#------------------------------------------------------------------------------
#$Date: 2016-03-26 23:00:42 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180526 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/95/7219532.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7219532
loop_
_publ_author_name
'Gholivand, K.'
'Gholami, A.'
'Ebrahimi, A. A. V.'
'Abolghasemi, S. T.'
'Esrafili, M. D.'
'Fadaei, F. T.'
'Schenk, K. J.'
_publ_section_title
;
 Triphenyltin(iv) adducts of diphosphoryl ligands: structural, electronic
 and energy aspects from X-ray crystallography and theoretical
 calculations
;
_journal_issue                   23
_journal_name_full               'RSC Adv.'
_journal_page_first              17482
_journal_paper_doi               10.1039/C4RA12925C
_journal_volume                  5
_journal_year                    2015
_chemical_formula_moiety         'C64 H58 Cl2 N2 O2 P2 Sn2'
_chemical_formula_sum            'C64 H58 Cl2 N2 O2 P2 Sn2'
_chemical_formula_weight         1257.34
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2014-04-22 deposited with the CCDC.
2015-01-28 downloaded from the CCDC.
;
_cell_angle_alpha                65.7630(10)
_cell_angle_beta                 83.3280(10)
_cell_angle_gamma                74.3130(10)
_cell_formula_units_Z            1
_cell_length_a                   10.5009(4)
_cell_length_b                   11.9976(5)
_cell_length_c                   12.6149(5)
_cell_measurement_reflns_used    9794
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      32.20
_cell_measurement_theta_min      2.50
_cell_volume                     1395.20(10)
_computing_cell_refinement       'APEX2 (Bruker, 2005)'
_computing_data_collection       'APEX2 (Bruker, 2005)'
_computing_data_reduction        'APEX2 (Bruker, 2005)'
_computing_molecular_graphics    'SHELXTL ver. 5.1 (Sheldrick, 1998)'
_computing_publication_material  'SHELXTL ver. 5.1 (Sheldrick, 1998)'
_computing_structure_refinement  'SHELXTL ver. 5.1 (Sheldrick, 1998)'
_computing_structure_solution    'SHELXTL ver. 5.1 (Sheldrick, 1998)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker SMART APEX2 CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0224
_diffrn_reflns_av_sigmaI/netI    0.0159
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            48407
_diffrn_reflns_theta_full        32.00
_diffrn_reflns_theta_max         32.00
_diffrn_reflns_theta_min         2.01
_exptl_absorpt_coefficient_mu    1.095
_exptl_absorpt_correction_T_max  0.849
_exptl_absorpt_correction_T_min  0.728
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'APEX2 (Bruker, 2005)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.496
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prizm
_exptl_crystal_F_000             636
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.598
_refine_diff_density_min         -0.399
_refine_diff_density_rms         0.059
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.038
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     334
_refine_ls_number_reflns         9670
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.038
_refine_ls_R_factor_all          0.0191
_refine_ls_R_factor_gt           0.0171
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0211P)²+0.5711P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0432
_refine_ls_wR_factor_ref         0.0445
_reflns_number_gt                9102
_reflns_number_total             9670
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            c4ra12925c2.cif
_cod_data_source_block           e8
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        1395.21(10)
_cod_database_code               7219532
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Sn1 Sn 0.804581(6) 0.482392(6) 0.806220(5) 0.01119(2) Uani 1 1 d .
Cl1 Cl 0.83079(2) 0.65861(2) 0.85330(2) 0.01693(4) Uani 1 1 d .
P1 P 0.82521(2) 0.17722(2) 0.78761(2) 0.01152(4) Uani 1 1 d .
O1 O 0.77670(7) 0.31373(7) 0.76889(6) 0.01506(13) Uani 1 1 d .
N1 N 0.91856(8) 0.08075(8) 0.90221(7) 0.01349(14) Uani 1 1 d .
C1 C 0.66098(10) 0.59883(9) 0.67229(8) 0.01341(16) Uani 1 1 d .
C2 C 0.65784(11) 0.72704(10) 0.61317(9) 0.01673(18) Uani 1 1 d .
H2A H 0.7176 0.7612 0.6344 0.020 Uiso 1 1 calc R
C3 C 0.56792(12) 0.80541(10) 0.52327(9) 0.0207(2) Uani 1 1 d .
H3A H 0.5682 0.8918 0.4828 0.025 Uiso 1 1 calc R
C4 C 0.47827(12) 0.75715(11) 0.49317(10) 0.0222(2) Uani 1 1 d .
H4A H 0.4164 0.8104 0.4327 0.027 Uiso 1 1 calc R
C5 C 0.47949(12) 0.63041(11) 0.55203(10) 0.0225(2) Uani 1 1 d .
H5A H 0.4177 0.5972 0.5321 0.027 Uiso 1 1 calc R
C6 C 0.57078(11) 0.55148(10) 0.64027(10) 0.01844(19) Uani 1 1 d .
H6A H 0.5716 0.4646 0.6790 0.022 Uiso 1 1 calc R
C7 C 1.00754(10) 0.43999(9) 0.75820(8) 0.01298(16) Uani 1 1 d .
C8 C 1.04456(10) 0.41715(10) 0.65738(9) 0.01579(17) Uani 1 1 d .
H8A H 0.9790 0.4157 0.6123 0.019 Uiso 1 1 calc R
C9 C 1.17687(11) 0.39645(11) 0.62240(10) 0.0203(2) Uani 1 1 d .
H9A H 1.2012 0.3803 0.5542 0.024 Uiso 1 1 calc R
C10 C 1.27299(11) 0.39944(11) 0.68747(11) 0.0228(2) Uani 1 1 d .
H10A H 1.3630 0.3860 0.6633 0.027 Uiso 1 1 calc R
C11 C 1.23772(11) 0.42207(12) 0.78788(11) 0.0221(2) Uani 1 1 d .
H11A H 1.3036 0.4241 0.8323 0.027 Uiso 1 1 calc R
C12 C 1.10561(10) 0.44185(10) 0.82347(9) 0.01643(18) Uani 1 1 d .
H12A H 1.0820 0.4567 0.8924 0.020 Uiso 1 1 calc R
C13 C 0.74226(10) 0.38191(9) 0.97757(8) 0.01378(16) Uani 1 1 d .
C14 C 0.61248(11) 0.36852(10) 0.99835(10) 0.01855(19) Uani 1 1 d .
H14A H 0.5538 0.4008 0.9349 0.022 Uiso 1 1 calc R
C15 C 0.56799(13) 0.30843(11) 1.11088(11) 0.0249(2) Uani 1 1 d .
H15A H 0.4792 0.3009 1.1239 0.030 Uiso 1 1 calc R
C16 C 0.65370(14) 0.25965(11) 1.20393(10) 0.0268(2) Uani 1 1 d .
H16A H 0.6237 0.2186 1.2808 0.032 Uiso 1 1 calc R
C17 C 0.78358(14) 0.27100(11) 1.18451(10) 0.0242(2) Uani 1 1 d .
H17A H 0.8425 0.2367 1.2481 0.029 Uiso 1 1 calc R
C18 C 0.82777(11) 0.33263(10) 1.07192(9) 0.01840(19) Uani 1 1 d .
H18A H 0.9163 0.3411 1.0594 0.022 Uiso 1 1 calc R
C19 C 0.92012(10) 0.16359(9) 0.66368(8) 0.01430(17) Uani 1 1 d .
C20 C 0.88139(12) 0.26108(10) 0.55508(9) 0.01833(19) Uani 1 1 d .
H20A H 0.8101 0.3314 0.5502 0.022 Uiso 1 1 calc R
C21 C 0.94716(13) 0.25505(12) 0.45455(9) 0.0240(2) Uani 1 1 d .
H21A H 0.9206 0.3211 0.3811 0.029 Uiso 1 1 calc R
C22 C 1.05130(13) 0.15273(13) 0.46172(10) 0.0256(2) Uani 1 1 d .
H22A H 1.0960 0.1488 0.3929 0.031 Uiso 1 1 calc R
C23 C 1.09104(12) 0.05535(12) 0.56934(11) 0.0237(2) Uani 1 1 d .
H23A H 1.1632 -0.0141 0.5738 0.028 Uiso 1 1 calc R
C24 C 1.02475(11) 0.06011(10) 0.67030(9) 0.01801(18) Uani 1 1 d .
H24A H 1.0506 -0.0068 0.7435 0.022 Uiso 1 1 calc R
C25 C 0.68781(10) 0.10895(9) 0.80352(8) 0.01317(16) Uani 1 1 d .
C26 C 0.70408(11) -0.00073(10) 0.78409(10) 0.01826(19) Uani 1 1 d .
H26A H 0.7887 -0.0408 0.7639 0.022 Uiso 1 1 calc R
C27 C 0.59650(12) -0.05113(11) 0.79439(11) 0.0222(2) Uani 1 1 d .
H27A H 0.6073 -0.1248 0.7798 0.027 Uiso 1 1 calc R
C28 C 0.47296(11) 0.00601(11) 0.82599(11) 0.0216(2) Uani 1 1 d .
H28A H 0.3996 -0.0288 0.8330 0.026 Uiso 1 1 calc R
C29 C 0.45659(11) 0.11355(11) 0.84734(11) 0.0216(2) Uani 1 1 d .
H29A H 0.3725 0.1515 0.8703 0.026 Uiso 1 1 calc R
C30 C 0.56355(11) 0.16604(10) 0.83517(10) 0.01808(18) Uani 1 1 d .
H30A H 0.5519 0.2406 0.8484 0.022 Uiso 1 1 calc R
C31 C 1.04716(10) 0.10278(9) 0.91305(8) 0.01485(17) Uani 1 1 d .
H31A H 1.0348 0.1612 0.9526 0.018 Uiso 1 1 calc R
H31B H 1.0850 0.1418 0.8349 0.018 Uiso 1 1 calc R
C32 C 0.85883(10) 0.02226(10) 1.01722(8) 0.01506(17) Uani 1 1 d .
H32A H 0.7731 0.0080 1.0075 0.018 Uiso 1 1 calc R
H32B H 0.8425 0.0790 1.0589 0.018 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C13 Sn1 C7 120.06(4) . .
C13 Sn1 C1 120.04(4) . .
C7 Sn1 C1 118.75(4) . .
C13 Sn1 O1 84.65(3) . .
C7 Sn1 O1 89.19(3) . .
C1 Sn1 O1 85.47(3) . .
C13 Sn1 Cl1 93.26(3) . .
C7 Sn1 Cl1 92.04(3) . .
C1 Sn1 Cl1 95.41(3) . .
O1 Sn1 Cl1 177.897(19) . .
O1 P1 N1 118.15(4) . .
O1 P1 C19 109.77(5) . .
N1 P1 C19 105.92(5) . .
O1 P1 C25 110.33(4) . .
N1 P1 C25 104.48(4) . .
C19 P1 C25 107.62(5) . .
P1 O1 Sn1 147.74(5) . .
C31 N1 C32 111.51(8) . .
C31 N1 P1 119.39(6) . .
C32 N1 P1 121.05(7) . .
C6 C1 C2 118.32(9) . .
C6 C1 Sn1 122.53(7) . .
C2 C1 Sn1 119.15(7) . .
C3 C2 C1 120.87(10) . .
C3 C2 H2A 119.6 . .
C1 C2 H2A 119.6 . .
C4 C3 C2 120.09(10) . .
C4 C3 H3A 120.0 . .
C2 C3 H3A 120.0 . .
C3 C4 C5 119.56(10) . .
C3 C4 H4A 120.2 . .
C5 C4 H4A 120.2 . .
C4 C5 C6 120.46(11) . .
C4 C5 H5A 119.8 . .
C6 C5 H5A 119.8 . .
C5 C6 C1 120.68(10) . .
C5 C6 H6A 119.7 . .
C1 C6 H6A 119.7 . .
C8 C7 C12 118.86(9) . .
C8 C7 Sn1 120.64(7) . .
C12 C7 Sn1 120.40(7) . .
C9 C8 C7 120.62(10) . .
C9 C8 H8A 119.7 . .
C7 C8 H8A 119.7 . .
C10 C9 C8 119.93(10) . .
C10 C9 H9A 120.0 . .
C8 C9 H9A 120.0 . .
C9 C10 C11 120.12(10) . .
C9 C10 H10A 119.9 . .
C11 C10 H10A 119.9 . .
C10 C11 C12 120.03(10) . .
C10 C11 H11A 120.0 . .
C12 C11 H11A 120.0 . .
C11 C12 C7 120.44(10) . .
C11 C12 H12A 119.8 . .
C7 C12 H12A 119.8 . .
C14 C13 C18 118.79(9) . .
C14 C13 Sn1 120.14(7) . .
C18 C13 Sn1 121.02(8) . .
C15 C14 C13 120.92(11) . .
C15 C14 H14A 119.5 . .
C13 C14 H14A 119.5 . .
C16 C15 C14 119.85(11) . .
C16 C15 H15A 120.1 . .
C14 C15 H15A 120.1 . .
C15 C16 C17 119.90(10) . .
C15 C16 H16A 120.1 . .
C17 C16 H16A 120.1 . .
C16 C17 C18 120.29(11) . .
C16 C17 H17A 119.9 . .
C18 C17 H17A 119.9 . .
C17 C18 C13 120.24(11) . .
C17 C18 H18A 119.9 . .
C13 C18 H18A 119.9 . .
C24 C19 C20 119.65(10) . .
C24 C19 P1 123.51(8) . .
C20 C19 P1 116.79(8) . .
C21 C20 C19 120.15(11) . .
C21 C20 H20A 119.9 . .
C19 C20 H20A 119.9 . .
C22 C21 C20 119.94(11) . .
C22 C21 H21A 120.0 . .
C20 C21 H21A 120.0 . .
C21 C22 C23 120.43(11) . .
C21 C22 H22A 119.8 . .
C23 C22 H22A 119.8 . .
C24 C23 C22 119.95(11) . .
C24 C23 H23A 120.0 . .
C22 C23 H23A 120.0 . .
C23 C24 C19 119.87(10) . .
C23 C24 H24A 120.1 . .
C19 C24 H24A 120.1 . .
C30 C25 C26 119.64(9) . .
C30 C25 P1 119.82(8) . .
C26 C25 P1 120.54(8) . .
C27 C26 C25 119.97(10) . .
C27 C26 H26A 120.0 . .
C25 C26 H26A 120.0 . .
C26 C27 C28 120.17(10) . .
C26 C27 H27A 119.9 . .
C28 C27 H27A 119.9 . .
C29 C28 C27 120.16(10) . .
C29 C28 H28A 119.9 . .
C27 C28 H28A 119.9 . .
C28 C29 C30 120.03(10) . .
C28 C29 H29A 120.0 . .
C30 C29 H29A 120.0 . .
C29 C30 C25 120.00(10) . .
C29 C30 H30A 120.0 . .
C25 C30 H30A 120.0 . .
N1 C31 C32 109.36(8) . 2_757
N1 C31 H31A 109.8 . .
C32 C31 H31A 109.8 2_757 .
N1 C31 H31B 109.8 . .
C32 C31 H31B 109.8 2_757 .
H31A C31 H31B 108.3 . .
N1 C32 C31 109.01(8) . 2_757
N1 C32 H32A 109.9 . .
C31 C32 H32A 109.9 2_757 .
N1 C32 H32B 109.9 . .
C31 C32 H32B 109.9 2_757 .
H32A C32 H32B 108.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sn1 C13 2.1243(10) .
Sn1 C7 2.1295(10) .
Sn1 C1 2.1436(10) .
Sn1 O1 2.3531(7) .
Sn1 Cl1 2.5064(3) .
P1 O1 1.5022(8) .
P1 N1 1.6530(8) .
P1 C19 1.7956(10) .
P1 C25 1.7973(10) .
N1 C31 1.4758(13) .
N1 C32 1.4770(13) .
C1 C6 1.3968(14) .
C1 C2 1.3999(14) .
C2 C3 1.3983(15) .
C2 H2A 0.9500 .
C3 C4 1.3871(17) .
C3 H3A 0.9500 .
C4 C5 1.3886(17) .
C4 H4A 0.9500 .
C5 C6 1.3952(15) .
C5 H5A 0.9500 .
C6 H6A 0.9500 .
C7 C8 1.3990(14) .
C7 C12 1.4012(14) .
C8 C9 1.3956(15) .
C8 H8A 0.9500 .
C9 C10 1.3893(17) .
C9 H9A 0.9500 .
C10 C11 1.3907(17) .
C10 H10A 0.9500 .
C11 C12 1.3954(15) .
C11 H11A 0.9500 .
C12 H12A 0.9500 .
C13 C14 1.3972(14) .
C13 C18 1.3986(14) .
C14 C15 1.3932(15) .
C14 H14A 0.9500 .
C15 C16 1.388(2) .
C15 H15A 0.9500 .
C16 C17 1.3907(19) .
C16 H16A 0.9500 .
C17 C18 1.3962(15) .
C17 H17A 0.9500 .
C18 H18A 0.9500 .
C19 C24 1.3979(15) .
C19 C20 1.4024(14) .
C20 C21 1.3911(16) .
C20 H20A 0.9500 .
C21 C22 1.385(2) .
C21 H21A 0.9500 .
C22 C23 1.3957(18) .
C22 H22A 0.9500 .
C23 C24 1.3935(15) .
C23 H23A 0.9500 .
C24 H24A 0.9500 .
C25 C30 1.3969(14) .
C25 C26 1.3979(14) .
C26 C27 1.3890(15) .
C26 H26A 0.9500 .
C27 C28 1.3912(16) .
C27 H27A 0.9500 .
C28 C29 1.3860(16) .
C28 H28A 0.9500 .
C29 C30 1.3945(15) .
C29 H29A 0.9500 .
C30 H30A 0.9500 .
C31 C32 1.5220(14) 2_757
C31 H31A 0.9900 .
C31 H31B 0.9900 .
C32 C31 1.5220(14) 2_757
C32 H32A 0.9900 .
C32 H32B 0.9900 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
N1 P1 O1 Sn1 21.66(11) .
C19 P1 O1 Sn1 -99.87(9) .
C25 P1 O1 Sn1 141.69(8) .
C13 Sn1 O1 P1 -70.60(9) .
C7 Sn1 O1 P1 49.70(9) .
C1 Sn1 O1 P1 168.62(9) .
O1 P1 N1 C31 -61.65(9) .
C19 P1 N1 C31 61.82(9) .
C25 P1 N1 C31 175.32(8) .
O1 P1 N1 C32 84.48(9) .
C19 P1 N1 C32 -152.05(8) .
C25 P1 N1 C32 -38.54(9) .
C13 Sn1 C1 C6 -58.61(10) .
C7 Sn1 C1 C6 109.13(9) .
O1 Sn1 C1 C6 22.54(9) .
Cl1 Sn1 C1 C6 -155.55(8) .
C13 Sn1 C1 C2 122.23(8) .
C7 Sn1 C1 C2 -70.04(9) .
O1 Sn1 C1 C2 -156.63(8) .
Cl1 Sn1 C1 C2 25.29(8) .
C6 C1 C2 C3 -0.85(16) .
Sn1 C1 C2 C3 178.35(8) .
C1 C2 C3 C4 1.39(17) .
C2 C3 C4 C5 -0.69(18) .
C3 C4 C5 C6 -0.53(18) .
C4 C5 C6 C1 1.08(18) .
C2 C1 C6 C5 -0.38(16) .
Sn1 C1 C6 C5 -179.55(9) .
C13 Sn1 C7 C8 129.64(8) .
C1 Sn1 C7 C8 -38.09(9) .
O1 Sn1 C7 C8 46.30(8) .
Cl1 Sn1 C7 C8 -135.40(8) .
C13 Sn1 C7 C12 -54.13(9) .
C1 Sn1 C7 C12 138.14(8) .
O1 Sn1 C7 C12 -137.47(8) .
Cl1 Sn1 C7 C12 40.83(8) .
C12 C7 C8 C9 0.05(15) .
Sn1 C7 C8 C9 176.34(8) .
C7 C8 C9 C10 -0.52(16) .
C8 C9 C10 C11 0.50(18) .
C9 C10 C11 C12 -0.02(18) .
C10 C11 C12 C7 -0.45(17) .
C8 C7 C12 C11 0.43(15) .
Sn1 C7 C12 C11 -175.87(8) .
C7 Sn1 C13 C14 -153.45(8) .
C1 Sn1 C13 C14 14.13(10) .
O1 Sn1 C13 C14 -67.49(8) .
Cl1 Sn1 C13 C14 112.30(8) .
C7 Sn1 C13 C18 29.21(10) .
C1 Sn1 C13 C18 -163.22(8) .
O1 Sn1 C13 C18 115.16(8) .
Cl1 Sn1 C13 C18 -65.05(8) .
C18 C13 C14 C15 0.64(16) .
Sn1 C13 C14 C15 -176.76(8) .
C13 C14 C15 C16 -0.76(17) .
C14 C15 C16 C17 0.03(18) .
C15 C16 C17 C18 0.80(18) .
C16 C17 C18 C13 -0.91(17) .
C14 C13 C18 C17 0.19(16) .
Sn1 C13 C18 C17 177.57(8) .
O1 P1 C19 C24 149.62(9) .
N1 P1 C19 C24 21.03(10) .
C25 P1 C19 C24 -90.27(9) .
O1 P1 C19 C20 -33.01(9) .
N1 P1 C19 C20 -161.60(8) .
C25 P1 C19 C20 87.09(9) .
C24 C19 C20 C21 -0.28(15) .
P1 C19 C20 C21 -177.75(8) .
C19 C20 C21 C22 -0.15(16) .
C20 C21 C22 C23 -0.07(18) .
C21 C22 C23 C24 0.72(18) .
C22 C23 C24 C19 -1.15(17) .
C20 C19 C24 C23 0.93(16) .
P1 C19 C24 C23 178.23(9) .
O1 P1 C25 C30 -20.73(10) .
N1 P1 C25 C30 107.23(9) .
C19 P1 C25 C30 -140.48(8) .
O1 P1 C25 C26 159.05(8) .
N1 P1 C25 C26 -72.98(9) .
C19 P1 C25 C26 39.31(10) .
C30 C25 C26 C27 1.08(16) .
P1 C25 C26 C27 -178.71(9) .
C25 C26 C27 C28 -1.12(18) .
C26 C27 C28 C29 0.01(19) .
C27 C28 C29 C30 1.13(19) .
C28 C29 C30 C25 -1.16(18) .
C26 C25 C30 C29 0.06(16) .
P1 C25 C30 C29 179.85(9) .
C32 N1 C31 C32 59.36(12) 2_757
P1 N1 C31 C32 -151.51(7) 2_757
C31 N1 C32 C31 -59.16(12) 2_757
P1 N1 C32 C31 152.30(7) 2_757
