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#$Date: 2021-09-06 13:28:02 +0300 (Mon, 06 Sep 2021) $
#$Revision: 268667 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/31/7243135.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7243135
loop_
_publ_author_name
'Jiang, Wei'
'Lv, Mengying'
'Gao, Baihui'
'Liu, Bo'
'Yan, Guosong'
'Zhou, Shi'
'Liu, Chunbo'
'Xie, Wei'
'Che, Guangbo'
_publ_section_title
;
 Facile construction of an Ag0-doped Ag(i)-based coordination polymer via
 a self-photoreduction strategy for enhanced visible light driven
 photocatalysis
;
_journal_issue                   31
_journal_name_full               CrystEngComm
_journal_page_first              5397
_journal_page_last               5402
_journal_paper_doi               10.1039/D1CE00699A
_journal_volume                  23
_journal_year                    2021
_chemical_formula_sum            'C32 H30 Ag2 N7 O8.5'
_chemical_formula_weight         864.37
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2021-04-25 deposited with the CCDC.	2021-06-29 downloaded from the CCDC.
;
_cell_angle_alpha                100.520(5)
_cell_angle_beta                 109.121(5)
_cell_angle_gamma                97.132(5)
_cell_formula_units_Z            2
_cell_length_a                   11.388(3)
_cell_length_b                   12.621(3)
_cell_length_c                   14.493(4)
_cell_measurement_reflns_used    1173
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      19.85
_cell_measurement_theta_min      2.59
_cell_volume                     1896.7(9)
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0509
_diffrn_reflns_av_unetI/netI     0.1239
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.986
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            13005
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.986
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.152
_diffrn_reflns_theta_min         1.531
_exptl_absorpt_coefficient_mu    1.088
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.513
_exptl_crystal_description       block
_exptl_crystal_F_000             866
_refine_diff_density_max         0.691
_refine_diff_density_min         -0.729
_refine_diff_density_rms         0.102
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.847
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     370
_refine_ls_number_reflns         8311
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.847
_refine_ls_R_factor_all          0.1081
_refine_ls_R_factor_gt           0.0518
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0339P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1002
_refine_ls_wR_factor_ref         0.1149
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4088
_reflns_number_total             8311
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1ce00699a2.cif
_cod_data_source_block           shelx
_cod_depositor_comments          'Adding full bibliography for 7243135.cif.'
_cod_original_cell_volume        1896.8(8)
_cod_original_formula_sum        'C32 H30 Ag2 N7 O8.50'
_cod_database_code               7243135
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_platon_squeeze_void_probe_radius 1.20
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.8166(5) 0.3590(4) 0.0739(4) 0.0364(13) Uani 1 1 d . . . . .
H1 H 0.8378 0.2942 0.0479 0.044 Uiso 1 1 calc R U . . .
C2 C 0.8704(5) 0.5436(4) 0.1439(4) 0.0333(13) Uani 1 1 d . . . . .
H2 H 0.9304 0.6088 0.1677 0.040 Uiso 1 1 calc R U . . .
C3 C 0.6986(5) 0.3545(4) 0.0764(4) 0.0388(14) Uani 1 1 d . . . . .
H3 H 0.6415 0.2876 0.0526 0.047 Uiso 1 1 calc R U . . .
C4 C 0.6608(5) 0.4503(4) 0.1149(3) 0.0282(12) Uani 1 1 d . . . . .
C5 C 0.7528(5) 0.5470(4) 0.1485(4) 0.0377(14) Uani 1 1 d . . . . .
H5 H 0.7340 0.6133 0.1738 0.045 Uiso 1 1 calc R U . . .
C6 C 0.5340(5) 0.4504(4) 0.1176(3) 0.0282(12) Uani 1 1 d . . . . .
C7 C 0.4529(6) 0.3544(4) 0.1116(4) 0.0445(15) Uani 1 1 d . . . . .
H7 H 0.4795 0.2876 0.1059 0.053 Uiso 1 1 calc R U . . .
C8 C 0.4857(5) 0.5460(4) 0.1263(3) 0.0339(13) Uani 1 1 d . . . . .
H8 H 0.5354 0.6123 0.1307 0.041 Uiso 1 1 calc R U . . .
C9 C 0.3348(5) 0.3588(5) 0.1144(4) 0.0464(15) Uani 1 1 d . . . . .
H9 H 0.2836 0.2936 0.1105 0.056 Uiso 1 1 calc R U . . .
C10 C 0.3659(5) 0.5443(4) 0.1286(3) 0.0318(12) Uani 1 1 d . . . . .
H10 H 0.3372 0.6102 0.1348 0.038 Uiso 1 1 calc R U . . .
C11 C 0.5235(5) 0.3936(4) 0.3802(4) 0.0428(15) Uani 1 1 d . . . . .
H11 H 0.4740 0.3300 0.3816 0.051 Uiso 1 1 calc R U . . .
C12 C 0.5471(5) 0.5722(4) 0.3772(4) 0.0344(13) Uani 1 1 d . . . . .
H12 H 0.5156 0.6367 0.3773 0.041 Uiso 1 1 calc R U . . .
C13 C 0.6434(5) 0.3901(4) 0.3838(4) 0.0381(13) Uani 1 1 d . . . . .
H13 H 0.6743 0.3258 0.3888 0.046 Uiso 1 1 calc R U . . .
C14 C 0.6697(5) 0.5760(4) 0.3799(4) 0.0334(13) Uani 1 1 d . . . . .
H14 H 0.7184 0.6415 0.3814 0.040 Uiso 1 1 calc R U . . .
C15 C 0.7193(5) 0.4820(4) 0.3802(3) 0.0265(12) Uani 1 1 d . . . . .
C16 C 0.8498(5) 0.4827(4) 0.3766(3) 0.0263(11) Uani 1 1 d . . . . .
C17 C 0.8790(5) 0.3851(4) 0.3346(4) 0.0319(12) Uani 1 1 d . . . . .
H17 H 0.8190 0.3199 0.3111 0.038 Uiso 1 1 calc R U . . .
C18 C 0.9411(5) 0.5772(4) 0.4088(4) 0.0298(12) Uani 1 1 d . . . . .
H18 H 0.9246 0.6436 0.4364 0.036 Uiso 1 1 calc R U . . .
C19 C 0.9981(5) 0.3866(4) 0.3286(4) 0.0378(14) Uani 1 1 d . . . . .
H19 H 1.0178 0.3214 0.3017 0.045 Uiso 1 1 calc R U . . .
C20 C 1.0573(5) 0.5728(4) 0.3999(3) 0.0341(13) Uani 1 1 d . . . . .
H20 H 1.1182 0.6374 0.4221 0.041 Uiso 1 1 calc R U . . .
C21 C 1.3365(5) 0.8752(4) 0.1577(4) 0.0402(14) Uani 1 1 d . . . . .
C22 C 1.2761(5) 0.9164(4) 0.2331(4) 0.0335(12) Uani 1 1 d . . . . .
C23 C 1.2325(5) 0.8497(4) 0.2866(4) 0.0327(12) Uani 1 1 d . . . . .
C24 C 1.2252(6) 0.7259(4) 0.2616(5) 0.0418(14) Uani 1 1 d . . . . .
C25 C 1.1884(6) 0.8931(4) 0.3583(4) 0.0453(15) Uani 1 1 d . . . . .
H25 H 1.1624 0.8483 0.3951 0.054 Uiso 1 1 calc R U . . .
C26 C 1.1813(6) 1.0044(4) 0.3778(4) 0.0480(16) Uani 1 1 d . . . . .
H26 H 1.1512 1.0350 0.4269 0.058 Uiso 1 1 calc R U . . .
C27 C 1.2217(5) 1.0669(4) 0.3203(4) 0.0398(14) Uani 1 1 d . . . . .
C28 C 1.2662(5) 1.0267(4) 0.2500(4) 0.0386(13) Uani 1 1 d . . . . .
H28 H 1.2905 1.0716 0.2126 0.046 Uiso 1 1 calc R U . . .
N1 N 0.9045(4) 0.4511(3) 0.1067(3) 0.0342(11) Uani 1 1 d . . . . .
N2 N 0.2877(4) 0.4513(3) 0.1223(3) 0.0316(10) Uani 1 1 d . . . . .
N3 N 0.4721(4) 0.4826(3) 0.3746(3) 0.0348(11) Uani 1 1 d . . . . .
N4 N 1.0861(4) 0.4803(3) 0.3608(3) 0.0311(10) Uani 1 1 d . . . . .
N5 N 1.2121(5) 1.1853(4) 0.3398(4) 0.0544(14) Uani 1 1 d . . . . .
O1 O 1.4177(4) 0.8168(3) 0.1849(3) 0.0499(10) Uani 1 1 d . . . . .
O2 O 1.3026(4) 0.9021(3) 0.0759(3) 0.0616(12) Uani 1 1 d . . . . .
O3 O 1.1559(4) 0.6739(3) 0.1744(3) 0.0454(10) Uani 1 1 d . . . . .
O4 O 1.2876(4) 0.6863(3) 0.3337(3) 0.0516(11) Uani 1 1 d . . . . .
O5 O 1.1909(5) 1.2253(3) 0.4156(3) 0.0708(14) Uani 1 1 d . . . . .
O6 O 1.2283(5) 1.2370(3) 0.2806(4) 0.0717(15) Uani 1 1 d . . . . .
Ag1 Ag 1.09865(4) 0.45902(4) 0.11589(3) 0.04730(15) Uani 1 1 d . . . . .
Ag2 Ag 1.27506(4) 0.48588(3) 0.35377(3) 0.04434(15) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 C3 123.6(5) . . ?
N1 C1 H1 118.2 . . ?
C3 C1 H1 118.2 . . ?
N1 C2 C5 123.8(5) . . ?
N1 C2 H2 118.1 . . ?
C5 C2 H2 118.1 . . ?
C1 C3 C4 120.8(5) . . ?
C1 C3 H3 119.6 . . ?
C4 C3 H3 119.6 . . ?
C5 C4 C3 115.5(5) . . ?
C5 C4 C6 121.5(5) . . ?
C3 C4 C6 123.0(5) . . ?
C2 C5 C4 119.7(5) . . ?
C2 C5 H5 120.1 . . ?
C4 C5 H5 120.1 . . ?
C8 C6 C7 115.5(5) . . ?
C8 C6 C4 122.2(5) . . ?
C7 C6 C4 122.3(4) . . ?
C9 C7 C6 120.1(5) . . ?
C9 C7 H7 119.9 . . ?
C6 C7 H7 119.9 . . ?
C10 C8 C6 121.2(5) . . ?
C10 C8 H8 119.4 . . ?
C6 C8 H8 119.4 . . ?
N2 C9 C7 124.4(5) . . ?
N2 C9 H9 117.8 . . ?
C7 C9 H9 117.8 . . ?
N2 C10 C8 123.0(5) . . ?
N2 C10 H10 118.5 . . ?
C8 C10 H10 118.5 . . ?
N3 C11 C13 124.1(5) . . ?
N3 C11 H11 117.9 . . ?
C13 C11 H11 117.9 . . ?
N3 C12 C14 123.8(5) . . ?
N3 C12 H12 118.1 . . ?
C14 C12 H12 118.1 . . ?
C11 C13 C15 119.9(5) . . ?
C11 C13 H13 120.1 . . ?
C15 C13 H13 120.1 . . ?
C15 C14 C12 119.5(5) . . ?
C15 C14 H14 120.2 . . ?
C12 C14 H14 120.2 . . ?
C14 C15 C13 116.5(5) . . ?
C14 C15 C16 120.3(5) . . ?
C13 C15 C16 123.2(4) . . ?
C18 C16 C17 118.0(5) . . ?
C18 C16 C15 122.6(4) . . ?
C17 C16 C15 119.4(4) . . ?
C19 C17 C16 119.3(5) . . ?
C19 C17 H17 120.3 . . ?
C16 C17 H17 120.3 . . ?
C16 C18 C20 119.6(5) . . ?
C16 C18 H18 120.2 . . ?
C20 C18 H18 120.2 . . ?
N4 C19 C17 121.6(5) . . ?
N4 C19 H19 119.2 . . ?
C17 C19 H19 119.2 . . ?
N4 C20 C18 122.8(5) . . ?
N4 C20 H20 118.6 . . ?
C18 C20 H20 118.6 . . ?
O2 C21 O1 126.0(5) . . ?
O2 C21 C22 117.8(5) . . ?
O1 C21 C22 116.2(5) . . ?
C28 C22 C23 119.0(5) . . ?
C28 C22 C21 117.9(5) . . ?
C23 C22 C21 123.1(4) . . ?
C25 C23 C22 120.3(5) . . ?
C25 C23 C24 118.4(5) . . ?
C22 C23 C24 121.2(4) . . ?
O3 C24 O4 127.3(5) . . ?
O3 C24 C23 116.7(5) . . ?
O4 C24 C23 116.0(5) . . ?
C23 C25 C26 121.0(5) . . ?
C23 C25 H25 119.5 . . ?
C26 C25 H25 119.5 . . ?
C27 C26 C25 116.6(5) . . ?
C27 C26 H26 121.7 . . ?
C25 C26 H26 121.7 . . ?
C28 C27 C26 123.6(5) . . ?
C28 C27 N5 119.7(5) . . ?
C26 C27 N5 116.7(5) . . ?
C27 C28 C22 119.3(5) . . ?
C27 C28 H28 120.4 . . ?
C22 C28 H28 120.4 . . ?
C1 N1 C2 116.5(4) . . ?
C1 N1 Ag1 124.6(3) . . ?
C2 N1 Ag1 118.6(3) . . ?
C9 N2 C10 115.8(4) . . ?
C9 N2 Ag1 125.2(4) . 1_455 ?
C10 N2 Ag1 118.9(3) . 1_455 ?
C12 N3 C11 116.0(5) . . ?
C12 N3 Ag2 119.3(3) . 1_455 ?
C11 N3 Ag2 124.7(4) . 1_455 ?
C20 N4 C19 118.7(4) . . ?
C20 N4 Ag2 118.6(3) . . ?
C19 N4 Ag2 122.7(3) . . ?
O6 N5 O5 123.9(5) . . ?
O6 N5 C27 117.6(5) . . ?
O5 N5 C27 118.5(5) . . ?
C24 O4 Ag2 130.9(4) . . ?
N2 Ag1 N1 174.92(16) 1_655 . ?
N2 Ag1 Ag2 72.62(10) 1_655 . ?
N1 Ag1 Ag2 107.64(11) . . ?
N3 Ag2 N4 168.83(15) 1_655 . ?
N3 Ag2 O4 95.28(14) 1_655 . ?
N4 Ag2 O4 91.00(14) . . ?
N3 Ag2 Ag1 112.36(11) 1_655 . ?
N4 Ag2 Ag1 78.10(11) . . ?
O4 Ag2 Ag1 76.20(9) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.333(6) . ?
C1 C3 1.351(7) . ?
C1 H1 0.9300 . ?
C2 N1 1.351(6) . ?
C2 C5 1.369(7) . ?
C2 H2 0.9300 . ?
C3 C4 1.413(6) . ?
C3 H3 0.9300 . ?
C4 C5 1.398(7) . ?
C4 C6 1.457(6) . ?
C5 H5 0.9300 . ?
C6 C8 1.388(6) . ?
C6 C7 1.400(7) . ?
C7 C9 1.366(7) . ?
C7 H7 0.9300 . ?
C8 C10 1.374(7) . ?
C8 H8 0.9300 . ?
C9 N2 1.345(6) . ?
C9 H9 0.9300 . ?
C10 N2 1.351(6) . ?
C10 H10 0.9300 . ?
C11 N3 1.332(6) . ?
C11 C13 1.355(7) . ?
C11 H11 0.9300 . ?
C12 N3 1.317(6) . ?
C12 C14 1.378(7) . ?
C12 H12 0.9300 . ?
C13 C15 1.378(7) . ?
C13 H13 0.9300 . ?
C14 C15 1.375(6) . ?
C14 H14 0.9300 . ?
C15 C16 1.503(6) . ?
C16 C18 1.376(6) . ?
C16 C17 1.400(6) . ?
C17 C19 1.386(7) . ?
C17 H17 0.9300 . ?
C18 C20 1.378(6) . ?
C18 H18 0.9300 . ?
C19 N4 1.349(6) . ?
C19 H19 0.9300 . ?
C20 N4 1.329(6) . ?
C20 H20 0.9300 . ?
C21 O2 1.245(6) . ?
C21 O1 1.261(6) . ?
C21 C22 1.520(7) . ?
C22 C28 1.393(6) . ?
C22 C23 1.394(6) . ?
C23 C25 1.355(6) . ?
C23 C24 1.524(7) . ?
C24 O3 1.251(6) . ?
C24 O4 1.280(6) . ?
C25 C26 1.399(7) . ?
C25 H25 0.9300 . ?
C26 C27 1.390(7) . ?
C26 H26 0.9300 . ?
C27 C28 1.328(7) . ?
C27 N5 1.493(6) . ?
C28 H28 0.9300 . ?
N1 Ag1 2.159(4) . ?
N2 Ag1 2.139(4) 1_455 ?
N3 Ag2 2.170(4) 1_455 ?
N4 Ag2 2.180(4) . ?
N5 O6 1.214(6) . ?
N5 O5 1.234(6) . ?
O4 Ag2 2.591(4) . ?
Ag1 N2 2.140(4) 1_655 ?
Ag1 Ag2 3.3022(10) . ?
Ag2 N3 2.170(4) 1_655 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C1 C3 C4 0.2(8) . . . . ?
C1 C3 C4 C5 0.4(7) . . . . ?
C1 C3 C4 C6 178.8(5) . . . . ?
N1 C2 C5 C4 1.1(8) . . . . ?
C3 C4 C5 C2 -0.9(7) . . . . ?
C6 C4 C5 C2 -179.4(4) . . . . ?
C5 C4 C6 C8 18.1(7) . . . . ?
C3 C4 C6 C8 -160.2(5) . . . . ?
C5 C4 C6 C7 -161.8(5) . . . . ?
C3 C4 C6 C7 19.9(7) . . . . ?
C8 C6 C7 C9 0.2(8) . . . . ?
C4 C6 C7 C9 -179.9(5) . . . . ?
C7 C6 C8 C10 -0.2(7) . . . . ?
C4 C6 C8 C10 180.0(4) . . . . ?
C6 C7 C9 N2 0.2(9) . . . . ?
C6 C8 C10 N2 -0.2(8) . . . . ?
N3 C11 C13 C15 -1.1(8) . . . . ?
N3 C12 C14 C15 -0.2(8) . . . . ?
C12 C14 C15 C13 -3.7(7) . . . . ?
C12 C14 C15 C16 176.2(4) . . . . ?
C11 C13 C15 C14 4.3(7) . . . . ?
C11 C13 C15 C16 -175.6(5) . . . . ?
C14 C15 C16 C18 24.2(7) . . . . ?
C13 C15 C16 C18 -155.9(5) . . . . ?
C14 C15 C16 C17 -152.6(5) . . . . ?
C13 C15 C16 C17 27.3(7) . . . . ?
C18 C16 C17 C19 1.1(7) . . . . ?
C15 C16 C17 C19 178.0(4) . . . . ?
C17 C16 C18 C20 -0.7(7) . . . . ?
C15 C16 C18 C20 -177.5(4) . . . . ?
C16 C17 C19 N4 -1.0(7) . . . . ?
C16 C18 C20 N4 0.1(8) . . . . ?
O2 C21 C22 C28 -45.6(7) . . . . ?
O1 C21 C22 C28 134.0(5) . . . . ?
O2 C21 C22 C23 135.4(6) . . . . ?
O1 C21 C22 C23 -45.0(7) . . . . ?
C28 C22 C23 C25 -4.1(8) . . . . ?
C21 C22 C23 C25 174.9(5) . . . . ?
C28 C22 C23 C24 172.1(5) . . . . ?
C21 C22 C23 C24 -9.0(8) . . . . ?
C25 C23 C24 O3 116.3(6) . . . . ?
C22 C23 C24 O3 -59.9(7) . . . . ?
C25 C23 C24 O4 -61.3(7) . . . . ?
C22 C23 C24 O4 122.5(6) . . . . ?
C22 C23 C25 C26 2.3(9) . . . . ?
C24 C23 C25 C26 -173.9(5) . . . . ?
C23 C25 C26 C27 -0.1(9) . . . . ?
C25 C26 C27 C28 -0.5(9) . . . . ?
C25 C26 C27 N5 179.0(5) . . . . ?
C26 C27 C28 C22 -1.3(9) . . . . ?
N5 C27 C28 C22 179.3(5) . . . . ?
C23 C22 C28 C27 3.5(8) . . . . ?
C21 C22 C28 C27 -175.5(5) . . . . ?
C3 C1 N1 C2 -0.1(8) . . . . ?
C3 C1 N1 Ag1 174.4(4) . . . . ?
C5 C2 N1 C1 -0.5(7) . . . . ?
C5 C2 N1 Ag1 -175.4(4) . . . . ?
C7 C9 N2 C10 -0.5(8) . . . . ?
C7 C9 N2 Ag1 175.2(4) . . . 1_455 ?
C8 C10 N2 C9 0.6(7) . . . . ?
C8 C10 N2 Ag1 -175.5(4) . . . 1_455 ?
C14 C12 N3 C11 3.5(8) . . . . ?
C14 C12 N3 Ag2 -173.2(4) . . . 1_455 ?
C13 C11 N3 C12 -2.9(8) . . . . ?
C13 C11 N3 Ag2 173.6(4) . . . 1_455 ?
C18 C20 N4 C19 0.0(7) . . . . ?
C18 C20 N4 Ag2 -179.1(4) . . . . ?
C17 C19 N4 C20 0.5(7) . . . . ?
C17 C19 N4 Ag2 179.5(3) . . . . ?
C28 C27 N5 O6 10.5(8) . . . . ?
C26 C27 N5 O6 -169.0(5) . . . . ?
C28 C27 N5 O5 -168.1(5) . . . . ?
C26 C27 N5 O5 12.4(8) . . . . ?
O3 C24 O4 Ag2 -13.1(8) . . . . ?
C23 C24 O4 Ag2 164.2(3) . . . . ?
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 -0.020 0.000 0.010 723 225 ' '
