#------------------------------------------------------------------------------
#$Date: 2022-05-12 01:54:19 +0300 (Thu, 12 May 2022) $
#$Revision: 275349 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/02/7710241.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7710241
loop_
_publ_author_name
'Vidlak, Julia F.'
'Cosio, Mario N.'
'Sriramaneni, Nihal K.'
'Bhuvanesh, Nattamai'
'Ozerov, Oleg V.'
'Johnson, Miles W.'
_publ_section_title
;
 Synthesis of pyrrole-based PSiP pincer ligands and their palladium,
 rhodium, and platinum complexes
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D2DT00948J
_journal_year                    2022
_chemical_formula_moiety         'C32 H28 Cl2 N2 P2 Pt'
_chemical_formula_sum            'C32 H28 Cl2 N2 P2 Pt'
_chemical_formula_weight         768.49
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_audit_creation_date             2021-08-11
_audit_creation_method
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_audit_update_record
;
2022-01-21 deposited with the CCDC.	2022-05-04 downloaded from the CCDC.
;
_cell_angle_alpha                99.4630(10)
_cell_angle_beta                 100.9600(10)
_cell_angle_gamma                111.2430(10)
_cell_formula_units_Z            2
_cell_length_a                   9.3937(4)
_cell_length_b                   12.2210(4)
_cell_length_c                   14.1646(5)
_cell_measurement_reflns_used    9825
_cell_measurement_temperature    110.0
_cell_measurement_theta_max      27.578
_cell_measurement_theta_min      2.373
_cell_volume                     1438.79(9)
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_diffrn_ambient_temperature      110.0
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker QUEST PHOTON-III'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0291
_diffrn_reflns_av_unetI/netI     0.0275
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            26811
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.595
_diffrn_reflns_theta_min         1.849
_diffrn_source_current           1.0
_diffrn_source_power             0.05
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    5.199
_exptl_absorpt_correction_T_max  0.3334
_exptl_absorpt_correction_T_min  0.2010
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0786 before and 0.0400 after correction.
The Ratio of minimum to maximum transmission is 0.6029.
The λ/2 correction factor is Not present.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.774
_exptl_crystal_description       block
_exptl_crystal_F_000             752
_exptl_crystal_size_max          0.207
_exptl_crystal_size_mid          0.124
_exptl_crystal_size_min          0.081
_refine_diff_density_max         1.560
_refine_diff_density_min         -1.247
_refine_diff_density_rms         0.115
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.165
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     360
_refine_ls_number_reflns         6631
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.165
_refine_ls_R_factor_all          0.0270
_refine_ls_R_factor_gt           0.0244
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+3.7605P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0540
_refine_ls_wR_factor_ref         0.0554
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6256
_reflns_number_total             6631
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2dt00948j2.cif
_cod_data_source_block           mwjiii4041a
_cod_database_code               7710241
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.678
_shelx_estimated_absorpt_t_min   0.412
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C2(H2A), C3(H3), C4(H4), C6(H6), C7(H7), C8(H8), C9(H9), C10(H10), C12(H12),
 C13(H13), C14(H14), C15(H15), C16(H16), C18(H18), C19(H19), C20(H20), C22(H22),
  C23(H23), C24(H24), C25(H25), C26(H26), C28(H28), C29(H29), C30(H30),
 C31(H31), C32(H32)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.40727(2) 0.09459(2) 0.64531(2) 0.01549(4) Uani 1 1 d . . . . .
Cl1 Cl 0.24310(10) -0.02946(7) 0.48910(6) 0.02191(16) Uani 1 1 d . . . . .
Cl2 Cl 0.40300(9) -0.08448(6) 0.68956(6) 0.01984(15) Uani 1 1 d . . . . .
P1 P 0.41577(10) 0.25988(7) 0.59213(6) 0.01528(15) Uani 1 1 d . . . . .
P2 P 0.57037(10) 0.19554(7) 0.79953(6) 0.01669(15) Uani 1 1 d . . . . .
N1 N 0.7036(4) 0.2798(3) 0.5637(2) 0.0234(6) Uani 1 1 d . . . . .
H1 H 0.662(6) 0.199(4) 0.546(4) 0.043(13) Uiso 1 1 d . . . . .
N2 N 0.7720(4) 0.0889(3) 0.7483(2) 0.0245(6) Uani 1 1 d . . . . .
H2 H 0.698(6) 0.047(4) 0.694(4) 0.045(14) Uiso 1 1 d . . . . .
C1 C 0.6131(4) 0.3431(3) 0.5859(2) 0.0180(6) Uani 1 1 d . . . . .
C2 C 0.7052(4) 0.4648(3) 0.5965(3) 0.0253(7) Uani 1 1 d . . . . .
H2A H 0.675084 0.530427 0.611888 0.030 Uiso 1 1 calc R U . . .
C3 C 0.8538(4) 0.4730(3) 0.5800(3) 0.0298(8) Uani 1 1 d . . . . .
H3 H 0.940801 0.545105 0.582495 0.036 Uiso 1 1 calc R U . . .
C4 C 0.8473(4) 0.3568(3) 0.5598(3) 0.0286(8) Uani 1 1 d . . . . .
H4 H 0.929432 0.334485 0.545573 0.034 Uiso 1 1 calc R U . . .
C5 C 0.3491(4) 0.3613(3) 0.6625(2) 0.0208(6) Uani 1 1 d . . . . .
C6 C 0.3736(4) 0.4744(3) 0.6446(3) 0.0244(7) Uani 1 1 d . . . . .
H6 H 0.430671 0.500922 0.598194 0.029 Uiso 1 1 calc R U . . .
C7 C 0.3144(5) 0.5486(3) 0.6947(3) 0.0335(9) Uani 1 1 d . . . . .
H7 H 0.333941 0.626833 0.683828 0.040 Uiso 1 1 calc R U . . .
C8 C 0.2277(5) 0.5091(3) 0.7597(3) 0.0340(9) Uani 1 1 d . . . . .
H8 H 0.188408 0.560439 0.794059 0.041 Uiso 1 1 calc R U . . .
C9 C 0.1975(5) 0.3945(4) 0.7754(3) 0.0339(9) Uani 1 1 d . . . . .
H9 H 0.135974 0.366776 0.819398 0.041 Uiso 1 1 calc R U . . .
C10 C 0.2577(4) 0.3204(3) 0.7262(3) 0.0257(7) Uani 1 1 d . . . . .
H10 H 0.236232 0.241617 0.736262 0.031 Uiso 1 1 calc R U . . .
C11 C 0.2910(4) 0.2312(3) 0.4673(2) 0.0169(6) Uani 1 1 d . . . . .
C12 C 0.3555(4) 0.2409(3) 0.3870(2) 0.0212(7) Uani 1 1 d . . . . .
H12 H 0.464785 0.257627 0.395833 0.025 Uiso 1 1 calc R U . . .
C13 C 0.2607(5) 0.2264(3) 0.2940(3) 0.0265(7) Uani 1 1 d . . . . .
H13 H 0.304617 0.232927 0.238968 0.032 Uiso 1 1 calc R U . . .
C14 C 0.1032(5) 0.2024(3) 0.2821(3) 0.0301(8) Uani 1 1 d . . . . .
H14 H 0.038985 0.195080 0.218871 0.036 Uiso 1 1 calc R U . . .
C15 C 0.0364(4) 0.1888(3) 0.3602(3) 0.0276(8) Uani 1 1 d . . . . .
H15 H -0.073594 0.170103 0.350182 0.033 Uiso 1 1 calc R U . . .
C16 C 0.1289(4) 0.2021(3) 0.4531(3) 0.0238(7) Uani 1 1 d . . . . .
H16 H 0.082802 0.191644 0.506952 0.029 Uiso 1 1 calc R U . . .
C17 C 0.7461(4) 0.1661(3) 0.8179(2) 0.0202(6) Uani 1 1 d . . . . .
C18 C 0.8815(5) 0.2172(4) 0.8965(3) 0.0307(8) Uani 1 1 d . . . . .
H18 H 0.899713 0.276235 0.955324 0.037 Uiso 1 1 calc R U . . .
C19 C 0.9883(5) 0.1665(3) 0.8742(3) 0.0297(8) Uani 1 1 d . . . . .
H19 H 1.089890 0.183104 0.915504 0.036 Uiso 1 1 calc R U . . .
C20 C 0.9163(4) 0.0882(3) 0.7806(3) 0.0277(8) Uani 1 1 d . . . . .
H20 H 0.960609 0.041889 0.745180 0.033 Uiso 1 1 calc R U . . .
C21 C 0.4769(4) 0.1502(3) 0.8971(2) 0.0226(7) Uani 1 1 d . . . . .
C22 C 0.3199(5) 0.0703(3) 0.8747(3) 0.0278(8) Uani 1 1 d . . . . .
H22 H 0.257510 0.039613 0.807484 0.033 Uiso 1 1 calc R U . . .
C23 C 0.2520(5) 0.0343(4) 0.9500(3) 0.0342(9) Uani 1 1 d . . . . .
H23 H 0.143154 -0.019036 0.934131 0.041 Uiso 1 1 calc R U . . .
C24 C 0.3430(5) 0.0763(4) 1.0472(3) 0.0349(9) Uani 1 1 d . . . . .
H24 H 0.297654 0.050087 1.098323 0.042 Uiso 1 1 calc R U . . .
C25 C 0.4996(6) 0.1561(4) 1.0705(3) 0.0405(10) Uani 1 1 d . . . . .
H25 H 0.561991 0.185745 1.137761 0.049 Uiso 1 1 calc R U . . .
C26 C 0.5663(5) 0.1931(4) 0.9956(3) 0.0347(9) Uani 1 1 d . . . . .
H26 H 0.674371 0.248493 1.011976 0.042 Uiso 1 1 calc R U . . .
C27 C 0.6555(4) 0.3612(3) 0.8393(2) 0.0207(6) Uani 1 1 d . . . . .
C28 C 0.7939(4) 0.4287(3) 0.8169(3) 0.0243(7) Uani 1 1 d . . . . .
H28 H 0.846103 0.388298 0.782892 0.029 Uiso 1 1 calc R U . . .
C29 C 0.8562(5) 0.5547(3) 0.8440(3) 0.0304(8) Uani 1 1 d . . . . .
H29 H 0.950973 0.600304 0.828758 0.037 Uiso 1 1 calc R U . . .
C30 C 0.7806(5) 0.6138(3) 0.8931(3) 0.0331(9) Uani 1 1 d . . . . .
H30 H 0.823825 0.699968 0.912001 0.040 Uiso 1 1 calc R U . . .
C31 C 0.6430(5) 0.5483(3) 0.9146(3) 0.0348(9) Uani 1 1 d . . . . .
H31 H 0.590000 0.589489 0.946876 0.042 Uiso 1 1 calc R U . . .
C32 C 0.5804(5) 0.4216(3) 0.8893(3) 0.0294(8) Uani 1 1 d . . . . .
H32 H 0.486985 0.376704 0.906206 0.035 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cl1 Pt1 Cl2 87.15(3) . . ?
P1 Pt1 Cl1 89.85(3) . . ?
P1 Pt1 Cl2 175.48(3) . . ?
P1 Pt1 P2 96.49(3) . . ?
P2 Pt1 Cl1 173.43(3) . . ?
P2 Pt1 Cl2 86.42(3) . . ?
C1 P1 Pt1 108.90(10) . . ?
C1 P1 C5 109.75(15) . . ?
C1 P1 C11 104.39(15) . . ?
C5 P1 Pt1 116.72(11) . . ?
C5 P1 C11 100.18(15) . . ?
C11 P1 Pt1 116.00(10) . . ?
C17 P2 Pt1 110.64(11) . . ?
C17 P2 C21 107.00(15) . . ?
C17 P2 C27 101.23(16) . . ?
C21 P2 Pt1 112.30(12) . . ?
C27 P2 Pt1 121.12(11) . . ?
C27 P2 C21 103.24(15) . . ?
C1 N1 H1 121(3) . . ?
C4 N1 H1 127(3) . . ?
C4 N1 C1 110.5(3) . . ?
C17 N2 H2 119(3) . . ?
C20 N2 H2 130(3) . . ?
C20 N2 C17 110.7(3) . . ?
N1 C1 P1 118.7(2) . . ?
N1 C1 C2 106.7(3) . . ?
C2 C1 P1 134.6(3) . . ?
C1 C2 H2A 126.3 . . ?
C1 C2 C3 107.4(3) . . ?
C3 C2 H2A 126.3 . . ?
C2 C3 H3 126.4 . . ?
C4 C3 C2 107.2(3) . . ?
C4 C3 H3 126.4 . . ?
N1 C4 C3 108.2(3) . . ?
N1 C4 H4 125.9 . . ?
C3 C4 H4 125.9 . . ?
C6 C5 P1 120.2(3) . . ?
C10 C5 P1 119.8(2) . . ?
C10 C5 C6 119.6(3) . . ?
C5 C6 H6 120.0 . . ?
C5 C6 C7 119.9(3) . . ?
C7 C6 H6 120.0 . . ?
C6 C7 H7 119.9 . . ?
C8 C7 C6 120.2(3) . . ?
C8 C7 H7 119.9 . . ?
C7 C8 H8 119.9 . . ?
C7 C8 C9 120.3(3) . . ?
C9 C8 H8 119.9 . . ?
C8 C9 H9 120.1 . . ?
C8 C9 C10 119.7(3) . . ?
C10 C9 H9 120.1 . . ?
C5 C10 C9 120.2(3) . . ?
C5 C10 H10 119.9 . . ?
C9 C10 H10 119.9 . . ?
C12 C11 P1 121.0(3) . . ?
C12 C11 C16 119.7(3) . . ?
C16 C11 P1 119.3(3) . . ?
C11 C12 H12 119.9 . . ?
C13 C12 C11 120.1(3) . . ?
C13 C12 H12 119.9 . . ?
C12 C13 H13 120.3 . . ?
C14 C13 C12 119.4(3) . . ?
C14 C13 H13 120.3 . . ?
C13 C14 H14 119.5 . . ?
C13 C14 C15 121.1(3) . . ?
C15 C14 H14 119.5 . . ?
C14 C15 H15 119.9 . . ?
C14 C15 C16 120.2(3) . . ?
C16 C15 H15 119.9 . . ?
C11 C16 H16 120.3 . . ?
C15 C16 C11 119.4(3) . . ?
C15 C16 H16 120.3 . . ?
N2 C17 P2 123.6(3) . . ?
N2 C17 C18 106.5(3) . . ?
C18 C17 P2 129.7(3) . . ?
C17 C18 H18 126.0 . . ?
C17 C18 C19 108.1(3) . . ?
C19 C18 H18 126.0 . . ?
C18 C19 H19 126.7 . . ?
C20 C19 C18 106.6(3) . . ?
C20 C19 H19 126.7 . . ?
N2 C20 C19 108.1(3) . . ?
N2 C20 H20 126.0 . . ?
C19 C20 H20 126.0 . . ?
C22 C21 P2 121.5(3) . . ?
C22 C21 C26 118.8(3) . . ?
C26 C21 P2 119.6(3) . . ?
C21 C22 H22 119.7 . . ?
C21 C22 C23 120.6(4) . . ?
C23 C22 H22 119.7 . . ?
C22 C23 H23 120.1 . . ?
C24 C23 C22 119.9(4) . . ?
C24 C23 H23 120.1 . . ?
C23 C24 H24 120.0 . . ?
C23 C24 C25 120.1(4) . . ?
C25 C24 H24 120.0 . . ?
C24 C25 H25 120.0 . . ?
C24 C25 C26 119.9(4) . . ?
C26 C25 H25 120.0 . . ?
C21 C26 C25 120.7(4) . . ?
C21 C26 H26 119.7 . . ?
C25 C26 H26 119.7 . . ?
C28 C27 P2 120.1(3) . . ?
C32 C27 P2 120.6(3) . . ?
C32 C27 C28 119.2(3) . . ?
C27 C28 H28 119.8 . . ?
C29 C28 C27 120.3(3) . . ?
C29 C28 H28 119.8 . . ?
C28 C29 H29 120.0 . . ?
C30 C29 C28 120.0(4) . . ?
C30 C29 H29 120.0 . . ?
C29 C30 H30 119.9 . . ?
C31 C30 C29 120.2(3) . . ?
C31 C30 H30 119.9 . . ?
C30 C31 H31 119.8 . . ?
C30 C31 C32 120.4(4) . . ?
C32 C31 H31 119.8 . . ?
C27 C32 C31 119.8(4) . . ?
C27 C32 H32 120.1 . . ?
C31 C32 H32 120.1 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 Cl1 2.3405(8) . ?
Pt1 Cl2 2.3624(7) . ?
Pt1 P1 2.2495(7) . ?
Pt1 P2 2.2612(8) . ?
P1 C1 1.790(3) . ?
P1 C5 1.822(3) . ?
P1 C11 1.826(3) . ?
P2 C17 1.794(3) . ?
P2 C21 1.830(3) . ?
P2 C27 1.827(3) . ?
N1 H1 0.89(5) . ?
N1 C1 1.385(4) . ?
N1 C4 1.355(5) . ?
N2 H2 0.86(5) . ?
N2 C17 1.369(4) . ?
N2 C20 1.350(5) . ?
C1 C2 1.389(4) . ?
C2 H2A 0.9500 . ?
C2 C3 1.429(5) . ?
C3 H3 0.9500 . ?
C3 C4 1.379(5) . ?
C4 H4 0.9500 . ?
C5 C6 1.391(4) . ?
C5 C10 1.390(5) . ?
C6 H6 0.9500 . ?
C6 C7 1.393(5) . ?
C7 H7 0.9500 . ?
C7 C8 1.375(6) . ?
C8 H8 0.9500 . ?
C8 C9 1.390(5) . ?
C9 H9 0.9500 . ?
C9 C10 1.392(5) . ?
C10 H10 0.9500 . ?
C11 C12 1.389(4) . ?
C11 C16 1.397(5) . ?
C12 H12 0.9500 . ?
C12 C13 1.386(5) . ?
C13 H13 0.9500 . ?
C13 C14 1.371(6) . ?
C14 H14 0.9500 . ?
C14 C15 1.377(6) . ?
C15 H15 0.9500 . ?
C15 C16 1.380(5) . ?
C16 H16 0.9500 . ?
C17 C18 1.380(5) . ?
C18 H18 0.9500 . ?
C18 C19 1.414(5) . ?
C19 H19 0.9500 . ?
C19 C20 1.379(5) . ?
C20 H20 0.9500 . ?
C21 C22 1.380(5) . ?
C21 C26 1.386(5) . ?
C22 H22 0.9500 . ?
C22 C23 1.395(5) . ?
C23 H23 0.9500 . ?
C23 C24 1.376(6) . ?
C24 H24 0.9500 . ?
C24 C25 1.376(6) . ?
C25 H25 0.9500 . ?
C25 C26 1.390(5) . ?
C26 H26 0.9500 . ?
C27 C28 1.392(5) . ?
C27 C32 1.392(5) . ?
C28 H28 0.9500 . ?
C28 C29 1.389(5) . ?
C29 H29 0.9500 . ?
C29 C30 1.379(6) . ?
C30 H30 0.9500 . ?
C30 C31 1.373(6) . ?
C31 H31 0.9500 . ?
C31 C32 1.397(5) . ?
C32 H32 0.9500 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Pt1 P1 C1 N1 31.4(3) . . . . ?
Pt1 P1 C1 C2 -150.3(3) . . . . ?
Pt1 P1 C5 C6 169.9(3) . . . . ?
Pt1 P1 C5 C10 -17.5(3) . . . . ?
Pt1 P1 C11 C12 -101.8(2) . . . . ?
Pt1 P1 C11 C16 79.9(3) . . . . ?
Pt1 P2 C17 N2 -2.5(3) . . . . ?
Pt1 P2 C17 C18 173.3(3) . . . . ?
Pt1 P2 C21 C22 -4.9(3) . . . . ?
Pt1 P2 C21 C26 172.7(3) . . . . ?
Pt1 P2 C27 C28 -84.6(3) . . . . ?
Pt1 P2 C27 C32 93.3(3) . . . . ?
P1 C1 C2 C3 -178.4(3) . . . . ?
P1 C5 C6 C7 176.4(3) . . . . ?
P1 C5 C10 C9 -175.8(3) . . . . ?
P1 C11 C12 C13 -175.9(2) . . . . ?
P1 C11 C16 C15 175.5(3) . . . . ?
P2 C17 C18 C19 -178.0(3) . . . . ?
P2 C21 C22 C23 178.3(3) . . . . ?
P2 C21 C26 C25 -177.4(3) . . . . ?
P2 C27 C28 C29 177.8(3) . . . . ?
P2 C27 C32 C31 -176.7(3) . . . . ?
N1 C1 C2 C3 0.0(4) . . . . ?
N2 C17 C18 C19 -1.7(4) . . . . ?
C1 P1 C5 C6 45.4(3) . . . . ?
C1 P1 C5 C10 -141.9(3) . . . . ?
C1 P1 C11 C12 18.1(3) . . . . ?
C1 P1 C11 C16 -160.2(3) . . . . ?
C1 N1 C4 C3 0.3(4) . . . . ?
C1 C2 C3 C4 0.1(4) . . . . ?
C2 C3 C4 N1 -0.2(4) . . . . ?
C4 N1 C1 P1 178.5(3) . . . . ?
C4 N1 C1 C2 -0.2(4) . . . . ?
C5 P1 C1 N1 160.3(3) . . . . ?
C5 P1 C1 C2 -21.4(4) . . . . ?
C5 P1 C11 C12 131.7(3) . . . . ?
C5 P1 C11 C16 -46.6(3) . . . . ?
C5 C6 C7 C8 -1.9(6) . . . . ?
C6 C5 C10 C9 -3.1(6) . . . . ?
C6 C7 C8 C9 -0.5(7) . . . . ?
C7 C8 C9 C10 1.1(7) . . . . ?
C8 C9 C10 C5 0.7(6) . . . . ?
C10 C5 C6 C7 3.7(6) . . . . ?
C11 P1 C1 N1 -93.1(3) . . . . ?
C11 P1 C1 C2 85.2(4) . . . . ?
C11 P1 C5 C6 -64.0(3) . . . . ?
C11 P1 C5 C10 108.6(3) . . . . ?
C11 C12 C13 C14 0.1(5) . . . . ?
C12 C11 C16 C15 -2.8(5) . . . . ?
C12 C13 C14 C15 -2.1(5) . . . . ?
C13 C14 C15 C16 1.6(5) . . . . ?
C14 C15 C16 C11 0.9(5) . . . . ?
C16 C11 C12 C13 2.4(5) . . . . ?
C17 P2 C21 C22 -126.5(3) . . . . ?
C17 P2 C21 C26 51.2(3) . . . . ?
C17 P2 C27 C28 38.0(3) . . . . ?
C17 P2 C27 C32 -144.1(3) . . . . ?
C17 N2 C20 C19 0.2(4) . . . . ?
C17 C18 C19 C20 1.8(4) . . . . ?
C18 C19 C20 N2 -1.2(4) . . . . ?
C20 N2 C17 P2 177.6(2) . . . . ?
C20 N2 C17 C18 0.9(4) . . . . ?
C21 P2 C17 N2 120.2(3) . . . . ?
C21 P2 C17 C18 -64.0(4) . . . . ?
C21 P2 C27 C28 148.7(3) . . . . ?
C21 P2 C27 C32 -33.4(3) . . . . ?
C21 C22 C23 C24 -1.6(6) . . . . ?
C22 C21 C26 C25 0.4(6) . . . . ?
C22 C23 C24 C25 1.7(6) . . . . ?
C23 C24 C25 C26 -0.8(6) . . . . ?
C24 C25 C26 C21 -0.3(7) . . . . ?
C26 C21 C22 C23 0.6(5) . . . . ?
C27 P2 C17 N2 -132.1(3) . . . . ?
C27 P2 C17 C18 43.7(4) . . . . ?
C27 P2 C21 C22 127.2(3) . . . . ?
C27 P2 C21 C26 -55.2(3) . . . . ?
C27 C28 C29 C30 -0.2(5) . . . . ?
C28 C27 C32 C31 1.2(5) . . . . ?
C28 C29 C30 C31 -0.5(6) . . . . ?
C29 C30 C31 C32 1.6(6) . . . . ?
C30 C31 C32 C27 -2.0(6) . . . . ?
C32 C27 C28 C29 -0.1(5) . . . . ?
