) . . . . ?
C14 C15 C23 O5 24.8(8) . . . . ?
C16 C15 C23 O6 26.4(8) . . . . ?
C14 C15 C23 O6 -157.9(5) . . . . ?
C21 C20 C24 O7 179.8(5) . . . . ?
C19 C20 C24 O7 -8.7(8) . . . . ?
C21 C20 C24 O8 -5.9(8) . . . . ?
C19 C20 C24 O8 165.6(5) . . . . ?
C21 C20 C24 Eu2 -27.1(12) . . . 1_655 ?
C19 C20 C24 Eu2 144.3(7) . . . 1_655 ?
N5 C25 C26 C27 -7.5(8) . . . . ?
C25 C26 C27 C28 8.9(8) . . . . ?
C25 C26 C27 C35 -171.7(5) . . . . ?
C26 C27 C28 C29 -6.1(7) . . . . ?
C35 C27 C28 C29 174.5(4) . . . . ?
C27 C28 C29 N5 1.6(6) . . . . ?
C27 C28 C29 C30 176.9(4) . . . . ?
C28 C29 C30 C31 -3.7(8) . . . . ?
N5 C29 C30 C31 172.0(5) . . . . ?
C28 C29 C30 N6 176.4(4) . . . . ?
N5 C29 C30 N6 -7.9(6) . . . . ?
N6 C30 C31 C32 0.8(8) . . . . ?
C29 C30 C31 C32 -179.0(5) . . . . ?
C30 C31 C32 C33 -3.5(8) . . . . ?
C30 C31 C32 C36 179.0(5) . . . . ?
C31 C32 C33 C34 2.7(8) . . . . ?
C36 C32 C33 C34 -179.7(5) . . . . ?
C32 C33 C34 N6 0.8(8) . . . . ?
C26 C27 C35 O9 -18.1(8) . . . . ?
C28 C27 C35 O9 161.3(4) . . . . ?
C26 C27 C35 O10 166.3(5) . . . . ?
C28 C27 C35 O10 -14.2(7) . . . . ?
C33 C32 C36 O12 -17.5(8) . . . . ?
C31 C32 C36 O12 160.0(5) . . . . ?
C33 C32 C36 O11 175.2(5) . . . . ?
C31 C32 C36 O11 -7.3(8) . . . . ?
C4 C5 N1 C1 -5.1(6) . . . . ?
C6 C5 N1 C1 -180.0(4) . . . . ?
C4 C5 N1 Co1 177.6(4) . . . . ?
C6 C5 N1 Co1 2.7(4) . . . . ?
C2 C1 N1 C5 0.9(7) . . . . ?
C2 C1 N1 Co1 178.0(4) . . . . ?
N4 Co1 N1 C5 -81.4(3) . . . . ?
N2 Co1 N1 C5 5.0(3) . . . . ?
N6 Co1 N1 C5 100.2(3) . . . . ?
N5 Co1 N1 C5 -175.2(3) . . . . ?
N4 Co1 N1 C1 101.5(3) . . . . ?
N2 Co1 N1 C1 -172.1(3) . . . . ?
N6 Co1 N1 C1 -76.8(3) . . . . ?
N5 Co1 N1 C1 7.8(4) . . . . ?
C7 C6 N2 C10 1.2(6) . . . . ?
C5 C6 N2 C10 -177.2(4) . . . . ?
C7 C6 N2 Co1 -164.7(4) . . . . ?
C5 C6 N2 Co1 17.0(5) . . . . ?
C9 C10 N2 C6 2.3(6) . . . . ?
C9 C10 N2 Co1 165.1(3) . . . . ?
N1 Co1 N2 C6 -12.0(3) . . . . ?
N4 Co1 N2 C6 79.7(3) . . . . ?
N3 Co1 N2 C6 164.0(3) . . . . ?
N6 Co1 N2 C6 -102.0(3) . . . . ?
N1 Co1 N2 C10 -175.9(4) . . . . ?
N4 Co1 N2 C10 -84.2(4) . . . . ?
N3 Co1 N2 C10 0.2(4) . . . . ?
N6 Co1 N2 C10 94.2(4) . . . . ?
C16 C17 N3 C13 -2.6(6) . . . . ?
C18 C17 N3 C13 -178.4(4) . . . . ?
C16 C17 N3 Co1 -175.7(4) . . . . ?
C18 C17 N3 Co1 8.6(5) . . . . ?
C14 C13 N3 C17 1.1(6) . . . . ?
C14 C13 N3 Co1 173.1(4) . . . . ?
N4 Co1 N3 C17 -2.9(3) . . . . ?
N2 Co1 N3 C17 -89.2(3) . . . . ?
N6 Co1 N3 C17 175.3(3) . . . . ?
N5 Co1 N3 C17 91.1(3) . . . . ?
N4 Co1 N3 C13 -175.1(3) . . . . ?
N2 Co1 N3 C13 98.6(3) . . . . ?
N6 Co1 N3 C13 3.2(3) . . . . ?
N5 Co1 N3 C13 -81.0(3) . . . . ?
C21 C22 N4 C18 -0.6(6) . . . . ?
C21 C22 N4 Co1 179.7(4) . . . . ?
C19 C18 N4 C22 -0.2(6) . . . . ?
C17 C18 N4 C22 -170.6(4) . . . . ?
C19 C18 N4 Co1 179.5(4) . . . . ?
C17 C18 N4 Co1 9.1(5) . . . . ?
N1 Co1 N4 C22 -7.0(4) . . . . ?
N2 Co1 N4 C22 -91.1(4) . . . . ?
N3 Co1 N4 C22 176.0(4) . . . . ?
N5 Co1 N4 C22 91.3(4) . . . . ?
N1 Co1 N4 C18 173.3(3) . . . . ?
N2 Co1 N4 C18 89.3(3) . . . . ?
N3 Co1 N4 C18 -3.6(3) . . . . ?
N5 Co1 N4 C18 -88.3(3) . . . . ?
C26 C25 N5 C29 3.3(6) . . . . ?
C26 C25 N5 Co1 177.1(4) . . . . ?
C28 C29 N5 C25 -0.4(6) . . . . ?
C30 C29 N5 C25 -176.1(4) . . . . ?
C28 C29 N5 Co1 -174.9(4) . . . . ?
C30 C29 N5 Co1 9.3(4) . . . . ?
N1 Co1 N5 C25 89.9(4) . . . . ?
N4 Co1 N5 C25 -2.0(4) . . . . ?
N3 Co1 N5 C25 -86.2(4) . . . . ?
N6 Co1 N5 C25 179.5(4) . . . . ?
N1 Co1 N5 C29 -96.0(3) . . . . ?
N4 Co1 N5 C29 172.1(3) . . . . ?
N3 Co1 N5 C29 88.0(3) . . . . ?
N6 Co1 N5 C29 -6.3(3) . . . . ?
C33 C34 N6 C30 -3.6(6) . . . . ?
C33 C34 N6 Co1 176.5(3) . . . . ?
C31 C30 N6 C34 2.8(7) . . . . ?
C29 C30 N6 C34 -177.3(4) . . . . ?
C31 C30 N6 Co1 -177.3(4) . . . . ?
C29 C30 N6 Co1 2.6(5) . . . . ?
N1 Co1 N6 C34 -79.9(3) . . . . ?
N2 Co1 N6 C34 4.2(3) . . . . ?
N3 Co1 N6 C34 97.2(3) . . . . ?
N5 Co1 N6 C34 -178.1(3) . . . . ?
N1 Co1 N6 C30 100.2(3) . . . . ?
N2 Co1 N6 C30 -175.7(2) . . . . ?
N3 Co1 N6 C30 -82.7(2) . . . . ?
N5 Co1 N6 C30 1.9(2) . . . . ?
O1 C11 O2 Eu1 -2.0(5) . . . 2_666 ?
C3 C11 O2 Eu1 178.8(3) . . . 2_666 ?
O4 C12 O3 Eu2 25.2(10) . . . . ?
C8 C12 O3 Eu2 -160.0(3) . . . . ?
O4 Eu2 O3 C12 -40.1(5) 2_565 . . . ?
O7 Eu2 O3 C12 21.1(5) 2_665 . . . ?
O5 Eu2 O3 C12 -145.9(5) 1_445 . . . ?
O5W Eu2 O3 C12 104.9(5) . . . . ?
O8 Eu2 O3 C12 -106.3(5) 1_455 . . . ?
O4W Eu2 O3 C12 176.3(5) . . . . ?
O6W Eu2 O3 C12 57.5(5) . . . . ?
C24 Eu2 O3 C12 -86.8(5) 1_455 . . . ?
Eu2 Eu2 O3 C12 -26.6(5) 2_565 . . . ?
O3 C12 O4 Eu2 15.0(10) . . . 2_565 ?
C8 C12 O4 Eu2 -159.9(3) . . . 2_565 ?
O6 C23 O5 Eu2 -16.0(8) . . . 1_665 ?
C15 C23 O5 Eu2 161.2(3) . . . 1_665 ?
O7 C24 O8 Eu2 7.6(5) . . . 1_655 ?
C20 C24 O8 Eu2 -166.7(3) . . . 1_655 ?
O9 C35 O10 Eu1 46.3(7) . . . 2_776 ?
C27 C35 O10 Eu1 -138.4(4) . . . 2_776 ?
O12 C36 O11 Eu1 -0.7(10) . . . 1_565 ?
C32 C36 O11 Eu1 166.1(3) . . . 1_565 ?
O11 C36 O12 Eu1 -38.3(10) . . . 2_676 ?
C32 C36 O12 Eu1 155.9(3) . . . 2_676 ?
