#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/86/7208633.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7208633
loop_
_publ_author_name
'Du, Dong-Ying'
'Qin, Jun-Sheng'
'Sun, Cheng-Xin'
'Wang, Xin-Long'
'Zhang, Shu-Ran'
'Shen, Ping'
'Li, Shun-Li'
'Su, Zhong-Min'
'Lan, Ya-Qian'
_publ_section_title
;
 Functional heterometallic coordination polymers with metalloligands as
 tunable luminescent crystalline materials
;
_journal_issue                   37
_journal_name_full               'Journal of Materials Chemistry'
_journal_page_first              19673
_journal_paper_doi               10.1039/c2jm34661c
_journal_volume                  22
_journal_year                    2012
_chemical_formula_moiety         'C66 H59 Br4 Eu N10 O11 Zn2'
_chemical_formula_sum            'C66 H59 Br4 Eu N10 O11 Zn2'
_chemical_formula_weight         1770.57
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 99.9330(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   15.6650(10)
_cell_length_b                   13.5120(8)
_cell_length_c                   33.082(2)
_cell_measurement_temperature    293(2)
_cell_volume                     6897.4(7)
_computing_cell_refinement       'SMART (Bruker, 1997)'
_computing_data_collection       'SMART (Bruker, 1997)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXTL-PLUS (Sheldrick, 1990)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97(Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEX CCD area-detector'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0556
_diffrn_reflns_av_sigmaI/netI    0.0708
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       39
_diffrn_reflns_limit_l_min       -39
_diffrn_reflns_number            34093
_diffrn_reflns_theta_full        25.08
_diffrn_reflns_theta_max         25.08
_diffrn_reflns_theta_min         1.25
_exptl_absorpt_coefficient_mu    3.971
_exptl_absorpt_correction_T_max  0.5351
_exptl_absorpt_correction_T_min  0.4491
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS(Sheldrick, 1996)'
_exptl_crystal_density_diffrn    1.705
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3504
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.823
_refine_diff_density_min         -1.156
_refine_diff_density_rms         0.124
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.044
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     842
_refine_ls_number_reflns         12212
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.044
_refine_ls_R_factor_all          0.1012
_refine_ls_R_factor_gt           0.0545
_refine_ls_shift/su_max          0.038
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0926P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1513
_refine_ls_wR_factor_ref         0.1744
_reflns_number_gt                7353
_reflns_number_total             12212
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            c2jm34661c.txt
_cod_data_source_block           ifmc-21
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_Hall     -P2yn
_cod_original_sg_symbol_H-M      P21/n
_cod_database_code               7208633
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.9267(4) 0.2763(6) 0.6399(2) 0.0376(18) Uani 1 1 d .
C2 C 0.8728(5) 0.3109(6) 0.5765(2) 0.048(2) Uani 1 1 d .
C3 C 0.8813(5) 0.2093(6) 0.5798(3) 0.048(2) Uani 1 1 d .
C4 C 0.8560(6) 0.1475(7) 0.5471(3) 0.065(3) Uani 1 1 d .
H4 H 0.8606 0.0791 0.5498 0.078 Uiso 1 1 calc R
C5 C 0.8234(6) 0.1911(9) 0.5100(3) 0.083(3) Uani 1 1 d .
H5 H 0.8052 0.1509 0.4873 0.100 Uiso 1 1 calc R
C6 C 0.8169(7) 0.2922(9) 0.5053(3) 0.083(3) Uani 1 1 d .
H6 H 0.7970 0.3193 0.4796 0.099 Uiso 1 1 calc R
C7 C 0.8404(7) 0.3550(7) 0.5396(3) 0.075(3) Uani 1 1 d .
H7 H 0.8342 0.4233 0.5373 0.090 Uiso 1 1 calc R
C8 C 0.9524(5) 0.0931(6) 0.6352(3) 0.048(2) Uani 1 1 d .
H8A H 0.9108 0.0412 0.6260 0.058 Uiso 1 1 calc R
H8B H 0.9639 0.0925 0.6650 0.058 Uiso 1 1 calc R
C9 C 1.0357(5) 0.0739(6) 0.6190(2) 0.0416(18) Uani 1 1 d .
C10 C 1.0516(6) -0.0160(6) 0.6024(3) 0.057(2) Uani 1 1 d .
H10 H 1.0093 -0.0650 0.5997 0.068 Uiso 1 1 calc R
C11 C 1.1299(6) -0.0348(7) 0.5898(2) 0.053(2) Uani 1 1 d .
H11 H 1.1398 -0.0969 0.5794 0.064 Uiso 1 1 calc R
C12 C 1.1932(5) 0.0365(6) 0.5922(2) 0.0418(19) Uani 1 1 d .
C13 C 1.1770(5) 0.1294(7) 0.6075(3) 0.055(2) Uani 1 1 d .
H13 H 1.2182 0.1794 0.6087 0.067 Uiso 1 1 calc R
C14 C 1.0987(5) 0.1469(6) 0.6210(3) 0.051(2) Uani 1 1 d .
H14 H 1.0886 0.2087 0.6316 0.062 Uiso 1 1 calc R
C15 C 1.2772(6) 0.0172(7) 0.5791(2) 0.053(2) Uani 1 1 d .
C16 C 1.1089(4) 0.4379(5) 0.6818(2) 0.0360(17) Uani 1 1 d .
C17 C 1.1352(5) 0.4659(6) 0.6209(2) 0.046(2) Uani 1 1 d .
C18 C 1.2154(5) 0.4518(6) 0.6462(2) 0.049(2) Uani 1 1 d .
C19 C 1.2914(6) 0.4546(8) 0.6309(3) 0.068(3) Uani 1 1 d .
H19 H 1.3447 0.4449 0.6477 0.082 Uiso 1 1 calc R
C20 C 1.2854(7) 0.4722(10) 0.5899(3) 0.095(4) Uani 1 1 d .
H20 H 1.3363 0.4761 0.5790 0.114 Uiso 1 1 calc R
C21 C 1.2064(7) 0.4845(8) 0.5636(3) 0.083(3) Uani 1 1 d .
H21 H 1.2051 0.4937 0.5356 0.099 Uiso 1 1 calc R
C22 C 1.1301(6) 0.4830(7) 0.5793(3) 0.066(3) Uani 1 1 d .
H22 H 1.0769 0.4932 0.5623 0.079 Uiso 1 1 calc R
C23 C 1.2606(5) 0.4005(6) 0.7201(2) 0.047(2) Uani 1 1 d .
H23A H 1.2342 0.4010 0.7445 0.057 Uiso 1 1 calc R
H23B H 1.3078 0.4479 0.7240 0.057 Uiso 1 1 calc R
C24 C 1.2957(5) 0.2987(6) 0.7142(2) 0.045(2) Uani 1 1 d .
C25 C 1.2439(5) 0.2176(7) 0.7153(3) 0.056(2) Uani 1 1 d .
H25 H 1.1881 0.2256 0.7209 0.067 Uiso 1 1 calc R
C26 C 1.2728(5) 0.1253(7) 0.7082(3) 0.057(2) Uani 1 1 d .
H26 H 1.2373 0.0708 0.7098 0.068 Uiso 1 1 calc R
C27 C 1.3552(5) 0.1117(6) 0.6985(2) 0.046(2) Uani 1 1 d .
C28 C 1.4091(5) 0.1923(7) 0.6995(2) 0.055(2) Uani 1 1 d .
H28 H 1.4655 0.1840 0.6948 0.066 Uiso 1 1 calc R
C29 C 1.3799(5) 0.2860(7) 0.7074(2) 0.050(2) Uani 1 1 d .
H29 H 1.4168 0.3402 0.7082 0.060 Uiso 1 1 calc R
C30 C 1.3861(6) 0.0141(7) 0.6867(2) 0.053(2) Uani 1 1 d .
C31 C 0.7753(5) 0.5582(5) 0.5979(2) 0.0397(18) Uani 1 1 d .
C32 C 0.8587(5) 0.6309(6) 0.5615(2) 0.0446(19) Uani 1 1 d .
C33 C 0.7722(5) 0.6506(6) 0.5424(2) 0.046(2) Uani 1 1 d .
C34 C 0.7540(7) 0.7090(7) 0.5078(3) 0.065(3) Uani 1 1 d .
H34 H 0.6971 0.7224 0.4957 0.078 Uiso 1 1 calc R
C35 C 0.8207(8) 0.7460(8) 0.4923(3) 0.081(3) Uani 1 1 d .
H35 H 0.8092 0.7843 0.4686 0.098 Uiso 1 1 calc R
C36 C 0.9090(8) 0.7290(8) 0.5107(3) 0.088(3) Uani 1 1 d .
H36 H 0.9536 0.7571 0.4993 0.105 Uiso 1 1 calc R
C37 C 0.9281(6) 0.6701(7) 0.5458(3) 0.064(3) Uani 1 1 d .
H37 H 0.9850 0.6577 0.5581 0.077 Uiso 1 1 calc R
C38 C 0.6265(5) 0.5987(6) 0.5585(3) 0.052(2) Uani 1 1 d .
H38A H 0.6039 0.6458 0.5373 0.063 Uiso 1 1 calc R
H38B H 0.6042 0.6160 0.5832 0.063 Uiso 1 1 calc R
C39 C 0.5968(5) 0.4957(6) 0.5450(2) 0.046(2) Uani 1 1 d .
C40 C 0.5437(5) 0.4444(7) 0.5663(3) 0.055(2) Uani 1 1 d .
H40 H 0.5252 0.4729 0.5889 0.066 Uiso 1 1 calc R
C41 C 0.5172(5) 0.3480(7) 0.5537(3) 0.055(2) Uani 1 1 d .
H41 H 0.4813 0.3129 0.5682 0.066 Uiso 1 1 calc R
C42 C 1.5442(5) 0.3042(6) 0.5198(2) 0.0440(19) Uani 1 1 d .
C43 C 1.5952(5) 0.3604(7) 0.4983(3) 0.056(2) Uani 1 1 d .
H43 H 1.6122 0.3343 0.4749 0.067 Uiso 1 1 calc R
C44 C 0.6210(5) 0.4548(7) 0.5111(3) 0.056(2) Uani 1 1 d .
H44 H 0.6556 0.4910 0.4964 0.067 Uiso 1 1 calc R
C45 C 1.5184(5) 0.2007(7) 0.5070(2) 0.049(2) Uani 1 1 d .
C46 C 0.8901(5) 0.6602(6) 0.6883(2) 0.0370(17) Uani 1 1 d .
C47 C 1.0192(5) 0.7026(6) 0.6827(2) 0.0408(18) Uani 1 1 d .
C48 C 0.9793(5) 0.7858(6) 0.6942(2) 0.044(2) Uani 1 1 d .
C49 C 1.0217(7) 0.8786(6) 0.6994(2) 0.060(3) Uani 1 1 d .
H49 H 0.9945 0.9347 0.7074 0.072 Uiso 1 1 calc R
C50 C 1.1035(7) 0.8810(8) 0.6922(3) 0.068(3) Uani 1 1 d .
H50 H 1.1339 0.9403 0.6961 0.082 Uiso 1 1 calc R
C51 C 1.1448(6) 0.7989(8) 0.6791(3) 0.069(3) Uani 1 1 d .
H51 H 1.2002 0.8059 0.6730 0.083 Uiso 1 1 calc R
C52 C 1.1050(5) 0.7062(7) 0.6748(2) 0.052(2) Uani 1 1 d .
H52 H 1.1331 0.6504 0.6672 0.063 Uiso 1 1 calc R
C53 C 0.8260(5) 0.8245(6) 0.7013(2) 0.047(2) Uani 1 1 d .
H53A H 0.8476 0.8782 0.7198 0.057 Uiso 1 1 calc R
H53B H 0.7817 0.7899 0.7130 0.057 Uiso 1 1 calc R
C54 C 0.7850(5) 0.8680(5) 0.6595(2) 0.0391(18) Uani 1 1 d .
C55 C 0.7163(5) 0.9333(6) 0.6568(2) 0.047(2) Uani 1 1 d .
H55 H 0.6971 0.9533 0.6806 0.057 Uiso 1 1 calc R
C56 C 0.6765(5) 0.9686(6) 0.6200(2) 0.049(2) Uani 1 1 d .
H56 H 0.6300 1.0119 0.6190 0.058 Uiso 1 1 calc R
C57 C 1.2967(4) 0.0581(5) 0.4157(2) 0.0356(17) Uani 1 1 d .
C58 C 1.2258(4) 0.1170(6) 0.4134(2) 0.0405(19) Uani 1 1 d .
H58 H 1.2043 0.1316 0.4372 0.049 Uiso 1 1 calc R
C59 C 0.8148(5) 0.8445(6) 0.6234(2) 0.0443(19) Uani 1 1 d .
H59 H 0.8623 0.8028 0.6241 0.053 Uiso 1 1 calc R
C60 C 1.3442(5) 0.0276(5) 0.4575(2) 0.0381(18) Uani 1 1 d .
C61 C 0.9653(4) 0.2887(5) 0.6845(2) 0.0366(17) Uani 1 1 d .
H61A H 0.9309 0.2515 0.7009 0.044 Uiso 1 1 calc R
H61B H 1.0234 0.2612 0.6893 0.044 Uiso 1 1 calc R
C62 C 1.0591(4) 0.4237(6) 0.7161(2) 0.0391(18) Uani 1 1 d .
H62A H 1.0866 0.3734 0.7349 0.047 Uiso 1 1 calc R
H62B H 1.0574 0.4850 0.7312 0.047 Uiso 1 1 calc R
C63 C 0.7455(4) 0.4958(6) 0.6310(2) 0.0421(18) Uani 1 1 d .
H63A H 0.6904 0.5196 0.6366 0.051 Uiso 1 1 calc R
H63B H 0.7390 0.4272 0.6224 0.051 Uiso 1 1 calc R
C64 C 0.8080(5) 0.6032(6) 0.6869(2) 0.0422(19) Uani 1 1 d .
H64A H 0.7965 0.5947 0.7146 0.051 Uiso 1 1 calc R
H64B H 0.7603 0.6402 0.6714 0.051 Uiso 1 1 calc R
C65 C 0.9045(4) 0.4148(6) 0.7240(2) 0.0426(19) Uani 1 1 d .
H65A H 0.9196 0.4763 0.7386 0.051 Uiso 1 1 calc R
H65B H 0.9041 0.3625 0.7440 0.051 Uiso 1 1 calc R
C66 C 0.8153(4) 0.4239(6) 0.6976(2) 0.0412(19) Uani 1 1 d .
H66A H 0.8005 0.3623 0.6830 0.049 Uiso 1 1 calc R
H66B H 0.7726 0.4361 0.7150 0.049 Uiso 1 1 calc R
N1 N 0.9021(4) 0.3525(5) 0.61535(18) 0.0420(15) Uani 1 1 d .
N2 N 0.9160(4) 0.1897(5) 0.6206(2) 0.0415(15) Uani 1 1 d .
N3 N 1.0704(4) 0.4604(5) 0.64455(18) 0.0399(15) Uani 1 1 d .
N4 N 1.1961(4) 0.4302(5) 0.68469(18) 0.0453(16) Uani 1 1 d .
N5 N 0.8581(4) 0.5708(4) 0.59598(17) 0.0361(14) Uani 1 1 d .
N6 N 0.7212(4) 0.6040(4) 0.56671(18) 0.0405(15) Uani 1 1 d .
N7 N 0.9617(4) 0.6235(4) 0.67886(18) 0.0376(15) Uani 1 1 d .
N8 N 0.8959(4) 0.7572(5) 0.69844(17) 0.0405(15) Uani 1 1 d .
N9 N 0.9692(4) 0.3922(5) 0.69770(16) 0.0361(14) Uani 1 1 d .
N10 N 0.8134(4) 0.5055(4) 0.66784(18) 0.0362(14) Uani 1 1 d .
Zn1 Zn 0.93855(5) 0.49283(6) 0.64148(2) 0.0355(2) Uani 1 1 d .
Zn2 Zn 0.56187(6) 0.59201(8) 0.71294(3) 0.0538(3) Uani 1 1 d .
Eu1 Eu 1.42727(2) 0.00055(3) 0.542874(11) 0.04320(14) Uani 1 1 d .
Br1 Br 0.57017(7) 0.42741(8) 0.68767(3) 0.0737(3) Uani 1 1 d .
Br2 Br 0.67716(7) 0.61794(9) 0.77036(3) 0.0774(3) Uani 1 1 d .
Br3 Br 0.42550(7) 0.61870(9) 0.73475(4) 0.0855(4) Uani 1 1 d .
Br4 Br 0.57803(7) 0.70919(9) 0.66003(4) 0.0881(4) Uani 1 1 d .
O1 O 1.3290(4) 0.0903(5) 0.5784(2) 0.078(2) Uani 1 1 d .
O2 O 1.2957(4) -0.0670(5) 0.56790(17) 0.0576(15) Uani 1 1 d .
O1W O 1.4782(4) -0.0980(5) 0.60504(17) 0.0668(17) Uani 1 1 d .
O3 O 1.3268(4) -0.0561(5) 0.68563(19) 0.0706(18) Uani 1 1 d .
H3 H 1.3466 -0.1088 0.6792 0.106 Uiso 1 1 calc R
O2W O 1.4949(6) 0.1118(7) 0.6058(3) 0.127(3) Uani 1 1 d .
O4 O 1.4571(4) -0.0012(5) 0.6778(2) 0.0737(19) Uani 1 1 d .
O3W O 1.3526(7) 0.7782(8) 0.6474(3) 0.157(4) Uiso 1 1 d .
O5 O 1.4600(3) 0.1621(4) 0.52381(17) 0.0547(15) Uani 1 1 d .
O6 O 1.4429(4) -0.1624(4) 0.51966(17) 0.0590(15) Uani 1 1 d .
O7 O 1.3072(3) 0.0310(4) 0.48758(15) 0.0485(14) Uani 1 1 d .
O8 O 1.5773(3) -0.0024(4) 0.53889(16) 0.0506(14) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 C1 N2 112.9(6) . .
N1 C1 C61 122.7(7) . .
N2 C1 C61 124.4(7) . .
C7 C2 C3 121.1(8) . .
C7 C2 N1 130.6(8) . .
C3 C2 N1 108.2(7) . .
C4 C3 C2 122.1(9) . .
C4 C3 N2 131.4(8) . .
C2 C3 N2 106.5(7) . .
C3 C4 C5 117.1(9) . .
C4 C5 C6 122.2(9) . .
C5 C6 C7 120.2(10) . .
C2 C7 C6 117.2(9) . .
N2 C8 C9 110.1(6) . .
C10 C9 C14 118.1(7) . .
C10 C9 C8 121.3(7) . .
C14 C9 C8 120.6(7) . .
C9 C10 C11 120.9(8) . .
C12 C11 C10 121.4(8) . .
C11 C12 C13 118.6(7) . .
C11 C12 C15 121.9(8) . .
C13 C12 C15 119.5(8) . .
C12 C13 C14 119.6(8) . .
C9 C14 C13 121.4(8) . .
O2 C15 O1 121.2(8) . .
O2 C15 C12 120.8(9) . .
O1 C15 C12 117.9(8) . .
O2 C15 Eu1 63.1(4) . .
O1 C15 Eu1 58.5(4) . .
C12 C15 Eu1 170.5(6) . .
N3 C16 N4 112.3(6) . .
N3 C16 C62 121.8(6) . .
N4 C16 C62 125.8(6) . .
N3 C17 C22 130.3(7) . .
N3 C17 C18 109.0(7) . .
C22 C17 C18 120.6(7) . .
C19 C18 N4 133.2(8) . .
C19 C18 C17 121.5(8) . .
N4 C18 C17 105.2(6) . .
C20 C19 C18 117.3(9) . .
C19 C20 C21 122.8(9) . .
C22 C21 C20 119.7(9) . .
C17 C22 C21 118.0(8) . .
N4 C23 C24 111.3(6) . .
C25 C24 C29 119.3(8) . .
C25 C24 C23 119.8(7) . .
C29 C24 C23 120.9(8) . .
C26 C25 C24 120.8(8) . .
C25 C26 C27 120.6(8) . .
C28 C27 C26 118.6(8) . .
C28 C27 C30 119.1(7) . .
C26 C27 C30 122.3(8) . .
C29 C28 C27 120.5(7) . .
C28 C29 C24 119.9(8) . .
O4 C30 O3 122.6(9) . .
O4 C30 C27 124.6(9) . .
O3 C30 C27 112.7(7) . .
N5 C31 N6 113.0(6) . .
N5 C31 C63 122.2(6) . .
N6 C31 C63 124.7(7) . .
C37 C32 N5 129.9(8) . .
C37 C32 C33 120.7(8) . .
N5 C32 C33 109.4(7) . .
N6 C33 C34 133.4(8) . .
N6 C33 C32 105.0(6) . .
C34 C33 C32 121.5(8) . .
C35 C34 C33 118.0(9) . .
C34 C35 C36 122.6(9) . .
C37 C36 C35 119.9(10) . .
C32 C37 C36 117.3(9) . .
N6 C38 C39 110.6(6) . .
C44 C39 C40 119.9(8) . .
C44 C39 C38 120.2(8) . .
C40 C39 C38 119.9(7) . .
C39 C40 C41 119.4(8) . .
C42 C41 C40 120.9(8) 1_455 .
C43 C42 C41 117.6(8) . 1_655
C43 C42 C45 121.2(7) . .
C41 C42 C45 121.2(8) 1_655 .
C44 C43 C42 120.7(8) 1_655 .
C39 C44 C43 121.4(8) . 1_455
O5 C45 O6 127.5(8) . 3_856
O5 C45 C42 116.3(7) . .
O6 C45 C42 116.2(8) 3_856 .
N7 C46 N8 113.6(7) . .
N7 C46 C64 124.4(7) . .
N8 C46 C64 121.9(7) . .
C48 C47 N7 109.6(7) . .
C48 C47 C52 121.1(8) . .
N7 C47 C52 129.2(8) . .
C47 C48 N8 106.4(7) . .
C47 C48 C49 122.2(8) . .
N8 C48 C49 131.5(8) . .
C50 C49 C48 116.2(9) . .
C49 C50 C51 123.1(9) . .
C50 C51 C52 121.6(9) . .
C51 C52 C47 115.8(9) . .
N8 C53 C54 112.7(6) . .
C55 C54 C59 117.5(7) . .
C55 C54 C53 120.1(7) . .
C59 C54 C53 122.4(7) . .
C56 C55 C54 121.0(7) . .
C55 C56 C57 121.4(7) . 3_766
C58 C57 C56 118.4(7) . 3_766
C58 C57 C60 118.7(6) . .
C56 C57 C60 122.9(7) 3_766 .
C57 C58 C59 121.4(7) . 3_766
C58 C59 C54 120.0(7) 3_766 .
O7 C60 O8 121.3(7) . 3_856
O7 C60 C57 120.1(7) . .
O8 C60 C57 118.6(7) 3_856 .
O7 C60 Eu1 54.5(4) . .
O8 C60 Eu1 67.1(4) 3_856 .
C57 C60 Eu1 170.5(5) . .
N9 C61 C1 112.9(6) . .
N9 C62 C16 107.7(6) . .
N10 C63 C31 106.2(6) . .
N10 C64 C46 111.3(6) . .
N9 C65 C66 109.6(6) . .
N10 C66 C65 110.8(6) . .
C1 N1 C2 105.4(6) . .
C1 N1 Zn1 114.5(5) . .
C2 N1 Zn1 138.8(5) . .
C1 N2 C3 107.1(6) . .
C1 N2 C8 127.7(7) . .
C3 N2 C8 123.6(7) . .
C16 N3 C17 106.2(6) . .
C16 N3 Zn1 112.6(5) . .
C17 N3 Zn1 140.6(5) . .
C16 N4 C18 107.1(6) . .
C16 N4 C23 128.7(6) . .
C18 N4 C23 124.2(6) . .
C31 N5 C32 105.0(6) . .
C31 N5 Zn1 112.2(5) . .
C32 N5 Zn1 142.7(5) . .
C31 N6 C33 107.6(6) . .
C31 N6 C38 126.4(7) . .
C33 N6 C38 125.8(6) . .
C46 N7 C47 104.8(6) . .
C46 N7 Zn1 112.4(5) . .
C47 N7 Zn1 136.6(5) . .
C46 N8 C48 105.6(6) . .
C46 N8 C53 127.5(7) . .
C48 N8 C53 124.7(7) . .
C61 N9 C65 112.1(6) . .
C61 N9 C62 112.4(6) . .
C65 N9 C62 113.3(5) . .
C61 N9 Zn1 109.4(4) . .
C65 N9 Zn1 106.6(4) . .
C62 N9 Zn1 102.3(4) . .
C64 N10 C66 112.3(6) . .
C64 N10 C63 110.2(6) . .
C66 N10 C63 114.4(6) . .
C64 N10 Zn1 110.3(4) . .
C66 N10 Zn1 106.2(4) . .
C63 N10 Zn1 102.8(4) . .
N5 Zn1 N3 127.7(2) . .
N5 Zn1 N1 94.1(2) . .
N3 Zn1 N1 91.5(2) . .
N5 Zn1 N7 91.2(2) . .
N3 Zn1 N7 94.4(2) . .
N1 Zn1 N7 167.3(2) . .
N5 Zn1 N10 77.6(2) . .
N3 Zn1 N10 154.1(2) . .
N1 Zn1 N10 91.9(2) . .
N7 Zn1 N10 77.9(2) . .
N5 Zn1 N9 155.2(2) . .
N3 Zn1 N9 76.7(2) . .
N1 Zn1 N9 78.7(2) . .
N7 Zn1 N9 91.7(2) . .
N10 Zn1 N9 78.9(2) . .
Br1 Zn2 Br3 110.53(5) . .
Br1 Zn2 Br4 109.85(6) . .
Br3 Zn2 Br4 109.33(6) . .
Br1 Zn2 Br2 109.43(6) . .
Br3 Zn2 Br2 109.05(5) . .
Br4 Zn2 Br2 108.61(6) . .
O6 Eu1 O5 137.65(19) . .
O6 Eu1 O8 78.85(19) . .
O5 Eu1 O8 74.80(18) . .
O6 Eu1 O1 137.5(2) . .
O5 Eu1 O1 81.5(2) . .
O8 Eu1 O1 138.9(2) . .
O6 Eu1 O7 91.36(19) . .
O5 Eu1 O7 79.43(19) . .
O8 Eu1 O7 127.42(18) . .
O1 Eu1 O7 78.8(2) . .
O6 Eu1 O1W 74.4(2) . .
O5 Eu1 O1W 132.1(2) . .
O8 Eu1 O1W 81.74(19) . .
O1 Eu1 O1W 90.4(2) . .
O7 Eu1 O1W 145.0(2) . .
O6 Eu1 O2 84.6(2) . .
O5 Eu1 O2 130.70(19) . .
O8 Eu1 O2 152.17(19) . .
O1 Eu1 O2 52.9(2) . .
O7 Eu1 O2 74.76(18) . .
O1W Eu1 O2 72.27(19) . .
O6 Eu1 O2W 137.6(3) . .
O5 Eu1 O2W 66.9(3) . .
O8 Eu1 O2W 77.7(2) . .
O1 Eu1 O2W 62.2(3) . .
O7 Eu1 O2W 130.8(3) . .
O1W Eu1 O2W 67.7(3) . .
O2 Eu1 O2W 100.7(2) . .
O6 Eu1 O8 70.61(18) . 3_856
O5 Eu1 O8 72.02(18) . 3_856
O8 Eu1 O8 78.45(18) . 3_856
O1 Eu1 O8 125.1(2) . 3_856
O7 Eu1 O8 50.02(16) . 3_856
O1W Eu1 O8 142.35(18) . 3_856
O2 Eu1 O8 116.85(17) . 3_856
O2W Eu1 O8 136.5(2) . 3_856
O6 Eu1 C15 110.7(3) . .
O5 Eu1 C15 106.0(2) . .
O8 Eu1 C15 158.1(2) . .
O1 Eu1 C15 26.8(2) . .
O7 Eu1 C15 73.3(2) . .
O1W Eu1 C15 82.1(2) . .
O2 Eu1 C15 26.2(2) . .
O2W Eu1 C15 82.5(3) . .
O8 Eu1 C15 123.03(19) 3_856 .
O6 Eu1 C60 81.7(2) . .
O5 Eu1 C60 72.9(2) . .
O8 Eu1 C60 103.2(2) . .
O1 Eu1 C60 101.1(2) . .
O7 Eu1 C60 24.55(18) . .
O1W Eu1 C60 154.2(2) . .
O2 Eu1 C60 96.3(2) . .
O2W Eu1 C60 138.0(3) . .
O8 Eu1 C60 25.54(18) 3_856 .
C15 Eu1 C60 97.8(2) . .
O6 Eu1 Eu1 69.87(14) . 3_856
O5 Eu1 Eu1 68.29(13) . 3_856
O8 Eu1 Eu1 42.15(13) . 3_856
O1 Eu1 Eu1 148.14(18) . 3_856
O7 Eu1 Eu1 85.82(13) . 3_856
O1W Eu1 Eu1 117.10(14) . 3_856
O2 Eu1 Eu1 147.53(14) . 3_856
O2W Eu1 Eu1 111.6(2) . 3_856
O8 Eu1 Eu1 36.30(11) 3_856 3_856
C15 Eu1 Eu1 159.06(16) . 3_856
C60 Eu1 Eu1 61.31(16) . 3_856
C15 O1 Eu1 94.6(5) . .
C15 O2 Eu1 90.7(5) . .
C45 O5 Eu1 135.2(5) . .
C45 O6 Eu1 134.4(6) 3_856 .
C60 O7 Eu1 101.0(4) . .
C60 O8 Eu1 163.0(5) 3_856 .
C60 O8 Eu1 87.4(4) 3_856 3_856
Eu1 O8 Eu1 101.55(18) . 3_856
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.326(9) .
C1 N2 1.331(9) .
C1 C61 1.503(10) .
C2 C7 1.375(11) .
C2 C3 1.381(11) .
C2 N1 1.405(9) .
C3 C4 1.370(11) .
C3 N2 1.389(10) .
C4 C5 1.379(13) .
C5 C6 1.376(14) .
C6 C7 1.412(13) .
C8 N2 1.472(9) .
C8 C9 1.517(10) .
C9 C10 1.373(11) .
C9 C14 1.389(10) .
C10 C11 1.386(11) .
C11 C12 1.375(11) .
C12 C13 1.393(11) .
C12 C15 1.478(11) .
C13 C14 1.396(10) .
C15 O2 1.246(10) .
C15 O1 1.280(10) .
C15 Eu1 2.826(9) .
C16 N3 1.309(9) .
C16 N4 1.357(8) .
C16 C62 1.498(9) .
C17 N3 1.385(9) .
C17 C22 1.387(11) .
C17 C18 1.397(10) .
C18 C19 1.373(11) .
C18 N4 1.388(9) .
C19 C20 1.363(12) .
C20 C21 1.395(14) .
C21 C22 1.384(13) .
C23 N4 1.464(9) .
C23 C24 1.507(11) .
C24 C25 1.369(11) .
C24 C29 1.387(10) .
C25 C26 1.361(12) .
C26 C27 1.395(11) .
C27 C28 1.374(11) .
C27 C30 1.480(12) .
C28 C29 1.385(11) .
C30 O4 1.217(10) .
C30 O3 1.323(10) .
C31 N5 1.321(9) .
C31 N6 1.365(9) .
C31 C63 1.517(10) .
C32 C37 1.388(11) .
C32 N5 1.403(9) .
C32 C33 1.417(10) .
C33 N6 1.380(9) .
C33 C34 1.377(11) .
C34 C35 1.339(13) .
C35 C36 1.430(14) .
C36 C37 1.397(12) .
C38 N6 1.463(9) .
C38 C39 1.511(11) .
C39 C44 1.360(11) .
C39 C40 1.368(11) .
C40 C41 1.407(12) .
C41 C42 1.397(11) 1_455
C42 C43 1.383(11) .
C42 C41 1.397(11) 1_655
C42 C45 1.497(11) .
C43 C44 1.383(12) 1_655
C44 C43 1.383(12) 1_455
C45 O5 1.262(9) .
C45 O6 1.265(9) 3_856
C46 N7 1.312(9) .
C46 N8 1.352(9) .
C46 C64 1.492(10) .
C47 C48 1.371(11) .
C47 N7 1.390(9) .
C47 C52 1.413(10) .
C48 N8 1.391(9) .
C48 C49 1.416(11) .
C49 C50 1.345(13) .
C50 C51 1.390(13) .
C51 C52 1.395(12) .
C53 N8 1.440(9) .
C53 C54 1.538(10) .
C54 C55 1.382(10) .
C54 C59 1.393(10) .
C55 C56 1.355(10) .
C56 C57 1.369(10) 3_766
C57 C58 1.358(10) .
C57 C56 1.369(10) 3_766
C57 C60 1.509(10) .
C58 C59 1.375(10) 3_766
C59 C58 1.375(10) 3_766
C60 O7 1.237(9) .
C60 O8 1.261(8) 3_856
C60 Eu1 2.922(7) .
C61 N9 1.464(9) .
C62 N9 1.496(8) .
C63 N10 1.479(9) .
C64 N10 1.473(9) .
C65 N9 1.476(8) .
C65 C66 1.519(10) .
C66 N10 1.474(9) .
N1 Zn1 2.122(6) .
N3 Zn1 2.097(6) .
N5 Zn1 2.076(6) .
N7 Zn1 2.151(6) .
N9 Zn1 2.287(6) .
N10 Zn1 2.285(6) .
Zn2 Br1 2.3874(15) .
Zn2 Br3 2.3971(13) .
Zn2 Br4 2.4057(14) .
Zn2 Br2 2.4102(15) .
Eu1 O6 2.358(6) .
Eu1 O5 2.353(6) .
Eu1 O8 2.377(5) .
Eu1 O1 2.418(6) .
Eu1 O7 2.422(5) .
Eu1 O1W 2.465(5) .
Eu1 O2 2.521(6) .
Eu1 O2W 2.638(8) .
Eu1 O8 2.694(5) 3_856
Eu1 Eu1 3.9331(8) 3_856
O6 C45 1.265(9) 3_856
O8 C60 1.261(8) 3_856
O8 Eu1 2.694(5) 3_856
