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#$Date: 2023-08-05 12:04:12 +0300 (Sat, 05 Aug 2023) $
#$Revision: 285464 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/32/7713272.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7713272
loop_
_publ_author_name
'Li, Jiahe'
'Wang, Zhiyuan'
'Chen, Zhongting'
'Xue, Xingyong'
'Lin, Kejuan'
'Chen, Hailan'
'Pan, Lixia'
'Yuan, Yulin'
'Ma, Zhen'
_publ_section_title
;
 Silver complexes with substituted terpyridines as promising anticancer
 metallodrugs and their crystal structure, photoluminescence, and DNA
 interactions.
;
_journal_issue                   28
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9607
_journal_page_last               9621
_journal_paper_doi               10.1039/d2dt03463h
_journal_volume                  52
_journal_year                    2023
_chemical_formula_moiety         'C24 H20 Ag F6 N4 Sb'
_chemical_formula_sum            'C24 H20 Ag F6 N4 Sb'
_chemical_formula_weight         708.06
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2020-01-15 deposited with the CCDC.	2023-06-13 downloaded from the CCDC.
;
_cell_angle_alpha                101.01(3)
_cell_angle_beta                 91.44(3)
_cell_angle_gamma                103.32(3)
_cell_formula_units_Z            2
_cell_length_a                   7.3381(15)
_cell_length_b                   12.389(3)
_cell_length_c                   14.819(3)
_cell_measurement_reflns_used    12108
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.470
_cell_measurement_theta_min      2.860
_cell_volume                     1283.5(5)
_computing_cell_refinement       'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_molecular_graphics    'Diamond 3.2 (2012)'
_computing_publication_material  'SHELXL2018 and PLATON (Spek, 2009)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 10.3818
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.844
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0454
_diffrn_reflns_av_unetI/netI     0.0606
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.844
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            12108
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.844
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.470
_diffrn_reflns_theta_min         2.860
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    1.879
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.60324
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.832
_exptl_crystal_description       prism
_exptl_crystal_F_000             688
_exptl_crystal_size_max          0.46
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.31
_refine_diff_density_max         0.644
_refine_diff_density_min         -1.126
_refine_diff_density_rms         0.115
_refine_ls_extinction_coef       0.0479(19)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.039
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     327
_refine_ls_number_reflns         6022
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.039
_refine_ls_R_factor_all          0.0797
_refine_ls_R_factor_gt           0.0484
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0675P)²+0.0654P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1171
_refine_ls_wR_factor_ref         0.1485
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3839
_reflns_number_total             6022
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2dt03463h2.cif
_cod_data_source_block           M_CCDC1
_cod_depositor_comments
'Adding full bibliography for 7713268--7713273.cif.'
_cod_database_code               7713272
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.76008(6) 0.55622(3) 0.14838(2) 0.0671(2) Uani 1 1 d . . . . .
Sb1 Sb 0.21634(6) 0.04097(3) 0.28328(2) 0.0751(2) Uani 1 1 d . . . . .
F1 F 0.4450(7) 0.0813(6) 0.2348(4) 0.167(2) Uani 1 1 d . . . . .
F2 F 0.2069(8) 0.1915(4) 0.3003(4) 0.1486(19) Uani 1 1 d . . . . .
F3 F 0.3253(10) 0.0664(5) 0.3995(3) 0.171(3) Uani 1 1 d . . . . .
F4 F 0.2265(12) -0.1080(4) 0.2626(4) 0.184(3) Uani 1 1 d . . . . .
F5 F 0.1058(7) 0.0165(4) 0.1644(3) 0.1238(15) Uani 1 1 d . . . . .
F6 F -0.0150(9) 0.0082(7) 0.3263(5) 0.220(3) Uani 1 1 d . . . . .
N1 N 0.8097(5) 0.3748(3) 0.0943(3) 0.0525(9) Uani 1 1 d . . . . .
N2 N 0.7428(4) 0.5111(3) -0.0151(2) 0.0414(7) Uani 1 1 d . . . . .
N3 N 0.6817(5) 0.7054(3) 0.0797(3) 0.0555(9) Uani 1 1 d . . . . .
N4 N 0.8166(7) 0.6440(5) 0.2938(3) 0.0877(15) Uani 1 1 d . . . . .
C1 C 0.8407(7) 0.3070(5) 0.1508(3) 0.0648(13) Uani 1 1 d . . . . .
H1A H 0.836237 0.332438 0.213723 0.078 Uiso 1 1 calc R U . . .
C2 C 0.8782(7) 0.2039(5) 0.1224(4) 0.0659(13) Uani 1 1 d . . . . .
H2A H 0.896428 0.159982 0.164600 0.079 Uiso 1 1 calc R U . . .
C3 C 0.8884(6) 0.1671(4) 0.0312(4) 0.0606(12) Uani 1 1 d . . . . .
H3A H 0.917050 0.097801 0.009572 0.073 Uiso 1 1 calc R U . . .
C4 C 0.8555(5) 0.2340(4) -0.0301(3) 0.0497(10) Uani 1 1 d . . . . .
H4A H 0.860431 0.209597 -0.093174 0.060 Uiso 1 1 calc R U . . .
C5 C 0.8154(5) 0.3371(3) 0.0040(3) 0.0429(9) Uani 1 1 d . . . . .
C6 C 0.7738(5) 0.4126(3) -0.0570(3) 0.0399(9) Uani 1 1 d . . . . .
C7 C 0.7659(5) 0.3826(4) -0.1535(3) 0.0452(9) Uani 1 1 d . . . . .
H7A H 0.793269 0.314937 -0.181619 0.054 Uiso 1 1 calc R U . . .
C8 C 0.7173(5) 0.4535(4) -0.2069(3) 0.0472(10) Uani 1 1 d . . . . .
C9 C 0.6784(6) 0.5539(4) -0.1593(3) 0.0502(10) Uani 1 1 d . . . . .
H9A H 0.640655 0.602598 -0.192430 0.060 Uiso 1 1 calc R U . . .
C10 C 0.6950(5) 0.5819(3) -0.0648(3) 0.0422(9) Uani 1 1 d . . . . .
C11 C 0.6683(5) 0.6907(3) -0.0112(3) 0.0454(10) Uani 1 1 d . . . . .
C12 C 0.6390(6) 0.7758(4) -0.0556(4) 0.0576(11) Uani 1 1 d . . . . .
H12A H 0.632811 0.764859 -0.119553 0.069 Uiso 1 1 calc R U . . .
C13 C 0.6195(7) 0.8760(4) -0.0029(4) 0.0672(14) Uani 1 1 d . . . . .
H13A H 0.596687 0.933210 -0.030731 0.081 Uiso 1 1 calc R U . . .
C14 C 0.6341(7) 0.8904(4) 0.0908(5) 0.0728(16) Uani 1 1 d . . . . .
H14A H 0.624018 0.958246 0.127653 0.087 Uiso 1 1 calc R U . . .
C15 C 0.6632(7) 0.8050(4) 0.1295(4) 0.0666(14) Uani 1 1 d . . . . .
H15A H 0.670947 0.815292 0.193390 0.080 Uiso 1 1 calc R U . . .
C16 C 0.7089(6) 0.4253(4) -0.3085(3) 0.0544(11) Uani 1 1 d . . . . .
C17 C 0.7509(8) 0.5106(5) -0.3590(4) 0.0768(16) Uani 1 1 d . . . . .
H17A H 0.782403 0.586066 -0.328629 0.092 Uiso 1 1 calc R U . . .
C18 C 0.7460(10) 0.4840(6) -0.4531(4) 0.098(2) Uani 1 1 d . . . . .
H18A H 0.775241 0.542707 -0.485039 0.117 Uiso 1 1 calc R U . . .
C19 C 0.6999(9) 0.3746(6) -0.5025(4) 0.0865(19) Uani 1 1 d . . . . .
C20 C 0.6565(8) 0.2898(6) -0.4522(4) 0.0784(17) Uani 1 1 d . . . . .
H20A H 0.622842 0.214499 -0.483041 0.094 Uiso 1 1 calc R U . . .
C21 C 0.6622(7) 0.3149(5) -0.3562(3) 0.0660(13) Uani 1 1 d . . . . .
H21A H 0.634130 0.256244 -0.324097 0.079 Uiso 1 1 calc R U . . .
C22 C 0.6993(14) 0.3458(9) -0.6057(4) 0.139(4) Uani 1 1 d . . . . .
H22A H 0.663242 0.265063 -0.626446 0.209 Uiso 1 1 calc R U . . .
H22B H 0.611502 0.379476 -0.632617 0.209 Uiso 1 1 calc R U . . .
H22C H 0.822660 0.374511 -0.624138 0.209 Uiso 1 1 calc R U . . .
C23 C 0.8466(8) 0.7073(6) 0.3584(4) 0.0789(16) Uani 1 1 d . . . . .
C24 C 0.8816(13) 0.7870(7) 0.4473(5) 0.119(3) Uani 1 1 d . . . . .
H24A H 0.885306 0.861945 0.437632 0.178 Uiso 1 1 calc R U . . .
H24B H 0.999554 0.786037 0.476159 0.178 Uiso 1 1 calc R U . . .
H24C H 0.782748 0.765366 0.486210 0.178 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N4 Ag1 N1 122.95(19) . . ?
N4 Ag1 N2 164.25(18) . . ?
N1 Ag1 N2 68.70(12) . . ?
N4 Ag1 N3 100.29(19) . . ?
N1 Ag1 N3 136.39(13) . . ?
N2 Ag1 N3 67.76(12) . . ?
F6 Sb1 F3 90.6(4) . . ?
F6 Sb1 F4 91.7(4) . . ?
F3 Sb1 F4 91.5(3) . . ?
F6 Sb1 F1 175.7(4) . . ?
F3 Sb1 F1 92.3(3) . . ?
F4 Sb1 F1 91.4(3) . . ?
F6 Sb1 F2 89.2(4) . . ?
F3 Sb1 F2 90.1(3) . . ?
F4 Sb1 F2 178.2(3) . . ?
F1 Sb1 F2 87.6(3) . . ?
F6 Sb1 F5 89.6(3) . . ?
F3 Sb1 F5 179.5(3) . . ?
F4 Sb1 F5 89.0(2) . . ?
F1 Sb1 F5 87.5(3) . . ?
F2 Sb1 F5 89.5(2) . . ?
C5 N1 C1 117.1(4) . . ?
C5 N1 Ag1 119.9(3) . . ?
C1 N1 Ag1 122.9(3) . . ?
C6 N2 C10 120.4(3) . . ?
C6 N2 Ag1 119.1(3) . . ?
C10 N2 Ag1 120.5(3) . . ?
C11 N3 C15 118.2(5) . . ?
C11 N3 Ag1 118.2(3) . . ?
C15 N3 Ag1 123.5(4) . . ?
C23 N4 Ag1 165.1(6) . . ?
N1 C1 C2 124.7(5) . . ?
N1 C1 H1A 117.7 . . ?
C2 C1 H1A 117.7 . . ?
C3 C2 C1 118.2(5) . . ?
C3 C2 H2A 120.9 . . ?
C1 C2 H2A 120.9 . . ?
C2 C3 C4 119.2(5) . . ?
C2 C3 H3A 120.4 . . ?
C4 C3 H3A 120.4 . . ?
C5 C4 C3 119.2(4) . . ?
C5 C4 H4A 120.4 . . ?
C3 C4 H4A 120.4 . . ?
N1 C5 C4 121.6(4) . . ?
N1 C5 C6 115.8(4) . . ?
C4 C5 C6 122.6(4) . . ?
N2 C6 C7 121.0(4) . . ?
N2 C6 C5 116.4(3) . . ?
C7 C6 C5 122.6(4) . . ?
C8 C7 C6 120.2(4) . . ?
C8 C7 H7A 119.9 . . ?
C6 C7 H7A 119.9 . . ?
C7 C8 C9 116.5(4) . . ?
C7 C8 C16 121.7(4) . . ?
C9 C8 C16 121.8(4) . . ?
C10 C9 C8 121.4(4) . . ?
C10 C9 H9A 119.3 . . ?
C8 C9 H9A 119.3 . . ?
N2 C10 C9 120.5(4) . . ?
N2 C10 C11 116.0(4) . . ?
C9 C10 C11 123.5(4) . . ?
N3 C11 C12 121.6(4) . . ?
N3 C11 C10 117.4(4) . . ?
C12 C11 C10 120.9(4) . . ?
C13 C12 C11 118.7(5) . . ?
C13 C12 H12A 120.7 . . ?
C11 C12 H12A 120.7 . . ?
C14 C13 C12 119.2(5) . . ?
C14 C13 H13A 120.4 . . ?
C12 C13 H13A 120.4 . . ?
C15 C14 C13 119.2(5) . . ?
C15 C14 H14A 120.4 . . ?
C13 C14 H14A 120.4 . . ?
N3 C15 C14 123.1(5) . . ?
N3 C15 H15A 118.4 . . ?
C14 C15 H15A 118.4 . . ?
C21 C16 C17 117.9(5) . . ?
C21 C16 C8 121.6(4) . . ?
C17 C16 C8 120.5(4) . . ?
C18 C17 C16 120.3(6) . . ?
C18 C17 H17A 119.8 . . ?
C16 C17 H17A 119.8 . . ?
C17 C18 C19 123.0(6) . . ?
C17 C18 H18A 118.5 . . ?
C19 C18 H18A 118.5 . . ?
C18 C19 C20 116.6(5) . . ?
C18 C19 C22 122.8(6) . . ?
C20 C19 C22 120.6(7) . . ?
C19 C20 C21 121.4(6) . . ?
C19 C20 H20A 119.3 . . ?
C21 C20 H20A 119.3 . . ?
C16 C21 C20 120.8(5) . . ?
C16 C21 H21A 119.6 . . ?
C20 C21 H21A 119.6 . . ?
C19 C22 H22A 109.5 . . ?
C19 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C19 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
N4 C23 C24 176.9(8) . . ?
C23 C24 H24A 109.5 . . ?
C23 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C23 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N4 2.202(5) . ?
Ag1 N1 2.351(4) . ?
Ag1 N2 2.372(3) . ?
Ag1 N3 2.442(4) . ?
Sb1 F6 1.813(6) . ?
Sb1 F3 1.820(4) . ?
Sb1 F4 1.831(5) . ?
Sb1 F1 1.842(5) . ?
Sb1 F2 1.851(4) . ?
Sb1 F5 1.861(4) . ?
N1 C5 1.336(5) . ?
N1 C1 1.343(6) . ?
N2 C6 1.332(5) . ?
N2 C10 1.346(5) . ?
N3 C11 1.322(6) . ?
N3 C15 1.348(6) . ?
N4 C23 1.097(7) . ?
C1 C2 1.359(8) . ?
C1 H1A 0.9300 . ?
C2 C3 1.352(7) . ?
C2 H2A 0.9300 . ?
C3 C4 1.393(6) . ?
C3 H3A 0.9300 . ?
C4 C5 1.381(6) . ?
C4 H4A 0.9300 . ?
C5 C6 1.491(6) . ?
C6 C7 1.402(6) . ?
C7 C8 1.387(6) . ?
C7 H7A 0.9300 . ?
C8 C9 1.402(6) . ?
C8 C16 1.475(6) . ?
C9 C10 1.373(6) . ?
C9 H9A 0.9300 . ?
C10 C11 1.485(6) . ?
C11 C12 1.398(6) . ?
C12 C13 1.374(7) . ?
C12 H12A 0.9300 . ?
C13 C14 1.364(8) . ?
C13 H13A 0.9300 . ?
C14 C15 1.350(8) . ?
C14 H14A 0.9300 . ?
C15 H15A 0.9300 . ?
C16 C21 1.375(7) . ?
C16 C17 1.391(7) . ?
C17 C18 1.367(8) . ?
C17 H17A 0.9300 . ?
C18 C19 1.373(9) . ?
C18 H18A 0.9300 . ?
C19 C20 1.385(9) . ?
C19 C22 1.503(8) . ?
C20 C21 1.393(7) . ?
C20 H20A 0.9300 . ?
C21 H21A 0.9300 . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C23 C24 1.465(9) . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 N1 C1 C2 0.4(7) . . . . ?
Ag1 N1 C1 C2 -176.9(4) . . . . ?
N1 C1 C2 C3 1.2(8) . . . . ?
C1 C2 C3 C4 -1.7(7) . . . . ?
C2 C3 C4 C5 0.8(6) . . . . ?
C1 N1 C5 C4 -1.3(6) . . . . ?
Ag1 N1 C5 C4 176.0(3) . . . . ?
C1 N1 C5 C6 178.0(4) . . . . ?
Ag1 N1 C5 C6 -4.7(4) . . . . ?
C3 C4 C5 N1 0.8(6) . . . . ?
C3 C4 C5 C6 -178.4(3) . . . . ?
C10 N2 C6 C7 2.9(5) . . . . ?
Ag1 N2 C6 C7 -179.7(3) . . . . ?
C10 N2 C6 C5 -176.7(3) . . . . ?
Ag1 N2 C6 C5 0.7(4) . . . . ?
N1 C5 C6 N2 2.6(5) . . . . ?
C4 C5 C6 N2 -178.2(3) . . . . ?
N1 C5 C6 C7 -177.0(3) . . . . ?
C4 C5 C6 C7 2.3(5) . . . . ?
N2 C6 C7 C8 -2.8(5) . . . . ?
C5 C6 C7 C8 176.7(3) . . . . ?
C6 C7 C8 C9 0.1(5) . . . . ?
C6 C7 C8 C16 179.5(4) . . . . ?
C7 C8 C9 C10 2.4(6) . . . . ?
C16 C8 C9 C10 -177.0(4) . . . . ?
C6 N2 C10 C9 -0.3(5) . . . . ?
Ag1 N2 C10 C9 -177.7(3) . . . . ?
C6 N2 C10 C11 -178.5(3) . . . . ?
Ag1 N2 C10 C11 4.1(4) . . . . ?
C8 C9 C10 N2 -2.4(6) . . . . ?
C8 C9 C10 C11 175.7(3) . . . . ?
C15 N3 C11 C12 1.0(6) . . . . ?
Ag1 N3 C11 C12 -174.8(3) . . . . ?
C15 N3 C11 C10 178.1(4) . . . . ?
Ag1 N3 C11 C10 2.3(4) . . . . ?
N2 C10 C11 N3 -4.2(5) . . . . ?
C9 C10 C11 N3 177.6(4) . . . . ?
N2 C10 C11 C12 172.9(3) . . . . ?
C9 C10 C11 C12 -5.3(6) . . . . ?
N3 C11 C12 C13 -1.5(6) . . . . ?
C10 C11 C12 C13 -178.5(4) . . . . ?
C11 C12 C13 C14 1.7(7) . . . . ?
C12 C13 C14 C15 -1.4(7) . . . . ?
C11 N3 C15 C14 -0.8(7) . . . . ?
Ag1 N3 C15 C14 174.8(4) . . . . ?
C13 C14 C15 N3 1.0(8) . . . . ?
C7 C8 C16 C21 30.6(6) . . . . ?
C9 C8 C16 C21 -150.1(4) . . . . ?
C7 C8 C16 C17 -148.5(5) . . . . ?
C9 C8 C16 C17 30.8(7) . . . . ?
C21 C16 C17 C18 -0.3(9) . . . . ?
C8 C16 C17 C18 178.9(6) . . . . ?
C16 C17 C18 C19 0.3(11) . . . . ?
C17 C18 C19 C20 0.3(11) . . . . ?
C17 C18 C19 C22 -178.5(8) . . . . ?
C18 C19 C20 C21 -0.9(10) . . . . ?
C22 C19 C20 C21 177.9(7) . . . . ?
C17 C16 C21 C20 -0.3(8) . . . . ?
C8 C16 C21 C20 -179.4(5) . . . . ?
C19 C20 C21 C16 0.9(9) . . . . ?
