#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/49/7214957.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7214957
loop_
_publ_author_name
'Gao, Jia-Zhen'
'Yang, Jin'
'Liu, Ying-Ying'
'Ma, Jian-Fang'
_publ_section_title
;
 Ten new coordination polymers based on
 3-carboxy-1-(4′-carboxybenzyl)-2-oxidopyridinium and different
 N-donor ligands: syntheses, structures, and photoluminescent properties
;
_journal_issue                   23
_journal_name_full               CrystEngComm
_journal_page_first              8173
_journal_paper_doi               10.1039/c2ce25953b
_journal_volume                  14
_journal_year                    2012
_chemical_formula_moiety         'C26 H19 Cu N3 O6'
_chemical_formula_sum            'C26 H19 Cu N3 O6'
_chemical_formula_weight         532.98
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 92.448(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.4242(3)
_cell_length_b                   16.2523(4)
_cell_length_c                   12.0073(4)
_cell_measurement_reflns_used    4214
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.0961
_cell_measurement_theta_min      2.8046
_cell_volume                     2227.36(11)
_computing_cell_refinement       CrysAlis
_computing_data_collection       'CrysAlis (Oxford Diffraction, 2006)'
_computing_data_reduction        CrysAlis
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXL-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 10.0
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Oxford Diffraction Gemini R Ultra'
_diffrn_measurement_method       'ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0390
_diffrn_reflns_av_sigmaI/netI    0.0390
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            13668
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         2.81
_exptl_absorpt_coefficient_mu    1.032
_exptl_absorpt_correction_T_max  0.8950
_exptl_absorpt_correction_T_min  0.8048
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlis (Oxford Diffraction, 2006)
;
_exptl_crystal_colour            Blue
_exptl_crystal_density_diffrn    1.589
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1092
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.11
_refine_diff_density_max         0.448
_refine_diff_density_min         -0.351
_refine_diff_density_rms         0.055
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     325
_refine_ls_number_reflns         3934
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.034
_refine_ls_R_factor_all          0.0516
_refine_ls_R_factor_gt           0.0374
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0343P)²+1.3304P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0809
_refine_ls_wR_factor_ref         0.0866
_reflns_number_gt                3180
_reflns_number_total             3934
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            c2ce25953b.txt
_cod_data_source_block           Compound-6
_cod_original_sg_symbol_Hall     '-p 2yn'
_cod_original_sg_symbol_H-M      p21/n
_cod_database_code               7214957
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cu1 Cu 0.70886(3) 0.395819(18) 0.36635(3) 0.02851(12) Uani 1 1 d .
C1 C 0.2885(2) 0.10481(16) 0.6312(3) 0.0345(7) Uani 1 1 d .
C2 C 0.3846(2) 0.11033(14) 0.5492(2) 0.0287(6) Uani 1 1 d .
C3 C 0.3586(2) 0.12496(16) 0.4368(2) 0.0342(7) Uani 1 1 d .
H3 H 0.2808 0.1308 0.4119 0.041 Uiso 1 1 calc R
C4 C 0.4455(2) 0.13098(16) 0.3619(2) 0.0336(7) Uani 1 1 d .
H4 H 0.4260 0.1418 0.2873 0.040 Uiso 1 1 calc R
C5 C 0.5624(2) 0.12115(15) 0.3959(2) 0.0282(6) Uani 1 1 d .
C6 C 0.5883(2) 0.10576(17) 0.5074(2) 0.0368(7) Uani 1 1 d .
H6 H 0.6660 0.0988 0.5320 0.044 Uiso 1 1 calc R
C7 C 0.5009(2) 0.10061(17) 0.5830(3) 0.0365(7) Uani 1 1 d .
H7 H 0.5206 0.0905 0.6577 0.044 Uiso 1 1 calc R
C8 C 0.6554(2) 0.12204(16) 0.3106(2) 0.0310(6) Uani 1 1 d .
H8A H 0.6622 0.0674 0.2788 0.037 Uiso 1 1 calc R
H8B H 0.6320 0.1595 0.2508 0.037 Uiso 1 1 calc R
C9 C 0.8568(2) 0.09049(16) 0.3776(2) 0.0361(7) Uani 1 1 d .
H9 H 0.8441 0.0364 0.3548 0.043 Uiso 1 1 calc R
C10 C 0.9600(3) 0.11130(17) 0.4287(3) 0.0418(8) Uani 1 1 d .
H10 H 1.0198 0.0728 0.4384 0.050 Uiso 1 1 calc R
C11 C 0.9752(2) 0.19180(17) 0.4665(3) 0.0379(7) Uani 1 1 d .
H11 H 1.0449 0.2060 0.5047 0.045 Uiso 1 1 calc R
C12 C 0.8907(2) 0.25068(16) 0.4491(2) 0.0294(6) Uani 1 1 d .
C13 C 0.7846(2) 0.22898(15) 0.3899(2) 0.0260(6) Uani 1 1 d .
C14 C 0.9096(2) 0.33497(16) 0.5003(2) 0.0322(6) Uani 1 1 d .
C15 C 0.4752(3) 0.34471(18) 0.2589(3) 0.0411(7) Uani 1 1 d .
H15 H 0.5094 0.2944 0.2427 0.049 Uiso 1 1 calc R
C16 C 0.3572(3) 0.3568(2) 0.2293(3) 0.0485(8) Uani 1 1 d .
H16 H 0.3138 0.3148 0.1950 0.058 Uiso 1 1 calc R
C17 C 0.3059(3) 0.4302(2) 0.2506(3) 0.0483(8) Uani 1 1 d .
H17 H 0.2268 0.4384 0.2324 0.058 Uiso 1 1 calc R
C18 C 0.3730(2) 0.49377(18) 0.3004(2) 0.0383(7) Uani 1 1 d .
C19 C 0.3289(3) 0.5740(2) 0.3249(3) 0.0493(8) Uani 1 1 d .
H19 H 0.2506 0.5862 0.3084 0.059 Uiso 1 1 calc R
C20 C 0.3996(3) 0.6322(2) 0.3719(3) 0.0514(9) Uani 1 1 d .
H20 H 0.3692 0.6841 0.3858 0.062 Uiso 1 1 calc R
C21 C 0.5200(3) 0.61586(17) 0.4006(3) 0.0388(7) Uani 1 1 d .
C22 C 0.5986(3) 0.67312(18) 0.4492(3) 0.0508(9) Uani 1 1 d .
H22 H 0.5737 0.7263 0.4645 0.061 Uiso 1 1 calc R
C23 C 0.7115(3) 0.65047(17) 0.4740(3) 0.0488(8) Uani 1 1 d .
H23 H 0.7642 0.6885 0.5051 0.059 Uiso 1 1 calc R
C24 C 0.7483(3) 0.57024(17) 0.4528(3) 0.0382(7) Uani 1 1 d .
H24 H 0.8252 0.5553 0.4718 0.046 Uiso 1 1 calc R
C25 C 0.5640(2) 0.53737(15) 0.3804(2) 0.0290(6) Uani 1 1 d .
C26 C 0.4903(2) 0.47619(16) 0.3286(2) 0.0294(6) Uani 1 1 d .
N1 N 0.77075(18) 0.14763(12) 0.35900(19) 0.0279(5) Uani 1 1 d .
N2 N 0.54060(19) 0.40223(13) 0.30939(19) 0.0309(5) Uani 1 1 d .
N3 N 0.67665(19) 0.51492(13) 0.40651(18) 0.0288(5) Uani 1 1 d .
O1 O 0.31817(17) 0.08591(12) 0.73024(18) 0.0430(5) Uani 1 1 d .
O2 O 0.1872(2) 0.11499(19) 0.5966(2) 0.0766(8) Uani 1 1 d .
O1W O 0.95437(19) 0.51634(13) 0.65383(19) 0.0548(6) Uani 1 1 d .
H1B H 1.0248 0.5398 0.6565 0.082 Uiso 1 1 d R
H1A H 0.9596 0.4695 0.6161 0.082 Uiso 1 1 d R
O3 O 0.69934(15) 0.27602(10) 0.36498(16) 0.0337(5) Uani 1 1 d .
O4 O 0.84272(16) 0.39401(11) 0.46946(18) 0.0406(5) Uani 1 1 d .
O5 O 0.98840(19) 0.34252(12) 0.5728(2) 0.0537(6) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
O4 Cu1 O3 91.87(7) .
O4 Cu1 N2 159.80(9) .
O3 Cu1 N2 89.82(8) .
O4 Cu1 N3 90.51(8) .
O3 Cu1 N3 160.46(9) .
N2 Cu1 N3 81.46(8) .
O4 Cu1 O1 91.14(9) 4_665
O3 Cu1 O1 99.66(8) 4_665
N2 Cu1 O1 108.42(9) 4_665
N3 Cu1 O1 99.68(8) 4_665
O2 C1 O1 124.4(3) .
O2 C1 C2 118.3(3) .
O1 C1 C2 117.2(2) .
C7 C2 C3 117.9(3) .
C7 C2 C1 121.3(3) .
C3 C2 C1 120.8(2) .
C4 C3 C2 121.2(3) .
C4 C3 H3 119.4 .
C2 C3 H3 119.4 .
C3 C4 C5 120.8(3) .
C3 C4 H4 119.6 .
C5 C4 H4 119.6 .
C6 C5 C4 118.0(3) .
C6 C5 C8 122.1(2) .
C4 C5 C8 119.7(2) .
C7 C6 C5 121.1(3) .
C7 C6 H6 119.4 .
C5 C6 H6 119.4 .
C6 C7 C2 120.9(3) .
C6 C7 H7 119.5 .
C2 C7 H7 119.5 .
N1 C8 C5 112.2(2) .
N1 C8 H8A 109.2 .
C5 C8 H8A 109.2 .
N1 C8 H8B 109.2 .
C5 C8 H8B 109.2 .
H8A C8 H8B 107.9 .
C10 C9 N1 120.9(2) .
C10 C9 H9 119.5 .
N1 C9 H9 119.5 .
C9 C10 C11 118.6(3) .
C9 C10 H10 120.7 .
C11 C10 H10 120.7 .
C12 C11 C10 121.9(3) .
C12 C11 H11 119.0 .
C10 C11 H11 119.0 .
C11 C12 C13 118.9(2) .
C11 C12 C14 118.8(2) .
C13 C12 C14 122.1(2) .
O3 C13 N1 115.9(2) .
O3 C13 C12 126.8(2) .
N1 C13 C12 117.2(2) .
O5 C14 O4 122.9(2) .
O5 C14 C12 117.7(2) .
O4 C14 C12 119.4(2) .
N2 C15 C16 122.5(3) .
N2 C15 H15 118.8 .
C16 C15 H15 118.8 .
C17 C16 C15 119.7(3) .
C17 C16 H16 120.1 .
C15 C16 H16 120.1 .
C16 C17 C18 119.6(3) .
C16 C17 H17 120.2 .
C18 C17 H17 120.2 .
C26 C18 C17 116.9(3) .
C26 C18 C19 118.5(3) .
C17 C18 C19 124.5(3) .
C20 C19 C18 121.0(3) .
C20 C19 H19 119.5 .
C18 C19 H19 119.5 .
C19 C20 C21 121.5(3) .
C19 C20 H20 119.3 .
C21 C20 H20 119.3 .
C25 C21 C22 116.7(3) .
C25 C21 C20 118.6(3) .
C22 C21 C20 124.7(3) .
C23 C22 C21 119.7(3) .
C23 C22 H22 120.2 .
C21 C22 H22 120.2 .
C22 C23 C24 120.1(3) .
C22 C23 H23 119.9 .
C24 C23 H23 119.9 .
N3 C24 C23 121.7(3) .
N3 C24 H24 119.1 .
C23 C24 H24 119.1 .
N3 C25 C21 123.3(2) .
N3 C25 C26 116.6(2) .
C21 C25 C26 120.1(2) .
N2 C26 C18 123.3(2) .
N2 C26 C25 116.4(2) .
C18 C26 C25 120.3(2) .
C9 N1 C13 122.3(2) .
C9 N1 C8 119.8(2) .
C13 N1 C8 117.7(2) .
C15 N2 C26 117.9(2) .
C15 N2 Cu1 128.97(19) .
C26 N2 Cu1 113.13(17) .
C24 N3 C25 118.5(2) .
C24 N3 Cu1 129.23(19) .
C25 N3 Cu1 112.31(16) .
C1 O1 Cu1 123.36(18) 4_566
H1B O1W H1A 107.7 .
C13 O3 Cu1 124.04(16) .
C14 O4 Cu1 130.51(17) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cu1 O4 1.9262(18) .
Cu1 O3 1.9501(17) .
Cu1 N2 2.015(2) .
Cu1 N3 2.032(2) .
Cu1 O1 2.120(2) 4_665
C1 O2 1.225(3) .
C1 O1 1.261(3) .
C1 C2 1.508(4) .
C2 C7 1.382(4) .
C2 C3 1.390(4) .
C3 C4 1.372(4) .
C3 H3 0.9300 .
C4 C5 1.388(4) .
C4 H4 0.9300 .
C5 C6 1.382(4) .
C5 C8 1.508(4) .
C6 C7 1.380(4) .
C6 H6 0.9300 .
C7 H7 0.9300 .
C8 N1 1.477(3) .
C8 H8A 0.9700 .
C8 H8B 0.9700 .
C9 C10 1.349(4) .
C9 N1 1.364(3) .
C9 H9 0.9300 .
C10 C11 1.393(4) .
C10 H10 0.9300 .
C11 C12 1.369(4) .
C11 H11 0.9300 .
C12 C13 1.423(4) .
C12 C14 1.514(4) .
C13 O3 1.264(3) .
C13 N1 1.381(3) .
C14 O5 1.231(3) .
C14 O4 1.272(3) .
C15 N2 1.327(3) .
C15 C16 1.393(4) .
C15 H15 0.9300 .
C16 C17 1.359(4) .
C16 H16 0.9300 .
C17 C18 1.404(4) .
C17 H17 0.9300 .
C18 C26 1.398(4) .
C18 C19 1.433(4) .
C19 C20 1.351(5) .
C19 H19 0.9300 .
C20 C21 1.429(4) .
C20 H20 0.9300 .
C21 C25 1.396(4) .
C21 C22 1.403(4) .
C22 C23 1.362(4) .
C22 H22 0.9300 .
C23 C24 1.397(4) .
C23 H23 0.9300 .
C24 N3 1.322(3) .
C24 H24 0.9300 .
C25 N3 1.361(3) .
C25 C26 1.428(4) .
C26 N2 1.356(3) .
O1 Cu1 2.120(2) 4_566
O1W H1B 0.8898 .
O1W H1A 0.8888 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1W H1B O1 0.89 2.33 3.108(3) 146.3 2_656
O1W H1A O5 0.89 2.16 3.018(3) 163.0 .
C10 H10 O2 0.93 2.73 3.218(4) 114.0 1_655
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O2 C1 C2 C7 179.1(3) . .
O1 C1 C2 C7 -4.3(4) . .
O2 C1 C2 C3 -1.3(4) . .
O1 C1 C2 C3 175.3(2) . .
C7 C2 C3 C4 -1.1(4) . .
C1 C2 C3 C4 179.3(2) . .
C2 C3 C4 C5 1.2(4) . .
C3 C4 C5 C6 -0.5(4) . .
C3 C4 C5 C8 175.6(2) . .
C4 C5 C6 C7 -0.3(4) . .
C8 C5 C6 C7 -176.3(2) . .
C5 C6 C7 C2 0.3(4) . .
C3 C2 C7 C6 0.4(4) . .
C1 C2 C7 C6 -180.0(2) . .
C6 C5 C8 N1 -29.5(3) . .
C4 C5 C8 N1 154.6(2) . .
N1 C9 C10 C11 2.8(5) . .
C9 C10 C11 C12 -2.9(5) . .
C10 C11 C12 C13 -0.4(4) . .
C10 C11 C12 C14 175.3(3) . .
C11 C12 C13 O3 -178.5(3) . .
C14 C12 C13 O3 6.0(4) . .
C11 C12 C13 N1 3.6(4) . .
C14 C12 C13 N1 -171.9(2) . .
C11 C12 C14 O5 -13.9(4) . .
C13 C12 C14 O5 161.7(3) . .
C11 C12 C14 O4 167.8(3) . .
C13 C12 C14 O4 -16.6(4) . .
N2 C15 C16 C17 1.0(5) . .
C15 C16 C17 C18 1.3(5) . .
C16 C17 C18 C26 -2.0(5) . .
C16 C17 C18 C19 178.8(3) . .
C26 C18 C19 C20 1.6(5) . .
C17 C18 C19 C20 -179.2(3) . .
C18 C19 C20 C21 -1.1(5) . .
C19 C20 C21 C25 -0.8(5) . .
C19 C20 C21 C22 179.9(3) . .
C25 C21 C22 C23 0.1(5) . .
C20 C21 C22 C23 179.4(3) . .
C21 C22 C23 C24 -1.1(5) . .
C22 C23 C24 N3 1.5(5) . .
C22 C21 C25 N3 0.7(4) . .
C20 C21 C25 N3 -178.7(3) . .
C22 C21 C25 C26 -178.5(3) . .
C20 C21 C25 C26 2.1(4) . .
C17 C18 C26 N2 0.6(4) . .
C19 C18 C26 N2 179.8(3) . .
C17 C18 C26 C25 -179.5(3) . .
C19 C18 C26 C25 -0.2(4) . .
N3 C25 C26 N2 -0.9(4) . .
C21 C25 C26 N2 178.4(3) . .
N3 C25 C26 C18 179.2(3) . .
C21 C25 C26 C18 -1.6(4) . .
C10 C9 N1 C13 0.6(4) . .
C10 C9 N1 C8 -175.5(3) . .
O3 C13 N1 C9 178.1(2) . .
C12 C13 N1 C9 -3.8(4) . .
O3 C13 N1 C8 -5.8(3) . .
C12 C13 N1 C8 172.3(2) . .
C5 C8 N1 C9 105.8(3) . .
C5 C8 N1 C13 -70.5(3) . .
C16 C15 N2 C26 -2.4(4) . .
C16 C15 N2 Cu1 176.5(2) . .
C18 C26 N2 C15 1.6(4) . .
C25 C26 N2 C15 -178.4(3) . .
C18 C26 N2 Cu1 -177.4(2) . .
C25 C26 N2 Cu1 2.6(3) . .
O4 Cu1 N2 C15 -113.9(3) . .
O3 Cu1 N2 C15 -19.0(3) . .
N3 Cu1 N2 C15 178.6(3) . .
O1 Cu1 N2 C15 81.2(3) 4_665 .
O4 Cu1 N2 C26 65.0(3) . .
O3 Cu1 N2 C26 159.92(19) . .
N3 Cu1 N2 C26 -2.53(19) . .
O1 Cu1 N2 C26 -99.95(19) 4_665 .
C23 C24 N3 C25 -0.8(4) . .
C23 C24 N3 Cu1 179.4(2) . .
C21 C25 N3 C24 -0.3(4) . .
C26 C25 N3 C24 178.9(2) . .
C21 C25 N3 Cu1 179.5(2) . .
C26 C25 N3 Cu1 -1.3(3) . .
O4 Cu1 N3 C24 20.5(3) . .
O3 Cu1 N3 C24 117.5(3) . .
N2 Cu1 N3 C24 -178.1(3) . .
O1 Cu1 N3 C24 -70.8(3) 4_665 .
O4 Cu1 N3 C25 -159.32(19) . .
O3 Cu1 N3 C25 -62.3(3) . .
N2 Cu1 N3 C25 2.07(18) . .
O1 Cu1 N3 C25 109.43(18) 4_665 .
O2 C1 O1 Cu1 -20.0(4) . 4_566
C2 C1 O1 Cu1 163.67(16) . 4_566
N1 C13 O3 Cu1 -164.87(17) . .
C12 C13 O3 Cu1 17.2(4) . .
O4 Cu1 O3 C13 -23.0(2) . .
N2 Cu1 O3 C13 177.1(2) . .
N3 Cu1 O3 C13 -119.8(3) . .
O1 Cu1 O3 C13 68.5(2) 4_665 .
O5 C14 O4 Cu1 -175.5(2) . .
C12 C14 O4 Cu1 2.7(4) . .
O3 Cu1 O4 C14 13.4(3) . .
N2 Cu1 O4 C14 108.0(3) . .
N3 Cu1 O4 C14 174.0(3) . .
O1 Cu1 O4 C14 -86.3(3) 4_665 .
