#------------------------------------------------------------------------------
#$Date: 2016-03-26 18:14:25 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180418 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/87/7208766.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7208766
loop_
_publ_author_name
'Girard, Jerome'
'Fromm, Katharina'
_publ_section_title
;
 Single crystal to single crystal polymorphic phase transition of a silver
 nitrate 24-crown-8 complex and its pseudo-polymorphism
;
_journal_issue                   20
_journal_name_full               CrystEngComm
_journal_page_first              6487
_journal_paper_doi               10.1039/c2ce25875g
_journal_volume                  14
_journal_year                    2012
_chemical_formula_moiety         'C8 H16 Ag2 N2 O10'
_chemical_formula_sum            'C8 H16 Ag2 N2 O10'
_chemical_formula_weight         515.97
_chemical_name_common            '(24-crown-8) tetrasilver nitrate'
_chemical_name_systematic        '(24-crown-8) tetrasilver nitrate'
_space_group_IT_number           73
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      73
_symmetry_space_group_name_Hall  '-I 2b 2c'
_symmetry_space_group_name_H-M   'I b c a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            16
_cell_length_a                   13.4204(6)
_cell_length_b                   16.5076(7)
_cell_length_c                   28.1263(13)
_cell_measurement_reflns_used    15799
_cell_measurement_temperature    273(2)
_cell_measurement_theta_max      26.30
_cell_measurement_theta_min      1.45
_cell_volume                     6231.1(5)
_computing_cell_refinement       X-Area
_computing_data_collection       X-Area
_computing_data_reduction        X-Red32
_computing_molecular_graphics    Diamond
_computing_publication_material  enCIFer
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXL-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      273(2)
_diffrn_detector_area_resol_mean 6.67
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'STOE IPDS 2T'
_diffrn_measurement_method       'rotation method'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0456
_diffrn_reflns_av_sigmaI/netI    0.0149
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            36758
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.45
_diffrn_source                   'fine-focus sealed tube'
_diffrn_source_type              'STOE IPDS 2T'
_exptl_absorpt_coefficient_mu    2.564
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.200
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             4032
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.12
_refine_diff_density_max         1.089
_refine_diff_density_min         -0.601
_refine_diff_density_rms         0.073
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.070
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     215
_refine_ls_number_reflns         2732
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.070
_refine_ls_R_factor_all          0.0464
_refine_ls_R_factor_gt           0.0365
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0223P)²+35.9168P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0753
_refine_ls_wR_factor_ref         0.0785
_reflns_number_gt                2294
_reflns_number_total             2732
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            c2ce25875g.txt
_cod_data_source_block           01_1
_cod_database_code               7208766
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y+1/2, z'
'x, -y, -z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1, z+1/2'
'x+1/2, -y+1/2, -z+1'
'-x+1/2, y+1, -z+1'
'-x, -y, -z'
'x, y-1/2, -z'
'-x, y, z-1/2'
'x, -y-1/2, z-1/2'
'-x+1/2, -y+1/2, -z+1/2'
'x+1/2, y, -z+1/2'
'-x+1/2, y+1/2, z'
'x+1/2, -y, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C3 C 0.0836(6) 0.4638(5) 0.0723(3) 0.097(2) Uani 1 1 d .
H3A H 0.1248 0.5024 0.0553 0.116 Uiso 1 1 calc R
H3B H 0.1256 0.4346 0.0945 0.116 Uiso 1 1 calc R
C4 C 0.0042(7) 0.5070(4) 0.0983(3) 0.101(2) Uani 1 1 d .
H4A H 0.0331 0.5483 0.1186 0.122 Uiso 1 1 calc R
H4B H -0.0407 0.5331 0.0760 0.122 Uiso 1 1 calc R
C5 C -0.1245(6) 0.4874(4) 0.1538(3) 0.101(2) Uani 1 1 d .
H5A H -0.1712 0.5152 0.1332 0.121 Uiso 1 1 calc R
H5B H -0.0952 0.5269 0.1752 0.121 Uiso 1 1 calc R
C6 C -0.1770(6) 0.4232(5) 0.1816(3) 0.101(2) Uani 1 1 d .
H6A H -0.2323 0.4470 0.1990 0.121 Uiso 1 1 calc R
H6B H -0.2035 0.3826 0.1601 0.121 Uiso 1 1 calc R
C7 C -0.1529(5) 0.3227(4) 0.2412(2) 0.087(2) Uani 1 1 d .
H7A H -0.1789 0.2814 0.2200 0.104 Uiso 1 1 calc R
H7B H -0.2078 0.3439 0.2599 0.104 Uiso 1 1 calc R
C8 C -0.0759(5) 0.2867(4) 0.2733(2) 0.085(2) Uani 1 1 d .
H8A H -0.0469 0.3286 0.2932 0.102 Uiso 1 1 calc R
H8B H -0.1061 0.2463 0.2938 0.102 Uiso 1 1 calc R
O3 O -0.0490(3) 0.4493(2) 0.12640(14) 0.0722(11) Uani 1 1 d .
O4 O -0.1091(3) 0.3862(3) 0.21419(15) 0.0772(11) Uani 1 1 d .
O5 O 0.0000 0.2500 0.24429(18) 0.0643(13) Uani 1 2 d S
O11 O 0.0829(10) 0.5189(13) 0.2117(7) 0.108(5) Uani 0.50 1 d P
O12 O 0.1368(9) 0.4553(17) 0.2184(11) 0.175(9) Uani 0.50 1 d P
O13 O 0.1023(14) 0.4266(12) 0.2618(7) 0.118(4) Uani 0.50 1 d P
N3 N 0.1052(5) 0.5000 0.2500 0.079(3) Uani 1 2 d S
C1 C 0.1082(5) 0.3634(5) 0.0122(3) 0.089(2) Uani 1 1 d .
H1A H 0.1519 0.3331 0.0332 0.106 Uiso 1 1 calc R
H1B H 0.1488 0.4000 -0.0066 0.106 Uiso 1 1 calc R
C2 C 0.0543(5) 0.3074(5) -0.0192(2) 0.095(2) Uani 1 1 d .
H2A H 0.0086 0.3375 -0.0393 0.114 Uiso 1 1 calc R
H2B H 0.1012 0.2792 -0.0396 0.114 Uiso 1 1 calc R
O1 O 0.0000 0.2500 0.00920(18) 0.0705(15) Uani 1 2 d S
O2 O 0.0394(3) 0.4076(3) 0.03908(16) 0.0825(12) Uani 1 1 d .
O6 O -0.1220(3) 0.2326(2) 0.12680(13) 0.0677(10) Uani 1 1 d .
O7 O -0.2727(4) 0.2579(4) 0.10440(17) 0.1065(16) Uani 1 1 d .
O8 O -0.2418(4) 0.1593(3) 0.15325(16) 0.0920(14) Uani 1 1 d .
O9 O -0.1984(3) 0.4418(2) 0.02916(15) 0.0783(12) Uani 1 1 d .
O10 O -0.2500 0.3305(4) 0.0000 0.0878(19) Uani 1 2 d S
Ag1 Ag -0.10648(3) 0.33405(3) 0.068572(16) 0.06588(15) Uani 1 1 d .
Ag2 Ag 0.05310(3) 0.35865(3) 0.182566(17) 0.07237(16) Uani 1 1 d .
N1 N -0.2148(4) 0.2161(3) 0.12833(17) 0.0703(13) Uani 1 1 d .
N2 N -0.2500 0.4043(4) 0.0000 0.0590(15) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 C3 C4 109.5(6) . .
O2 C3 H3A 109.8 . .
C4 C3 H3A 109.8 . .
O2 C3 H3B 109.8 . .
C4 C3 H3B 109.8 . .
H3A C3 H3B 108.2 . .
O3 C4 C3 108.3(5) . .
O3 C4 H4A 110.0 . .
C3 C4 H4A 110.0 . .
O3 C4 H4B 110.0 . .
C3 C4 H4B 110.0 . .
H4A C4 H4B 108.4 . .
O3 C5 C6 107.9(5) . .
O3 C5 H5A 110.1 . .
C6 C5 H5A 110.1 . .
O3 C5 H5B 110.1 . .
C6 C5 H5B 110.1 . .
H5A C5 H5B 108.4 . .
O4 C6 C5 109.7(6) . .
O4 C6 H6A 109.7 . .
C5 C6 H6A 109.7 . .
O4 C6 H6B 109.7 . .
C5 C6 H6B 109.7 . .
H6A C6 H6B 108.2 . .
O4 C7 C8 109.2(5) . .
O4 C7 H7A 109.8 . .
C8 C7 H7A 109.8 . .
O4 C7 H7B 109.8 . .
C8 C7 H7B 109.8 . .
H7A C7 H7B 108.3 . .
O5 C8 C7 108.3(5) . .
O5 C8 H8A 110.0 . .
C7 C8 H8A 110.0 . .
O5 C8 H8B 110.0 . .
C7 C8 H8B 110.0 . .
H8A C8 H8B 108.4 . .
C5 O3 C4 111.3(5) . .
C5 O3 Ag2 107.7(4) . .
C4 O3 Ag2 117.4(4) . .
C7 O4 C6 113.2(6) . .
C7 O4 Ag2 115.8(4) . .
C6 O4 Ag2 115.0(4) . .
C8 O5 C8 110.9(7) . 2
C8 O5 Ag2 118.4(3) . 2
C8 O5 Ag2 106.4(3) 2 2
C8 O5 Ag2 106.4(3) . .
C8 O5 Ag2 118.4(3) 2 .
Ag2 O5 Ag2 96.05(17) 2 .
N3 O11 O13 64.4(13) . 3_565
N3 O11 O12 60.1(12) . .
O13 O11 O12 113.6(16) 3_565 .
N3 O12 O11 54.8(8) . .
N3 O12 O13 56.9(8) . .
O11 O12 O13 102.6(11) . .
N3 O12 Ag2 126.2(8) . .
O11 O12 Ag2 103.8(17) . .
O13 O12 Ag2 89.1(15) . .
O11 O13 N3 56.4(12) 3_565 .
O11 O13 O12 111(2) 3_565 .
N3 O13 O12 55.2(10) . .
O11 O13 Ag2 144.0(16) 3_565 .
N3 O13 Ag2 101.5(9) . .
O12 O13 Ag2 58.3(9) . .
O11 N3 O11 150.1(17) 3_565 .
O11 N3 O12 65.1(12) 3_565 3_565
O11 N3 O12 126.8(13) . 3_565
O11 N3 O12 126.8(13) 3_565 .
O11 N3 O12 65.1(12) . .
O12 N3 O12 139.7(14) 3_565 .
O11 N3 O13 119.7(9) 3_565 3_565
O11 N3 O13 59.2(9) . 3_565
O12 N3 O13 67.9(11) 3_565 3_565
O12 N3 O13 113.4(14) . 3_565
O11 N3 O13 59.2(9) 3_565 .
O11 N3 O13 119.7(9) . .
O12 N3 O13 113.4(14) 3_565 .
O12 N3 O13 67.9(11) . .
O13 N3 O13 176.4(19) 3_565 .
O2 C1 C2 109.2(5) . .
O2 C1 H1A 109.8 . .
C2 C1 H1A 109.8 . .
O2 C1 H1B 109.8 . .
C2 C1 H1B 109.8 . .
H1A C1 H1B 108.3 . .
O1 C2 C1 109.2(5) . .
O1 C2 H2A 109.8 . .
C1 C2 H2A 109.8 . .
O1 C2 H2B 109.8 . .
C1 C2 H2B 109.8 . .
H2A C2 H2B 108.3 . .
C2 O1 C2 112.5(7) . 2
C2 O1 Ag1 106.5(3) . .
C2 O1 Ag1 115.5(3) 2 .
C2 O1 Ag1 115.5(3) . 2
C2 O1 Ag1 106.5(3) 2 2
Ag1 O1 Ag1 100.04(17) . 2
C1 O2 C3 114.4(6) . .
C1 O2 Ag1 116.9(4) . .
C3 O2 Ag1 115.3(4) . .
N1 O6 Ag1 105.2(3) . .
N1 O6 Ag2 102.9(3) . 2
Ag1 O6 Ag2 151.80(18) . 2
N2 O9 Ag1 102.7(3) . .
O6 Ag1 O9 142.49(14) . .
O6 Ag1 O2 131.30(13) . .
O9 Ag1 O2 83.60(14) . .
O6 Ag1 O1 96.66(12) . .
O9 Ag1 O1 112.12(14) . .
O2 Ag1 O1 66.88(12) . .
O12 Ag2 O6 124.5(3) . 2
O12 Ag2 O4 99.0(3) . .
O6 Ag2 O4 136.33(13) 2 .
O12 Ag2 O3 97.6(10) . .
O6 Ag2 O3 99.89(13) 2 .
O4 Ag2 O3 68.49(14) . .
O12 Ag2 O13 32.6(8) . .
O6 Ag2 O13 138.6(5) 2 .
O4 Ag2 O13 80.2(5) . .
O3 Ag2 O13 114.4(4) . .
O12 Ag2 O5 109.6(10) . .
O6 Ag2 O5 96.38(12) 2 .
O4 Ag2 O5 68.48(11) . .
O3 Ag2 O5 131.81(10) . .
O13 Ag2 O5 78.0(4) . .
O8 N1 O7 123.5(6) . .
O8 N1 O6 118.1(6) . .
O7 N1 O6 118.4(5) . .
O10 N2 O9 120.0(3) . 8_444
O10 N2 O9 120.0(3) . .
O9 N2 O9 120.1(7) 8_444 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C3 O2 1.443(8) .
C3 C4 1.477(10) .
C3 H3A 0.9700 .
C3 H3B 0.9700 .
C4 O3 1.429(8) .
C4 H4A 0.9700 .
C4 H4B 0.9700 .
C5 O3 1.420(8) .
C5 C6 1.493(10) .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C6 O4 1.430(8) .
C6 H6A 0.9700 .
C6 H6B 0.9700 .
C7 O4 1.421(7) .
C7 C8 1.496(9) .
C7 H7A 0.9700 .
C7 H7B 0.9700 .
C8 O5 1.439(7) .
C8 H8A 0.9700 .
C8 H8B 0.9700 .
O3 Ag2 2.572(4) .
O4 Ag2 2.395(4) .
O5 C8 1.439(7) 2
O5 Ag2 2.596(3) 2
O5 Ag2 2.596(3) .
O11 N3 1.161(16) .
O11 O13 1.198(19) 3_565
O11 O12 1.29(2) .
O12 N3 1.232(11) .
O12 O13 1.39(3) .
O12 Ag2 2.196(11) .
O13 O11 1.198(19) 3_565
O13 N3 1.257(17) .
O13 Ag2 2.580(19) .
N3 O11 1.161(16) 3_565
N3 O12 1.232(11) 3_565
N3 O13 1.257(17) 3_565
C1 O2 1.399(8) .
C1 C2 1.469(10) .
C1 H1A 0.9700 .
C1 H1B 0.9700 .
C2 O1 1.439(7) .
C2 H2A 0.9700 .
C2 H2B 0.9700 .
O1 C2 1.439(7) 2
O1 Ag1 2.599(3) .
O1 Ag1 2.599(3) 2
O2 Ag1 2.449(4) .
O6 N1 1.275(6) .
O6 Ag1 2.352(4) .
O6 Ag2 2.363(4) 2
O7 N1 1.237(7) .
O8 N1 1.226(6) .
O9 N2 1.239(5) .
O9 Ag1 2.433(4) .
O10 N2 1.218(8) .
Ag2 O6 2.363(4) 2
N2 O9 1.239(5) 8_444
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O2 C3 C4 O3 64.8(7) . .
O3 C5 C6 O4 63.5(7) . .
O4 C7 C8 O5 -64.3(6) . .
C6 C5 O3 C4 179.4(6) . .
C6 C5 O3 Ag2 -50.5(7) . .
C3 C4 O3 C5 177.9(6) . .
C3 C4 O3 Ag2 53.1(7) . .
C8 C7 O4 C6 178.8(5) . .
C8 C7 O4 Ag2 43.0(6) . .
C5 C6 O4 C7 -178.4(5) . .
C5 C6 O4 Ag2 -42.2(6) . .
C7 C8 O5 C8 -179.3(6) . 2
C7 C8 O5 Ag2 -55.8(6) . 2
C7 C8 O5 Ag2 50.7(5) . .
O13 O11 O12 N3 37(2) 3_565 .
N3 O11 O12 O13 32.6(9) . .
O13 O11 O12 O13 70.0(19) 3_565 .
N3 O11 O12 Ag2 124.8(16) . .
O13 O11 O12 Ag2 162.2(11) 3_565 .
N3 O12 O13 O11 -6(2) . 3_565
O11 O12 O13 O11 -37(3) . 3_565
Ag2 O12 O13 O11 -141.2(14) . 3_565
O11 O12 O13 N3 -31.7(10) . .
Ag2 O12 O13 N3 -135.6(11) . .
N3 O12 O13 Ag2 135.6(11) . .
O11 O12 O13 Ag2 103.9(15) . .
O13 O11 N3 O11 97.0(14) 3_565 3_565
O12 O11 N3 O11 -121.1(8) . 3_565
O13 O11 N3 O12 -7(2) 3_565 3_565
O12 O11 N3 O12 134.6(16) . 3_565
O13 O11 N3 O12 -141.9(18) 3_565 .
O12 O11 N3 O13 141.9(17) . 3_565
O13 O11 N3 O13 176(2) 3_565 .
O12 O11 N3 O13 -42.1(11) . .
O11 O12 N3 O11 148(2) . 3_565
O13 O12 N3 O11 7(2) . 3_565
Ag2 O12 N3 O11 67(4) . 3_565
O13 O12 N3 O11 -141.1(11) . .
Ag2 O12 N3 O11 -81(3) . .
O11 O12 N3 O12 -118.2(11) . 3_565
O13 O12 N3 O12 100.7(14) . 3_565
Ag2 O12 N3 O12 161(3) . 3_565
O11 O12 N3 O13 -35.3(14) . 3_565
O13 O12 N3 O13 -176.4(19) . 3_565
Ag2 O12 N3 O13 -116(3) . 3_565
O11 O12 N3 O13 141.1(11) . .
Ag2 O12 N3 O13 60(2) . .
O12 O13 N3 O11 -174(2) . 3_565
Ag2 O13 N3 O11 148.9(19) . 3_565
O11 O13 N3 O11 -145(2) 3_565 .
O12 O13 N3 O11 41.0(12) . .
Ag2 O13 N3 O11 3.6(13) . .
O11 O13 N3 O12 37.6(14) 3_565 3_565
O12 O13 N3 O12 -136.1(18) . 3_565
Ag2 O13 N3 O12 -173.5(11) . 3_565
O11 O13 N3 O12 174(2) 3_565 .
Ag2 O13 N3 O12 -37.4(8) . .
O2 C1 C2 O1 -63.4(6) . .
C1 C2 O1 C2 -179.6(6) . 2
C1 C2 O1 Ag1 53.0(5) . .
C1 C2 O1 Ag1 -57.1(6) . 2
C2 C1 O2 C3 178.8(5) . .
C2 C1 O2 Ag1 39.6(6) . .
C4 C3 O2 C1 179.7(5) . .
C4 C3 O2 Ag1 -40.4(6) . .
N1 O6 Ag1 O9 25.2(4) . .
Ag2 O6 Ag1 O9 -158.7(3) 2 .
N1 O6 Ag1 O2 179.4(3) . .
Ag2 O6 Ag1 O2 -4.5(5) 2 .
N1 O6 Ag1 O1 -115.6(3) . .
Ag2 O6 Ag1 O1 60.5(4) 2 .
N2 O9 Ag1 O6 -78.5(3) . .
N2 O9 Ag1 O2 120.7(3) . .
N2 O9 Ag1 O1 58.8(3) . .
C1 O2 Ag1 O6 69.4(5) . .
C3 O2 Ag1 O6 -69.4(5) . .
C1 O2 Ag1 O9 -126.0(4) . .
C3 O2 Ag1 O9 95.2(4) . .
C1 O2 Ag1 O1 -8.6(4) . .
C3 O2 Ag1 O1 -147.4(4) . .
C2 O1 Ag1 O6 -155.8(4) . .
C2 O1 Ag1 O6 78.6(4) 2 .
Ag1 O1 Ag1 O6 -35.22(9) 2 .
C2 O1 Ag1 O9 48.8(4) . .
C2 O1 Ag1 O9 -76.8(4) 2 .
Ag1 O1 Ag1 O9 169.34(10) 2 .
C2 O1 Ag1 O2 -23.5(4) . .
C2 O1 Ag1 O2 -149.1(4) 2 .
Ag1 O1 Ag1 O2 97.05(11) 2 .
N3 O12 Ag2 O6 -174(2) . 2
O11 O12 Ag2 O6 129.4(15) . 2
O13 O12 Ag2 O6 -127.9(12) . 2
N3 O12 Ag2 O4 9(3) . .
O11 O12 Ag2 O4 -47(2) . .
O13 O12 Ag2 O4 55(2) . .
N3 O12 Ag2 O3 78(3) . .
O11 O12 Ag2 O3 22(2) . .
O13 O12 Ag2 O3 124.6(18) . .
N3 O12 Ag2 O13 -46.6(16) . .
O11 O12 Ag2 O13 -102.8(12) . .
N3 O12 Ag2 O5 -62(3) . .
O11 O12 Ag2 O5 -118(2) . .
O13 O12 Ag2 O5 -15.0(19) . .
C7 O4 Ag2 O12 -119.2(11) . .
C6 O4 Ag2 O12 105.8(11) . .
C7 O4 Ag2 O6 64.5(5) . 2
C6 O4 Ag2 O6 -70.5(5) . 2
C7 O4 Ag2 O3 146.1(4) . .
C6 O4 Ag2 O3 11.1(4) . .
C7 O4 Ag2 O13 -92.5(5) . .
C6 O4 Ag2 O13 132.5(6) . .
C7 O4 Ag2 O5 -11.6(4) . .
C6 O4 Ag2 O5 -146.6(5) . .
C5 O3 Ag2 O12 -74.9(6) . .
C4 O3 Ag2 O12 51.6(6) . .
C5 O3 Ag2 O6 157.9(4) . 2
C4 O3 Ag2 O6 -75.6(5) . 2
C5 O3 Ag2 O4 21.8(4) . .
C4 O3 Ag2 O4 148.3(5) . .
C5 O3 Ag2 O13 -45.8(6) . .
C4 O3 Ag2 O13 80.7(7) . .
C5 O3 Ag2 O5 50.0(4) . .
C4 O3 Ag2 O5 176.5(4) . .
O11 O13 Ag2 O12 83(3) 3_565 .
N3 O13 Ag2 O12 35.9(12) . .
O11 O13 Ag2 O6 162(3) 3_565 2
N3 O13 Ag2 O6 115.4(11) . 2
O12 O13 Ag2 O6 79.5(19) . 2
O11 O13 Ag2 O4 -42(3) 3_565 .
N3 O13 Ag2 O4 -88.7(13) . .
O12 O13 Ag2 O4 -124.5(19) . .
O11 O13 Ag2 O3 19(3) 3_565 .
N3 O13 Ag2 O3 -27.8(14) . .
O12 O13 Ag2 O3 -64(2) . .
O11 O13 Ag2 O5 -112(3) 3_565 .
N3 O13 Ag2 O5 -158.6(13) . .
O12 O13 Ag2 O5 165.6(19) . .
C8 O5 Ag2 O12 70.7(6) . .
C8 O5 Ag2 O12 -54.9(6) 2 .
Ag2 O5 Ag2 O12 -167.3(5) 2 .
C8 O5 Ag2 O6 -159.1(3) . 2
C8 O5 Ag2 O6 75.3(4) 2 2
Ag2 O5 Ag2 O6 -37.08(9) 2 2
C8 O5 Ag2 O4 -21.5(3) . .
C8 O5 Ag2 O4 -147.2(4) 2 .
Ag2 O5 Ag2 O4 100.51(11) 2 .
C8 O5 Ag2 O3 -49.7(4) . .
C8 O5 Ag2 O3 -175.4(4) 2 .
Ag2 O5 Ag2 O3 72.31(14) 2 .
C8 O5 Ag2 O13 62.5(6) . .
C8 O5 Ag2 O13 -63.1(6) 2 .
Ag2 O5 Ag2 O13 -175.5(5) 2 .
Ag1 O6 N1 O8 173.6(4) . .
Ag2 O6 N1 O8 -4.5(5) 2 .
Ag1 O6 N1 O7 -5.9(6) . .
Ag2 O6 N1 O7 176.0(4) 2 .
Ag1 O9 N2 O10 5.5(3) . .
Ag1 O9 N2 O9 -174.5(3) . 8_444
