#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/81/7208156.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7208156
loop_
_publ_author_name
'Sha, Jing-Quan'
'Sun, Jing-Wen'
'Wang, Cheng'
'Li, Guang-Ming'
'Yan, Peng-Fei'
'Li, Meng-Ting'
'Liu, Ming-Yuan'
_publ_section_title
;
 Syntheses of POM-templated MOFs containing the isomeric pyridyltetrazole
;
_journal_issue                   15
_journal_name_full               CrystEngComm
_journal_page_first              5053
_journal_paper_doi               10.1039/c2ce00025c
_journal_volume                  14
_journal_year                    2012
_chemical_formula_moiety         'Ag O40 P W12, 2(C12 H8 Ag3 N10) '
_chemical_formula_sum            'C24 H16 Ag7 N20 O40 P W12'
_chemical_formula_weight         4216.71
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                96.035(5)
_cell_angle_beta                 112.394(5)
_cell_angle_gamma                97.434(5)
_cell_formula_units_Z            1
_cell_length_a                   10.231(5)
_cell_length_b                   12.979(5)
_cell_length_c                   13.330(5)
_cell_measurement_temperature    293(2)
_cell_volume                     1599.6(12)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0360
_diffrn_reflns_av_sigmaI/netI    0.0844
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            8087
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.61
_exptl_absorpt_coefficient_mu    23.688
_exptl_absorpt_correction_T_max  0.011
_exptl_absorpt_correction_T_min  0.005
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs(Sheldrick,1996)
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    4.377
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1852
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.19
_refine_diff_density_max         4.436
_refine_diff_density_min         -2.897
_refine_diff_density_rms         0.567
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     470
_refine_ls_number_reflns         5555
_refine_ls_number_restraints     222
_refine_ls_restrained_S_all      1.027
_refine_ls_R_factor_all          0.0967
_refine_ls_R_factor_gt           0.0623
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1111P)²+25.9421P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1712
_refine_ls_wR_factor_ref         0.2002
_reflns_number_gt                3799
_reflns_number_total             5638
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2ce00025c.txt
_cod_data_source_block           2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_original_formula_sum        'C24 H16 Ag7 N20 O40 P W12 '
_cod_database_code               7208156
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.631(3) 0.841(2) 0.652(2) 0.020(5) Uani 1 1 d U
H1 H 0.7136 0.8154 0.6903 0.025 Uiso 1 1 calc R
C2 C 0.469(3) 0.954(2) 0.645(2) 0.024(5) Uani 1 1 d U
H2 H 0.4405 1.0035 0.6836 0.029 Uiso 1 1 calc R
C3 C 0.434(3) 0.856(2) 0.482(2) 0.026(5) Uani 1 1 d U
H3 H 0.3895 0.8415 0.4051 0.031 Uiso 1 1 calc R
C4 C 0.586(3) 0.9148(18) 0.7010(19) 0.013(4) Uani 1 1 d U
C5 C 0.658(2) 0.9546(18) 0.8242(19) 0.014(5) Uani 1 1 d .
C6 C 0.121(3) 0.821(2) 0.622(2) 0.018(5) Uani 1 1 d U
C7 C 0.187(3) 0.739(2) 0.597(2) 0.022(6) Uani 1 1 d U
C8 C 0.298(3) 0.707(2) 0.677(2) 0.036(7) Uani 1 1 d .
H8 H 0.3378 0.7436 0.7485 0.043 Uiso 1 1 calc R
C9 C 0.143(4) 0.688(2) 0.489(3) 0.042(9) Uani 1 1 d .
H9 H 0.0707 0.7107 0.4339 0.051 Uiso 1 1 calc R
C10 C 0.298(4) 0.576(2) 0.539(3) 0.039(8) Uani 1 1 d U
H10 H 0.3386 0.5215 0.5191 0.047 Uiso 1 1 calc R
C11 C 0.546(3) 0.803(2) 0.538(2) 0.028(5) Uani 1 1 d U
H11 H 0.5629 0.7446 0.5015 0.034 Uiso 1 1 calc R
C12 C 0.351(4) 0.621(2) 0.652(3) 0.047(10) Uani 1 1 d .
H12 H 0.4180 0.5927 0.7056 0.057 Uiso 1 1 calc R
N1 N 0.812(2) 0.9922(18) 0.9883(16) 0.020(5) Uani 1 1 d .
N2 N 0.799(2) 0.9623(16) 0.8810(17) 0.018(5) Uani 1 1 d .
N3 N 0.056(2) 0.9397(17) 0.7096(18) 0.025(6) Uani 1 1 d .
N4 N -0.031(2) 0.9236(17) 0.6010(18) 0.024(5) Uani 1 1 d .
N5 N 0.002(2) 0.8523(19) 0.5446(17) 0.026(5) Uani 1 1 d .
N6 N 0.391(2) 0.9253(17) 0.5348(17) 0.021(4) Uani 1 1 d U
N7 N 0.690(2) 1.0002(16) 0.9878(16) 0.018(5) Uani 1 1 d U
N8 N 0.155(2) 0.8775(15) 0.7207(15) 0.013(4) Uani 1 1 d U
N9 N 0.198(3) 0.607(2) 0.461(2) 0.060(10) Uani 1 1 d .
N10 N 0.585(2) 0.9732(16) 0.8805(16) 0.014(4) Uani 1 1 d U
O1 O 0.111(2) 0.3126(16) 0.3380(16) 0.038(5) Uani 1 1 d .
O2 O 0.244(2) 0.6764(15) 0.2491(16) 0.033(5) Uani 1 1 d U
O3 O 0.355(2) 0.4474(15) 0.1435(17) 0.038(5) Uani 1 1 d U
O4 O -0.269(2) 0.616(2) 0.0661(18) 0.051(7) Uani 1 1 d .
O5 O 0.281(2) 0.5749(18) -0.096(2) 0.064(9) Uani 1 1 d .
O6 O 0.191(2) 0.7723(17) 0.0749(19) 0.044(6) Uani 1 1 d U
O7 O -0.362(2) 0.7574(15) -0.0802(17) 0.033(5) Uani 1 1 d .
O8 O 0.166(2) 0.3001(18) 0.1557(18) 0.044(6) Uani 1 1 d U
O9 O -0.019(2) 0.6694(18) 0.2272(18) 0.049(6) Uani 1 1 d U
O10 O 0.373(2) 0.6428(15) 0.1180(16) 0.031(5) Uani 1 1 d U
O11 O 0.058(4) 0.548(3) -0.069(3) 0.024(8) Uiso 0.50 1 d P
O12 O -0.243(2) 0.5767(15) 0.2690(15) 0.028(4) Uani 1 1 d .
O13 O -0.034(2) 0.4701(16) 0.2584(17) 0.042(6) Uani 1 1 d U
O14 O 0.103(2) 0.7097(18) -0.135(2) 0.058(8) Uani 1 1 d .
O15 O 0.230(3) 0.4847(15) 0.281(2) 0.049(7) Uani 1 1 d .
O16 O 0.142(2) 0.8652(14) 0.2568(16) 0.032(5) Uani 1 1 d U
O17 O 0.500(2) 0.6033(16) 0.3310(16) 0.036(5) Uani 1 1 d U
O18 O 0.393(2) 0.7894(14) -0.0146(18) 0.031(5) Uani 1 1 d .
O19 O -0.074(2) 0.7587(19) 0.0560(18) 0.051(6) Uani 1 1 d U
O20 O -0.054(3) 0.591(2) 0.054(2) 0.010(7) Uiso 0.50 1 d P
O21 O 0.120(3) 0.586(2) 0.060(3) 0.015(7) Uiso 0.50 1 d P
O22 O 0.113(3) 0.463(2) 0.084(2) 0.010(7) Uiso 0.50 1 d P
P1 P 0.0000 0.5000 0.0000 0.0058(16) Uani 1 2 d SU
Ag1 Ag -0.5000 0.5000 0.0000 0.0702(15) Uani 1 2 d S
Ag2 Ag -0.0063(2) 0.97860(19) 0.84881(17) 0.0307(6) Uani 1 1 d .
Ag3 Ag 0.3611(2) 0.94814(19) 0.86413(17) 0.0283(5) Uani 1 1 d .
Ag4 Ag -0.2076(3) 1.0064(2) 0.54591(19) 0.0384(6) Uani 1 1 d .
W1 W 0.09642(12) 0.74896(8) 0.17069(9) 0.0207(3) Uani 1 1 d .
W2 W 0.34032(12) 0.57031(9) 0.22399(9) 0.0216(3) Uani 1 1 d .
W3 W 0.26796(12) 0.69613(8) -0.00901(10) 0.0244(3) Uani 1 1 d .
W4 W -0.24442(13) 0.67783(9) -0.05016(11) 0.0310(3) Uani 1 1 d .
W5 W 0.07285(14) 0.36974(9) 0.23001(10) 0.0301(3) Uani 1 1 d .
W6 W -0.16533(14) 0.55183(11) 0.18534(10) 0.0326(3) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C4 C1 C11 117(2) . .
C4 C1 H1 121.7 . .
C11 C1 H1 121.7 . .
C4 C2 N6 124(2) . .
C4 C2 H2 118.1 . .
N6 C2 H2 118.1 . .
N6 C3 C11 121(2) . .
N6 C3 H3 119.4 . .
C11 C3 H3 119.4 . .
C1 C4 C2 122(2) . .
C1 C4 C5 122(2) . .
C2 C4 C5 116(2) . .
N10 C5 N2 116(2) . .
N10 C5 C4 121(2) . .
N2 C5 C4 122(2) . .
N8 C6 N5 109(2) . .
N8 C6 C7 127(2) . .
N5 C6 C7 124(2) . .
C8 C7 C9 117(2) . .
C8 C7 C6 122(3) . .
C9 C7 C6 121(2) . .
C12 C8 C7 121(3) . .
C12 C8 H8 119.7 . .
C7 C8 H8 119.7 . .
N9 C9 C7 124(3) . .
N9 C9 H9 118.2 . .
C7 C9 H9 118.2 . .
N9 C10 C12 124(3) . .
N9 C10 H10 117.8 . .
C12 C10 H10 117.8 . .
C3 C11 C1 118(2) . .
C3 C11 H11 120.8 . .
C1 C11 H11 120.8 . .
C8 C12 C10 117(3) . .
C8 C12 H12 121.7 . .
C10 C12 H12 121.7 . .
N7 N1 N2 109.6(19) . .
N7 N1 Ag2 119.4(16) . 2_677
N2 N1 Ag2 130.9(15) . 2_677
C5 N2 N1 101.6(19) . .
C5 N2 Ag2 137.6(18) . 1_655
N1 N2 Ag2 118.5(15) . 1_655
N8 N3 N4 106.7(19) . .
N8 N3 Ag2 118.8(16) . .
N4 N3 Ag2 126.4(16) . .
N5 N4 N3 112(2) . .
N5 N4 Ag4 128.5(18) . .
N3 N4 Ag4 119.4(16) . .
N4 N5 C6 105(2) . .
C3 N6 C2 117(2) . .
C3 N6 Ag4 122.1(18) . 2_576
C2 N6 Ag4 120.4(17) . 2_576
N1 N7 N10 110.0(19) . .
N1 N7 Ag3 127.1(16) . 2_677
N10 N7 Ag3 122.9(15) . 2_677
C6 N8 N3 107.2(19) . .
C6 N8 Ag3 134.7(16) . .
N3 N8 Ag3 110.7(14) . .
C10 N9 C9 117(3) . .
C5 N10 N7 102.7(19) . .
C5 N10 Ag3 140.0(17) . .
N7 N10 Ag3 116.0(14) . .
W2 O2 W1 140.4(11) . .
W4 O3 W2 142.2(12) 2_565 .
W6 O4 W4 139.6(13) . .
W6 O4 Ag1 99.6(9) . .
W4 O4 Ag1 110.8(9) . .
W6 O5 W3 140.0(14) 2_565 .
W6 O5 Ag1 96.8(8) 2_565 1_655
W3 O5 Ag1 112.7(9) . 1_655
W3 O6 W1 139.2(13) . .
W5 O8 W4 139.2(14) . 2_565
W6 O9 W1 141.0(14) . .
W3 O10 W2 139.1(12) . .
P1 O11 O21 57.5(18) . .
P1 O11 O22 55.4(17) . 2_565
O21 O11 O22 94(2) . 2_565
P1 O11 W5 127(2) . 2_565
O21 O11 W5 133(2) . 2_565
O22 O11 W5 71.6(16) 2_565 2_565
P1 O11 W3 127(2) . .
O21 O11 W3 69.2(17) . .
O22 O11 W3 135(2) 2_565 .
W5 O11 W3 89.8(12) 2_565 .
W6 O13 W5 140.7(12) . .
W5 O14 W3 139.0(15) 2_565 .
W2 O15 W5 139.1(14) . .
W1 O19 W4 142.6(14) . .
P1 O20 O22 51.5(13) . 2_565
P1 O20 O21 50.9(14) . .
O22 O20 O21 85(2) 2_565 .
P1 O20 W1 124.9(16) . .
O22 O20 W1 136.1(19) 2_565 .
O21 O20 W1 74.1(15) . .
P1 O20 W4 123.7(16) . .
O22 O20 W4 72.2(14) 2_565 .
O21 O20 W4 134.0(19) . .
W1 O20 W4 94.8(10) . .
P1 O20 W6 119.1(16) . .
O22 O20 W6 128.5(18) 2_565 .
O21 O20 W6 131.1(19) . .
W1 O20 W6 93.0(10) . .
W4 O20 W6 93.2(10) . .
P1 O21 O11 55.8(17) . .
P1 O21 O22 55.0(15) . .
O11 O21 O22 92(2) . .
P1 O21 O20 58.2(15) . .
O11 O21 O20 91(2) . .
O22 O21 O20 93(2) . .
P1 O21 W3 129.3(19) . .
O11 O21 W3 73.6(18) . .
O22 O21 W3 133(2) . .
O20 O21 W3 130.0(19) . .
P1 O21 W2 124.0(18) . .
O11 O21 W2 136(2) . .
O22 O21 W2 69.1(15) . .
O20 O21 W2 127.8(19) . .
W3 O21 W2 90.8(11) . .
P1 O22 O21 54.9(15) . .
P1 O22 O11 53.7(16) . 2_565
O21 O22 O11 92(2) . 2_565
P1 O22 O20 58.9(15) . 2_565
O21 O22 O20 93(2) . 2_565
O11 O22 O20 89(2) 2_565 2_565
P1 O22 W2 126.8(17) . .
O21 O22 W2 72.0(15) . .
O11 O22 W2 133(2) 2_565 .
O20 O22 W2 134.6(19) 2_565 .
P1 O22 W4 125.4(17) . 2_565
O21 O22 W4 131(2) . 2_565
O11 O22 W4 129(2) 2_565 2_565
O20 O22 W4 66.5(13) 2_565 2_565
W2 O22 W4 90.8(10) . 2_565
P1 O22 W5 123.3(17) . .
O21 O22 W5 135.1(19) . .
O11 O22 W5 69.6(16) 2_565 .
O20 O22 W5 125.6(18) 2_565 .
W2 O22 W5 90.6(10) . .
W4 O22 W5 88.9(9) 2_565 .
O11 P1 O11 180(3) 2_565 .
O11 P1 O21 66.7(19) 2_565 2_565
O11 P1 O21 113.3(19) . 2_565
O11 P1 O21 113.3(19) 2_565 .
O11 P1 O21 66.7(19) . .
O21 P1 O21 180(2) 2_565 .
O11 P1 O22 70.9(18) 2_565 .
O11 P1 O22 109.1(18) . .
O21 P1 O22 109.9(17) 2_565 .
O21 P1 O22 70.1(17) . .
O11 P1 O22 109.1(18) 2_565 2_565
O11 P1 O22 70.9(18) . 2_565
O21 P1 O22 70.1(17) 2_565 2_565
O21 P1 O22 109.9(17) . 2_565
O22 P1 O22 180.000(5) . 2_565
O11 P1 O20 75.0(18) 2_565 .
O11 P1 O20 105.0(18) . .
O21 P1 O20 109.1(16) 2_565 .
O21 P1 O20 70.9(16) . .
O22 P1 O20 110.4(16) . .
O22 P1 O20 69.6(16) 2_565 .
O11 P1 O20 105.0(18) 2_565 2_565
O11 P1 O20 75.0(18) . 2_565
O21 P1 O20 70.9(16) 2_565 2_565
O21 P1 O20 109.1(16) . 2_565
O22 P1 O20 69.6(16) . 2_565
O22 P1 O20 110.4(16) 2_565 2_565
O20 P1 O20 180.000(4) . 2_565
O4 Ag1 O4 180.0(11) 2_465 .
O4 Ag1 O5 117.8(8) 2_465 2_565
O4 Ag1 O5 62.2(8) . 2_565
O4 Ag1 O5 62.2(8) 2_465 1_455
O4 Ag1 O5 117.8(8) . 1_455
O5 Ag1 O5 180.000(1) 2_565 1_455
O4 Ag1 W6 34.3(5) 2_465 2_465
O4 Ag1 W6 145.7(5) . 2_465
O5 Ag1 W6 145.6(5) 2_565 2_465
O5 Ag1 W6 34.4(5) 1_455 2_465
O4 Ag1 W6 145.7(5) 2_465 .
O4 Ag1 W6 34.3(5) . .
O5 Ag1 W6 34.4(5) 2_565 .
O5 Ag1 W6 145.6(5) 1_455 .
W6 Ag1 W6 180.00(5) 2_465 .
N2 Ag2 N3 138.3(8) 1_455 .
N2 Ag2 N1 108.9(7) 1_455 2_677
N3 Ag2 N1 110.8(8) . 2_677
N10 Ag3 N8 131.6(7) . .
N10 Ag3 N7 119.7(7) . 2_677
N8 Ag3 N7 108.7(7) . 2_677
N6 Ag4 N4 170.7(8) 2_576 .
O16 W1 O19 104.4(10) . .
O16 W1 O9 100.1(10) . .
O19 W1 O9 86.9(9) . .
O16 W1 O6 104.4(10) . .
O19 W1 O6 87.6(10) . .
O9 W1 O6 155.4(10) . .
O16 W1 O2 101.7(9) . .
O19 W1 O2 153.7(10) . .
O9 W1 O2 85.8(9) . .
O6 W1 O2 88.6(9) . .
O16 W1 O20 157.6(10) . .
O19 W1 O20 61.3(10) . .
O9 W1 O20 63.9(11) . .
O6 W1 O20 92.5(10) . .
O2 W1 O20 93.0(9) . .
O17 W2 O2 102.5(9) . .
O17 W2 O3 104.1(9) . .
O2 W2 O3 153.4(9) . .
O17 W2 O10 102.0(10) . .
O2 W2 O10 87.6(8) . .
O3 W2 O10 86.7(8) . .
O17 W2 O15 102.2(11) . .
O2 W2 O15 85.9(9) . .
O3 W2 O15 88.8(8) . .
O10 W2 O15 155.8(11) . .
O17 W2 O22 160.6(10) . .
O2 W2 O22 91.3(9) . .
O3 W2 O22 63.0(10) . .
O10 W2 O22 92.0(10) . .
O15 W2 O22 64.9(11) . .
O17 W2 O21 160.5(11) . .
O2 W2 O21 65.3(9) . .
O3 W2 O21 89.0(10) . .
O10 W2 O21 63.7(10) . .
O15 W2 O21 92.4(11) . .
O22 W2 O21 38.9(10) . .
O18 W3 O6 101.9(10) . .
O18 W3 O10 101.9(10) . .
O6 W3 O10 88.3(8) . .
O18 W3 O5 102.8(11) . .
O6 W3 O5 155.3(12) . .
O10 W3 O5 88.6(9) . .
O18 W3 O14 100.9(11) . .
O6 W3 O14 86.3(9) . .
O10 W3 O14 157.2(11) . .
O5 W3 O14 87.1(9) . .
O18 W3 O21 162.0(11) . .
O6 W3 O21 66.1(10) . .
O10 W3 O21 65.7(10) . .
O5 W3 O21 90.3(12) . .
O14 W3 O21 92.0(12) . .
O18 W3 O11 160.7(11) . .
O6 W3 O11 90.4(11) . .
O10 W3 O11 93.1(10) . .
O5 W3 O11 65.3(12) . .
O14 W3 O11 64.8(12) . .
O21 W3 O11 37.2(11) . .
O7 W4 O19 106.0(11) . .
O7 W4 O3 101.2(10) . 2_565
O19 W4 O3 152.7(10) . 2_565
O7 W4 O8 99.8(10) . 2_565
O19 W4 O8 87.5(10) . 2_565
O3 W4 O8 87.4(9) 2_565 2_565
O7 W4 O4 104.1(10) . .
O19 W4 O4 87.3(9) . .
O3 W4 O4 86.6(10) 2_565 .
O8 W4 O4 156.0(10) 2_565 .
O7 W4 O20 161.1(10) . .
O19 W4 O20 60.5(10) . .
O3 W4 O20 93.1(10) 2_565 .
O8 W4 O20 93.1(10) 2_565 .
O4 W4 O20 64.1(10) . .
O7 W4 O22 157.6(10) . 2_565
O19 W4 O22 91.0(11) . 2_565
O3 W4 O22 62.6(10) 2_565 2_565
O8 W4 O22 65.8(10) 2_565 2_565
O4 W4 O22 90.9(11) . 2_565
O20 W4 O22 41.3(10) . 2_565
O1 W5 O14 102.4(11) . 2_565
O1 W5 O8 100.8(11) . .
O14 W5 O8 90.9(10) 2_565 .
O1 W5 O13 102.0(11) . .
O14 W5 O13 86.0(9) 2_565 .
O8 W5 O13 157.2(10) . .
O1 W5 O15 100.8(10) . .
O14 W5 O15 156.4(12) 2_565 .
O8 W5 O15 88.5(9) . .
O13 W5 O15 85.5(9) . .
O1 W5 O11 162.4(11) . 2_565
O14 W5 O11 65.8(12) 2_565 2_565
O8 W5 O11 92.7(11) . 2_565
O13 W5 O11 65.5(11) . 2_565
O15 W5 O11 90.7(11) . 2_565
O1 W5 O22 158.7(10) . .
O14 W5 O22 94.5(12) 2_565 .
O8 W5 O22 65.8(10) . .
O13 W5 O22 91.9(10) . .
O15 W5 O22 63.8(10) . .
O11 W5 O22 38.8(11) 2_565 .
O12 W6 O13 103.0(10) . .
O12 W6 O9 102.4(10) . .
O13 W6 O9 90.8(10) . .
O12 W6 O5 102.6(11) . 2_565
O13 W6 O5 86.7(9) . 2_565
O9 W6 O5 154.8(12) . 2_565
O12 W6 O4 101.3(10) . .
O13 W6 O4 155.5(11) . .
O9 W6 O4 87.3(9) . .
O5 W6 O4 84.8(11) 2_565 .
O12 W6 O20 156.3(10) . .
O13 W6 O20 95.2(10) . .
O9 W6 O20 61.7(10) . .
O5 W6 O20 93.6(12) 2_565 .
O4 W6 O20 62.6(10) . .
O12 W6 Ag1 82.6(7) . .
O13 W6 Ag1 134.7(7) . .
O9 W6 Ag1 132.5(6) . .
O5 W6 Ag1 48.8(6) 2_565 .
O4 W6 Ag1 46.1(6) . .
O20 W6 Ag1 95.5(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C4 1.32(3) .
C1 C11 1.43(4) .
C1 H1 0.9300 .
C2 C4 1.34(3) .
C2 N6 1.36(3) .
C2 H2 0.9300 .
C3 N6 1.30(3) .
C3 C11 1.42(4) .
C3 H3 0.9300 .
C4 C5 1.52(3) .
C5 N10 1.27(3) .
C5 N2 1.33(3) .
C6 N8 1.33(3) .
C6 N5 1.41(3) .
C6 C7 1.41(3) .
C7 C8 1.38(4) .
C7 C9 1.39(4) .
C8 C12 1.36(4) .
C8 H8 0.9300 .
C9 N9 1.34(4) .
C9 H9 0.9300 .
C10 N9 1.29(4) .
C10 C12 1.42(5) .
C10 H10 0.9300 .
C11 H11 0.9300 .
C12 H12 0.9300 .
N1 N7 1.26(3) .
N1 N2 1.39(3) .
N1 Ag2 2.27(2) 2_677
N2 Ag2 2.18(2) 1_655
N3 N8 1.35(3) .
N3 N4 1.36(3) .
N3 Ag2 2.21(2) .
N4 N5 1.29(3) .
N4 Ag4 2.15(2) .
N6 Ag4 2.14(2) 2_576
N7 N10 1.40(3) .
N7 Ag3 2.28(2) 2_677
N8 Ag3 2.237(19) .
N10 Ag3 2.19(2) .
O1 W5 1.63(2) .
O2 W2 1.866(18) .
O2 W1 1.907(18) .
O3 W4 1.869(19) 2_565
O3 W2 1.881(19) .
O4 W6 1.89(2) .
O4 W4 1.91(2) .
O4 Ag1 2.41(2) .
O5 W6 1.88(2) 2_565
O5 W3 1.90(2) .
O5 Ag1 2.50(2) 1_655
O6 W3 1.87(2) .
O6 W1 1.90(2) .
O7 W4 1.650(17) .
O8 W5 1.86(2) .
O8 W4 1.90(2) 2_565
O9 W6 1.87(2) .
O9 W1 1.88(2) .
O10 W3 1.885(18) .
O10 W2 1.886(19) .
O11 P1 1.42(4) .
O11 O21 1.58(5) .
O11 O22 1.67(5) 2_565
O11 W5 2.49(4) 2_565
O11 W3 2.50(4) .
O12 W6 1.626(18) .
O13 W6 1.865(19) .
O13 W5 1.898(18) .
O14 W5 1.85(2) 2_565
O14 W3 1.92(2) .
O15 W2 1.89(2) .
O15 W5 1.90(2) .
O16 W1 1.691(18) .
O17 W2 1.676(19) .
O18 W3 1.673(19) .
O19 W1 1.86(2) .
O19 W4 1.87(2) .
O20 P1 1.59(3) .
O20 O22 1.74(4) 2_565
O20 O21 1.76(4) .
O20 W1 2.38(3) .
O20 W4 2.41(3) .
O20 W6 2.49(3) .
O21 P1 1.45(3) .
O21 O22 1.67(4) .
O21 W3 2.44(3) .
O21 W2 2.52(3) .
O22 P1 1.45(3) .
O22 O11 1.67(5) 2_565
O22 O20 1.74(4) 2_565
O22 W2 2.48(3) .
O22 W4 2.50(3) 2_565
O22 W5 2.52(3) .
P1 O11 1.42(4) 2_565
P1 O21 1.45(3) 2_565
P1 O22 1.45(3) 2_565
P1 O20 1.59(3) 2_565
Ag1 O4 2.41(2) 2_465
Ag1 O5 2.50(2) 2_565
Ag1 O5 2.50(2) 1_455
Ag1 W6 3.2999(18) 2_465
Ag1 W6 3.2999(18) .
Ag2 N2 2.18(2) 1_455
Ag2 N1 2.27(2) 2_677
Ag3 N7 2.28(2) 2_677
Ag4 N6 2.14(2) 2_576
W4 O3 1.869(19) 2_565
W4 O8 1.90(2) 2_565
W4 O22 2.50(3) 2_565
W5 O14 1.85(2) 2_565
W5 O11 2.49(4) 2_565
W6 O5 1.88(2) 2_565
