#------------------------------------------------------------------------------
#$Date: 2023-10-07 02:08:16 +0300 (Sat, 07 Oct 2023) $
#$Revision: 286838 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/41/7714158.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7714158
loop_
_publ_author_name
'Franc, Michal'
'Vosahlo, Petr'
'Schulz, Jiří'
'Cisarova, Ivana'
'Štěpnička, Petr'
_publ_section_title
;
 Synthesis and reactivity of Pd(II) imidoyl complexes obtained by
 insertion of isocyanoferrocene into the Pd-C bonds of orthopalladated
 precursors
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D3DT02717A
_journal_year                    2023
_chemical_formula_moiety         'C23 H30 Cl Fe N2 P Pd, 0.35(H2 O)'
_chemical_formula_sum            'C23 H30.7 Cl Fe N2 O0.35 P Pd'
_chemical_formula_weight         569.60
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2023-08-15 deposited with the CCDC.	2023-10-06 downloaded from the CCDC.
;
_cell_angle_alpha                101.004(2)
_cell_angle_beta                 95.440(2)
_cell_angle_gamma                96.566(2)
_cell_formula_units_Z            4
_cell_length_a                   10.3488(5)
_cell_length_b                   13.7820(7)
_cell_length_c                   17.1619(9)
_cell_measurement_reflns_used    9834
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.50
_cell_measurement_theta_min      2.44
_cell_volume                     2369.9(2)
_computing_cell_refinement       'SAINT V8.38A (Bruker AXS Inc., 2017)'
_computing_data_collection       'Bruker Instrument Service vV6.2.10'
_computing_data_reduction        'SAINT V8.38A (Bruker AXS Inc., 2017)'
_computing_molecular_graphics    'PLATON (Spek, 2017)'
_computing_publication_material  'PLATON (Spek, 2017)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker D8 VENTURE Kappa Duo'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  'Quazar Mo multilayer optic'
_diffrn_radiation_source         'I\mS micro-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0199
_diffrn_reflns_av_unetI/netI     0.0180
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            46893
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.515
_diffrn_reflns_theta_min         2.338
_exptl_absorpt_coefficient_mu    1.565
_exptl_absorpt_correction_T_max  0.80
_exptl_absorpt_correction_T_min  0.69
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS-2016/2 - Bruker AXS'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.596
_exptl_crystal_description       prism
_exptl_crystal_F_000             1158
_exptl_crystal_size_max          0.49
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.618
_refine_diff_density_min         -0.794
_refine_diff_density_rms         0.075
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.078
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     535
_refine_ls_number_reflns         10857
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.078
_refine_ls_R_factor_all          0.0225
_refine_ls_R_factor_gt           0.0208
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0224P)²+1.7290P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0500
_refine_ls_wR_factor_ref         0.0510
_reflns_Friedel_coverage         0.000
_reflns_number_gt                10235
_reflns_number_total             10857
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d3dt02717a3.cif
_cod_data_source_block           mf19
_cod_original_formula_sum        'C23 H30.70 Cl Fe N2 O0.35 P Pd'
_cod_database_code               7714158
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.514
_shelx_estimated_absorpt_t_max   0.799
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pd1 Pd 0.49102(2) 0.19535(2) 0.27872(2) 0.01171(3) Uani 1 1 d . . . . .
Fe1 Fe 0.28187(2) 0.28417(2) 0.51992(2) 0.01414(5) Uani 1 1 d . . . . .
Cl1 Cl 0.51502(4) 0.02871(3) 0.21237(2) 0.02234(8) Uani 1 1 d . . . . .
P1 P 0.68717(4) 0.20130(3) 0.34976(2) 0.01528(8) Uani 1 1 d . . . . .
N1 N 0.45045(12) 0.37031(9) 0.40337(8) 0.0152(2) Uani 1 1 d . . . . .
N2 N 0.30069(13) 0.19192(10) 0.20730(8) 0.0168(3) Uani 1 1 d . . . . .
C1 C 0.47152(14) 0.33223(11) 0.33283(9) 0.0141(3) Uani 1 1 d . . . . .
C2 C 0.46691(16) 0.39512(11) 0.27099(9) 0.0171(3) Uani 1 1 d . . . . .
C3 C 0.35845(17) 0.37270(12) 0.21218(10) 0.0204(3) Uani 1 1 d . . . . .
C4 C 0.3507(2) 0.42732(15) 0.15174(11) 0.0309(4) Uani 1 1 d . . . . .
H4 H 0.276812 0.413222 0.112115 0.037 Uiso 1 1 calc R U . . .
C5 C 0.4511(2) 0.50222(15) 0.14953(12) 0.0373(5) Uani 1 1 d . . . . .
H5 H 0.446632 0.538360 0.107651 0.045 Uiso 1 1 calc R U . . .
C6 C 0.5572(2) 0.52447(14) 0.20780(12) 0.0334(4) Uani 1 1 d . . . . .
H6 H 0.624971 0.576429 0.206107 0.040 Uiso 1 1 calc R U . . .
C7 C 0.56609(18) 0.47159(12) 0.26910(11) 0.0242(3) Uani 1 1 d . . . . .
H7 H 0.639221 0.487539 0.309320 0.029 Uiso 1 1 calc R U . . .
C8 C 0.25295(16) 0.29103(13) 0.21852(10) 0.0211(3) Uani 1 1 d . . . . .
H8A H 0.221735 0.306215 0.271714 0.025 Uiso 1 1 calc R U . . .
H8B H 0.177918 0.288522 0.177519 0.025 Uiso 1 1 calc R U . . .
C9 C 0.20574(16) 0.12006(14) 0.23413(11) 0.0253(4) Uani 1 1 d . . . . .
H9A H 0.119549 0.115671 0.203625 0.038 Uiso 1 1 calc R U . . .
H9B H 0.199482 0.142757 0.291181 0.038 Uiso 1 1 calc R U . . .
H9C H 0.235391 0.054222 0.225328 0.038 Uiso 1 1 calc R U . . .
C10 C 0.30834(17) 0.15700(14) 0.12088(10) 0.0237(3) Uani 1 1 d . . . . .
H10A H 0.340031 0.091900 0.112213 0.036 Uiso 1 1 calc R U . . .
H10B H 0.368860 0.205153 0.102162 0.036 Uiso 1 1 calc R U . . .
H10C H 0.221172 0.150871 0.091123 0.036 Uiso 1 1 calc R U . . .
C11 C 0.44525(14) 0.31525(11) 0.46473(9) 0.0147(3) Uani 1 1 d . . . . .
C12 C 0.46531(15) 0.36478(12) 0.54707(9) 0.0181(3) Uani 1 1 d . . . . .
H12 H 0.485309 0.434702 0.566749 0.022 Uiso 1 1 calc R U . . .
C13 C 0.44998(15) 0.29069(14) 0.59421(10) 0.0213(3) Uani 1 1 d . . . . .
H13 H 0.458648 0.302703 0.650958 0.026 Uiso 1 1 calc R U . . .
C14 C 0.41945(16) 0.19548(13) 0.54194(10) 0.0212(3) Uani 1 1 d . . . . .
H14 H 0.404468 0.133145 0.557763 0.025 Uiso 1 1 calc R U . . .
C15 C 0.41525(15) 0.21005(12) 0.46142(9) 0.0171(3) Uani 1 1 d . . . . .
H15 H 0.396112 0.159367 0.414344 0.021 Uiso 1 1 calc R U . . .
C16 C 0.12487(18) 0.31089(19) 0.45150(13) 0.0383(5) Uani 1 1 d . . . . .
H16 H 0.126420 0.327200 0.400225 0.046 Uiso 1 1 calc R U . . .
C17 C 0.14470(19) 0.37925(15) 0.52564(16) 0.0420(6) Uani 1 1 d . . . . .
H17 H 0.161678 0.449818 0.532989 0.050 Uiso 1 1 calc R U . . .
C18 C 0.13496(18) 0.32477(18) 0.58641(12) 0.0379(5) Uani 1 1 d . . . . .
H18 H 0.144032 0.351945 0.642151 0.045 Uiso 1 1 calc R U . . .
C19 C 0.10946(17) 0.22299(16) 0.55052(13) 0.0338(4) Uani 1 1 d . . . . .
H19 H 0.098855 0.169395 0.577920 0.041 Uiso 1 1 calc R U . . .
C20 C 0.10231(17) 0.21388(16) 0.46743(12) 0.0328(4) Uani 1 1 d . . . . .
H20 H 0.085316 0.153274 0.428711 0.039 Uiso 1 1 calc R U . . .
C21 C 0.75765(17) 0.31180(14) 0.42400(11) 0.0252(4) Uani 1 1 d . . . . .
H21A H 0.844590 0.302307 0.446890 0.038 Uiso 1 1 calc R U . . .
H21B H 0.700852 0.322844 0.466509 0.038 Uiso 1 1 calc R U . . .
H21C H 0.765526 0.369814 0.398622 0.038 Uiso 1 1 calc R U . . .
C22 C 0.69638(18) 0.09988(14) 0.40290(11) 0.0262(4) Uani 1 1 d . . . . .
H22A H 0.665569 0.036178 0.365897 0.039 Uiso 1 1 calc R U . . .
H22B H 0.641212 0.108333 0.446424 0.039 Uiso 1 1 calc R U . . .
H22C H 0.787338 0.100369 0.425058 0.039 Uiso 1 1 calc R U . . .
C23 C 0.81347(16) 0.18545(13) 0.28363(10) 0.0231(3) Uani 1 1 d . . . . .
H23A H 0.894153 0.175002 0.313825 0.035 Uiso 1 1 calc R U . . .
H23B H 0.830189 0.245313 0.261179 0.035 Uiso 1 1 calc R U . . .
H23C H 0.784250 0.127471 0.240181 0.035 Uiso 1 1 calc R U . . .
Pd2 Pd 0.02258(2) 0.80690(2) 0.23463(2) 0.01216(3) Uani 1 1 d . . . . .
Fe2 Fe 0.23050(2) 0.78517(2) -0.00842(2) 0.01480(5) Uani 1 1 d . . . . .
Cl2 Cl 0.01338(4) 0.96233(3) 0.32565(3) 0.02626(9) Uani 1 1 d . . . . .
P2 P -0.17345(4) 0.82120(3) 0.17226(2) 0.01592(8) Uani 1 1 d . . . . .
N3 N 0.05084(12) 0.66549(9) 0.08414(7) 0.0136(2) Uani 1 1 d . . . . .
N4 N 0.20684(13) 0.78136(10) 0.29800(8) 0.0178(3) Uani 1 1 d . . . . .
C31 C 0.03103(14) 0.68242(11) 0.15757(9) 0.0127(3) Uani 1 1 d . . . . .
C32 C 0.02306(15) 0.59840(11) 0.20092(9) 0.0148(3) Uani 1 1 d . . . . .
C33 C 0.12630(15) 0.59956(12) 0.26024(10) 0.0183(3) Uani 1 1 d . . . . .
C34 C 0.11981(18) 0.52657(14) 0.30633(11) 0.0258(4) Uani 1 1 d . . . . .
H34 H 0.189881 0.526398 0.346275 0.031 Uiso 1 1 calc R U . . .
C35 C 0.01087(19) 0.45400(14) 0.29393(12) 0.0286(4) Uani 1 1 d . . . . .
H35 H 0.005679 0.405314 0.326339 0.034 Uiso 1 1 calc R U . . .
C36 C -0.08980(18) 0.45242(13) 0.23468(11) 0.0253(4) Uani 1 1 d . . . . .
H36 H -0.163398 0.402041 0.225961 0.030 Uiso 1 1 calc R U . . .
C37 C -0.08397(16) 0.52426(12) 0.18770(10) 0.0196(3) Uani 1 1 d . . . . .
H37 H -0.153055 0.522605 0.146653 0.024 Uiso 1 1 calc R U . . .
C38 C 0.24182(15) 0.67942(13) 0.26939(10) 0.0210(3) Uani 1 1 d . . . . .
H38A H 0.312019 0.666430 0.307879 0.025 Uiso 1 1 calc R U . . .
H38B H 0.276291 0.676603 0.217240 0.025 Uiso 1 1 calc R U . . .
C39 C 0.31269(17) 0.85652(14) 0.28561(11) 0.0265(4) Uani 1 1 d . . . . .
H39A H 0.292983 0.923550 0.307393 0.040 Uiso 1 1 calc R U . . .
H39B H 0.319243 0.849617 0.228270 0.040 Uiso 1 1 calc R U . . .
H39C H 0.395993 0.846210 0.312956 0.040 Uiso 1 1 calc R U . . .
C40 C 0.19658(18) 0.79417(15) 0.38480(10) 0.0267(4) Uani 1 1 d . . . . .
H40A H 0.280981 0.787521 0.412982 0.040 Uiso 1 1 calc R U . . .
H40B H 0.129040 0.743009 0.393926 0.040 Uiso 1 1 calc R U . . .
H40C H 0.172923 0.860458 0.404908 0.040 Uiso 1 1 calc R U . . .
C41 C 0.06495(14) 0.74222(11) 0.04060(9) 0.0145(3) Uani 1 1 d . . . . .
C42 C 0.04112(15) 0.72190(13) -0.04508(9) 0.0196(3) Uani 1 1 d . . . . .
H42 H 0.013450 0.658323 -0.078810 0.024 Uiso 1 1 calc R U . . .
C43 C 0.06631(16) 0.81401(15) -0.07054(10) 0.0251(4) Uani 1 1 d . . . . .
H43 H 0.057410 0.822594 -0.124320 0.030 Uiso 1 1 calc R U . . .
C44 C 0.10704(17) 0.89089(13) -0.00178(11) 0.0242(4) Uani 1 1 d . . . . .
H44 H 0.130021 0.959634 -0.001756 0.029 Uiso 1 1 calc R U . . .
C45 C 0.10755(15) 0.84718(12) 0.06733(10) 0.0175(3) Uani 1 1 d . . . . .
H45 H 0.131701 0.881399 0.121205 0.021 Uiso 1 1 calc R U . . .
C46 C 0.3906(4) 0.7425(3) 0.0503(3) 0.0243(3) Uani 0.533(5) 1 d . . P A 1
H46 H 0.393588 0.724192 0.101043 0.029 Uiso 0.533(5) 1 calc R U P A 1
C47 C 0.3564(3) 0.6771(3) -0.0243(3) 0.0243(3) Uani 0.533(5) 1 d . . P A 1
H47 H 0.332273 0.606950 -0.032657 0.029 Uiso 0.533(5) 1 calc R U P A 1
C48 C 0.3641(3) 0.7334(4) -0.0846(2) 0.0243(3) Uani 0.533(5) 1 d . . P A 1
H48 H 0.347011 0.707202 -0.140450 0.029 Uiso 0.533(5) 1 calc R U P A 1
C49 C 0.4013(3) 0.8353(3) -0.0485(3) 0.0243(3) Uani 0.533(5) 1 d . . P A 1
H49 H 0.411966 0.889358 -0.075336 0.029 Uiso 0.533(5) 1 calc R U P A 1
C50 C 0.4201(4) 0.8416(3) 0.0366(3) 0.0243(3) Uani 0.533(5) 1 d . . P A 1
H50 H 0.447094 0.900538 0.076245 0.029 Uiso 0.533(5) 1 calc R U P A 1
C46D C 0.3747(4) 0.7137(4) 0.0312(3) 0.0243(3) Uani 0.467(5) 1 d . . P A 2
H46D H 0.366909 0.669213 0.067033 0.029 Uiso 0.467(5) 1 calc R U P A 2
C47D C 0.3501(4) 0.6868(4) -0.0527(3) 0.0243(3) Uani 0.467(5) 1 d . . P A 2
H47D H 0.324085 0.620969 -0.082945 0.029 Uiso 0.467(5) 1 calc R U P A 2
C48D C 0.3707(4) 0.7736(5) -0.0842(3) 0.0243(3) Uani 0.467(5) 1 d . . P A 2
H48D H 0.360118 0.776551 -0.139258 0.029 Uiso 0.467(5) 1 calc R U P A 2
C49D C 0.4101(4) 0.8563(4) -0.0193(3) 0.0243(3) Uani 0.467(5) 1 d . . P A 2
H49D H 0.430806 0.923993 -0.023247 0.029 Uiso 0.467(5) 1 calc R U P A 2
C50D C 0.4130(4) 0.8185(4) 0.0536(3) 0.0243(3) Uani 0.467(5) 1 d . . P A 2
H50D H 0.436027 0.856482 0.106455 0.029 Uiso 0.467(5) 1 calc R U P A 2
C51 C -0.25161(17) 0.72712(14) 0.08696(11) 0.0268(4) Uani 1 1 d . . . . .
H51A H -0.338724 0.742898 0.070441 0.040 Uiso 1 1 calc R U . . .
H51B H -0.260072 0.661597 0.101699 0.040 Uiso 1 1 calc R U . . .
H51C H -0.198257 0.726026 0.042653 0.040 Uiso 1 1 calc R U . . .
C52 C -0.17512(19) 0.93525(14) 0.13518(12) 0.0306(4) Uani 1 1 d . . . . .
H52A H -0.265899 0.944896 0.120457 0.046 Uiso 1 1 calc R U . . .
H52B H -0.127766 0.931039 0.088089 0.046 Uiso 1 1 calc R U . . .
H52C H -0.132613 0.991705 0.176875 0.046 Uiso 1 1 calc R U . . .
C53 C -0.29428(17) 0.82508(14) 0.24237(11) 0.0260(4) Uani 1 1 d . . . . .
H53A H -0.264273 0.879289 0.288706 0.039 Uiso 1 1 calc R U . . .
H53B H -0.305946 0.761427 0.260044 0.039 Uiso 1 1 calc R U . . .
H53C H -0.377900 0.836604 0.216230 0.039 Uiso 1 1 calc R U . . .
O1W O 0.16169(19) 0.48872(14) 0.01223(11) 0.0309(6) Uani 0.707(5) 1 d . . P . .
H2W H 0.081281 0.443932 -0.015586 0.037 Uiso 0.707(5) 1 d R U P . .
H1W H 0.126892 0.550098 0.038372 0.037 Uiso 0.707(5) 1 d R U P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Pd1 N2 87.46(6) . . ?
C1 Pd1 P1 92.16(4) . . ?
N2 Pd1 P1 178.63(4) . . ?
C1 Pd1 Cl1 179.80(5) . . ?
N2 Pd1 Cl1 92.50(4) . . ?
P1 Pd1 Cl1 87.880(15) . . ?
C16 Fe1 C14 150.39(9) . . ?
C16 Fe1 C20 40.75(9) . . ?
C14 Fe1 C20 116.65(8) . . ?
C16 Fe1 C17 40.75(10) . . ?
C14 Fe1 C17 166.83(9) . . ?
C20 Fe1 C17 68.17(8) . . ?
C16 Fe1 C15 116.62(8) . . ?
C14 Fe1 C15 41.16(6) . . ?
C20 Fe1 C15 106.18(7) . . ?
C17 Fe1 C15 151.55(9) . . ?
C16 Fe1 C13 167.33(9) . . ?
C14 Fe1 C13 40.93(7) . . ?
C20 Fe1 C13 151.06(8) . . ?
C17 Fe1 C13 129.44(9) . . ?
C15 Fe1 C13 69.09(7) . . ?
C16 Fe1 C19 68.03(8) . . ?
C14 Fe1 C19 107.47(7) . . ?
C20 Fe1 C19 40.21(9) . . ?
C17 Fe1 C19 67.65(8) . . ?
C15 Fe1 C19 126.95(8) . . ?
C13 Fe1 C19 118.67(8) . . ?
C16 Fe1 C18 67.98(9) . . ?
C14 Fe1 C18 128.47(8) . . ?
C20 Fe1 C18 67.69(8) . . ?
C17 Fe1 C18 40.10(10) . . ?
C15 Fe1 C18 165.54(9) . . ?
C13 Fe1 C18 109.50(7) . . ?
C19 Fe1 C18 40.12(9) . . ?
C16 Fe1 C12 128.72(8) . . ?
C14 Fe1 C12 68.88(7) . . ?
C20 Fe1 C12 166.33(8) . . ?
C17 Fe1 C12 109.44(8) . . ?
C15 Fe1 C12 69.14(6) . . ?
C13 Fe1 C12 40.71(7) . . ?
C19 Fe1 C12 152.65(8) . . ?
C18 Fe1 C12 119.81(7) . . ?
C16 Fe1 C11 107.67(7) . . ?
C14 Fe1 C11 68.88(6) . . ?
C20 Fe1 C11 127.51(7) . . ?
C17 Fe1 C11 118.99(8) . . ?
C15 Fe1 C11 41.08(6) . . ?
C13 Fe1 C11 68.56(6) . . ?
C19 Fe1 C11 165.29(8) . . ?
C18 Fe1 C11 152.93(8) . . ?
C12 Fe1 C11 40.79(6) . . ?
C22 P1 C23 103.35(8) . . ?
C22 P1 C21 103.98(9) . . ?
C23 P1 C21 102.80(8) . . ?
C22 P1 Pd1 113.64(6) . . ?
C23 P1 Pd1 110.42(6) . . ?
C21 P1 Pd1 120.80(6) . . ?
C1 N1 C11 122.65(13) . . ?
C9 N2 C10 108.83(13) . . ?
C9 N2 C8 109.19(13) . . ?
C10 N2 C8 108.15(13) . . ?
C9 N2 Pd1 106.57(10) . . ?
C10 N2 Pd1 111.18(10) . . ?
C8 N2 Pd1 112.84(10) . . ?
N1 C1 C2 118.42(13) . . ?
N1 C1 Pd1 133.37(12) . . ?
C2 C1 Pd1 107.77(10) . . ?
C7 C2 C3 120.11(15) . . ?
C7 C2 C1 122.76(15) . . ?
C3 C2 C1 117.12(14) . . ?
C4 C3 C2 119.56(17) . . ?
C4 C3 C8 122.76(16) . . ?
C2 C3 C8 117.66(14) . . ?
C5 C4 C3 119.94(19) . . ?
C5 C4 H4 120.0 . . ?
C3 C4 H4 120.0 . . ?
C6 C5 C4 120.30(17) . . ?
C6 C5 H5 119.8 . . ?
C4 C5 H5 119.8 . . ?
C5 C6 C7 120.65(18) . . ?
C5 C6 H6 119.7 . . ?
C7 C6 H6 119.7 . . ?
C6 C7 C2 119.43(18) . . ?
C6 C7 H7 120.3 . . ?
C2 C7 H7 120.3 . . ?
N2 C8 C3 111.82(13) . . ?
N2 C8 H8A 109.3 . . ?
C3 C8 H8A 109.3 . . ?
N2 C8 H8B 109.3 . . ?
C3 C8 H8B 109.3 . . ?
H8A C8 H8B 107.9 . . ?
N2 C9 H9A 109.5 . . ?
N2 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
N2 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
N2 C10 H10A 109.5 . . ?
N2 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
N2 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
N1 C11 C12 120.80(14) . . ?
N1 C11 C15 131.16(14) . . ?
C12 C11 C15 107.96(14) . . ?
N1 C11 Fe1 124.87(10) . . ?
C12 C11 Fe1 69.38(8) . . ?
C15 C11 Fe1 68.71(8) . . ?
C13 C12 C11 107.87(14) . . ?
C13 C12 Fe1 69.21(9) . . ?
C11 C12 Fe1 69.84(9) . . ?
C13 C12 H12 126.1 . . ?
C11 C12 H12 126.1 . . ?
Fe1 C12 H12 126.5 . . ?
C12 C13 C14 108.47(14) . . ?
C12 C13 Fe1 70.08(9) . . ?
C14 C13 Fe1 69.31(9) . . ?
C12 C13 H13 125.8 . . ?
C14 C13 H13 125.8 . . ?
Fe1 C13 H13 126.4 . . ?
C13 C14 C15 108.12(14) . . ?
C13 C14 Fe1 69.76(9) . . ?
C15 C14 Fe1 69.55(9) . . ?
C13 C14 H14 125.9 . . ?
C15 C14 H14 125.9 . . ?
Fe1 C14 H14 126.3 . . ?
C14 C15 C11 107.57(14) . . ?
C14 C15 Fe1 69.28(9) . . ?
C11 C15 Fe1 70.21(8) . . ?
C14 C15 H15 126.2 . . ?
C11 C15 H15 126.2 . . ?
Fe1 C15 H15 125.9 . . ?
C20 C16 C17 107.63(18) . . ?
C20 C16 Fe1 70.06(11) . . ?
C17 C16 Fe1 70.09(11) . . ?
C20 C16 H16 126.2 . . ?
C17 C16 H16 126.2 . . ?
Fe1 C16 H16 125.3 . . ?
C18 C17 C16 108.06(19) . . ?
C18 C17 Fe1 70.53(11) . . ?
C16 C17 Fe1 69.16(11) . . ?
C18 C17 H17 126.0 . . ?
C16 C17 H17 126.0 . . ?
Fe1 C17 H17 125.9 . . ?
C17 C18 C19 108.07(18) . . ?
C17 C18 Fe1 69.37(11) . . ?
C19 C18 Fe1 69.63(10) . . ?
C17 C18 H18 126.0 . . ?
C19 C18 H18 126.0 . . ?
Fe1 C18 H18 126.6 . . ?
C20 C19 C18 108.41(19) . . ?
C20 C19 Fe1 69.60(10) . . ?
C18 C19 Fe1 70.25(11) . . ?
C20 C19 H19 125.8 . . ?
C18 C19 H19 125.8 . . ?
Fe1 C19 H19 125.9 . . ?
C19 C20 C16 107.83(18) . . ?
C19 C20 Fe1 70.20(11) . . ?
C16 C20 Fe1 69.19(11) . . ?
C19 C20 H20 126.1 . . ?
C16 C20 H20 126.1 . . ?
Fe1 C20 H20 126.1 . . ?
P1 C21 H21A 109.5 . . ?
P1 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
P1 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
P1 C22 H22A 109.5 . . ?
P1 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
P1 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
P1 C23 H23A 109.5 . . ?
P1 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
P1 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C31 Pd2 N4 87.27(6) . . ?
C31 Pd2 P2 90.59(4) . . ?
N4 Pd2 P2 175.26(4) . . ?
C31 Pd2 Cl2 178.15(4) . . ?
N4 Pd2 Cl2 93.45(4) . . ?
P2 Pd2 Cl2 88.819(16) . . ?
C46D Fe2 C47D 40.74(17) . . ?
C46D Fe2 C50D 41.07(17) . . ?
C47D Fe2 C50D 68.90(19) . . ?
C46D Fe2 C48D 68.66(18) . . ?
C47D Fe2 C48D 40.49(17) . . ?
C50D Fe2 C48D 69.20(18) . . ?
C46D Fe2 C43 161.90(16) . . ?
C47D Fe2 C43 124.93(16) . . ?
C50D Fe2 C43 155.72(16) . . ?
C48D Fe2 C43 107.31(13) . . ?
C46D Fe2 C44 156.16(16) . . ?
C47D Fe2 C44 161.04(18) . . ?
C50D Fe2 C44 119.85(15) . . ?
C48D Fe2 C44 123.72(16) . . ?
C43 Fe2 C44 40.79(8) . . ?
C46D Fe2 C42 124.97(15) . . ?
C47D Fe2 C42 108.35(13) . . ?
C50D Fe2 C42 161.44(16) . . ?
C48D Fe2 C42 121.42(14) . . ?
C43 Fe2 C42 40.87(7) . . ?
C44 Fe2 C42 68.87(7) . . ?
C46D Fe2 C49D 69.09(19) . . ?
C47D Fe2 C49D 68.59(17) . . ?
C50D Fe2 C49D 41.43(16) . . ?
C48D Fe2 C49D 40.87(16) . . ?
C43 Fe2 C49D 120.19(15) . . ?
C44 Fe2 C49D 105.99(14) . . ?
C42 Fe2 C49D 156.22(16) . . ?
C46D Fe2 C45 120.87(15) . . ?
C47D Fe2 C45 157.21(18) . . ?
C50D Fe2 C45 105.84(14) . . ?
C48D Fe2 C45 160.32(18) . . ?
C43 Fe2 C45 68.96(7) . . ?
C44 Fe2 C45 40.97(6) . . ?
C42 Fe2 C45 69.22(7) . . ?
C49D Fe2 C45 123.00(15) . . ?
C43 Fe2 C50 143.76(14) . . ?
C44 Fe2 C50 113.42(13) . . ?
C42 Fe2 C50 174.81(14) . . ?
C45 Fe2 C50 109.20(13) . . ?
C43 Fe2 C49 113.73(13) . . ?
C44 Fe2 C49 110.30(12) . . ?
C42 Fe2 C49 143.35(14) . . ?
C45 Fe2 C49 135.40(14) . . ?
C50 Fe2 C49 41.09(14) . . ?
C46D Fe2 C41 107.81(14) . . ?
C47D Fe2 C41 122.30(15) . . ?
C50D Fe2 C41 123.76(15) . . ?
C48D Fe2 C41 157.38(17) . . ?
C43 Fe2 C41 68.73(6) . . ?
C44 Fe2 C41 68.73(6) . . ?
C42 Fe2 C41 41.02(6) . . ?
C49D Fe2 C41 160.68(16) . . ?
C45 Fe2 C41 40.99(6) . . ?
C50 Fe2 C41 134.68(14) . . ?
C49 Fe2 C41 175.34(15) . . ?
C52 P2 C51 102.68(10) . . ?
C52 P2 C53 105.28(8) . . ?
C51 P2 C53 103.50(9) . . ?
C52 P2 Pd2 113.38(7) . . ?
C51 P2 Pd2 120.92(6) . . ?
C53 P2 Pd2 109.62(6) . . ?
C31 N3 C41 122.11(13) . . ?
C39 N4 C40 108.74(13) . . ?
C39 N4 C38 109.10(13) . . ?
C40 N4 C38 107.95(13) . . ?
C39 N4 Pd2 108.02(10) . . ?
C40 N4 Pd2 110.03(10) . . ?
C38 N4 Pd2 112.93(10) . . ?
N3 C31 C32 119.21(13) . . ?
N3 C31 Pd2 132.19(11) . . ?
C32 C31 Pd2 108.36(10) . . ?
C37 C32 C33 120.09(14) . . ?
C37 C32 C31 122.80(14) . . ?
C33 C32 C31 117.01(13) . . ?
C34 C33 C32 119.47(15) . . ?
C34 C33 C38 123.03(15) . . ?
C32 C33 C38 117.48(14) . . ?
C35 C34 C33 120.04(16) . . ?
C35 C34 H34 120.0 . . ?
C33 C34 H34 120.0 . . ?
C36 C35 C34 120.24(16) . . ?
C36 C35 H35 119.9 . . ?
C34 C35 H35 119.9 . . ?
C35 C36 C37 120.30(16) . . ?
C35 C36 H36 119.8 . . ?
C37 C36 H36 119.8 . . ?
C32 C37 C36 119.84(15) . . ?
C32 C37 H37 120.1 . . ?
C36 C37 H37 120.1 . . ?
N4 C38 C33 112.18(13) . . ?
N4 C38 H38A 109.2 . . ?
C33 C38 H38A 109.2 . . ?
N4 C38 H38B 109.2 . . ?
C33 C38 H38B 109.2 . . ?
H38A C38 H38B 107.9 . . ?
N4 C39 H39A 109.5 . . ?
N4 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
N4 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
N4 C40 H40A 109.5 . . ?
N4 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
N4 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
N3 C41 C42 121.65(14) . . ?
N3 C41 C45 130.48(14) . . ?
C42 C41 C45 107.82(13) . . ?
N3 C41 Fe2 125.34(10) . . ?
C42 C41 Fe2 68.93(8) . . ?
C45 C41 Fe2 69.07(8) . . ?
C43 C42 C41 107.84(15) . . ?
C43 C42 Fe2 69.48(9) . . ?
C41 C42 Fe2 70.05(9) . . ?
C43 C42 H42 126.1 . . ?
C41 C42 H42 126.1 . . ?
Fe2 C42 H42 126.0 . . ?
C44 C43 C42 108.36(14) . . ?
C44 C43 Fe2 69.64(10) . . ?
C42 C43 Fe2 69.65(9) . . ?
C44 C43 H43 125.8 . . ?
C42 C43 H43 125.8 . . ?
Fe2 C43 H43 126.5 . . ?
C43 C44 C45 108.37(15) . . ?
C43 C44 Fe2 69.57(10) . . ?
C45 C44 Fe2 69.69(9) . . ?
C43 C44 H44 125.8 . . ?
C45 C44 H44 125.8 . . ?
Fe2 C44 H44 126.5 . . ?
C44 C45 C41 107.60(14) . . ?
C44 C45 Fe2 69.34(9) . . ?
C41 C45 Fe2 69.94(8) . . ?
C44 C45 H45 126.2 . . ?
C41 C45 H45 126.2 . . ?
Fe2 C45 H45 126.1 . . ?
C47 C46 C50 108.1(4) . . ?
C47 C46 Fe2 71.2(2) . . ?
C50 C46 Fe2 69.1(2) . . ?
C47 C46 H46 125.9 . . ?
C50 C46 H46 125.9 . . ?
Fe2 C46 H46 125.4 . . ?
C46 C47 C48 108.3(4) . . ?
C46 C47 Fe2 69.2(2) . . ?
C48 C47 Fe2 70.2(2) . . ?
C46 C47 H47 125.8 . . ?
C48 C47 H47 125.8 . . ?
Fe2 C47 H47 126.4 . . ?
C47 C48 C49 109.0(4) . . ?
C47 C48 Fe2 70.3(2) . . ?
C49 C48 Fe2 68.8(2) . . ?
C47 C48 H48 125.5 . . ?
C49 C48 H48 125.5 . . ?
Fe2 C48 H48 127.0 . . ?
C48 C49 C50 107.2(4) . . ?
C48 C49 Fe2 71.2(2) . . ?
C50 C49 Fe2 69.3(2) . . ?
C48 C49 H49 126.4 . . ?
C50 C49 H49 126.4 . . ?
Fe2 C49 H49 124.7 . . ?
C46 C50 C49 107.3(4) . . ?
C46 C50 Fe2 70.0(2) . . ?
C49 C50 Fe2 69.7(2) . . ?
C46 C50 H50 126.3 . . ?
C49 C50 H50 126.3 . . ?
Fe2 C50 H50 125.6 . . ?
C47D C46D C50D 108.8(5) . . ?
C47D C46D Fe2 70.2(3) . . ?
C50D C46D Fe2 70.3(3) . . ?
C47D C46D H46D 125.6 . . ?
C50D C46D H46D 125.6 . . ?
Fe2 C46D H46D 125.5 . . ?
C46D C47D C48D 108.6(4) . . ?
C46D C47D Fe2 69.1(3) . . ?
C48D C47D Fe2 70.1(2) . . ?
C46D C47D H47D 125.7 . . ?
C48D C47D H47D 125.7 . . ?
Fe2 C47D H47D 126.7 . . ?
C47D C48D C49D 108.2(4) . . ?
C47D C48D Fe2 69.4(2) . . ?
C49D C48D Fe2 69.7(2) . . ?
C47D C48D H48D 125.9 . . ?
C49D C48D H48D 125.9 . . ?
Fe2 C48D H48D 126.5 . . ?
C48D C49D C50D 107.6(4) . . ?
C48D C49D Fe2 69.4(2) . . ?
C50D C49D Fe2 69.0(3) . . ?
C48D C49D H49D 126.2 . . ?
C50D C49D H49D 126.2 . . ?
Fe2 C49D H49D 126.9 . . ?
C46D C50D C49D 106.9(5) . . ?
C46D C50D Fe2 68.7(3) . . ?
C49D C50D Fe2 69.5(2) . . ?
C46D C50D H50D 126.6 . . ?
C49D C50D H50D 126.6 . . ?
Fe2 C50D H50D 126.8 . . ?
P2 C51 H51A 109.5 . . ?
P2 C51 H51B 109.5 . . ?
H51A C51 H51B 109.5 . . ?
P2 C51 H51C 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
P2 C52 H52A 109.5 . . ?
P2 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
P2 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
P2 C53 H53A 109.5 . . ?
P2 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
P2 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
H2W O1W H1W 103.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pd1 C1 1.9789(15) . ?
Pd1 N2 2.2097(13) . ?
Pd1 P1 2.2512(4) . ?
Pd1 Cl1 2.4121(4) . ?
Fe1 C16 2.0235(18) . ?
Fe1 C14 2.0337(16) . ?
Fe1 C20 2.0349(18) . ?
Fe1 C17 2.0358(19) . ?
Fe1 C15 2.0373(15) . ?
Fe1 C13 2.0396(16) . ?
Fe1 C19 2.0427(18) . ?
Fe1 C18 2.0508(18) . ?
Fe1 C12 2.0512(15) . ?
Fe1 C11 2.0574(15) . ?
P1 C22 1.8153(17) . ?
P1 C23 1.8156(16) . ?
P1 C21 1.8175(17) . ?
N1 C1 1.274(2) . ?
N1 C11 1.4121(19) . ?
N2 C9 1.482(2) . ?
N2 C10 1.482(2) . ?
N2 C8 1.490(2) . ?
C1 C2 1.494(2) . ?
C2 C7 1.392(2) . ?
C2 C3 1.400(2) . ?
C3 C4 1.395(2) . ?
C3 C8 1.503(2) . ?
C4 C5 1.387(3) . ?
C4 H4 0.9500 . ?
C5 C6 1.377(3) . ?
C5 H5 0.9500 . ?
C6 C7 1.392(3) . ?
C6 H6 0.9500 . ?
C7 H7 0.9500 . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 C12 1.432(2) . ?
C11 C15 1.437(2) . ?
C12 C13 1.423(2) . ?
C12 H12 0.9500 . ?
C13 C14 1.424(2) . ?
C13 H13 0.9500 . ?
C14 C15 1.431(2) . ?
C14 H14 0.9500 . ?
C15 H15 0.9500 . ?
C16 C20 1.413(3) . ?
C16 C17 1.413(3) . ?
C16 H16 0.9500 . ?
C17 C18 1.401(3) . ?
C17 H17 0.9500 . ?
C18 C19 1.404(3) . ?
C18 H18 0.9500 . ?
C19 C20 1.402(3) . ?
C19 H19 0.9500 . ?
C20 H20 0.9500 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
Pd2 C31 1.9723(15) . ?
Pd2 N4 2.2021(13) . ?
Pd2 P2 2.2495(4) . ?
Pd2 Cl2 2.4156(4) . ?
Fe2 C46D 2.014(5) . ?
Fe2 C47D 2.029(4) . ?
Fe2 C50D 2.036(5) . ?
Fe2 C48D 2.038(4) . ?
Fe2 C43 2.0382(16) . ?
Fe2 C44 2.0391(17) . ?
Fe2 C42 2.0404(16) . ?
Fe2 C49D 2.042(4) . ?
Fe2 C45 2.0439(15) . ?
Fe2 C50 2.046(4) . ?
Fe2 C49 2.051(4) . ?
Fe2 C41 2.0554(14) . ?
P2 C52 1.8061(18) . ?
P2 C51 1.8137(18) . ?
P2 C53 1.8139(17) . ?
N3 C31 1.2776(19) . ?
N3 C41 1.4088(19) . ?
N4 C39 1.479(2) . ?
N4 C40 1.482(2) . ?
N4 C38 1.494(2) . ?
C31 C32 1.490(2) . ?
C32 C37 1.388(2) . ?
C32 C33 1.401(2) . ?
C33 C34 1.393(2) . ?
C33 C38 1.504(2) . ?
C34 C35 1.390(3) . ?
C34 H34 0.9500 . ?
C35 C36 1.380(3) . ?
C35 H35 0.9500 . ?
C36 C37 1.391(2) . ?
C36 H36 0.9500 . ?
C37 H37 0.9500 . ?
C38 H38A 0.9900 . ?
C38 H38B 0.9900 . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C41 C42 1.435(2) . ?
C41 C45 1.435(2) . ?
C42 C43 1.424(2) . ?
C42 H42 0.9500 . ?
C43 C44 1.421(3) . ?
C43 H43 0.9500 . ?
C44 C45 1.429(2) . ?
C44 H44 0.9500 . ?
C45 H45 0.9500 . ?
C46 C47 1.407(5) . ?
C46 C50 1.434(5) . ?
C46 H46 0.9500 . ?
C47 C48 1.409(5) . ?
C47 H47 0.9500 . ?
C48 C49 1.415(5) . ?
C48 H48 0.9500 . ?
C49 C50 1.438(5) . ?
C49 H49 0.9500 . ?
C50 H50 0.9500 . ?
C46D C47D 1.408(6) . ?
C46D C50D 1.421(6) . ?
C46D H46D 0.9500 . ?
C47D C48D 1.408(6) . ?
C47D H47D 0.9500 . ?
C48D C49D 1.425(6) . ?
C48D H48D 0.9500 . ?
C49D C50D 1.443(6) . ?
C49D H49D 0.9500 . ?
C50D H50D 0.9500 . ?
C51 H51A 0.9800 . ?
C51 H51B 0.9800 . ?
C51 H51C 0.9800 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
O1W H2W 0.9981 . ?
O1W H1W 1.0010 . ?
