#------------------------------------------------------------------------------
#$Date: 2016-03-26 22:23:39 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180503 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/72/7217254.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7217254
loop_
_publ_author_name
'Liu, Shuang-De'
'Kuo, Bing-Chiuan'
'Liu, Yen-Wen'
'Lee, Jing-Yi'
'Wong, Kwun Yip'
'Lee, Hon Man'
_publ_section_title
;
 Tuning of net architectures of Ni(ii) and Zn(ii) coordination polymers
 using isomeric organic linkers
;
_journal_issue                   37
_journal_name_full               CrystEngComm
_journal_page_first              8874
_journal_paper_doi               10.1039/C4CE01072H
_journal_volume                  16
_journal_year                    2014
_chemical_formula_moiety         'C22 H15 N3 O9 Zn2'
_chemical_formula_sum            'C22 H15 N3 O9 Zn2'
_chemical_formula_weight         596.11
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 118.658(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   7.5106(2)
_cell_length_b                   31.1959(7)
_cell_length_c                   10.5537(3)
_cell_measurement_reflns_used    2934
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.4
_cell_measurement_theta_min      2.6
_cell_volume                     2169.82(11)
_computing_cell_refinement       'SAINT (Bruker, 2007)'
_computing_data_collection       'APEX2 (Bruker, 2007)'
_computing_data_reduction        'SAINT (Bruker, 2007)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'DIAMOND (Brandenburg, 2006)'
_computing_structure_refinement  'SHELXTL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXTL (Sheldrick, 2008)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker SMART APEXII'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0778
_diffrn_reflns_av_unetI/netI     0.0886
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       39
_diffrn_reflns_limit_k_min       -35
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            15465
_diffrn_reflns_theta_full        26.50
_diffrn_reflns_theta_max         26.50
_diffrn_reflns_theta_min         2.61
_diffrn_source                   'fine-focus sealed tube'
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.274
_exptl_absorpt_correction_T_max  0.7152
_exptl_absorpt_correction_T_min  0.6287
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2003)'
_exptl_crystal_colour            orange-yellow
_exptl_crystal_density_diffrn    1.825
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1200
_exptl_crystal_preparation       Luminescent
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.16
_refine_diff_density_max         2.930
_refine_diff_density_min         -1.681
_refine_diff_density_rms         0.157
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.198
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     325
_refine_ls_number_reflns         4476
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.213
_refine_ls_R_factor_all          0.0867
_refine_ls_R_factor_gt           0.0774
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1135P)²+1.7955P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2130
_refine_ls_wR_factor_ref         0.2229
_reflns_number_gt                3651
_reflns_number_total             4476
_reflns_threshold_expression     I>2σ
_cod_data_source_file            c4ce01072h2.cif
_cod_data_source_block           sdl24201
_cod_depositor_comments
'Adding full bibliography for 7217251--7217256.cif.'
_cod_original_cell_volume        2169.82(10)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7217254
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.9536(9) 1.08703(17) 0.5248(6) 0.0352(12) Uani 1 1 d .
C2 C 0.8484(9) 1.04976(16) 0.4997(6) 0.0344(11) Uani 1 1 d .
H2 H 0.7312 1.0430 0.4112 0.041 Uiso 1 1 calc R
C3 C 1.0932(8) 1.04461(17) 0.7193(6) 0.0336(11) Uani 1 1 d .
C4 C 1.2342(9) 1.0331(2) 0.8622(6) 0.0383(12) Uani 1 1 d .
H4 H 1.2270 1.0059 0.8998 0.046 Uiso 1 1 calc R
C5 C 1.3797(9) 1.06157(19) 0.9444(7) 0.0414(13) Uani 1 1 d .
H5 H 1.4768 1.0541 1.0403 0.050 Uiso 1 1 calc R
C6 C 1.3890(9) 1.10178(19) 0.8901(7) 0.0411(13) Uani 1 1 d .
H6 H 1.4908 1.1215 0.9506 0.049 Uiso 1 1 calc R
C7 C 1.2565(9) 1.11323(18) 0.7536(7) 0.0391(12) Uani 1 1 d .
H7 H 1.2633 1.1408 0.7180 0.047 Uiso 1 1 calc R
C8 C 0.3274(8) 0.92205(16) 0.2695(5) 0.0307(10) Uani 1 1 d .
C9 C 0.1958(8) 0.93404(16) 0.1275(5) 0.0306(10) Uani 1 1 d .
H9 H 0.2052 0.9620 0.0955 0.037 Uiso 1 1 calc R
C10 C 0.0506(8) 0.90556(16) 0.0320(5) 0.0305(10) Uani 1 1 d .
C11 C 0.0367(8) 0.86496(16) 0.0806(6) 0.0332(11) Uani 1 1 d .
H11 H -0.0641 0.8456 0.0170 0.040 Uiso 1 1 calc R
C12 C 0.1696(8) 0.85237(16) 0.2223(6) 0.0328(11) Uani 1 1 d .
C13 C 0.3174(8) 0.88064(16) 0.3157(6) 0.0317(11) Uani 1 1 d .
H13 H 0.4113 0.8718 0.4108 0.038 Uiso 1 1 calc R
C14 C 0.4788(8) 0.95327(16) 0.3710(6) 0.0327(11) Uani 1 1 d .
C15 C 0.1538(9) 0.80854(17) 0.2749(6) 0.0369(12) Uani 1 1 d .
C16 C 1.0341(10) 1.17914(19) 0.3298(7) 0.0440(14) Uani 1 1 d .
H16 H 1.1434 1.1951 0.3323 0.053 Uiso 1 1 calc R
C17 C 1.0772(10) 1.14618(19) 0.4251(7) 0.0433(13) Uani 1 1 d .
H17 H 1.2142 1.1389 0.4897 0.052 Uiso 1 1 calc R
C18 C 0.9191(9) 1.12316(16) 0.4272(6) 0.0355(12) Uani 1 1 d .
C19 C 0.7194(9) 1.13426(18) 0.3261(6) 0.0398(12) Uani 1 1 d .
H19 H 0.6073 1.1192 0.3228 0.048 Uiso 1 1 calc R
C20 C 0.6898(9) 1.16755(19) 0.2317(7) 0.0424(13) Uani 1 1 d .
H20 H 0.5545 1.1749 0.1632 0.051 Uiso 1 1 calc R
C21 C -0.0939(9) 0.91875(17) -0.1203(6) 0.0352(12) Uani 1 1 d .
C22 C 0.5427(11) 0.7276(2) 0.6884(8) 0.0490(15) Uani 1 1 d .
H22 H 0.5561 0.7576 0.6808 0.059 Uiso 1 1 calc R
N1 N 0.9305(7) 1.02327(13) 0.6159(5) 0.0341(10) Uani 1 1 d .
N2 N 1.1103(7) 1.08398(14) 0.6662(5) 0.0355(10) Uani 1 1 d .
N3 N 0.8418(8) 1.19006(14) 0.2316(5) 0.0411(11) Uani 1 1 d .
O1 O 0.6293(6) 0.93786(11) 0.4819(4) 0.0352(8) Uani 1 1 d .
O2 O 0.4491(5) 0.99294(11) 0.3447(4) 0.0333(8) Uani 1 1 d .
O3 O -0.0356(6) 0.95180(12) -0.1636(4) 0.0386(9) Uani 1 1 d .
O4 O -0.2511(6) 0.89870(14) -0.1934(5) 0.0479(10) Uani 1 1 d .
O5 O 0.2830(7) 0.79757(13) 0.4024(5) 0.0457(10) Uani 1 1 d .
O6 O 0.0139(7) 0.78353(12) 0.1943(4) 0.0429(10) Uani 1 1 d .
O7 O -0.0306(5) 0.73435(12) 0.4386(4) 0.0521(11) Uani 1 1 d D
H7B H -0.0323 0.7289 0.5141 0.063 Uiso 1 1 d D
H7A H -0.1223 0.7506 0.4046 0.063 Uiso 1 1 d D
O8 O 0.4009(7) 0.70919(14) 0.5810(5) 0.0525(11) Uani 1 1 d .
O9 O 0.6649(7) 0.71054(14) 0.8014(5) 0.0496(11) Uani 1 1 d .
Zn1 Zn 0.78098(9) 0.974945(18) 0.65010(6) 0.0321(2) Uani 1 1 d .
Zn2 Zn 0.19596(12) 0.73785(2) 0.40921(8) 0.0424(3) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 C1 N2 105.3(5) . .
C2 C1 C18 129.2(5) . .
N2 C1 C18 125.5(5) . .
N1 C2 C1 112.1(5) . .
N1 C2 H2 124.0 . .
C1 C2 H2 124.0 . .
N1 C3 N2 109.4(5) . .
N1 C3 C4 131.2(5) . .
N2 C3 C4 119.4(5) . .
C5 C4 C3 118.8(6) . .
C5 C4 H4 120.6 . .
C3 C4 H4 120.6 . .
C4 C5 C6 120.7(6) . .
C4 C5 H5 119.6 . .
C6 C5 H5 119.6 . .
C7 C6 C5 121.3(6) . .
C7 C6 H6 119.3 . .
C5 C6 H6 119.3 . .
C6 C7 N2 118.7(5) . .
C6 C7 H7 120.6 . .
N2 C7 H7 120.6 . .
C9 C8 C13 119.7(5) . .
C9 C8 C14 120.1(5) . .
C13 C8 C14 120.3(5) . .
C10 C9 C8 120.8(5) . .
C10 C9 H9 119.6 . .
C8 C9 H9 119.6 . .
C11 C10 C9 119.1(5) . .
C11 C10 C21 120.1(5) . .
C9 C10 C21 120.8(5) . .
C10 C11 C12 120.6(5) . .
C10 C11 H11 119.7 . .
C12 C11 H11 119.7 . .
C13 C12 C11 119.9(5) . .
C13 C12 C15 119.5(5) . .
C11 C12 C15 120.6(5) . .
C12 C13 C8 119.8(5) . .
C12 C13 H13 120.1 . .
C8 C13 H13 120.1 . .
O2 C14 O1 124.0(5) . .
O2 C14 C8 119.2(5) . .
O1 C14 C8 116.8(5) . .
O6 C15 O5 121.0(5) . .
O6 C15 C12 120.2(5) . .
O5 C15 C12 118.7(5) . .
O6 C15 Zn2 71.4(3) . .
O5 C15 Zn2 49.7(3) . .
C12 C15 Zn2 168.3(4) . .
N3 C16 C17 122.8(6) . .
N3 C16 H16 118.6 . .
C17 C16 H16 118.6 . .
C16 C17 C18 119.8(6) . .
C16 C17 H17 120.1 . .
C18 C17 H17 120.1 . .
C17 C18 C19 117.9(5) . .
C17 C18 C1 122.8(5) . .
C19 C18 C1 119.2(5) . .
C20 C19 C18 118.5(5) . .
C20 C19 H19 120.8 . .
C18 C19 H19 120.8 . .
N3 C20 C19 123.5(6) . .
N3 C20 H20 118.3 . .
C19 C20 H20 118.3 . .
O4 C21 O3 125.0(5) . .
O4 C21 C10 121.1(5) . .
O3 C21 C10 113.9(5) . .
O9 C22 O8 126.4(6) . .
O9 C22 H22 116.8 . .
O8 C22 H22 116.8 . .
C2 N1 C3 105.7(4) . .
C2 N1 Zn1 124.6(4) . .
C3 N1 Zn1 125.9(4) . .
C3 N2 C7 120.9(5) . .
C3 N2 C1 107.5(5) . .
C7 N2 C1 131.4(5) . .
C20 N3 C16 117.6(5) . .
C20 N3 Zn2 124.5(4) . 2_655
C16 N3 Zn2 117.9(4) . 2_655
C14 O1 Zn1 119.0(3) . .
C14 O2 Zn1 122.8(3) . 3_676
C21 O3 Zn1 117.7(4) . 1_454
C15 O5 Zn2 101.1(4) . .
C15 O6 Zn2 79.7(3) . .
Zn2 O7 H7B 127.7 . .
Zn2 O7 H7A 123.4 . .
H7B O7 H7A 99.1 . .
C22 O8 Zn2 125.4(4) . .
O3 Zn1 O1 121.67(16) 1_656 .
O3 Zn1 N1 106.09(19) 1_656 .
O1 Zn1 N1 114.28(17) . .
O3 Zn1 O2 111.20(16) 1_656 3_676
O1 Zn1 O2 100.58(15) . 3_676
N1 Zn1 O2 101.05(17) . 3_676
O7 Zn2 O8 101.20(17) . .
O7 Zn2 O5 113.68(18) . .
O8 Zn2 O5 109.75(18) . .
O7 Zn2 N3 105.1(2) . 2_645
O8 Zn2 N3 96.6(2) . 2_645
O5 Zn2 N3 126.57(19) . 2_645
O7 Zn2 O6 92.23(13) . .
O8 Zn2 O6 165.09(18) . .
O5 Zn2 O6 58.08(16) . .
N3 Zn2 O6 85.98(17) 2_645 .
O7 Zn2 C15 105.14(15) . .
O8 Zn2 C15 138.22(19) . .
O5 Zn2 C15 29.19(18) . .
N3 Zn2 C15 106.94(18) 2_645 .
O6 Zn2 C15 28.91(16) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C2 1.358(8) .
C1 N2 1.391(7) .
C1 C18 1.464(7) .
C2 N1 1.357(7) .
C2 H2 0.9500 .
C3 N1 1.360(7) .
C3 N2 1.381(7) .
C3 C4 1.411(8) .
C4 C5 1.350(8) .
C4 H4 0.9500 .
C5 C6 1.395(9) .
C5 H5 0.9500 .
C6 C7 1.349(8) .
C6 H6 0.9500 .
C7 N2 1.385(7) .
C7 H7 0.9500 .
C8 C9 1.393(7) .
C8 C13 1.396(7) .
C8 C14 1.491(7) .
C9 C10 1.393(7) .
C9 H9 0.9500 .
C10 C11 1.389(7) .
C10 C21 1.503(7) .
C11 C12 1.398(7) .
C11 H11 0.9500 .
C12 C13 1.390(8) .
C12 C15 1.502(7) .
C13 H13 0.9500 .
C14 O2 1.264(6) .
C14 O1 1.268(7) .
C15 O6 1.257(7) .
C15 O5 1.271(7) .
C15 Zn2 2.557(5) .
C16 N3 1.356(8) .
C16 C17 1.364(8) .
C16 H16 0.9500 .
C17 C18 1.397(8) .
C17 H17 0.9500 .
C18 C19 1.405(8) .
C19 C20 1.382(8) .
C19 H19 0.9500 .
C20 N3 1.341(8) .
C20 H20 0.9500 .
C21 O4 1.228(7) .
C21 O3 1.286(7) .
C22 O9 1.224(8) .
C22 O8 1.261(8) .
C22 H22 0.9500 .
N1 Zn1 2.013(4) .
N3 Zn2 2.027(5) 2_655
O1 Zn1 1.961(4) .
O2 Zn1 2.021(4) 3_676
O3 Zn1 1.920(4) 1_454
O5 Zn2 1.987(4) .
O6 Zn2 2.463(4) .
O7 Zn2 1.874(4) .
O7 H7B 0.8200 .
O7 H7A 0.7889 .
O8 Zn2 1.944(5) .
Zn1 O3 1.920(4) 1_656
Zn1 O2 2.021(4) 3_676
Zn2 N3 2.027(5) 2_645
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
N2 C1 C2 N1 -0.7(6) .
C18 C1 C2 N1 177.9(5) .
N1 C3 C4 C5 -177.7(5) .
N2 C3 C4 C5 1.6(8) .
C3 C4 C5 C6 0.9(8) .
C4 C5 C6 C7 -1.4(9) .
C5 C6 C7 N2 -0.7(8) .
C13 C8 C9 C10 1.6(7) .
C14 C8 C9 C10 -178.7(5) .
C8 C9 C10 C11 0.8(7) .
C8 C9 C10 C21 178.9(5) .
C9 C10 C11 C12 -1.6(7) .
C21 C10 C11 C12 -179.7(5) .
C10 C11 C12 C13 0.0(8) .
C10 C11 C12 C15 179.7(5) .
C11 C12 C13 C8 2.5(8) .
C15 C12 C13 C8 -177.3(5) .
C9 C8 C13 C12 -3.3(7) .
C14 C8 C13 C12 177.0(5) .
C9 C8 C14 O2 21.4(7) .
C13 C8 C14 O2 -158.9(5) .
C9 C8 C14 O1 -160.2(5) .
C13 C8 C14 O1 19.5(7) .
C13 C12 C15 O6 176.0(5) .
C11 C12 C15 O6 -3.8(8) .
C13 C12 C15 O5 -3.4(8) .
C11 C12 C15 O5 176.9(5) .
C13 C12 C15 Zn2 -11(2) .
C11 C12 C15 Zn2 169.6(16) .
N3 C16 C17 C18 -2.3(9) .
C16 C17 C18 C19 2.1(8) .
C16 C17 C18 C1 179.1(5) .
C2 C1 C18 C17 -142.0(6) .
N2 C1 C18 C17 36.4(8) .
C2 C1 C18 C19 35.0(8) .
N2 C1 C18 C19 -146.7(5) .
C17 C18 C19 C20 -0.8(8) .
C1 C18 C19 C20 -177.9(5) .
C18 C19 C20 N3 -0.3(9) .
C11 C10 C21 O4 16.3(8) .
C9 C10 C21 O4 -161.7(5) .
C11 C10 C21 O3 -163.2(5) .
C9 C10 C21 O3 18.7(7) .
C1 C2 N1 C3 0.5(6) .
C1 C2 N1 Zn1 159.5(4) .
N2 C3 N1 C2 -0.1(6) .
C4 C3 N1 C2 179.3(6) .
N2 C3 N1 Zn1 -158.7(4) .
C4 C3 N1 Zn1 20.6(8) .
N1 C3 N2 C7 175.8(5) .
C4 C3 N2 C7 -3.6(8) .
N1 C3 N2 C1 -0.4(6) .
C4 C3 N2 C1 -179.8(5) .
C6 C7 N2 C3 3.2(8) .
C6 C7 N2 C1 178.3(5) .
C2 C1 N2 C3 0.6(6) .
C18 C1 N2 C3 -178.1(5) .
C2 C1 N2 C7 -175.0(5) .
C18 C1 N2 C7 6.3(9) .
C19 C20 N3 C16 0.2(9) .
C19 C20 N3 Zn2 178.1(4) 2_655
C17 C16 N3 C20 1.2(9) .
C17 C16 N3 Zn2 -176.9(5) 2_655
O2 C14 O1 Zn1 19.2(7) .
C8 C14 O1 Zn1 -159.1(3) .
O1 C14 O2 Zn1 -111.5(5) 3_676
C8 C14 O2 Zn1 66.8(5) 3_676
O4 C21 O3 Zn1 6.1(8) 1_454
C10 C21 O3 Zn1 -174.4(3) 1_454
O6 C15 O5 Zn2 2.6(6) .
C12 C15 O5 Zn2 -178.1(4) .
O5 C15 O6 Zn2 -2.1(5) .
C12 C15 O6 Zn2 178.6(5) .
O9 C22 O8 Zn2 174.8(5) .
C14 O1 Zn1 O3 164.3(4) 1_656
C14 O1 Zn1 N1 -66.2(4) .
C14 O1 Zn1 O2 41.2(4) 3_676
C2 N1 Zn1 O3 -175.6(4) 1_656
C3 N1 Zn1 O3 -20.7(5) 1_656
C2 N1 Zn1 O1 47.6(5) .
C3 N1 Zn1 O1 -157.6(4) .
C2 N1 Zn1 O2 -59.5(4) 3_676
C3 N1 Zn1 O2 95.3(4) 3_676
C22 O8 Zn2 O7 -105.1(6) .
C22 O8 Zn2 O5 15.3(6) .
C22 O8 Zn2 N3 148.1(6) 2_645
C22 O8 Zn2 O6 48.7(10) .
C22 O8 Zn2 C15 23.3(7) .
C15 O5 Zn2 O7 -78.4(4) .
C15 O5 Zn2 O8 169.1(4) .
C15 O5 Zn2 N3 54.3(4) 2_645
C15 O5 Zn2 O6 -1.3(3) .
C15 O6 Zn2 O7 118.0(3) .
C15 O6 Zn2 O8 -36.3(8) .
C15 O6 Zn2 O5 1.3(3) .
C15 O6 Zn2 N3 -137.0(3) 2_645
O6 C15 Zn2 O7 -66.0(3) .
O5 C15 Zn2 O7 111.6(4) .
C12 C15 Zn2 O7 120.0(19) .
O6 C15 Zn2 O8 166.8(3) .
O5 C15 Zn2 O8 -15.6(5) .
C12 C15 Zn2 O8 -7(2) .
O6 C15 Zn2 O5 -177.7(6) .
C12 C15 Zn2 O5 8.4(17) .
O6 C15 Zn2 N3 45.3(4) 2_645
O5 C15 Zn2 N3 -137.0(4) 2_645
C12 C15 Zn2 N3 -128.6(18) 2_645
O5 C15 Zn2 O6 177.7(6) .
C12 C15 Zn2 O6 -174(2) .
