#------------------------------------------------------------------------------
#$Date: 2025-03-04 21:48:03 +0200 (Tue, 04 Mar 2025) $
#$Revision: 298200 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/97/7249780.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7249780
loop_
_publ_author_name
'Wzgarda-Raj, Kinga'
'Rybarczyk-Pirek, Agnieszka J.'
'Palusiak, Marcin'
_publ_section_title
;
 The N--H⋯S hydrogen bonding pattern in trithiocyanuric acid in
 crystalline state: geometric, topological, and energetic analysis of
 trithiocyanuric acid cocrystals
;
_journal_issue                   6
_journal_name_full               CrystEngComm
_journal_page_first              784
_journal_page_last               794
_journal_paper_doi               10.1039/D4CE01153H
_journal_volume                  27
_journal_year                    2025
_chemical_formula_moiety         'C12 H8 N2, 2(C3 H3 N3 S3)'
_chemical_formula_sum            'C18 H14 N8 S6'
_chemical_formula_weight         534.73
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_audit_creation_date             2024-07-13
_audit_creation_method
;
Olex2 1.5
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
_audit_update_record
;
2024-07-13 deposited with the CCDC.	2024-12-27 downloaded from the CCDC.
;
_cell_angle_alpha                81.841(3)
_cell_angle_beta                 81.532(3)
_cell_angle_gamma                63.930(4)
_cell_formula_units_Z            1
_cell_length_a                   6.5124(3)
_cell_length_b                   6.7635(2)
_cell_length_c                   13.9013(5)
_cell_measurement_reflns_used    12148
_cell_measurement_temperature    100.00(10)
_cell_measurement_theta_max      75.7410
_cell_measurement_theta_min      3.2180
_cell_volume                     541.95(4)
_computing_cell_refinement       'CrysAlisPro 1.171.40.78a (Rigaku OD, 2020)'
_computing_data_collection       'CrysAlisPro 1.171.40.78a (Rigaku OD, 2020)'
_computing_data_reduction        'CrysAlisPro 1.171.40.78a (Rigaku OD, 2020)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100.00(10)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω   -119.00 -90.00   0.50    0.42    --  -47.48-125.00 -60.00   58
  2  ω    -62.00  25.00   0.50    0.42    --  -47.48  57.00 120.00  174
  3  ω   -120.00 -35.00   0.50    0.42    --  -47.48 -38.00   0.00  170
  4  ω   -120.00 -35.00   0.50    0.42    --  -47.48 -38.00 -90.00  170
  5  ω     92.00 120.00   0.50    0.42    --   47.48  57.00 120.00   56
  6  ω     -1.00  81.00   0.50    0.42    --   47.48 -99.00-180.00  164
  7  ω    -27.00  12.00   0.50    0.42    --   47.48 -19.00-120.00   78
  8  ω   -163.00 -97.00   0.50    1.68    --  -91.75 -61.00 120.00  132
  9  ω    -75.00 -19.00   0.50    1.68    --  -91.75  61.00   0.00  112
 10  ω   -163.00-104.00   0.50    1.68    --  -91.75 -77.00 150.00  118
 11  ω   -163.00-103.00   0.50    1.68    --  -91.75 -95.00 -90.00  120
 12  ω   -163.00 -97.00   0.50    1.68    --  -91.75 -61.00  30.00  132
 13  ω    -75.00 -19.00   0.50    1.68    --  -91.75  61.00  30.00  112
 14  ω   -163.00-104.00   0.50    1.68    --  -91.75 -77.00   0.00  118
 15  ω    -49.00 -20.00   0.50    1.68    --  -91.75  45.00 -30.00   58
 16  ω    -49.00 -20.00   0.50    1.68    --  -91.75  45.00-120.00   58
 17  ω    -49.00 -20.00   0.50    1.68    --  -91.75  45.00  90.00   58
 18  ω    -49.00 -20.00   0.50    1.68    --  -91.75  45.00 -90.00   58
 19  ω    -85.00 -19.00   0.50    1.68    --  -91.75 125.00  90.00  132
 20  ω    -75.00 -19.00   0.50    1.68    --  -91.75  61.00 120.00  112
 21  ω     33.00 105.00   0.50    1.68    --  105.71 -95.00  30.00  144
 22  ω    104.00 177.00   0.50    1.68    --  105.71  77.00-150.00  146
 23  ω     34.00 111.00   0.50    1.68    --  105.71-125.00-150.00  154
 24  ω     33.00  75.00   0.50    1.68    --  105.71 -61.00-180.00   84
 25  ω     33.00 105.00   0.50    1.68    --  105.71 -95.00 -90.00  144
 26  ω     34.00 111.00   0.50    1.68    --  105.71-125.00 120.00  154
 27  ω     33.00 105.00   0.50    1.68    --  105.71 -95.00 -30.00  144
 28  ω     33.00 105.00   0.50    1.68    --  105.71 -95.00-180.00  144
 29  ω     33.00 106.00   0.50    1.68    --  105.71 -97.00-141.58  146
 30  ω   -120.00 -35.00   0.50    0.42    --  -47.48 -38.00  60.00  170
 31  ω    -12.00  28.00   0.50    0.42    --  -47.48  19.00 -30.00   80
 32  ω   -119.00 -92.00   0.50    0.42    --  -47.48 -57.00-180.00   54
 33  ω   -119.00 -29.00   0.50    0.42    --  -47.48 -67.00-131.00  180
 34  ω     34.00 120.00   0.50    0.42    --   47.48  51.00-151.21  172
 35  ω     35.00 120.00   0.50    0.42    --   47.48  38.00-180.00  170
 36  ω     29.00 120.00   0.50    0.42    --   47.48  67.00   2.00  182
 37  ω   -163.00 -78.00   0.50    1.68    --  -91.75 -51.00 -85.03  170
 38  ω   -163.00 -82.00   0.50    1.68    --  -91.75 -53.00-160.72  162
 39  ω   -163.00 -79.00   0.50    1.68    --  -91.75 -47.00 139.04  168
 40  ω   -163.00 -78.00   0.50    1.68    --  -91.75 -51.00 -71.15  170
 41  ω   -163.00 -79.00   0.50    1.68    --  -91.75 -45.00 -30.00  168
 42  ω   -163.00 -73.00   0.50    1.68    --  -91.75 -67.00-131.00  180
 43  ω   -163.00 -78.00   0.50    1.68    --  -91.75 -52.00  22.51  170
 44  ω   -163.00 -78.00   0.50    1.68    --  -91.75 -52.00-123.82  170
 45  ω   -163.00 -78.00   0.50    1.68    --  -91.75 -48.00  83.67  170
 46  ω   -163.00 -78.00   0.50    1.68    --  -91.75 -49.00  64.90  170
 47  ω   -163.00 -78.00   0.50    1.68    --  -91.75 -52.00 171.08  170
 48  ω   -163.00 -78.00   0.50    1.68    --  -91.75 -50.00  -5.62  170
 49  ω   -163.00 -79.00   0.50    1.68    --  -91.75 -45.00  30.00  168
 50  ω   -163.00 -78.00   0.50    1.68    --  -91.75 -52.00 -94.91  170
 51  ω   -163.00 -86.00   0.50    1.68    --  -91.75 -54.00 160.66  154
 52  ω   -163.00 -79.00   0.50    1.68    --  -91.75 -45.00 -60.00  168
 53  ω   -163.00 -78.00   0.50    1.68    --  -91.75 -52.00 116.79  170
 54  ω   -163.00 -78.00   0.50    1.68    --  -91.75 -52.00  52.38  170
 55  ω    -49.00 -20.00   0.50    1.68    --  -91.75  45.00 150.00   58
 56  ω   -163.00 -78.00   0.50    1.68    --  -91.75 -51.00-149.87  170
 57  ω   -163.00 -79.00   0.50    1.68    --  -91.75 -45.00-180.00  168
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.2228489000
_diffrn_orient_matrix_UB_12      -0.0264485000
_diffrn_orient_matrix_UB_13      0.0372565000
_diffrn_orient_matrix_UB_21      0.1425862000
_diffrn_orient_matrix_UB_22      -0.1612705000
_diffrn_orient_matrix_UB_23      -0.0778915000
_diffrn_orient_matrix_UB_31      0.0005122000
_diffrn_orient_matrix_UB_32      0.1951471000
_diffrn_orient_matrix_UB_33      -0.0720692000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0329
_diffrn_reflns_av_unetI/netI     0.0171
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            15949
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         68.438
_diffrn_reflns_theta_min         3.226
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'PhotonJet (Cu) X-ray Source'
_exptl_absorpt_coefficient_mu    6.058
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.931
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.40.78a (Rigaku Oxford Diffraction, 2020)
Numerical absorption correction based on gaussian integration over
			a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.638
_exptl_crystal_description       block
_exptl_crystal_F_000             274
_exptl_crystal_size_max          0.11
_exptl_crystal_size_mid          0.058
_exptl_crystal_size_min          0.032
_refine_diff_density_max         0.262
_refine_diff_density_min         -0.249
_refine_diff_density_rms         0.050
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.057
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     157
_refine_ls_number_reflns         1997
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.057
_refine_ls_R_factor_all          0.0225
_refine_ls_R_factor_gt           0.0214
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0273P)²+0.3302P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0559
_refine_ls_wR_factor_ref         0.0564
_reflns_Friedel_coverage         0.000
_reflns_number_gt                1915
_reflns_number_total             1997
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d4ce01153h2.cif
_cod_data_source_block           exp_586
_cod_depositor_comments
'Adding full bibliography for 7249780--7249783.cif.'
_cod_database_code               7249780
_shelx_shelxl_version_number     2018/3
_chemical_oxdiff_formula         'C11 H10 N O'
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_reflns_odcompleteness_completeness 99.90
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C13(H13), C16(H16), C14(H14), C15(H15)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.582
_oxdiff_exptl_absorpt_empirical_full_min 0.682
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
S4 S 0.13940(6) 0.71471(6) -0.08766(2) 0.01403(10) Uani 1 1 d . . . . .
S6 S 0.09599(6) 0.43740(6) 0.28583(2) 0.01521(10) Uani 1 1 d . . . . .
S2 S 0.54933(6) 0.92539(6) 0.15530(2) 0.01524(10) Uani 1 1 d . . . . .
N1 N 0.3241(2) 0.67626(19) 0.20892(9) 0.0124(2) Uani 1 1 d . . . . .
N5 N 0.1473(2) 0.5828(2) 0.10175(8) 0.0133(3) Uani 1 1 d . . . . .
N11 N 0.47727(19) 0.57598(19) 0.39996(8) 0.0122(2) Uani 1 1 d . . . . .
N3 N 0.34040(19) 0.7958(2) 0.04485(9) 0.0120(2) Uani 1 1 d . . . . .
C2 C 0.3994(2) 0.7930(2) 0.13592(10) 0.0124(3) Uani 1 1 d . . . . .
C17 C 0.5836(2) 0.3592(2) 0.42875(10) 0.0122(3) Uani 1 1 d . . . . .
C12 C 0.3947(2) 0.7186(2) 0.46985(10) 0.0122(3) Uani 1 1 d . . . . .
C13 C 0.2866(2) 0.9497(2) 0.44253(10) 0.0138(3) Uani 1 1 d . . . . .
H13 H 0.273088 1.001522 0.377060 0.017 Uiso 1 1 calc R U . . .
C16 C 0.3245(2) 0.7982(2) 0.64226(10) 0.0146(3) Uani 1 1 d . . . . .
H16 H 0.335139 0.750953 0.708259 0.018 Uiso 1 1 calc R U . . .
C4 C 0.2114(2) 0.6963(2) 0.02442(10) 0.0121(3) Uani 1 1 d . . . . .
C14 C 0.2031(2) 1.0943(2) 0.51272(11) 0.0150(3) Uani 1 1 d . . . . .
H14 H 0.133162 1.245275 0.494742 0.018 Uiso 1 1 calc R U . . .
C15 C 0.2212(2) 1.0176(2) 0.61343(11) 0.0159(3) Uani 1 1 d . . . . .
H15 H 0.161387 1.119294 0.660206 0.019 Uiso 1 1 calc R U . . .
C6 C 0.1940(2) 0.5689(2) 0.19680(10) 0.0120(3) Uani 1 1 d . . . . .
H3 H 0.374(3) 0.877(3) -0.0016(14) 0.017(4) Uiso 1 1 d . . . . .
H1 H 0.367(3) 0.663(3) 0.2670(16) 0.026(5) Uiso 1 1 d . . . . .
H5 H 0.069(3) 0.518(3) 0.0929(14) 0.023(5) Uiso 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
-1 0 0 0.0212
1 0 0 0.0110
0 1 0 0.0320
0 -1 0 0.0249
0 0 1 0.0425
0 0 -1 0.0530
3 4 2 0.0138
-3 -4 -3 0.0396
1 -2 -6 0.0175
2 4 5 0.0214
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 N1 C6 124.72(12) . . ?
C2 N1 H1 118.0(13) . . ?
C6 N1 H1 117.2(13) . . ?
C4 N5 C6 125.63(12) . . ?
C4 N5 H5 118.7(13) . . ?
C6 N5 H5 115.7(13) . . ?
C17 N11 C12 117.46(12) . . ?
C2 N3 H3 117.6(12) . . ?
C4 N3 C2 124.87(13) . . ?
C4 N3 H3 117.2(12) . . ?
N1 C2 S2 122.66(11) . . ?
N1 C2 N3 115.42(12) . . ?
N3 C2 S2 121.91(11) . . ?
N11 C17 C12 121.49(13) . 2_666 ?
N11 C17 C16 119.70(13) . 2_666 ?
C16 C17 C12 118.81(13) 2_666 2_666 ?
N11 C12 C17 121.04(13) . 2_666 ?
N11 C12 C13 119.38(13) . . ?
C13 C12 C17 119.58(13) . 2_666 ?
C12 C13 H13 120.2 . . ?
C14 C13 C12 119.65(13) . . ?
C14 C13 H13 120.2 . . ?
C17 C16 H16 120.0 2_666 . ?
C15 C16 C17 119.93(13) . 2_666 ?
C15 C16 H16 120.0 . . ?
N5 C4 S4 123.04(11) . . ?
N5 C4 N3 115.02(12) . . ?
N3 C4 S4 121.94(11) . . ?
C13 C14 H14 119.6 . . ?
C13 C14 C15 120.90(14) . . ?
C15 C14 H14 119.6 . . ?
C16 C15 C14 121.13(13) . . ?
C16 C15 H15 119.4 . . ?
C14 C15 H15 119.4 . . ?
N1 C6 S6 124.26(11) . . ?
N1 C6 N5 114.27(12) . . ?
N5 C6 S6 121.46(11) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
S4 C4 1.6649(14) . ?
S6 C6 1.6382(14) . ?
S2 C2 1.6558(14) . ?
N1 C2 1.3640(19) . ?
N1 C6 1.3752(18) . ?
N1 H1 0.87(2) . ?
N5 C4 1.3542(19) . ?
N5 C6 1.3804(18) . ?
N5 H5 0.83(2) . ?
N11 C17 1.3463(19) . ?
N11 C12 1.3488(18) . ?
N3 C2 1.3716(18) . ?
N3 C4 1.3639(18) . ?
N3 H3 0.86(2) . ?
C17 C12 1.437(2) 2_666 ?
C17 C16 1.4249(19) 2_666 ?
C12 C13 1.423(2) . ?
C13 H13 0.9300 . ?
C13 C14 1.361(2) . ?
C16 H16 0.9300 . ?
C16 C15 1.359(2) . ?
C14 H14 0.9300 . ?
C14 C15 1.425(2) . ?
C15 H15 0.9300 . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
C13 H13 S6 0.93 2.83 3.5109(15) 131.0 1_565 yes
C16 H16 S4 0.93 2.96 3.8120(15) 153.5 1_556 yes
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N11 C12 C13 C14 -179.97(12) . . . . ?
C2 N1 C6 S6 -177.46(10) . . . . ?
C2 N1 C6 N5 1.55(19) . . . . ?
C2 N3 C4 S4 177.80(10) . . . . ?
C2 N3 C4 N5 -2.1(2) . . . . ?
C17 N11 C12 C17 -1.1(2) . . . 2_666 ?
C17 N11 C12 C13 178.30(12) . . . . ?
C17 C12 C13 C14 -0.6(2) 2_666 . . . ?
C17 C16 C15 C14 -0.1(2) 2_666 . . . ?
C12 N11 C17 C12 1.1(2) . . . 2_666 ?
C12 N11 C17 C16 -179.51(12) . . . 2_666 ?
C12 C13 C14 C15 -0.3(2) . . . . ?
C13 C14 C15 C16 0.7(2) . . . . ?
C4 N5 C6 S6 176.69(11) . . . . ?
C4 N5 C6 N1 -2.4(2) . . . . ?
C4 N3 C2 S2 -177.85(10) . . . . ?
C4 N3 C2 N1 1.5(2) . . . . ?
C6 N1 C2 S2 178.15(10) . . . . ?
C6 N1 C2 N3 -1.2(2) . . . . ?
C6 N5 C4 S4 -177.31(11) . . . . ?
C6 N5 C4 N3 2.6(2) . . . . ?
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
-0.9990 -0.0001 0.0003 -0.2226 -0.1425 -0.0006
0.9990 0.0001 -0.0003 0.2226 0.1425 0.0006
0.0003 0.9995 0.0003 -0.0264 -0.1612 0.1950
-0.0003 -0.9995 -0.0003 0.0264 0.1612 -0.1950
-0.0001 -0.0002 0.9989 0.0372 -0.0778 -0.0720
0.0001 0.0002 -0.9989 -0.0372 0.0778 0.0720
3.3030 3.9453 2.2799 0.7167 -0.3429 0.6073
-3.3941 -3.7924 -3.0927 -0.7713 0.3686 -0.5189
0.8409 -2.4888 -6.1300 0.0248 0.9987 -0.0435
1.9609 3.9772 4.9313 0.5155 -0.7459 0.4217
