#------------------------------------------------------------------------------
#$Date: 2025-03-04 21:48:03 +0200 (Tue, 04 Mar 2025) $
#$Revision: 298200 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/97/7249781.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7249781
loop_
_publ_author_name
'Wzgarda-Raj, Kinga'
'Rybarczyk-Pirek, Agnieszka J.'
'Palusiak, Marcin'
_publ_section_title
;
 The N--H⋯S hydrogen bonding pattern in trithiocyanuric acid in
 crystalline state: geometric, topological, and energetic analysis of
 trithiocyanuric acid cocrystals
;
_journal_issue                   6
_journal_name_full               CrystEngComm
_journal_page_first              784
_journal_page_last               794
_journal_paper_doi               10.1039/D4CE01153H
_journal_volume                  27
_journal_year                    2025
_chemical_formula_moiety         'C3 H3 N3 S3, C5 H5 N3 S'
_chemical_formula_sum            'C8 H8 N6 S4'
_chemical_formula_weight         316.44
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_audit_creation_date             2024-01-23
_audit_creation_method
;
Olex2 1.5
(compiled 2023.08.24 svn.re1ec1418 for OlexSys, GUI svn.r6817)
;
_audit_update_record
;
2024-07-13 deposited with the CCDC.	2024-12-27 downloaded from the CCDC.
;
_cell_angle_alpha                110.3160(10)
_cell_angle_beta                 106.3480(10)
_cell_angle_gamma                95.8180(10)
_cell_formula_units_Z            2
_cell_length_a                   8.01570(10)
_cell_length_b                   8.57070(10)
_cell_length_c                   11.04420(10)
_cell_measurement_reflns_used    11005
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      74.7220
_cell_measurement_theta_min      4.5060
_cell_volume                     665.851(15)
_computing_cell_refinement       'CrysAlisPro 1.171.40.78a (Rigaku OD, 2020)'
_computing_data_collection       'CrysAlisPro 1.171.40.78a (Rigaku OD, 2020)'
_computing_data_reduction        'CrysAlisPro 1.171.40.78a (Rigaku OD, 2020)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.965
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     32.00 119.00   0.50    0.11    --   47.27  57.00  60.00  174
  2  ω     25.00 119.00   0.50    0.11    --   47.27  77.00  90.00  188
  3  ω     25.00 119.00   0.50    0.11    --   47.27  77.00 -60.00  188
  4  ω     25.00 119.00   0.50    0.11    --   47.27  77.00 -90.00  188
  5  ω     32.00 119.00   0.50    0.11    --   47.27  57.00-120.00  174
  6  ω     25.00 119.00   0.50    0.11    --   47.27  77.00-180.00  188
  7  ω     32.00 119.00   0.50    0.11    --   47.27  57.00-180.00  174
  8  ω    -12.00  28.00   0.50    0.11    --  -47.27  19.00  60.00   80
  9  ω    -12.00  28.00   0.50    0.11    --  -47.27  19.00 150.00   80
 10  ω    -12.00  28.00   0.50    0.11    --  -47.27  19.00 -60.00   80
 11  ω    -12.00  28.00   0.50    0.11    --  -47.27  19.00 -90.00   80
 12  ω     92.00 176.00   0.50    0.45    --  105.67  15.00  30.00  168
 13  ω     89.00 177.00   0.50    0.45    --  105.67 135.00-147.00  176
 14  ω     95.00 177.00   0.50    0.45    --  105.67 125.00 -90.00  164
 15  ω     89.00 177.00   0.50    0.45    --  105.67 135.00  31.00  176
 16  ω     93.00 177.00   0.50    0.45    --  105.67  45.00 -90.00  168
 17  ω    -27.00  12.00   0.50    0.11    --   47.27 -19.00-120.00   78
 18  ω    -27.00  12.00   0.50    0.11    --   47.27 -19.00-150.00   78
 19  ω    -27.00  12.00   0.50    0.11    --   47.27 -19.00 -60.00   78
 20  ω     33.00 128.00   0.50    0.45    --  105.67 -77.00 120.00  190
 21  ω     33.00  75.00   0.50    0.45    --  105.67 -61.00   0.00   84
 22  ω     33.00 105.00   0.50    0.45    --  105.67 -95.00 -30.00  144
 23  ω     40.00 101.00   0.50    0.11    --   47.27-135.00 -33.00  122
 24  ω     40.00 119.00   0.50    0.45    --  105.67-135.00 -33.00  158
 25  ω     34.00 111.00   0.50    0.45    --  105.67-125.00  90.00  154
 26  ω     40.00 119.00   0.50    0.45    --  105.67-135.00 146.00  158
 27  ω     40.00 101.00   0.50    0.11    --   47.27-135.00 146.00  122
 28  ω     33.00 105.00   0.50    0.45    --  105.67 -95.00 -60.00  144
 29  ω     33.00 105.00   0.50    0.45    --  105.67 -95.00-150.00  144
 30  ω    -93.00 -18.00   0.50    0.11    --  -47.27 135.00  31.00  150
 31  ω    -93.00 -19.00   0.50    0.45    --  -91.75 135.00  31.00  148
 32  ω    -93.00 -18.00   0.50    0.11    --  -47.27 135.00-147.00  150
 33  ω    -93.00 -19.00   0.50    0.45    --  -91.75 135.00-147.00  148
 34  ω    -49.00 -20.00   0.50    0.45    --  -91.75  45.00-120.00   58
 35  ω    -49.00 -20.00   0.50    0.45    --  -91.75  45.00 -30.00   58
 36  ω    -49.00 -20.00   0.50    0.45    --  -91.75  45.00   0.00   58
 37  ω    -49.00 -20.00   0.50    0.45    --  -91.75  45.00  30.00   58
 38  ω    -49.00 -20.00   0.50    0.45    --  -91.75  45.00 150.00   58
 39  ω   -166.00 -79.00   0.50    0.45    --  -91.75 -30.00 150.00  174
 40  ω   -163.00 -69.00   0.50    0.45    --  -91.75 -77.00 150.00  188
 41  ω   -163.00 -69.00   0.50    0.45    --  -91.75 -77.00 120.00  188
 42  ω   -163.00 -69.00   0.50    0.45    --  -91.75 -77.00  90.00  188
 43  ω   -163.00 -71.00   0.50    0.45    --  -91.75 -77.00  60.00  184
 44  ω   -119.00 -25.00   0.50    0.11    --  -47.27 -77.00   0.00  188
 45  ω   -163.00 -69.00   0.50    0.45    --  -91.75 -77.00 -30.00  188
 46  ω   -163.00 -75.00   0.50    0.45    --  -91.75 -61.00   0.00  176
 47  ω   -163.00 -75.00   0.50    0.45    --  -91.75 -61.00  30.00  176
 48  ω   -163.00 -69.00   0.50    0.45    --  -91.75 -77.00 -60.00  188
 49  ω   -163.00 -69.00   0.50    0.45    --  -91.75 -77.00-180.00  188
 50  ω   -163.00 -75.00   0.50    0.45    --  -91.75 -61.00-150.00  176
 51  ω   -163.00 -79.00   0.50    0.45    --  -91.75 -45.00-150.00  168
 52  ω   -163.00 -79.00   0.50    0.45    --  -91.75 -45.00-120.00  168
 53  ω   -163.00 -73.00   0.50    0.45    --  -91.75-125.00 120.00  180
 54  ω   -160.00 -67.00   0.50    0.45    --  -91.75-135.00 146.00  186
 55  ω   -119.00 -67.00   0.50    0.11    --  -47.27-135.00 146.00  104
 56  ω   -119.00 -67.00   0.50    0.11    --  -47.27-135.00 -33.00  104
 57  ω   -160.00 -67.00   0.50    0.45    --  -91.75-135.00 -33.00  186
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0676543000
_diffrn_orient_matrix_UB_12      -0.0764086000
_diffrn_orient_matrix_UB_13      -0.1581220000
_diffrn_orient_matrix_UB_21      0.1861986000
_diffrn_orient_matrix_UB_22      0.0689198000
_diffrn_orient_matrix_UB_23      0.0017981000
_diffrn_orient_matrix_UB_31      0.0541689000
_diffrn_orient_matrix_UB_32      -0.1674541000
_diffrn_orient_matrix_UB_33      -0.0001621000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0409
_diffrn_reflns_av_unetI/netI     0.0215
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.965
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            20245
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.965
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         75.936
_diffrn_reflns_theta_min         4.539
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'PhotonJet (Cu) X-ray Source'
_exptl_absorpt_coefficient_mu    6.501
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.763
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.40.78a (Rigaku Oxford Diffraction, 2020)
Numerical absorption correction based on gaussian integration over
			a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.578
_exptl_crystal_description       block
_exptl_crystal_F_000             324
_exptl_crystal_size_max          0.222
_exptl_crystal_size_mid          0.048
_exptl_crystal_size_min          0.031
_refine_diff_density_max         0.206
_refine_diff_density_min         -0.264
_refine_diff_density_rms         0.042
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.051
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     183
_refine_ls_number_reflns         2685
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.051
_refine_ls_R_factor_all          0.0336
_refine_ls_R_factor_gt           0.0302
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0506P)²+0.1166P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0855
_refine_ls_wR_factor_ref         0.0886
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2393
_reflns_number_total             2685
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d4ce01153h2.cif
_cod_data_source_block           exp_204
_cod_depositor_comments
'Adding full bibliography for 7249780--7249783.cif.'
_cod_original_cell_volume        665.850(14)
_cod_database_code               7249781
_shelx_shelxl_version_number     2018/3
_chemical_oxdiff_formula         'C11 H10 N O'
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_reflns_odcompleteness_completeness 100.00
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C13(H13), C15(H15), C16(H16)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.933
_oxdiff_exptl_absorpt_empirical_full_min 0.647
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
S6 S 0.37445(7) 0.20636(6) 0.50653(4) 0.05962(15) Uani 1 1 d . . . . .
S17 S 0.03065(7) 0.46556(6) 0.23940(4) 0.05859(15) Uani 1 1 d . . . . .
S2 S 0.67710(7) 0.68549(6) 1.00226(4) 0.06371(16) Uani 1 1 d . . . . .
S4 S 0.81300(8) 0.06893(7) 0.89296(5) 0.07197(18) Uani 1 1 d . . . . .
N3 N 0.7299(2) 0.37073(18) 0.93110(15) 0.0516(3) Uani 1 1 d . . . . .
N1 N 0.5321(2) 0.42687(19) 0.76340(14) 0.0491(3) Uani 1 1 d . . . . .
N5 N 0.5994(2) 0.1629(2) 0.71384(15) 0.0533(4) Uani 1 1 d . . . . .
N14 N 0.3466(2) 0.6556(2) 0.68001(15) 0.0556(4) Uani 1 1 d . . . . .
N17 N -0.0371(3) 0.7709(3) 0.32314(19) 0.0721(5) Uani 1 1 d . . . . .
N11 N 0.1312(2) 0.8571(2) 0.59000(16) 0.0619(4) Uani 1 1 d . . . . .
C12 C 0.1454(2) 0.7100(2) 0.50287(17) 0.0474(4) Uani 1 1 d . . . . .
C6 C 0.5077(2) 0.2677(2) 0.66757(17) 0.0475(4) Uani 1 1 d . . . . .
C17 C 0.0413(2) 0.6568(2) 0.35391(17) 0.0485(4) Uani 1 1 d . . . . .
C13 C 0.2513(2) 0.6094(2) 0.54801(17) 0.0515(4) Uani 1 1 d . . . . .
H13 H 0.256042 0.506574 0.484249 0.062 Uiso 1 1 calc R U . . .
C4 C 0.7115(2) 0.2050(2) 0.84500(17) 0.0505(4) Uani 1 1 d . . . . .
C2 C 0.6459(2) 0.4855(2) 0.89570(16) 0.0481(4) Uani 1 1 d . . . . .
C15 C 0.3318(3) 0.8011(3) 0.7665(2) 0.0670(5) Uani 1 1 d . . . . .
H15 H 0.396577 0.838370 0.859481 0.080 Uiso 1 1 calc R U . . .
C16 C 0.2225(4) 0.8992(3) 0.7221(2) 0.0787(7) Uani 1 1 d . . . . .
H16 H 0.212252 0.998349 0.786878 0.094 Uiso 1 1 calc R U . . .
H1 H 0.475(3) 0.505(3) 0.738(2) 0.061(6) Uiso 1 1 d . . . . .
H3 H 0.803(3) 0.401(3) 1.018(2) 0.061(6) Uiso 1 1 d . . . . .
H5 H 0.589(3) 0.065(3) 0.655(3) 0.072(7) Uiso 1 1 d . . . . .
H17A H -0.098(4) 0.743(4) 0.237(3) 0.095(9) Uiso 1 1 d . . . . .
H17B H -0.020(4) 0.862(4) 0.384(3) 0.094(9) Uiso 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
1 0 0 0.1245
-1 0 0 0.0702
0 -1 0 0.0174
0 1 0 0.0139
0 0 1 0.0136
0 0 -1 0.0184
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C4 N3 H3 114.8(14) . . ?
C2 N3 C4 125.33(14) . . ?
C2 N3 H3 119.8(14) . . ?
C6 N1 C2 124.26(15) . . ?
C6 N1 H1 119.4(14) . . ?
C2 N1 H1 116.2(14) . . ?
C6 N5 C4 125.87(16) . . ?
C6 N5 H5 116.6(17) . . ?
C4 N5 H5 117.5(17) . . ?
C15 N14 C13 116.40(16) . . ?
C17 N17 H17A 116.4(19) . . ?
C17 N17 H17B 117(2) . . ?
H17A N17 H17B 126(3) . . ?
C16 N11 C12 115.94(16) . . ?
N11 C12 C17 117.36(15) . . ?
N11 C12 C13 121.53(15) . . ?
C13 C12 C17 121.11(15) . . ?
N1 C6 S6 122.15(13) . . ?
N1 C6 N5 115.09(15) . . ?
N5 C6 S6 122.76(13) . . ?
N17 C17 S17 123.94(14) . . ?
N17 C17 C12 114.98(16) . . ?
C12 C17 S17 121.08(13) . . ?
N14 C13 C12 122.01(16) . . ?
N14 C13 H13 119.0 . . ?
C12 C13 H13 119.0 . . ?
N3 C4 S4 123.75(13) . . ?
N5 C4 S4 122.64(14) . . ?
N5 C4 N3 113.61(15) . . ?
N3 C2 S2 123.44(12) . . ?
N3 C2 N1 115.72(15) . . ?
N1 C2 S2 120.84(13) . . ?
N14 C15 H15 119.2 . . ?
N14 C15 C16 121.65(17) . . ?
C16 C15 H15 119.2 . . ?
N11 C16 C15 122.39(19) . . ?
N11 C16 H16 118.8 . . ?
C15 C16 H16 118.8 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
S6 C6 1.6577(17) . ?
S17 C17 1.6624(18) . ?
S2 C2 1.6529(17) . ?
S4 C4 1.6372(18) . ?
N3 C4 1.373(2) . ?
N3 C2 1.352(2) . ?
N3 H3 0.90(2) . ?
N1 C6 1.359(2) . ?
N1 C2 1.366(2) . ?
N1 H1 0.93(2) . ?
N5 C6 1.360(2) . ?
N5 C4 1.369(2) . ?
N5 H5 0.84(3) . ?
N14 C13 1.333(2) . ?
N14 C15 1.323(3) . ?
N17 C17 1.305(2) . ?
N17 H17A 0.87(3) . ?
N17 H17B 0.80(3) . ?
N11 C12 1.333(2) . ?
N11 C16 1.332(2) . ?
C12 C17 1.497(2) . ?
C12 C13 1.386(2) . ?
C13 H13 0.9300 . ?
C15 H15 0.9300 . ?
C15 C16 1.382(3) . ?
C16 H16 0.9300 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N14 C15 C16 N11 -2.6(4) . . . . ?
N11 C12 C17 S17 -172.70(14) . . . . ?
N11 C12 C17 N17 7.6(3) . . . . ?
N11 C12 C13 N14 -1.2(3) . . . . ?
C12 N11 C16 C15 2.8(4) . . . . ?
C6 N1 C2 S2 175.81(14) . . . . ?
C6 N1 C2 N3 -3.6(3) . . . . ?
C6 N5 C4 S4 178.38(15) . . . . ?
C6 N5 C4 N3 -1.6(3) . . . . ?
C17 C12 C13 N14 179.19(16) . . . . ?
C13 N14 C15 C16 0.4(3) . . . . ?
C13 C12 C17 S17 7.0(2) . . . . ?
C13 C12 C17 N17 -172.75(18) . . . . ?
C4 N3 C2 S2 -178.20(15) . . . . ?
C4 N3 C2 N1 1.2(3) . . . . ?
C4 N5 C6 S6 179.94(15) . . . . ?
C4 N5 C6 N1 -0.5(3) . . . . ?
C2 N3 C4 S4 -178.78(15) . . . . ?
C2 N3 C4 N5 1.2(3) . . . . ?
C2 N1 C6 S6 -177.16(14) . . . . ?
C2 N1 C6 N5 3.3(3) . . . . ?
C15 N14 C13 C12 1.4(3) . . . . ?
C16 N11 C12 C17 178.7(2) . . . . ?
C16 N11 C12 C13 -1.0(3) . . . . ?
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
0.9996 -0.0003 -0.0001 -0.0676 0.1861 0.0542
-0.9996 0.0003 0.0001 0.0676 -0.1861 -0.0542
-0.0003 -0.9995 0.0002 0.0764 -0.0689 0.1673
0.0003 0.9995 -0.0002 -0.0764 0.0689 -0.1673
-0.0001 -0.0001 0.9998 -0.1581 0.0018 -0.0002
0.0001 0.0001 -0.9998 0.1581 -0.0018 0.0002
