#------------------------------------------------------------------------------
#$Date: 2016-03-26 23:00:42 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180526 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/95/7219530.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7219530
loop_
_publ_author_name
'Gholivand, K.'
'Gholami, A.'
'Ebrahimi, A. A. V.'
'Abolghasemi, S. T.'
'Esrafili, M. D.'
'Fadaei, F. T.'
'Schenk, K. J.'
_publ_section_title
;
 Triphenyltin(iv) adducts of diphosphoryl ligands: structural, electronic
 and energy aspects from X-ray crystallography and theoretical
 calculations
;
_journal_issue                   23
_journal_name_full               'RSC Adv.'
_journal_page_first              17482
_journal_paper_doi               10.1039/C4RA12925C
_journal_volume                  5
_journal_year                    2015
_chemical_formula_moiety         'C68 H62 Cl2 N4 O4 P2 Sn2'
_chemical_formula_sum            'C68 H62 Cl2 N4 O4 P2 Sn2'
_chemical_formula_weight         1369.48
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           13
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yc'
_symmetry_space_group_name_H-M   'P 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-01-09 deposited with the CCDC.
2015-01-28 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 104.235(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   20.193(3)
_cell_length_b                   9.5523(16)
_cell_length_c                   16.433(3)
_cell_measurement_reflns_used    315
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      25
_cell_measurement_theta_min      3
_cell_volume                     3072.4(9)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX II'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Bruker APEX II CCD area detector'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1015
_diffrn_reflns_av_unetI/netI     0.0764
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            25602
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.08
_exptl_absorpt_coefficient_mu    1.004
_exptl_absorpt_correction_T_max  0.840
_exptl_absorpt_correction_T_min  0.672
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.480
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1388
_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent: '
_exptl_crystal_size_max          0.43
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.278
_refine_diff_density_min         -0.974
_refine_diff_density_rms         0.109
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     370
_refine_ls_number_reflns         5347
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.033
_refine_ls_R_factor_all          0.0876
_refine_ls_R_factor_gt           0.0545
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0556P)²+3.6284P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1141
_refine_ls_wR_factor_ref         0.1259
_reflns_number_gt                3786
_reflns_number_total             5347
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            c4ra12925c2.cif
_cod_data_source_block           ag17
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      'P 2/c'
_cod_database_code               7219530
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Sn1 Sn 0.281644(14) 0.30764(3) 0.165345(17) 0.02397(7) Uani 1 1 d .
Cl1 Cl 0.31114(6) 0.19404(13) 0.30797(6) 0.0356(3) Uani 1 1 d .
P1 P 0.24540(6) 0.46207(13) -0.05228(7) 0.0310(3) Uani 1 1 d U
O1 O 0.25037(14) 0.4008(3) 0.03143(16) 0.0299(8) Uani 1 1 d .
N2 N 0.2287(2) 0.3544(4) -0.1317(2) 0.0433(12) Uani 1 1 d .
H2N H 0.2533 0.3652 -0.1687 0.052 Uiso 1 1 calc R
N1 N 0.3101(2) 0.5422(6) -0.0624(2) 0.0674(15) Uani 1 1 d .
H1N H 0.3141 0.5531 -0.1141 0.081 Uiso 1 1 d R
O2 O 0.1757(2) 0.5479(5) -0.0760(2) 0.0792(13) Uani 1 1 d U
C1 C 0.1747(2) 0.2928(4) 0.1506(2) 0.0259(10) Uani 1 1 d .
C2 C 0.1312(2) 0.2283(4) 0.0837(3) 0.0335(12) Uani 1 1 d .
H2B H 0.1492 0.1857 0.0415 0.040 Uiso 1 1 calc R
C3 C 0.0614(2) 0.2244(5) 0.0768(3) 0.0465(16) Uani 1 1 d .
H3A H 0.0323 0.1782 0.0303 0.056 Uiso 1 1 calc R
C4 C 0.0341(2) 0.2865(6) 0.1362(3) 0.0481(15) Uani 1 1 d .
H4A H -0.0138 0.2839 0.1310 0.058 Uiso 1 1 calc R
C5 C 0.0775(2) 0.3543(6) 0.2050(3) 0.0487(15) Uani 1 1 d .
H5A H 0.0593 0.3994 0.2462 0.058 Uiso 1 1 calc R
C6 C 0.1468(2) 0.3543(5) 0.2116(3) 0.0382(13) Uani 1 1 d .
H6A H 0.1764 0.3973 0.2590 0.046 Uiso 1 1 calc R
C7 C 0.3268(2) 0.5034(5) 0.2114(2) 0.0257(11) Uani 1 1 d .
C8 C 0.3919(2) 0.5088(5) 0.2653(3) 0.0408(14) Uani 1 1 d .
H8A H 0.4166 0.4246 0.2817 0.049 Uiso 1 1 calc R
C9 C 0.4212(3) 0.6377(6) 0.2955(3) 0.0537(16) Uani 1 1 d .
H9A H 0.4654 0.6407 0.3327 0.064 Uiso 1 1 calc R
C10 C 0.3861(3) 0.7582(5) 0.2713(3) 0.0442(14) Uani 1 1 d .
H10A H 0.4061 0.8454 0.2918 0.053 Uiso 1 1 calc R
C11 C 0.3225(2) 0.7558(5) 0.2178(3) 0.0375(13) Uani 1 1 d .
H11A H 0.2990 0.8411 0.2006 0.045 Uiso 1 1 calc R
C12 C 0.2917(2) 0.6273(5) 0.1883(3) 0.0333(12) Uani 1 1 d .
H12A H 0.2469 0.6256 0.1525 0.040 Uiso 1 1 calc R
C13 C 0.3430(2) 0.1631(4) 0.1167(2) 0.0233(10) Uani 1 1 d .
C14 C 0.4059(2) 0.1206(5) 0.1673(3) 0.0349(12) Uani 1 1 d .
H14A H 0.4196 0.1507 0.2241 0.042 Uiso 1 1 calc R
C15 C 0.4480(2) 0.0350(5) 0.1351(3) 0.0431(14) Uani 1 1 d .
H15A H 0.4914 0.0095 0.1696 0.052 Uiso 1 1 calc R
C16 C 0.4288(2) -0.0142(5) 0.0544(3) 0.0414(13) Uani 1 1 d .
H16A H 0.4583 -0.0739 0.0333 0.050 Uiso 1 1 calc R
C17 C 0.3668(2) 0.0237(5) 0.0046(3) 0.0413(14) Uani 1 1 d .
H17A H 0.3527 -0.0111 -0.0512 0.050 Uiso 1 1 calc R
C18 C 0.3238(2) 0.1135(5) 0.0354(3) 0.0344(12) Uani 1 1 d .
H18A H 0.2810 0.1405 0.0000 0.041 Uiso 1 1 calc R
C19 C 0.1801(2) 0.2469(6) -0.1482(3) 0.0442(15) Uani 1 1 d .
C20 C 0.1133(3) 0.2643(7) -0.1426(3) 0.0550(17) Uani 1 1 d .
H20A H 0.0986 0.3526 -0.1269 0.066 Uiso 1 1 calc R
C21 C 0.0675(3) 0.1527(8) -0.1597(4) 0.072(2) Uani 1 1 d .
H21A H 0.0216 0.1653 -0.1561 0.086 Uiso 1 1 calc R
C22 C 0.0884(3) 0.0254(7) -0.1816(4) 0.0656(19) Uani 1 1 d .
H22A H 0.0573 -0.0508 -0.1920 0.079 Uiso 1 1 calc R
C23 C 0.1535(3) 0.0065(7) -0.1888(3) 0.0580(18) Uani 1 1 d .
H23A H 0.1670 -0.0818 -0.2060 0.070 Uiso 1 1 calc R
C24 C 0.2001(3) 0.1145(7) -0.1714(3) 0.0521(17) Uani 1 1 d .
H24A H 0.2458 0.0996 -0.1750 0.062 Uiso 1 1 calc R
C25 C 0.1629(3) 0.6452(6) -0.0172(3) 0.0527(15) Uani 1 1 d U
C26 C 0.1884(3) 0.7766(7) -0.0100(5) 0.083(2) Uani 1 1 d .
H26A H 0.2186 0.8055 -0.0430 0.099 Uiso 1 1 calc R
C27 C 0.1710(4) 0.8651(7) 0.0436(5) 0.083(3) Uani 1 1 d U
H27A H 0.1889 0.9574 0.0467 0.099 Uiso 1 1 calc R
C28 C 0.1292(3) 0.8320(7) 0.0943(4) 0.083(2) Uani 1 1 d U
H28A H 0.1195 0.8976 0.1332 0.099 Uiso 1 1 calc R
C29 C 0.1000(2) 0.6924(7) 0.0862(3) 0.0596(17) Uani 1 1 d .
H29A H 0.0695 0.6636 0.1186 0.071 Uiso 1 1 calc R
C30 C 0.1186(2) 0.6027(5) 0.0293(3) 0.0433(14) Uani 1 1 d .
H30A H 0.1004 0.5105 0.0223 0.052 Uiso 1 1 calc R
C31 C 0.3649(3) 0.6007(6) 0.0034(3) 0.0551(16) Uani 1 1 d .
H31A H 0.3562 0.5773 0.0585 0.066 Uiso 1 1 calc R
H31B H 0.3639 0.7039 -0.0021 0.066 Uiso 1 1 calc R
C32 C 0.4342(3) 0.5500(6) 0.0019(3) 0.0457(14) Uani 1 1 d .
C33 C 0.4780(3) 0.6309(6) -0.0341(3) 0.0459(14) Uani 1 1 d .
H33A H 0.4634 0.7200 -0.0575 0.055 Uiso 1 1 calc R
C34 C 0.5415(3) 0.5815(6) -0.0355(3) 0.0497(15) Uani 1 1 d .
H34A H 0.5702 0.6380 -0.0600 0.060 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Sn1 C7 115.67(16) . .
C1 Sn1 C13 125.64(15) . .
C7 Sn1 C13 117.54(15) . .
C1 Sn1 O1 83.38(13) . .
C7 Sn1 O1 89.63(13) . .
C13 Sn1 O1 86.58(13) . .
C1 Sn1 Cl1 94.52(11) . .
C7 Sn1 Cl1 93.70(11) . .
C13 Sn1 Cl1 92.50(11) . .
O1 Sn1 Cl1 176.60(8) . .
O1 P1 N1 115.3(2) . .
O1 P1 O2 106.60(19) . .
N1 P1 O2 115.8(3) . .
O1 P1 N2 116.7(2) . .
N1 P1 N2 103.7(2) . .
O2 P1 N2 97.6(2) . .
P1 O1 Sn1 168.44(18) . .
C19 N2 P1 127.9(3) . .
C19 N2 H2N 116.0 . .
P1 N2 H2N 116.0 . .
C31 N1 P1 127.8(4) . .
C31 N1 H1N 116.1 . .
P1 N1 H1N 116.1 . .
C25 O2 P1 118.2(3) . .
C2 C1 C6 118.1(4) . .
C2 C1 Sn1 123.8(3) . .
C6 C1 Sn1 118.1(3) . .
C1 C2 C3 121.1(5) . .
C1 C2 H2B 119.4 . .
C3 C2 H2B 119.4 . .
C4 C3 C2 120.6(4) . .
C4 C3 H3A 119.7 . .
C2 C3 H3A 119.7 . .
C3 C4 C5 119.4(4) . .
C3 C4 H4A 120.3 . .
C5 C4 H4A 120.3 . .
C6 C5 C4 119.0(5) . .
C6 C5 H5A 120.5 . .
C4 C5 H5A 120.5 . .
C5 C6 C1 121.7(4) . .
C5 C6 H6A 119.2 . .
C1 C6 H6A 119.2 . .
C12 C7 C8 118.8(4) . .
C12 C7 Sn1 120.4(3) . .
C8 C7 Sn1 120.7(3) . .
C7 C8 C9 120.5(4) . .
C7 C8 H8A 119.8 . .
C9 C8 H8A 119.8 . .
C10 C9 C8 119.7(4) . .
C10 C9 H9A 120.1 . .
C8 C9 H9A 120.1 . .
C9 C10 C11 120.9(5) . .
C9 C10 H10A 119.5 . .
C11 C10 H10A 119.5 . .
C10 C11 C12 120.1(4) . .
C10 C11 H11A 119.9 . .
C12 C11 H11A 119.9 . .
C7 C12 C11 119.9(4) . .
C7 C12 H12A 120.1 . .
C11 C12 H12A 120.1 . .
C18 C13 C14 118.4(4) . .
C18 C13 Sn1 122.2(3) . .
C14 C13 Sn1 119.4(3) . .
C15 C14 C13 120.1(4) . .
C15 C14 H14A 120.0 . .
C13 C14 H14A 120.0 . .
C16 C15 C14 121.4(4) . .
C16 C15 H15A 119.3 . .
C14 C15 H15A 119.3 . .
C17 C16 C15 119.3(5) . .
C17 C16 H16A 120.4 . .
C15 C16 H16A 120.4 . .
C16 C17 C18 120.3(4) . .
C16 C17 H17A 119.8 . .
C18 C17 H17A 119.8 . .
C13 C18 C17 120.5(4) . .
C13 C18 H18A 119.7 . .
C17 C18 H18A 119.7 . .
C20 C19 N2 123.2(5) . .
C20 C19 C24 118.3(5) . .
N2 C19 C24 118.5(5) . .
C19 C20 C21 120.3(6) . .
C19 C20 H20A 119.9 . .
C21 C20 H20A 119.9 . .
C22 C21 C20 120.1(6) . .
C22 C21 H21A 120.0 . .
C20 C21 H21A 120.0 . .
C23 C22 C21 120.7(6) . .
C23 C22 H22A 119.7 . .
C21 C22 H22A 119.7 . .
C22 C23 C24 120.5(6) . .
C22 C23 H23A 119.8 . .
C24 C23 H23A 119.8 . .
C23 C24 C19 120.2(5) . .
C23 C24 H24A 119.9 . .
C19 C24 H24A 119.9 . .
C26 C25 C30 120.9(6) . .
C26 C25 O2 122.8(6) . .
C30 C25 O2 116.1(5) . .
C27 C26 C25 119.4(7) . .
C27 C26 H26A 120.3 . .
C25 C26 H26A 120.3 . .
C26 C27 C28 124.3(7) . .
C26 C27 H27A 117.9 . .
C28 C27 H27A 117.9 . .
C27 C28 C29 117.2(6) . .
C27 C28 H28A 121.4 . .
C29 C28 H28A 121.4 . .
C30 C29 C28 117.3(5) . .
C30 C29 H29A 121.4 . .
C28 C29 H29A 121.4 . .
C25 C30 C29 120.9(5) . .
C25 C30 H30A 119.5 . .
C29 C30 H30A 119.5 . .
N1 C31 C32 114.2(5) . .
N1 C31 H31A 108.7 . .
C32 C31 H31A 108.7 . .
N1 C31 H31B 108.7 . .
C32 C31 H31B 108.7 . .
H31A C31 H31B 107.6 . .
C33 C32 C34 117.3(5) . 3_665
C33 C32 C31 121.3(5) . .
C34 C32 C31 121.5(5) 3_665 .
C34 C33 C32 120.3(5) . .
C34 C33 H33A 119.9 . .
C32 C33 H33A 119.9 . .
C33 C34 C32 122.4(5) . 3_665
C33 C34 H34A 118.8 . .
C32 C34 H34A 118.8 3_665 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sn1 C1 2.117(4) .
Sn1 C7 2.136(4) .
Sn1 C13 2.137(4) .
Sn1 O1 2.313(3) .
Sn1 Cl1 2.5177(11) .
P1 O1 1.475(3) .
P1 N1 1.559(5) .
P1 O2 1.593(4) .
P1 N2 1.630(4) .
N2 C19 1.401(7) .
N2 H2N 0.8800 .
N1 C31 1.454(6) .
N1 H1N 0.8790 .
O2 C25 1.410(6) .
C1 C2 1.373(6) .
C1 C6 1.395(6) .
C2 C3 1.386(7) .
C2 H2B 0.9500 .
C3 C4 1.370(8) .
C3 H3A 0.9500 .
C4 C5 1.407(7) .
C4 H4A 0.9500 .
C5 C6 1.377(6) .
C5 H5A 0.9500 .
C6 H6A 0.9500 .
C7 C12 1.384(6) .
C7 C8 1.395(6) .
C8 C9 1.403(7) .
C8 H8A 0.9500 .
C9 C10 1.360(7) .
C9 H9A 0.9500 .
C10 C11 1.366(6) .
C10 H10A 0.9500 .
C11 C12 1.408(6) .
C11 H11A 0.9500 .
C12 H12A 0.9500 .
C13 C18 1.381(6) .
C13 C14 1.396(6) .
C14 C15 1.377(7) .
C14 H14A 0.9500 .
C15 C16 1.371(7) .
C15 H15A 0.9500 .
C16 C17 1.366(6) .
C16 H16A 0.9500 .
C17 C18 1.401(7) .
C17 H17A 0.9500 .
C18 H18A 0.9500 .
C19 C20 1.384(7) .
C19 C24 1.408(8) .
C20 C21 1.394(9) .
C20 H20A 0.9500 .
C21 C22 1.365(9) .
C21 H21A 0.9500 .
C22 C23 1.360(9) .
C22 H22A 0.9500 .
C23 C24 1.377(8) .
C23 H23A 0.9500 .
C24 H24A 0.9500 .
C25 C26 1.351(9) .
C25 C30 1.372(8) .
C26 C27 1.328(10) .
C26 H26A 0.9500 .
C27 C28 1.361(11) .
C27 H27A 0.9500 .
C28 C29 1.451(9) .
C28 H28A 0.9500 .
C29 C30 1.387(8) .
C29 H29A 0.9500 .
C30 H30A 0.9500 .
C31 C32 1.486(8) .
C31 H31A 0.9900 .
C31 H31B 0.9900 .
C32 C33 1.410(7) .
C32 C34 1.411(7) 3_665
C33 C34 1.372(8) .
C33 H33A 0.9500 .
C34 C32 1.411(7) 3_665
C34 H34A 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 P1 O1 Sn1 -21.6(10) . .
O2 P1 O1 Sn1 -151.6(9) . .
N2 P1 O1 Sn1 100.6(9) . .
C1 Sn1 O1 P1 -179.2(10) . .
C7 Sn1 O1 P1 64.9(9) . .
C13 Sn1 O1 P1 -52.7(9) . .
O1 P1 N2 C19 44.5(5) . .
N1 P1 N2 C19 172.5(4) . .
O2 P1 N2 C19 -68.5(5) . .
O1 P1 N1 C31 -20.7(6) . .
O2 P1 N1 C31 104.8(5) . .
N2 P1 N1 C31 -149.5(5) . .
O1 P1 O2 C25 51.1(5) . .
N1 P1 O2 C25 -78.7(5) . .
N2 P1 O2 C25 172.0(4) . .
C7 Sn1 C1 C2 139.5(3) . .
C13 Sn1 C1 C2 -27.9(4) . .
O1 Sn1 C1 C2 53.1(4) . .
Cl1 Sn1 C1 C2 -124.2(4) . .
C7 Sn1 C1 C6 -39.4(4) . .
C13 Sn1 C1 C6 153.3(3) . .
O1 Sn1 C1 C6 -125.7(4) . .
Cl1 Sn1 C1 C6 57.0(3) . .
C6 C1 C2 C3 0.1(7) . .
Sn1 C1 C2 C3 -178.7(3) . .
C1 C2 C3 C4 0.8(7) . .
C2 C3 C4 C5 -0.3(8) . .
C3 C4 C5 C6 -1.1(8) . .
C4 C5 C6 C1 2.1(8) . .
C2 C1 C6 C5 -1.5(7) . .
Sn1 C1 C6 C5 177.3(4) . .
C1 Sn1 C7 C12 -35.6(4) . .
C13 Sn1 C7 C12 132.8(3) . .
O1 Sn1 C7 C12 46.9(4) . .
Cl1 Sn1 C7 C12 -132.4(3) . .
C1 Sn1 C7 C8 144.4(4) . .
C13 Sn1 C7 C8 -47.1(4) . .
O1 Sn1 C7 C8 -133.1(4) . .
Cl1 Sn1 C7 C8 47.6(4) . .
C12 C7 C8 C9 0.1(7) . .
Sn1 C7 C8 C9 -179.9(4) . .
C7 C8 C9 C10 -0.8(8) . .
C8 C9 C10 C11 0.0(8) . .
C9 C10 C11 C12 1.3(8) . .
C8 C7 C12 C11 1.2(7) . .
Sn1 C7 C12 C11 -178.8(3) . .
C10 C11 C12 C7 -1.9(7) . .
C1 Sn1 C13 C18 45.7(4) . .
C7 Sn1 C13 C18 -121.4(3) . .
O1 Sn1 C13 C18 -33.7(3) . .
Cl1 Sn1 C13 C18 143.1(3) . .
C1 Sn1 C13 C14 -136.6(3) . .
C7 Sn1 C13 C14 56.2(4) . .
O1 Sn1 C13 C14 144.0(3) . .
Cl1 Sn1 C13 C14 -39.3(3) . .
C18 C13 C14 C15 2.1(7) . .
Sn1 C13 C14 C15 -175.6(4) . .
C13 C14 C15 C16 -2.2(8) . .
C14 C15 C16 C17 0.6(8) . .
C15 C16 C17 C18 1.0(8) . .
C14 C13 C18 C17 -0.5(7) . .
Sn1 C13 C18 C17 177.1(3) . .
C16 C17 C18 C13 -1.0(7) . .
P1 N2 C19 C20 46.6(6) . .
P1 N2 C19 C24 -133.0(4) . .
N2 C19 C20 C21 -179.8(5) . .
C24 C19 C20 C21 -0.2(7) . .
C19 C20 C21 C22 0.4(9) . .
C20 C21 C22 C23 -1.4(9) . .
C21 C22 C23 C24 2.2(9) . .
C22 C23 C24 C19 -1.9(8) . .
C20 C19 C24 C23 0.9(7) . .
N2 C19 C24 C23 -179.5(4) . .
P1 O2 C25 C26 82.7(6) . .
P1 O2 C25 C30 -101.8(5) . .
C30 C25 C26 C27 0.9(9) . .
O2 C25 C26 C27 176.2(6) . .
C25 C26 C27 C28 1.2(11) . .
C26 C27 C28 C29 -2.5(10) . .
C27 C28 C29 C30 1.8(8) . .
C26 C25 C30 C29 -1.4(8) . .
O2 C25 C30 C29 -177.1(4) . .
C28 C29 C30 C25 0.1(7) . .
P1 N1 C31 C32 124.5(5) . .
N1 C31 C32 C33 99.3(6) . .
N1 C31 C32 C34 -79.9(6) . 3_665
C34 C32 C33 C34 -0.2(7) 3_665 .
C31 C32 C33 C34 -179.4(4) . .
C32 C33 C34 C32 0.2(8) . 3_665
