#------------------------------------------------------------------------------
#$Date: 2021-09-06 13:27:43 +0300 (Mon, 06 Sep 2021) $
#$Revision: 268665 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/31/7243185.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7243185
loop_
_publ_author_name
'Breton, Logan S.'
'Smith, Mark D.'
'zur Loye, Hans-Conrad'
_publ_section_title
;
 Trends in rare earth thiophosphate syntheses: Rb3Ln(PS4)2 (Ln = La, Ce,
 Pr), Rb3−xNaxLn(PS4)2 (Ln = Ce, Pr; x = 0.50, 0.55), and RbEuPS4
 obtained by molten flux crystal growth
;
_journal_issue                   30
_journal_name_full               CrystEngComm
_journal_page_first              5241
_journal_page_last               5248
_journal_paper_doi               10.1039/D1CE00703C
_journal_volume                  23
_journal_year                    2021
_chemical_formula_moiety         '0.25(Eu4 P4 Rb4 S16)'
_chemical_formula_sum            'Eu P Rb S4'
_chemical_formula_weight         396.64
_chemical_properties_physical    Air-sensitive,Moisture-sensitive
_space_group_crystal_system      orthorhombic
_space_group_IT_number           62
_space_group_name_Hall           '-P 2ac 2n'
_space_group_name_H-M_alt        'P n m a'
_atom_sites_solution_primary     dual
_audit_creation_date             2021-05-17
_audit_creation_method
;
Olex2 1.2
(compiled May 18 2018 14:05:52 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2021-05-19 deposited with the CCDC.	2021-07-05 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   17.3308(4)
_cell_length_b                   6.6787(2)
_cell_length_c                   6.43470(10)
_cell_measurement_reflns_used    8916
_cell_measurement_temperature    301(2)
_cell_measurement_theta_max      36.22
_cell_measurement_theta_min      3.38
_cell_volume                     744.80(3)
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      301(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0306
_diffrn_reflns_av_unetI/netI     0.0154
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_number            12334
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.992
_diffrn_reflns_theta_min         3.377
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    16.132
_exptl_absorpt_correction_T_max  0.2740
_exptl_absorpt_correction_T_min  0.1919
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2016/2 (Bruker,2016) was used for absorption correction.
wR2(int) was 0.1122 before and 0.0516 after correction.
The Ratio of minimum to maximum transmission is 0.7004.
The λ/2 correction factor is Not present.
;
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    3.537
_exptl_crystal_description       plate
_exptl_crystal_F_000             716
_exptl_crystal_size_max          0.05
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.01
_refine_diff_density_max         1.177
_refine_diff_density_min         -0.995
_refine_diff_density_rms         0.167
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.171
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     43
_refine_ls_number_reflns         1170
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.171
_refine_ls_R_factor_all          0.0263
_refine_ls_R_factor_gt           0.0247
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0236P)²+4.3127P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0638
_refine_ls_wR_factor_ref         0.0647
_reflns_Friedel_coverage         0.000
_reflns_number_gt                1120
_reflns_number_total             1170
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1ce00703c2.cif
_cod_data_source_block           lb2017a_longscan
_cod_depositor_comments
'Adding full bibliography for 7243182--7243187.cif.'
_cod_database_code               7243185
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.855
_shelx_estimated_absorpt_t_min   0.499
_olex2_refinement_description
;
1. Uiso/Uaniso restraints and constraints
Uanis(Rb1A) = Uanis(Rb1B)
2. Others
 Sof(Rb1B)=0.5*(1-FVAR(2))
 Sof(Rb1A)=0.5*FVAR(2)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.51920(2) 0.250000 0.20500(5) 0.02405(10) Uani 1 2 d S T P . .
Rb1B Rb 0.29096(13) 0.250000 0.5015(10) 0.0334(6) Uani 0.739(17) 2 d S T P . .
P1 P 0.59651(8) 0.250000 0.7217(2) 0.0167(3) Uani 1 2 d S T P . .
S1 S 0.66161(8) 0.250000 0.4612(2) 0.0246(3) Uani 1 2 d S T P . .
S2 S 0.61878(6) 0.49552(14) 0.89933(17) 0.0244(2) Uani 1 1 d . . . . .
S3 S 0.48073(8) 0.250000 0.6593(3) 0.0308(3) Uani 1 2 d S T P . .
Rb1A Rb 0.2922(4) 0.250000 0.5627(16) 0.0334(6) Uani 0.261(17) 2 d S T P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rb Rb -0.9393 2.9676 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Eu1 Eu1 Eu1 101.653(13) 5_655 5_665 ?
P1 Eu1 Eu1 59.912(13) 1_554 5_655 ?
P1 Eu1 Eu1 128.744(7) . 5_655 ?
P1 Eu1 Eu1 128.744(7) . 5_665 ?
P1 Eu1 Eu1 59.912(13) 1_554 5_665 ?
P1 Eu1 P1 134.75(4) 1_554 . ?
P1 Eu1 S3 103.42(3) 1_554 5_656 ?
P1 Eu1 S3 103.42(3) 1_554 5_666 ?
S1 Eu1 Eu1 117.949(16) . 5_665 ?
S1 Eu1 Eu1 117.949(16) . 5_655 ?
S1 Eu1 P1 34.31(4) . . ?
S1 Eu1 P1 100.43(4) . 1_554 ?
S1 Eu1 S2 141.69(2) . 3_646 ?
S1 Eu1 S2 83.63(3) . 7_564 ?
S1 Eu1 S2 141.69(2) . 5_666 ?
S1 Eu1 S2 83.63(3) . 1_554 ?
S1 Eu1 S3 81.91(3) . 5_666 ?
S1 Eu1 S3 69.11(4) . . ?
S1 Eu1 S3 81.91(3) . 5_656 ?
S2 Eu1 Eu1 96.19(2) 1_554 5_655 ?
S2 Eu1 Eu1 44.32(2) 7_564 5_655 ?
S2 Eu1 Eu1 45.80(2) 5_666 5_665 ?
S2 Eu1 Eu1 44.32(2) 1_554 5_665 ?
S2 Eu1 Eu1 96.19(2) 7_564 5_665 ?
S2 Eu1 Eu1 100.28(2) 3_646 5_665 ?
S2 Eu1 Eu1 45.80(2) 3_646 5_655 ?
S2 Eu1 Eu1 100.28(2) 5_666 5_655 ?
S2 Eu1 P1 36.28(2) 1_554 1_554 ?
S2 Eu1 P1 120.25(3) 3_646 . ?
S2 Eu1 P1 112.45(3) 7_564 . ?
S2 Eu1 P1 96.29(3) 3_646 1_554 ?
S2 Eu1 P1 112.45(3) 1_554 . ?
S2 Eu1 P1 36.28(2) 7_564 1_554 ?
S2 Eu1 P1 120.25(3) 5_666 . ?
S2 Eu1 P1 96.29(3) 5_666 1_554 ?
S2 Eu1 S2 90.12(3) 3_646 7_564 ?
S2 Eu1 S2 68.77(4) 3_646 5_666 ?
S2 Eu1 S2 127.002(18) 5_666 7_564 ?
S2 Eu1 S2 127.002(18) 3_646 1_554 ?
S2 Eu1 S2 64.15(4) 7_564 1_554 ?
S2 Eu1 S2 90.12(3) 5_666 1_554 ?
S2 Eu1 S3 69.34(3) 1_554 5_666 ?
S2 Eu1 S3 132.43(3) 7_564 5_666 ?
S2 Eu1 S3 60.68(3) 3_646 5_656 ?
S2 Eu1 S3 132.43(3) 1_554 5_656 ?
S2 Eu1 S3 60.68(3) 5_666 5_666 ?
S2 Eu1 S3 127.09(3) 5_666 5_656 ?
S2 Eu1 S3 127.09(3) 3_646 5_666 ?
S2 Eu1 S3 69.34(3) 7_564 5_656 ?
S3 Eu1 Eu1 124.247(12) . 5_655 ?
S3 Eu1 Eu1 154.82(3) 5_656 5_665 ?
S3 Eu1 Eu1 53.48(3) 5_666 5_665 ?
S3 Eu1 Eu1 154.82(3) 5_666 5_655 ?
S3 Eu1 Eu1 124.247(12) . 5_665 ?
S3 Eu1 Eu1 53.48(3) 5_656 5_655 ?
S3 Eu1 P1 34.80(4) . . ?
S3 Eu1 P1 76.42(3) 5_656 . ?
S3 Eu1 P1 169.54(4) . 1_554 ?
S3 Eu1 P1 76.42(3) 5_666 . ?
S3 Eu1 S2 138.18(3) . 1_554 ?
S3 Eu1 S2 138.18(3) . 7_564 ?
S3 Eu1 S2 92.34(3) . 5_666 ?
S3 Eu1 S2 92.34(3) . 3_646 ?
S3 Eu1 S3 75.73(3) . 5_656 ?
S3 Eu1 S3 150.70(6) 5_666 5_656 ?
S3 Eu1 S3 75.73(3) . 5_666 ?
Eu1 Rb1B Rb1A 90.88(9) . 2_564 ?
Eu1 Rb1B Rb1A 90.88(9) . 2_554 ?
P1 Rb1B Eu1 177.89(17) 6_557 . ?
P1 Rb1B Rb1A 90.57(11) 6_557 2_554 ?
P1 Rb1B Rb1A 90.57(11) 6_557 2_564 ?
S1 Rb1B Eu1 79.37(5) 5_666 . ?
S1 Rb1B Eu1 101.23(13) 6_556 . ?
S1 Rb1B Eu1 79.37(5) 5_656 . ?
S1 Rb1B P1 100.27(7) 5_666 6_557 ?
S1 Rb1B P1 100.27(7) 5_656 6_557 ?
S1 Rb1B P1 80.88(6) 6_556 6_557 ?
S1 Rb1B S1 101.48(10) 5_656 6_556 ?
S1 Rb1B S1 101.48(10) 5_666 6_556 ?
S1 Rb1B S1 151.23(11) 5_666 5_656 ?
S1 Rb1B S2 57.91(5) 5_656 3_646 ?
S1 Rb1B S2 114.81(12) 5_666 3_646 ?
S1 Rb1B S2 74.58(4) 5_656 4_456 ?
S1 Rb1B S2 114.81(12) 5_656 5_666 ?
S1 Rb1B S2 130.62(8) 5_656 6_557 ?
S1 Rb1B S2 130.62(8) 5_666 4_456 ?
S1 Rb1B S2 74.58(4) 5_666 6_557 ?
S1 Rb1B S2 57.91(5) 5_666 5_666 ?
S1 Rb1B Rb1A 54.18(12) 5_656 2_554 ?
S1 Rb1B Rb1A 47.30(5) 6_556 2_564 ?
S1 Rb1B Rb1A 145.07(11) 5_656 2_564 ?
S1 Rb1B Rb1A 47.30(5) 6_556 2_554 ?
S1 Rb1B Rb1A 54.18(12) 5_666 2_564 ?
S1 Rb1B Rb1A 145.07(11) 5_666 2_554 ?
S2 Rb1B Eu1 43.07(4) 3_646 . ?
S2 Rb1B Eu1 148.86(9) 6_557 . ?
S2 Rb1B Eu1 148.86(9) 4_456 . ?
S2 Rb1B Eu1 43.07(4) 5_666 . ?
S2 Rb1B P1 138.38(9) 5_666 6_557 ?
S2 Rb1B P1 32.04(3) 6_557 6_557 ?
S2 Rb1B P1 32.04(3) 4_456 6_557 ?
S2 Rb1B P1 138.38(9) 3_646 6_557 ?
S2 Rb1B S1 68.23(7) 4_456 6_556 ?
S2 Rb1B S1 71.14(12) 3_646 6_556 ?
S2 Rb1B S1 68.23(7) 6_557 6_556 ?
S2 Rb1B S1 71.14(12) 5_666 6_556 ?
S2 Rb1B S2 56.50(5) 4_456 6_557 ?
S2 Rb1B S2 139.36(18) 3_646 6_557 ?
S2 Rb1B S2 139.36(18) 5_666 4_456 ?
S2 Rb1B S2 107.10(9) 5_666 6_557 ?
S2 Rb1B S2 58.80(9) 3_646 5_666 ?
S2 Rb1B S2 107.10(9) 3_646 4_456 ?
S2 Rb1B Rb1A 92.32(9) 3_646 2_564 ?
S2 Rb1B Rb1A 47.82(10) 3_646 2_554 ?
S2 Rb1B Rb1A 60.01(13) 6_557 2_564 ?
S2 Rb1B Rb1A 47.82(10) 5_666 2_564 ?
S2 Rb1B Rb1A 100.77(9) 4_456 2_564 ?
S2 Rb1B Rb1A 60.01(13) 4_456 2_554 ?
S2 Rb1B Rb1A 92.32(9) 5_666 2_554 ?
S2 Rb1B Rb1A 100.77(9) 6_557 2_554 ?
S3 Rb1B Eu1 42.91(4) . . ?
S3 Rb1B P1 134.98(19) . 6_557 ?
S3 Rb1B S1 144.14(16) . 6_556 ?
S3 Rb1B S1 75.62(6) . 5_666 ?
S3 Rb1B S1 75.62(6) . 5_656 ?
S3 Rb1B S2 140.23(14) . 4_456 ?
S3 Rb1B S2 77.77(6) . 3_646 ?
S3 Rb1B S2 140.23(14) . 6_557 ?
S3 Rb1B S2 77.77(6) . 5_666 ?
S3 Rb1B Rb1A 118.68(8) . 2_564 ?
S3 Rb1B Rb1A 118.68(8) . 2_554 ?
Rb1A Rb1B Rb1A 92.98(10) 2_554 2_564 ?
Eu1 P1 Eu1 134.75(4) 1_556 . ?
Eu1 P1 Rb1B 139.80(10) . 6_657 ?
Eu1 P1 Rb1B 85.45(9) 1_556 6_657 ?
Eu1 P1 Rb1A 134.20(17) . 6_657 ?
Eu1 P1 Rb1A 91.06(16) 1_556 6_657 ?
S1 P1 Eu1 169.37(8) . 1_556 ?
S1 P1 Eu1 55.88(6) . . ?
S1 P1 Rb1B 83.92(11) . 6_657 ?
S1 P1 S2 111.09(6) . . ?
S1 P1 S2 111.09(6) . 7_565 ?
S1 P1 S3 112.62(9) . . ?
S1 P1 Rb1A 78.31(17) . 6_657 ?
S2 P1 Eu1 63.86(5) 7_565 1_556 ?
S2 P1 Eu1 63.86(5) . 1_556 ?
S2 P1 Eu1 126.27(4) . . ?
S2 P1 Eu1 126.27(4) 7_565 . ?
S2 P1 Rb1B 64.54(6) . 6_657 ?
S2 P1 Rb1B 64.54(6) 7_565 6_657 ?
S2 P1 S2 107.33(9) . 7_565 ?
S2 P1 S3 107.22(6) 7_565 . ?
S2 P1 S3 107.22(6) . . ?
S2 P1 Rb1A 67.17(9) 7_565 6_657 ?
S2 P1 Rb1A 67.17(9) . 6_657 ?
S3 P1 Eu1 78.01(6) . 1_556 ?
S3 P1 Eu1 56.74(6) . . ?
S3 P1 Rb1B 163.46(12) . 6_657 ?
S3 P1 Rb1A 169.07(18) . 6_657 ?
Rb1A P1 Rb1B 5.60(12) 6_657 6_657 ?
Eu1 S1 Rb1B 103.71(8) . 5_666 ?
Eu1 S1 Rb1B 93.24(7) . 6_656 ?
Eu1 S1 Rb1B 103.71(8) . 5_656 ?
Eu1 S1 Rb1A 99.73(15) . 5_666 ?
Eu1 S1 Rb1A 99.73(15) . 5_656 ?
Eu1 S1 Rb1A 160.18(15) . 6_657 ?
Rb1B S1 Rb1B 151.23(11) 5_666 5_656 ?
Rb1B S1 Rb1B 84.97(7) 5_656 6_656 ?
Rb1B S1 Rb1B 84.97(7) 5_666 6_656 ?
Rb1B S1 Rb1A 78.60(9) 5_656 6_657 ?
Rb1B S1 Rb1A 78.60(9) 5_666 6_657 ?
Rb1B S1 Rb1A 106.58(10) 6_656 6_657 ?
P1 S1 Eu1 89.80(6) . . ?
P1 S1 Rb1B 94.32(9) . 5_656 ?
P1 S1 Rb1B 94.32(9) . 5_666 ?
P1 S1 Rb1B 176.96(10) . 6_656 ?
P1 S1 Rb1A 99.62(15) . 5_656 ?
P1 S1 Rb1A 99.62(15) . 5_666 ?
P1 S1 Rb1A 70.38(15) . 6_657 ?
Rb1A S1 Rb1B 6.56(11) 5_666 5_666 ?
Rb1A S1 Rb1B 79.87(14) 5_656 6_656 ?
Rb1A S1 Rb1B 152.69(11) 5_666 5_656 ?
Rb1A S1 Rb1B 152.69(11) 5_656 5_666 ?
Rb1A S1 Rb1B 6.56(11) 5_656 5_656 ?
Rb1A S1 Rb1B 79.87(14) 5_666 6_656 ?
Rb1A S1 Rb1A 84.11(14) 5_656 6_657 ?
Rb1A S1 Rb1A 152.5(2) 5_666 5_656 ?
Rb1A S1 Rb1A 84.11(14) 5_666 6_657 ?
Eu1 S2 Eu1 89.88(3) 5_666 1_556 ?
Eu1 S2 Rb1B 173.14(6) 5_666 6_657 ?
Eu1 S2 Rb1B 96.47(8) 1_556 6_657 ?
Eu1 S2 Rb1B 85.16(5) 5_666 5_666 ?
Eu1 S2 Rb1B 170.98(9) 1_556 5_666 ?
Eu1 S2 Rb1A 168.94(15) 5_666 6_657 ?
Eu1 S2 Rb1A 83.94(11) 5_666 5_666 ?
Eu1 S2 Rb1A 166.92(14) 1_556 5_666 ?
Eu1 S2 Rb1A 100.96(13) 1_556 6_657 ?
Rb1B S2 Rb1B 88.88(6) 5_666 6_657 ?
Rb1B S2 Rb1A 90.34(13) 6_657 5_666 ?
Rb1B S2 Rb1A 4.18(11) 5_666 5_666 ?
P1 S2 Eu1 79.86(5) . 1_556 ?
P1 S2 Eu1 100.31(5) . 5_666 ?
P1 S2 Rb1B 93.61(8) . 5_666 ?
P1 S2 Rb1B 83.42(8) . 6_657 ?
P1 S2 Rb1A 89.89(11) . 5_666 ?
P1 S2 Rb1A 79.70(11) . 6_657 ?
Rb1A S2 Rb1B 6.53(11) 6_657 6_657 ?
Rb1A S2 Rb1B 83.80(14) 6_657 5_666 ?
Rb1A S2 Rb1A 85.00(12) 6_657 5_666 ?
Eu1 S3 Eu1 150.70(6) 5_666 5_656 ?
Eu1 S3 Eu1 104.27(3) . 5_656 ?
Eu1 S3 Eu1 104.27(3) . 5_666 ?
Eu1 S3 Rb1B 85.69(11) . . ?
Eu1 S3 Rb1A 92.07(18) . . ?
Rb1B S3 Eu1 94.30(4) . 5_656 ?
Rb1B S3 Eu1 94.30(4) . 5_666 ?
P1 S3 Eu1 87.14(3) . 5_656 ?
P1 S3 Eu1 87.14(3) . 5_666 ?
P1 S3 Eu1 88.47(6) . . ?
P1 S3 Rb1B 174.15(13) . . ?
P1 S3 Rb1A 179.46(19) . . ?
Rb1A S3 Eu1 92.73(5) . 5_666 ?
Rb1A S3 Eu1 92.73(5) . 5_656 ?
Rb1A S3 Rb1B 6.39(11) . . ?
Eu1 Rb1A Rb1B 125.43(10) . 2_565 ?
Eu1 Rb1A Rb1B 125.43(10) . 2 ?
Rb1B Rb1A Rb1B 92.98(10) 2_565 2 ?
P1 Rb1A Eu1 171.9(3) 6_557 . ?
P1 Rb1A Rb1B 58.55(8) 6_557 2 ?
P1 Rb1A Rb1B 58.55(8) 6_557 2_565 ?
P1 Rb1A S1 31.31(8) 6_557 6_557 ?
P1 Rb1A S2 132.8(2) 6_557 5_666 ?
P1 Rb1A S2 132.8(2) 6_557 3_646 ?
S1 Rb1A Eu1 77.07(13) 5_656 . ?
S1 Rb1A Eu1 77.07(13) 5_666 . ?
S1 Rb1A Eu1 156.8(3) 6_557 . ?
S1 Rb1A Rb1B 52.82(11) 5_656 2 ?
S1 Rb1A Rb1B 143.6(2) 5_666 2 ?
S1 Rb1A Rb1B 47.22(5) 6_557 2_565 ?
S1 Rb1A Rb1B 143.6(2) 5_656 2_565 ?
S1 Rb1A Rb1B 47.22(5) 6_557 2 ?
S1 Rb1A Rb1B 52.82(12) 5_666 2_565 ?
S1 Rb1A P1 103.45(13) 5_656 6_557 ?
S1 Rb1A P1 103.45(13) 5_666 6_557 ?
S1 Rb1A S1 100.04(16) 5_656 6_557 ?
S1 Rb1A S1 100.04(16) 5_666 6_557 ?
S1 Rb1A S1 152.5(2) 5_666 5_656 ?
S1 Rb1A S2 108.0(2) 5_666 3_646 ?
S1 Rb1A S2 108.0(2) 5_656 5_666 ?
S1 Rb1A S2 55.20(9) 5_656 3_646 ?
S1 Rb1A S2 55.20(9) 5_666 5_666 ?
S2 Rb1A Eu1 41.04(8) 5_666 . ?
S2 Rb1A Eu1 142.4(2) 4_456 . ?
S2 Rb1A Eu1 41.04(8) 3_646 . ?
S2 Rb1A Eu1 142.4(2) 6_557 . ?
S2 Rb1A Rb1B 91.66(14) 6_557 2 ?
S2 Rb1A Rb1B 106.60(4) 3_646 2 ?
S2 Rb1A Rb1B 160.41(11) 3_646 2_565 ?
S2 Rb1A Rb1B 106.60(4) 5_666 2_565 ?
S2 Rb1A Rb1B 48.38(10) 4_456 2 ?
S2 Rb1A Rb1B 160.41(11) 5_666 2 ?
S2 Rb1A Rb1B 91.66(14) 4_456 2_565 ?
S2 Rb1A Rb1B 48.38(10) 6_557 2_565 ?
S2 Rb1A P1 33.14(7) 4_456 6_557 ?
S2 Rb1A P1 33.14(7) 6_557 6_557 ?
S2 Rb1A S1 54.73(12) 4_456 6_557 ?
S2 Rb1A S1 132.18(19) 4_456 5_666 ?
S2 Rb1A S1 151.74(9) 5_666 6_557 ?
S2 Rb1A S1 54.73(12) 6_557 6_557 ?
S2 Rb1A S1 151.74(9) 3_646 6_557 ?
S2 Rb1A S1 75.11(7) 6_557 5_666 ?
S2 Rb1A S1 132.18(19) 6_557 5_656 ?
S2 Rb1A S1 75.11(7) 4_456 5_656 ?
S2 Rb1A S2 101.54(17) 6_557 5_666 ?
S2 Rb1A S2 53.81(13) 3_646 5_666 ?
S2 Rb1A S2 129.2(3) 6_557 3_646 ?
S2 Rb1A S2 57.09(12) 4_456 6_557 ?
S2 Rb1A S2 101.54(17) 4_456 3_646 ?
S2 Rb1A S2 129.2(3) 4_456 5_666 ?
S3 Rb1A Eu1 41.10(9) . . ?
S3 Rb1A Rb1B 101.11(16) . 2 ?
S3 Rb1A Rb1B 101.11(16) . 2_565 ?
S3 Rb1A P1 147.0(3) . 6_557 ?
S3 Rb1A S1 77.25(13) . 5_656 ?
S3 Rb1A S1 77.25(13) . 5_666 ?
S3 Rb1A S1 115.7(3) . 6_557 ?
S3 Rb1A S2 75.18(15) . 3_646 ?
S3 Rb1A S2 147.87(17) . 4_456 ?
S3 Rb1A S2 75.18(15) . 5_666 ?
S3 Rb1A S2 147.87(17) . 6_557 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 Eu1 4.3075(4) 5_665 ?
Eu1 Eu1 4.3075(4) 5_655 ?
Eu1 P1 3.3860(14) 1_554 ?
Eu1 P1 3.5848(15) . ?
Eu1 S1 2.9679(16) . ?
Eu1 S2 3.0880(11) 7_564 ?
Eu1 S2 3.0096(11) 5_666 ?
Eu1 S2 3.0880(11) 1_554 ?
Eu1 S2 3.0096(11) 3_646 ?
Eu1 S3 2.9986(17) . ?
Eu1 S3 3.4516(4) 5_656 ?
Eu1 S3 3.4516(4) 5_666 ?
Rb1B P1 3.812(4) 6_557 ?
Rb1B S1 3.727(6) 6_556 ?
Rb1B S1 3.4474(9) 5_666 ?
Rb1B S1 3.4474(9) 5_656 ?
Rb1B S2 3.464(2) 6_557 ?
Rb1B S2 3.464(2) 4_456 ?
Rb1B S2 3.462(5) 3_646 ?
Rb1B S2 3.462(5) 5_666 ?
Rb1B S3 3.442(3) . ?
Rb1B Rb1A 4.604(4) 2_554 ?
Rb1B Rb1A 4.604(4) 2_564 ?
P1 S1 2.021(2) . ?
P1 S2 2.0356(13) 7_565 ?
P1 S2 2.0356(13) . ?
P1 S3 2.046(2) . ?
P1 Rb1A 3.664(8) 6_657 ?
S1 Rb1A 3.4376(18) 5_656 ?
S1 Rb1A 3.4376(18) 5_666 ?
S1 Rb1A 3.809(9) 6_657 ?
S2 Rb1A 3.432(7) 6_657 ?
S2 Rb1A 3.756(8) 5_666 ?
S3 Rb1A 3.327(8) . ?
