#------------------------------------------------------------------------------
#$Date: 2016-03-26 23:00:42 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180526 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/95/7219528.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7219528
loop_
_publ_author_name
'Gholivand, K.'
'Gholami, A.'
'Ebrahimi, A. A. V.'
'Abolghasemi, S. T.'
'Esrafili, M. D.'
'Fadaei, F. T.'
'Schenk, K. J.'
_publ_section_title
;
 Triphenyltin(iv) adducts of diphosphoryl ligands: structural, electronic
 and energy aspects from X-ray crystallography and theoretical
 calculations
;
_journal_issue                   23
_journal_name_full               'RSC Adv.'
_journal_page_first              17482
_journal_paper_doi               10.1039/C4RA12925C
_journal_volume                  5
_journal_year                    2015
_chemical_formula_analytical     'C33 H27 Cl O4 P Sn'
_chemical_formula_moiety         'C66 H54 Cl2 O8 P2 Sn2'
_chemical_formula_sum            'C66 H54 Cl2 O8 P2 Sn2'
_chemical_formula_weight         1345.42
_chemical_name_systematic
; 
 Mu-(1,4-phenylene tetraphenyl diphosphate) Bis(chlorotriphenyl tin(IV)) 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_update_record
;
2014-04-22 deposited with the CCDC.
2015-01-28 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 105.673(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   16.9373(7)
_cell_length_b                   9.79356(24)
_cell_length_c                   18.1950(7)
_cell_measurement_reflns_used    43799
_cell_measurement_temperature    90
_cell_measurement_theta_max      29.57
_cell_measurement_theta_min      2.08
_cell_volume                     2905.91(18)
_computing_cell_refinement       'X_Area, 1.36 (Stoe, 2006)'
_computing_data_collection       'X_Area, 1.36 (Stoe, 2006)'
_computing_data_reduction        'X_Area, 1.36 (Stoe, 2006)'
_computing_molecular_graphics    'Bruker SHELXTL, (Bruker, 1996)'
_computing_publication_material  'Bruker SHELXTL, PLATON (Spek, 2001)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR2004 (Burla, 2005)'
_diffrn_ambient_temperature      90
_diffrn_detector                 'image plate (34 cm diameter)'
_diffrn_detector_area_resol_mean 6.67
_diffrn_detector_type            STOE
_diffrn_measured_fraction_theta_full 0.977
_diffrn_measured_fraction_theta_max 0.977
_diffrn_measurement_details      ' 180 frames, detector distance = 100 mm'
_diffrn_measurement_device       '2-circle goniometer'
_diffrn_measurement_device_type  'STOE IPDS 2'
_diffrn_measurement_method       'rotation method'
_diffrn_radiation_collimation    '0.8 mm diameter'
_diffrn_radiation_monochromator  'plane graphite'
_diffrn_radiation_polarisn_norm  0
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0345
_diffrn_reflns_av_sigmaI/netI    0.0222
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            26834
_diffrn_reflns_theta_full        29.38
_diffrn_reflns_theta_max         29.38
_diffrn_reflns_theta_min         2.32
_diffrn_source
'sealed X-ray tube, 12 x 0.4 mm long-fine focus'
_diffrn_source_current           43
_diffrn_source_power             2.365
_diffrn_source_voltage           55
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.063
_exptl_absorpt_correction_T_max  0.8224
_exptl_absorpt_correction_T_min  0.5954
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   'Stoe XRed32 1.31, Stoe (2005)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.538
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       platelet
_exptl_crystal_F_000             1356
_exptl_crystal_size_max          0.565
_exptl_crystal_size_mid          0.446
_exptl_crystal_size_min          0.177
_refine_diff_density_max         0.537
_refine_diff_density_min         -0.555
_refine_diff_density_rms         0.075
_refine_ls_extinction_coef       0.00088(11)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.083
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     362
_refine_ls_number_reflns         7823
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.083
_refine_ls_R_factor_all          0.0248
_refine_ls_R_factor_gt           0.0199
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0245P)²+1.8916P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0482
_refine_ls_wR_factor_ref         0.0533
_reflns_number_gt                7056
_reflns_number_total             7823
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            c4ra12925c2.cif
_cod_data_source_block           518
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7219528
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x, -y+1/2, z+1/2'
'-x, -y, -z'
'-x, y-1/2, -z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Sn1 Sn 0.818491(6) 0.237075(9) 0.573321(5) 0.01190(4) Uani 1 1 d .
Cl1 Cl 0.92190(2) 0.14211(4) 0.68041(2) 0.02193(8) Uani 1 1 d .
P1 P 0.65071(2) 0.39057(4) 0.38604(2) 0.01138(7) Uani 1 1 d .
O1 O 0.70424(6) 0.33281(11) 0.45543(6) 0.01419(19) Uani 1 1 d .
O2 O 0.66791(7) 0.54285(11) 0.36755(6) 0.0161(2) Uani 1 1 d .
O3 O 0.64878(7) 0.31423(11) 0.30941(6) 0.0148(2) Uani 1 1 d .
O4 O 0.55634(6) 0.39423(11) 0.38230(6) 0.0157(2) Uani 1 1 d .
C1 C 0.64655(9) 0.16913(15) 0.30638(8) 0.0143(3) Uani 1 1 d .
C2 C 0.57193(10) 0.10356(16) 0.29409(9) 0.0179(3) Uani 1 1 d .
H2 H 0.5238 0.1526 0.2895 0.021 Uiso 1 1 calc R
C3 C 0.57093(11) -0.03882(17) 0.28877(10) 0.0222(3) Uani 1 1 d .
H3 H 0.5215 -0.0857 0.2803 0.027 Uiso 1 1 calc R
C4 C 0.64320(11) -0.11058(17) 0.29601(10) 0.0227(3) Uani 1 1 d .
H4 H 0.6421 -0.2054 0.2927 0.027 Uiso 1 1 calc R
C5 C 0.71712(11) -0.04185(17) 0.30819(10) 0.0222(3) Uani 1 1 d .
H5 H 0.7653 -0.0907 0.3129 0.027 Uiso 1 1 calc R
C6 C 0.71948(9) 0.10044(16) 0.31336(9) 0.0174(3) Uani 1 1 d .
H6 H 0.7687 0.1476 0.3213 0.021 Uiso 1 1 calc R
C7 C 0.75066(9) 0.58842(14) 0.37976(9) 0.0151(3) Uani 1 1 d .
C8 C 0.78924(10) 0.64904(15) 0.44847(9) 0.0188(3) Uani 1 1 d .
H8 H 0.7622 0.6606 0.4863 0.023 Uiso 1 1 calc R
C9 C 0.87004(11) 0.69256(16) 0.45951(10) 0.0236(3) Uani 1 1 d .
H9 H 0.8979 0.7326 0.5056 0.028 Uiso 1 1 calc R
C10 C 0.90925(11) 0.67628(16) 0.40181(11) 0.0245(3) Uani 1 1 d .
H10 H 0.9632 0.7049 0.4096 0.029 Uiso 1 1 calc R
C11 C 0.86811(10) 0.61785(17) 0.33321(10) 0.0223(3) Uani 1 1 d .
H11 H 0.8942 0.6086 0.2946 0.027 Uiso 1 1 calc R
C12 C 0.78779(10) 0.57265(16) 0.32140(9) 0.0178(3) Uani 1 1 d .
H12 H 0.7598 0.5328 0.2753 0.021 Uiso 1 1 calc R
C13 C 0.52946(8) 0.44825(15) 0.44318(8) 0.0134(3) Uani 1 1 d .
C14 C 0.49839(9) 0.57990(15) 0.43591(9) 0.0152(3) Uani 1 1 d .
H14 H 0.4976 0.6319 0.3930 0.018 Uiso 1 1 calc R
C15 C 0.46823(9) 0.63300(15) 0.49413(9) 0.0151(3) Uani 1 1 d .
H15 H 0.4470 0.7211 0.4909 0.023 Uiso 1 1 calc R
C16 C 0.87638(9) 0.20054(14) 0.48530(8) 0.0121(3) Uani 1 1 d .
C17 C 0.89382(9) 0.30778(15) 0.44121(8) 0.0149(3) Uani 1 1 d .
H17 H 0.8828 0.3973 0.4523 0.018 Uiso 1 1 calc R
C18 C 0.92753(10) 0.28087(16) 0.38092(9) 0.0183(3) Uani 1 1 d .
H18 H 0.9388 0.3525 0.3517 0.022 Uiso 1 1 calc R
C19 C 0.94445(10) 0.14703(16) 0.36411(9) 0.0181(3) Uani 1 1 d .
H19 H 0.9664 0.1292 0.3235 0.022 Uiso 1 1 calc R
C20 C 0.92844(10) 0.04068(16) 0.40812(9) 0.0184(3) Uani 1 1 d .
H20 H 0.9402 -0.0487 0.3973 0.022 Uiso 1 1 calc R
C21 C 0.89466(9) 0.06731(15) 0.46869(9) 0.0164(3) Uani 1 1 d .
H21 H 0.8843 -0.0045 0.4982 0.020 Uiso 1 1 calc R
C22 C 0.71855(9) 0.10704(14) 0.57536(8) 0.0134(3) Uani 1 1 d .
C23 C 0.68279(10) 0.02028(16) 0.51447(9) 0.0192(3) Uani 1 1 d .
H23 H 0.7031 0.0184 0.4718 0.023 Uiso 1 1 calc R
C24 C 0.61725(11) -0.06326(18) 0.51704(10) 0.0242(3) Uani 1 1 d .
H24 H 0.5939 -0.1206 0.4762 0.029 Uiso 1 1 calc R
C25 C 0.58659(10) -0.06131(18) 0.58043(10) 0.0228(3) Uani 1 1 d .
H25 H 0.5428 -0.1174 0.5822 0.027 Uiso 1 1 calc R
C26 C 0.62129(10) 0.02438(18) 0.64107(9) 0.0218(3) Uani 1 1 d .
H26 H 0.6007 0.0260 0.6836 0.026 Uiso 1 1 calc R
C27 C 0.68712(10) 0.10826(16) 0.63851(9) 0.0174(3) Uani 1 1 d .
H27 H 0.7102 0.1655 0.6794 0.021 Uiso 1 1 calc R
C28 C 0.80946(9) 0.43795(15) 0.61440(8) 0.0141(3) Uani 1 1 d .
C29 C 0.73179(10) 0.49330(16) 0.60781(9) 0.0178(3) Uani 1 1 d .
H29 H 0.6855 0.4390 0.5900 0.021 Uiso 1 1 calc R
C30 C 0.72286(11) 0.62872(17) 0.62756(9) 0.0216(3) Uani 1 1 d .
H30 H 0.6709 0.6646 0.6226 0.026 Uiso 1 1 calc R
C31 C 0.79179(12) 0.71000(18) 0.65459(10) 0.0252(4) Uani 1 1 d .
H31 H 0.7859 0.8014 0.6659 0.030 Uiso 1 1 calc R
C32 C 0.86941(11) 0.65463(18) 0.66473(11) 0.0267(4) Uani 1 1 d .
H32 H 0.9156 0.7078 0.6850 0.032 Uiso 1 1 calc R
C33 C 0.87816(10) 0.51880(17) 0.64443(10) 0.0217(3) Uani 1 1 d .
H33 H 0.9303 0.4823 0.6511 0.026 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0030 0.0020 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1480 0.1590 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0110 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1020 0.0940 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6540 1.4250 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
1 0 0 0.0730
-1 0 0 0.1040
0 0 1 0.2310
0 0 -1 0.2150
-1 2 0 0.2740
-1 -2 0 0.2910
1 5 0 0.3010
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
C16 Sn1 C28 120.89(5) .
C16 Sn1 C22 116.39(6) .
C28 Sn1 C22 114.53(5) .
C16 Sn1 Cl1 99.27(4) .
C28 Sn1 Cl1 100.22(4) .
C22 Sn1 Cl1 99.31(4) .
O1 P1 O2 116.49(6) .
O1 P1 O3 116.28(6) .
O2 P1 O3 102.80(6) .
O1 P1 O4 115.57(6) .
O2 P1 O4 102.28(6) .
O3 P1 O4 101.17(6) .
C7 O2 P1 119.54(9) .
C1 O3 P1 120.18(9) .
C13 O4 P1 120.79(9) .
C2 C1 C6 123.01(14) .
C2 C1 O3 118.98(13) .
C6 C1 O3 117.97(13) .
C1 C2 C3 117.95(15) .
C1 C2 H2 121.0 .
C3 C2 H2 121.0 .
C4 C3 C2 120.35(16) .
C4 C3 H3 119.8 .
C2 C3 H3 119.8 .
C5 C4 C3 120.35(15) .
C5 C4 H4 119.8 .
C3 C4 H4 119.8 .
C4 C5 C6 120.25(15) .
C4 C5 H5 119.9 .
C6 C5 H5 119.9 .
C1 C6 C5 118.09(15) .
C1 C6 H6 121.0 .
C5 C6 H6 121.0 .
C8 C7 C12 122.86(15) .
C8 C7 O2 118.67(13) .
C12 C7 O2 118.46(14) .
C7 C8 C9 117.92(15) .
C7 C8 H8 121.0 .
C9 C8 H8 121.0 .
C10 C9 C8 120.31(16) .
C10 C9 H9 119.8 .
C8 C9 H9 119.8 .
C11 C10 C9 120.13(16) .
C11 C10 H10 119.9 .
C9 C10 H10 119.9 .
C10 C11 C12 120.39(16) .
C10 C11 H11 119.8 .
C12 C11 H11 119.8 .
C7 C12 C11 118.36(15) .
C7 C12 H12 120.8 .
C11 C12 H12 120.8 .
C15 C13 C14 122.68(13) 3_666
C15 C13 O4 119.28(13) 3_666
C14 C13 O4 117.98(13) .
C13 C14 C15 118.81(13) .
C13 C14 H14 120.6 .
C15 C14 H14 120.6 .
C13 C15 C14 118.51(13) 3_666
C13 C15 H15 120.7 3_666
C14 C15 H15 120.7 .
C21 C16 C17 118.98(13) .
C21 C16 Sn1 119.79(10) .
C17 C16 Sn1 121.18(10) .
C18 C17 C16 120.28(13) .
C18 C17 H17 119.9 .
C16 C17 H17 119.9 .
C17 C18 C19 120.24(14) .
C17 C18 H18 119.9 .
C19 C18 H18 119.9 .
C20 C19 C18 119.79(14) .
C20 C19 H19 120.1 .
C18 C19 H19 120.1 .
C19 C20 C21 120.12(14) .
C19 C20 H20 119.9 .
C21 C20 H20 119.9 .
C16 C21 C20 120.57(13) .
C16 C21 H21 119.7 .
C20 C21 H21 119.7 .
C27 C22 C23 118.65(13) .
C27 C22 Sn1 119.57(11) .
C23 C22 Sn1 121.78(10) .
C24 C23 C22 120.67(14) .
C24 C23 H23 119.7 .
C22 C23 H23 119.7 .
C25 C24 C23 120.12(15) .
C25 C24 H24 119.9 .
C23 C24 H24 119.9 .
C26 C25 C24 119.83(15) .
C26 C25 H25 120.1 .
C24 C25 H25 120.1 .
C25 C26 C27 120.07(14) .
C25 C26 H26 120.0 .
C27 C26 H26 120.0 .
C22 C27 C26 120.66(15) .
C22 C27 H27 119.7 .
C26 C27 H27 119.7 .
C33 C28 C29 118.74(14) .
C33 C28 Sn1 122.22(11) .
C29 C28 Sn1 118.97(11) .
C30 C29 C28 120.82(15) .
C30 C29 H29 119.6 .
C28 C29 H29 119.6 .
C31 C30 C29 119.84(15) .
C31 C30 H30 120.1 .
C29 C30 H30 120.1 .
C32 C31 C30 119.93(15) .
C32 C31 H31 120.0 .
C30 C31 H31 120.0 .
C31 C32 C33 120.04(16) .
C31 C32 H32 120.0 .
C33 C32 H32 120.0 .
C28 C33 C32 120.52(16) .
C28 C33 H33 119.7 .
C32 C33 H33 119.7 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sn1 C16 2.1220(13) .
Sn1 C28 2.1246(14) .
Sn1 C22 2.1266(14) .
Sn1 Cl1 2.4260(4) .
P1 O1 1.4552(11) .
P1 O2 1.5733(11) .
P1 O3 1.5746(11) .
P1 O4 1.5818(11) .
O2 C7 1.4299(18) .
O3 C1 1.4222(18) .
O4 C13 1.4095(17) .
C1 C2 1.381(2) .
C1 C6 1.382(2) .
C2 C3 1.397(2) .
C2 H2 0.9300 .
C3 C4 1.386(2) .
C3 H3 0.9300 .
C4 C5 1.386(2) .
C4 H4 0.9300 .
C5 C6 1.397(2) .
C5 H5 0.9300 .
C6 H6 0.9300 .
C7 C8 1.379(2) .
C7 C12 1.381(2) .
C8 C9 1.395(2) .
C8 H8 0.9300 .
C9 C10 1.395(3) .
C9 H9 0.9300 .
C10 C11 1.379(3) .
C10 H10 0.9300 .
C11 C12 1.391(2) .
C11 H11 0.9300 .
C12 H12 0.9300 .
C13 C15 1.383(2) 3_666
C13 C14 1.385(2) .
C14 C15 1.395(2) .
C14 H14 0.9300 .
C15 C13 1.383(2) 3_666
C15 H15 0.9300 .
C16 C21 1.393(2) .
C16 C17 1.401(2) .
C17 C18 1.392(2) .
C17 H17 0.9300 .
C18 C19 1.393(2) .
C18 H18 0.9300 .
C19 C20 1.385(2) .
C19 H19 0.9300 .
C20 C21 1.397(2) .
C20 H20 0.9300 .
C21 H21 0.9300 .
C22 C27 1.391(2) .
C22 C23 1.398(2) .
C23 C24 1.390(2) .
C23 H23 0.9300 .
C24 C25 1.387(2) .
C24 H24 0.9300 .
C25 C26 1.384(2) .
C25 H25 0.9300 .
C26 C27 1.396(2) .
C26 H26 0.9300 .
C27 H27 0.9300 .
C28 C33 1.391(2) .
C28 C29 1.398(2) .
C29 C30 1.393(2) .
C29 H29 0.9300 .
C30 C31 1.389(3) .
C30 H30 0.9300 .
C31 C32 1.387(3) .
C31 H31 0.9300 .
C32 C33 1.399(2) .
C32 H32 0.9300 .
C33 H33 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 P1 O2 C7 40.94(12) . .
O3 P1 O2 C7 -87.40(11) . .
O4 P1 O2 C7 167.96(10) . .
O1 P1 O3 C1 42.28(13) . .
O2 P1 O3 C1 170.76(11) . .
O4 P1 O3 C1 -83.74(11) . .
O1 P1 O4 C13 49.91(13) . .
O2 P1 O4 C13 -77.70(12) . .
O3 P1 O4 C13 176.40(11) . .
P1 O3 C1 C2 83.90(15) . .
P1 O3 C1 C6 -98.26(14) . .
C6 C1 C2 C3 0.2(2) . .
O3 C1 C2 C3 177.89(14) . .
C1 C2 C3 C4 0.2(2) . .
C2 C3 C4 C5 -0.3(3) . .
C3 C4 C5 C6 0.1(3) . .
C2 C1 C6 C5 -0.4(2) . .
O3 C1 C6 C5 -178.18(13) . .
C4 C5 C6 C1 0.3(2) . .
P1 O2 C7 C8 -93.57(14) . .
P1 O2 C7 C12 87.95(15) . .
C12 C7 C8 C9 -1.8(2) . .
O2 C7 C8 C9 179.82(13) . .
C7 C8 C9 C10 0.9(2) . .
C8 C9 C10 C11 0.5(2) . .
C9 C10 C11 C12 -1.1(2) . .
C8 C7 C12 C11 1.2(2) . .
O2 C7 C12 C11 179.59(13) . .
C10 C11 C12 C7 0.3(2) . .
P1 O4 C13 C15 -82.18(16) . 3_666
P1 O4 C13 C14 100.51(14) . .
C15 C13 C14 C15 0.1(2) 3_666 .
O4 C13 C14 C15 177.28(13) . .
C13 C14 C15 C13 -0.1(2) . 3_666
C28 Sn1 C16 C21 168.57(11) . .
C22 Sn1 C16 C21 -44.62(14) . .
Cl1 Sn1 C16 C21 60.68(12) . .
C28 Sn1 C16 C17 -13.99(15) . .
C22 Sn1 C16 C17 132.82(12) . .
Cl1 Sn1 C16 C17 -121.88(12) . .
C21 C16 C17 C18 1.1(2) . .
Sn1 C16 C17 C18 -176.32(12) . .
C16 C17 C18 C19 -0.2(2) . .
C17 C18 C19 C20 -0.7(3) . .
C18 C19 C20 C21 0.6(2) . .
C17 C16 C21 C20 -1.2(2) . .
Sn1 C16 C21 C20 176.31(12) . .
C19 C20 C21 C16 0.3(2) . .
C16 Sn1 C22 C27 168.58(11) . .
C28 Sn1 C22 C27 -42.50(14) . .
Cl1 Sn1 C22 C27 63.30(12) . .
C16 Sn1 C22 C23 -11.85(14) . .
C28 Sn1 C22 C23 137.06(12) . .
Cl1 Sn1 C22 C23 -117.13(12) . .
C27 C22 C23 C24 -0.1(2) . .
Sn1 C22 C23 C24 -179.68(13) . .
C22 C23 C24 C25 0.0(3) . .
C23 C24 C25 C26 0.2(3) . .
C24 C25 C26 C27 -0.2(3) . .
C23 C22 C27 C26 0.1(2) . .
Sn1 C22 C27 C26 179.68(12) . .
C25 C26 C27 C22 0.0(3) . .
C16 Sn1 C28 C33 -57.58(15) . .
C22 Sn1 C28 C33 155.03(12) . .
Cl1 Sn1 C28 C33 49.79(13) . .
C16 Sn1 C28 C29 119.35(12) . .
C22 Sn1 C28 C29 -28.03(13) . .
Cl1 Sn1 C28 C29 -133.28(11) . .
C33 C28 C29 C30 2.9(2) . .
Sn1 C28 C29 C30 -174.11(12) . .
C28 C29 C30 C31 -0.4(2) . .
C29 C30 C31 C32 -2.6(3) . .
C30 C31 C32 C33 2.9(3) . .
C29 C28 C33 C32 -2.6(2) . .
Sn1 C28 C33 C32 174.39(13) . .
C31 C32 C33 C28 -0.4(3) . .
