#------------------------------------------------------------------------------
#$Date: 2023-11-22 01:55:47 +0200 (Wed, 22 Nov 2023) $
#$Revision: 287714 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/45/7714524.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7714524
loop_
_publ_author_name
'Jordan, Rose'
'Maisuls, Ivan'
'Nair, Shruti Santosh'
'Dietzek, Benjamin'
'Strassert, Cristian Alejandro'
'Klein, Axel'
_publ_section_title
;
 Enhanced luminescence properties through heavy ancillary ligands in
 [Pt(CNC)(L)] complexes, L = AsPh3 and SbPh3
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D3DT03225F
_journal_year                    2023
_chemical_formula_sum            'C35 H26 N Pt Sb'
_chemical_formula_weight         777.41
_chemical_name_common            '[Pt(PhPyPh)SbPh3]'
_chemical_name_systematic        '[Pt(dpp)SbPh3]'
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2023-04-18 deposited with the CCDC.	2023-11-21 downloaded from the CCDC.
;
_cell_angle_alpha                104.044(3)
_cell_angle_beta                 97.175(3)
_cell_angle_gamma                90.067(2)
_cell_formula_units_Z            4
_cell_length_a                   10.1552(6)
_cell_length_b                   15.5531(9)
_cell_length_c                   17.8316(12)
_cell_measurement_reflns_used    9885
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      30.08
_cell_measurement_theta_min      2.43
_cell_volume                     2709.4(3)
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker d8 Venture'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0832
_diffrn_reflns_av_unetI/netI     0.0500
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            153953
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.158
_diffrn_reflns_theta_min         2.004
_exptl_absorpt_coefficient_mu    6.180
_exptl_absorpt_correction_T_max  0.7460
_exptl_absorpt_correction_T_min  0.5143
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'SADABS-2016/2 - Bruker AXS area detector scaling and absorption correction'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.906
_exptl_crystal_description       prism
_exptl_crystal_F_000             1488
_exptl_crystal_preparation       Luminescent
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: CH2Cl2'
_exptl_crystal_size_max          0.150
_exptl_crystal_size_mid          0.080
_exptl_crystal_size_min          0.020
_refine_diff_density_max         3.746
_refine_diff_density_min         -6.415
_refine_diff_density_rms         0.333
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.097
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     667
_refine_ls_number_reflns         15935
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.097
_refine_ls_R_factor_all          0.0943
_refine_ls_R_factor_gt           0.0750
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+117.5621P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1514
_refine_ls_wR_factor_ref         0.1606
_reflns_Friedel_coverage         0.000
_reflns_number_gt                12751
_reflns_number_total             15935
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d3dt03225f2.cif
_cod_data_source_block           mo_Jordan_RJ_M_11_0m_a
_cod_database_code               7714524
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.457
_shelx_estimated_absorpt_t_max   0.886
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
N1A N 0.1223(8) 0.3265(5) 0.3462(5) 0.0171(16) Uani 1 1 d . . . . .
N1B N 0.6214(8) 1.0888(5) 0.3410(6) 0.023(2) Uani 1 1 d . . . . .
C1A C 0.0999(11) 0.3534(7) 0.4207(7) 0.024(2) Uani 1 1 d . . . . .
C1B C 0.5965(12) 1.1030(7) 0.4156(7) 0.030(3) Uani 1 1 d . . . . .
C2A C 0.0100(13) 0.3050(8) 0.4472(7) 0.033(3) Uani 1 1 d . . . . .
H2A H -0.004138 0.321453 0.500445 0.040 Uiso 1 1 calc R U . . .
C2B C 0.5022(12) 1.1653(7) 0.4418(8) 0.031(3) Uani 1 1 d . . . . .
H2B H 0.485378 1.179374 0.494561 0.037 Uiso 1 1 calc R U . . .
C3A C -0.0587(13) 0.2338(8) 0.3980(8) 0.035(3) Uani 1 1 d . . . . .
H3A H -0.120546 0.201306 0.417234 0.042 Uiso 1 1 calc R U . . .
C3B C 0.4341(10) 1.2056(7) 0.3874(8) 0.030(3) Uani 1 1 d . . . . .
H3B H 0.370883 1.248766 0.403895 0.036 Uiso 1 1 calc R U . . .
C4A C -0.0393(12) 0.2083(8) 0.3204(7) 0.028(2) Uani 1 1 d . . . . .
H4A H -0.088324 0.159576 0.285470 0.034 Uiso 1 1 calc R U . . .
C4B C 0.4556(10) 1.1847(7) 0.3108(8) 0.025(2) Uani 1 1 d . . . . .
H4B H 0.405093 1.211441 0.274538 0.030 Uiso 1 1 calc R U . . .
C5A C 0.0554(10) 0.2569(7) 0.2950(7) 0.023(2) Uani 1 1 d . . . . .
C5B C 0.5517(10) 1.1244(6) 0.2864(7) 0.024(2) Uani 1 1 d . . . . .
C6A C 0.0941(11) 0.2411(7) 0.2156(7) 0.024(2) Uani 1 1 d . . . . .
C6B C 0.5926(11) 1.0931(6) 0.2086(8) 0.026(2) Uani 1 1 d . . . . .
C8A C 0.2345(11) 0.2815(7) 0.1310(7) 0.025(2) Uani 1 1 d . . . . .
H8A H 0.302514 0.317920 0.121475 0.030 Uiso 1 1 calc R U . . .
C8B C 0.7424(12) 1.0069(7) 0.1275(8) 0.029(3) Uani 1 1 d . . . . .
H8B H 0.815338 0.968858 0.120450 0.035 Uiso 1 1 calc R U . . .
C9A C 0.1780(14) 0.2126(8) 0.0701(8) 0.036(3) Uani 1 1 d . . . . .
H9A H 0.209244 0.200921 0.020689 0.043 Uiso 1 1 calc R U . . .
C9B C 0.6811(14) 1.0365(8) 0.0646(8) 0.037(3) Uani 1 1 d . . . . .
H9B H 0.712713 1.018211 0.015424 0.045 Uiso 1 1 calc R U . . .
C10A C 0.0746(17) 0.1611(9) 0.0830(8) 0.047(4) Uani 1 1 d . . . . .
H10A H 0.032910 0.115437 0.041259 0.056 Uiso 1 1 calc R U . . .
C10B C 0.5740(16) 1.0924(8) 0.0726(8) 0.042(3) Uani 1 1 d . . . . .
H10B H 0.530619 1.110182 0.028732 0.051 Uiso 1 1 calc R U . . .
C7A C 0.1955(9) 0.2994(6) 0.2056(6) 0.0174(19) Uani 1 1 d . . . . .
C7B C 0.6994(10) 1.0318(6) 0.2005(8) 0.026(2) Uani 1 1 d . . . . .
Pt1A Pt 0.25667(3) 0.39489(2) 0.30805(2) 0.01516(9) Uani 1 1 d . . . . .
Pt1B Pt 0.75645(4) 0.99713(2) 0.30503(3) 0.02229(10) Uani 1 1 d . . . . .
Sb1A Sb 0.40030(6) 0.48737(4) 0.25168(4) 0.01869(14) Uani 1 1 d . . . . .
Sb1B Sb 0.88908(7) 0.86842(4) 0.24840(6) 0.0304(2) Uani 1 1 d . . . . .
C11A C 0.0325(13) 0.1751(8) 0.1545(7) 0.031(3) Uani 1 1 d . . . . .
H11A H -0.038645 0.139921 0.162282 0.038 Uiso 1 1 calc R U . . .
C11B C 0.5316(9) 1.1217(7) 0.1444(8) 0.0265(17) Uani 1 1 d . . . . .
H11B H 0.460604 1.161501 0.150510 0.032 Uiso 1 1 calc R U . . .
C12A C 0.1798(11) 0.4331(8) 0.4647(7) 0.025(2) Uani 1 1 d . . . . .
C12B C 0.6773(10) 1.0492(6) 0.4609(7) 0.026(2) Uani 1 1 d . . . . .
C13A C 0.2728(10) 0.4652(6) 0.4236(6) 0.0189(19) Uani 1 1 d . . . . .
C13B C 0.7704(11) 0.9937(7) 0.4207(8) 0.027(2) Uani 1 1 d . . . . .
C14A C 0.3512(12) 0.5409(7) 0.4672(7) 0.027(2) Uani 1 1 d . . . . .
H14A H 0.416723 0.564261 0.443325 0.033 Uiso 1 1 calc R U . . .
C14B C 0.8467(13) 0.9446(7) 0.4661(9) 0.039(3) Uani 1 1 d . . . . .
H14B H 0.911670 0.907095 0.442617 0.047 Uiso 1 1 calc R U . . .
C15A C 0.3346(13) 0.5815(8) 0.5437(8) 0.033(3) Uani 1 1 d . . . . .
H15A H 0.390417 0.631013 0.571449 0.040 Uiso 1 1 calc R U . . .
C15B C 0.8329(13) 0.9478(8) 0.5423(9) 0.040(3) Uani 1 1 d . . . . .
H15B H 0.889892 0.915034 0.570592 0.048 Uiso 1 1 calc R U . . .
C16A C 0.2382(14) 0.5511(9) 0.5799(8) 0.038(3) Uani 1 1 d . . . . .
H16A H 0.224951 0.580812 0.631522 0.045 Uiso 1 1 calc R U . . .
C16B C 0.7328(11) 1.0004(8) 0.5791(8) 0.032(3) Uani 1 1 d . . . . .
H16B H 0.717499 1.000165 0.630501 0.039 Uiso 1 1 calc R U . . .
C17A C 0.1612(15) 0.4768(8) 0.5401(7) 0.037(3) Uani 1 1 d . . . . .
H17A H 0.094794 0.455365 0.564733 0.044 Uiso 1 1 calc R U . . .
C17B C 0.6596(9) 1.0513(7) 0.5371(8) 0.0265(17) Uani 1 1 d . . . . .
H17B H 0.595100 1.088968 0.561047 0.032 Uiso 1 1 calc R U . . .
C18A C 0.2959(9) 0.5195(6) 0.1519(7) 0.021(2) Uani 1 1 d . . . . .
C18B C 1.0660(13) 0.8947(8) 0.2032(10) 0.041(4) Uani 1 1 d . . . . .
C19A C 0.1550(10) 0.5177(7) 0.1450(7) 0.024(2) Uani 1 1 d . . . . .
H19A H 0.110226 0.493029 0.178949 0.028 Uiso 1 1 calc R U . . .
C19B C 1.1083(14) 0.9775(9) 0.2108(10) 0.046(3) Uani 1 1 d . . . . .
H19B H 1.056688 1.025120 0.234085 0.055 Uiso 1 1 calc R U . . .
C20A C 0.0840(11) 0.5518(7) 0.0888(8) 0.028(2) Uani 1 1 d . . . . .
H20A H -0.010259 0.549258 0.082856 0.034 Uiso 1 1 calc R U . . .
C20B C 1.2277(17) 0.9960(10) 0.1850(12) 0.063(4) Uani 1 1 d . . . . .
H20B H 1.257082 1.055937 0.193351 0.076 Uiso 1 1 calc R U . . .
C21A C 0.1497(11) 0.5902(7) 0.0404(8) 0.030(3) Uani 1 1 d . . . . .
H21A H 0.099338 0.617543 0.004527 0.037 Uiso 1 1 calc R U . . .
C21B C 1.3007(13) 0.9319(9) 0.1494(11) 0.049(4) Uani 1 1 d . . . . .
H21B H 1.367589 0.943075 0.119849 0.059 Uiso 1 1 calc R U . . .
C22A C 0.2815(10) 0.5896(7) 0.0432(8) 0.025(2) Uani 1 1 d . . . . .
H22A H 0.323525 0.611734 0.006683 0.031 Uiso 1 1 calc R U . . .
C22B C 1.2729(17) 0.8459(10) 0.1580(12) 0.063(4) Uani 1 1 d . . . . .
H22B H 1.333905 0.800245 0.144357 0.076 Uiso 1 1 calc R U . . .
C23A C 0.3584(10) 0.5560(7) 0.1005(7) 0.024(2) Uani 1 1 d . . . . .
H23A H 0.452504 0.558085 0.104293 0.029 Uiso 1 1 calc R U . . .
C23B C 1.1576(14) 0.8279(9) 0.1862(10) 0.046(3) Uani 1 1 d . . . . .
H23B H 1.140798 0.770690 0.193804 0.055 Uiso 1 1 calc R U . . .
C25A C 0.5902(13) 0.6306(8) 0.3610(8) 0.038(3) Uani 1 1 d . . . . .
H25A H 0.625197 0.581691 0.379242 0.045 Uiso 1 1 calc R U . . .
C25B C 0.8241(12) 0.7065(8) 0.1067(7) 0.029(2) Uani 1 1 d . . . . .
H25B H 0.914497 0.693801 0.119413 0.035 Uiso 1 1 calc R U . . .
C26A C 0.6510(18) 0.7144(10) 0.3888(9) 0.054(5) Uani 1 1 d . . . . .
H26A H 0.728766 0.722587 0.425724 0.065 Uiso 1 1 calc R U . . .
C26B C 0.7480(12) 0.6505(8) 0.0460(8) 0.030(3) Uani 1 1 d . . . . .
H26B H 0.785463 0.599123 0.016805 0.036 Uiso 1 1 calc R U . . .
C27A C 0.599(2) 0.7857(10) 0.3633(11) 0.069(6) Uani 1 1 d . . . . .
H27A H 0.640040 0.842937 0.383077 0.083 Uiso 1 1 calc R U . . .
C27B C 0.6162(13) 0.6684(7) 0.0267(9) 0.034(3) Uani 1 1 d . . . . .
H27B H 0.563475 0.629601 -0.015804 0.041 Uiso 1 1 calc R U . . .
C28A C 0.488(2) 0.7737(9) 0.3095(10) 0.057(5) Uani 1 1 d . . . . .
H28A H 0.454265 0.823303 0.291961 0.068 Uiso 1 1 calc R U . . .
C28B C 0.5616(11) 0.7431(8) 0.0696(11) 0.049(4) Uani 1 1 d . . . . .
H28B H 0.471184 0.755355 0.056479 0.059 Uiso 1 1 calc R U . . .
C29A C 0.4233(14) 0.6910(7) 0.2793(8) 0.033(3) Uani 1 1 d . . . . .
H29A H 0.345735 0.683869 0.242264 0.040 Uiso 1 1 calc R U . . .
C29B C 0.6402(12) 0.8015(8) 0.1331(11) 0.050(4) Uani 1 1 d . . . . .
H29B H 0.602835 0.852693 0.162643 0.060 Uiso 1 1 calc R U . . .
C30A C 0.5799(10) 0.4362(7) 0.2114(7) 0.022(2) Uani 1 1 d . . . . .
C30B C 0.9728(12) 0.7707(7) 0.3050(8) 0.029(3) Uani 1 1 d . . . . .
C31A C 0.6084(11) 0.3478(7) 0.2082(7) 0.023(2) Uani 1 1 d . . . . .
H31A H 0.548204 0.310908 0.223936 0.028 Uiso 1 1 calc R U . . .
C31B C 0.9137(12) 0.6848(7) 0.2863(7) 0.027(2) Uani 1 1 d . . . . .
H31B H 0.830515 0.671781 0.254335 0.032 Uiso 1 1 calc R U . . .
C32A C 0.7263(11) 0.3138(7) 0.1818(7) 0.027(2) Uani 1 1 d . . . . .
H32A H 0.743742 0.252951 0.177458 0.032 Uiso 1 1 calc R U . . .
C32B C 0.9799(15) 0.6201(7) 0.3157(7) 0.033(3) Uani 1 1 d . . . . .
H32B H 0.942607 0.561536 0.302897 0.040 Uiso 1 1 calc R U . . .
C33A C 0.8178(10) 0.3675(8) 0.1617(7) 0.026(2) Uani 1 1 d . . . . .
H33A H 0.898583 0.344174 0.145041 0.031 Uiso 1 1 calc R U . . .
C33B C 1.0993(15) 0.6393(9) 0.3633(9) 0.040(3) Uani 1 1 d . . . . .
H33B H 1.143954 0.593828 0.382472 0.048 Uiso 1 1 calc R U . . .
C34A C 0.7903(11) 0.4560(8) 0.1663(7) 0.025(2) Uani 1 1 d . . . . .
H34A H 0.852439 0.493260 0.152443 0.030 Uiso 1 1 calc R U . . .
C34B C 1.1549(12) 0.7249(9) 0.3835(10) 0.041(3) Uani 1 1 d . . . . .
H34B H 1.236435 0.738040 0.417062 0.049 Uiso 1 1 calc R U . . .
C35A C 0.6723(10) 0.4905(7) 0.1911(7) 0.026(2) Uani 1 1 d . . . . .
H35A H 0.654473 0.551177 0.194307 0.031 Uiso 1 1 calc R U . . .
C35B C 1.0906(12) 0.7910(8) 0.3542(10) 0.043(4) Uani 1 1 d . . . . .
H35B H 1.127481 0.849765 0.368066 0.051 Uiso 1 1 calc R U . . .
C24A C 0.4770(11) 0.6192(7) 0.3057(8) 0.028(3) Uani 1 1 d . . . . .
C24B C 0.7701(11) 0.7831(6) 0.1511(8) 0.026(2) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1A N1A C5A 122.8(9) . . ?
C1A N1A Pt1A 118.6(7) . . ?
C5A N1A Pt1A 118.5(7) . . ?
C1B N1B C5B 124.2(9) . . ?
C1B N1B Pt1B 117.7(7) . . ?
C5B N1B Pt1B 117.7(8) . . ?
N1A C1A C2A 118.4(10) . . ?
N1A C1A C12A 113.3(9) . . ?
C2A C1A C12A 128.2(11) . . ?
N1B C1B C2B 118.9(11) . . ?
N1B C1B C12B 113.5(11) . . ?
C2B C1B C12B 127.7(12) . . ?
C3A C2A C1A 120.8(12) . . ?
C3B C2B C1B 117.4(13) . . ?
C2A C3A C4A 120.6(11) . . ?
C4B C3B C2B 121.9(10) . . ?
C3A C4A C5A 117.7(11) . . ?
C3B C4B C5B 119.7(10) . . ?
N1A C5A C4A 119.5(11) . . ?
N1A C5A C6A 113.3(9) . . ?
C4A C5A C6A 127.2(10) . . ?
N1B C5B C4B 117.5(11) . . ?
N1B C5B C6B 113.2(9) . . ?
C4B C5B C6B 129.3(11) . . ?
C11A C6A C7A 122.3(11) . . ?
C11A C6A C5A 121.7(10) . . ?
C7A C6A C5A 116.0(9) . . ?
C11B C6B C7B 120.9(11) . . ?
C11B C6B C5B 121.8(9) . . ?
C7B C6B C5B 117.4(11) . . ?
C9A C8A C7A 122.9(10) . . ?
C9B C8B C7B 121.5(11) . . ?
C8A C9A C10A 118.7(12) . . ?
C8B C9B C10B 121.0(13) . . ?
C11A C10A C9A 121.1(12) . . ?
C11B C10B C9B 119.6(13) . . ?
C8A C7A C6A 115.3(9) . . ?
C8A C7A Pt1A 133.0(7) . . ?
C6A C7A Pt1A 111.7(8) . . ?
C8B C7B C6B 116.7(11) . . ?
C8B C7B Pt1B 132.9(8) . . ?
C6B C7B Pt1B 110.4(9) . . ?
N1A Pt1A C13A 80.2(4) . . ?
N1A Pt1A C7A 80.4(4) . . ?
C13A Pt1A C7A 160.6(4) . . ?
N1A Pt1A Sb1A 172.9(2) . . ?
C13A Pt1A Sb1A 101.9(3) . . ?
C7A Pt1A Sb1A 97.4(3) . . ?
N1B Pt1B C13B 80.5(4) . . ?
N1B Pt1B C7B 81.0(4) . . ?
C13B Pt1B C7B 161.5(4) . . ?
N1B Pt1B Sb1B 170.2(2) . . ?
C13B Pt1B Sb1B 102.7(3) . . ?
C7B Pt1B Sb1B 95.7(3) . . ?
C18A Sb1A C30A 102.8(4) . . ?
C18A Sb1A C24A 95.6(5) . . ?
C30A Sb1A C24A 96.5(4) . . ?
C18A Sb1A Pt1A 110.9(3) . . ?
C30A Sb1A Pt1A 119.8(3) . . ?
C24A Sb1A Pt1A 126.6(3) . . ?
C18B Sb1B C30B 95.5(5) . . ?
C18B Sb1B C24B 104.3(5) . . ?
C30B Sb1B C24B 99.3(4) . . ?
C18B Sb1B Pt1B 117.9(3) . . ?
C30B Sb1B Pt1B 127.2(3) . . ?
C24B Sb1B Pt1B 109.2(3) . . ?
C10A C11A C6A 119.5(11) . . ?
C10B C11B C6B 120.3(10) . . ?
C17A C12A C13A 121.9(10) . . ?
C17A C12A C1A 122.2(10) . . ?
C13A C12A C1A 115.9(10) . . ?
C17B C12B C13B 122.5(10) . . ?
C17B C12B C1B 121.4(10) . . ?
C13B C12B C1B 116.0(12) . . ?
C14A C13A C12A 115.3(10) . . ?
C14A C13A Pt1A 132.8(8) . . ?
C12A C13A Pt1A 111.7(7) . . ?
C14B C13B C12B 114.3(12) . . ?
C14B C13B Pt1B 133.5(10) . . ?
C12B C13B Pt1B 112.2(8) . . ?
C15A C14A C13A 121.9(11) . . ?
C15B C14B C13B 123.9(13) . . ?
C16A C15A C14A 120.9(11) . . ?
C14B C15B C16B 120.1(12) . . ?
C15A C16A C17A 119.1(13) . . ?
C17B C16B C15B 117.4(13) . . ?
C16A C17A C12A 120.8(12) . . ?
C16B C17B C12B 121.7(11) . . ?
C23A C18A C19A 118.6(10) . . ?
C23A C18A Sb1A 123.0(7) . . ?
C19A C18A Sb1A 117.6(8) . . ?
C19B C18B C23B 117.3(12) . . ?
C19B C18B Sb1B 120.5(10) . . ?
C23B C18B Sb1B 119.7(9) . . ?
C20A C19A C18A 119.5(10) . . ?
C18B C19B C20B 121.3(13) . . ?
C19A C20A C21A 120.3(10) . . ?
C21B C20B C19B 121.7(14) . . ?
C22A C21A C20A 121.7(11) . . ?
C20B C21B C22B 115.9(14) . . ?
C21A C22A C23A 119.8(10) . . ?
C23B C22B C21B 120.5(15) . . ?
C18A C23A C22A 120.0(9) . . ?
C22B C23B C18B 119.3(13) . . ?
C26A C25A C24A 119.1(15) . . ?
C26B C25B C24B 120.8(11) . . ?
C27A C26A C25A 120.4(17) . . ?
C25B C26B C27B 120.2(11) . . ?
C28A C27A C26A 119.9(13) . . ?
C28B C27B C26B 119.8(13) . . ?
C27A C28A C29A 122.3(16) . . ?
C27B C28B C29B 120.3(12) . . ?
C28A C29A C24A 117.4(15) . . ?
C24B C29B C28B 119.1(12) . . ?
C31A C30A C35A 119.4(10) . . ?
C31A C30A Sb1A 119.4(8) . . ?
C35A C30A Sb1A 121.2(8) . . ?
C35B C30B C31B 121.1(11) . . ?
C35B C30B Sb1B 118.9(8) . . ?
C31B C30B Sb1B 119.8(9) . . ?
C30A C31A C32A 119.6(10) . . ?
C32B C31B C30B 118.3(12) . . ?
C33A C32A C31A 121.0(10) . . ?
C33B C32B C31B 121.0(12) . . ?
C32A C33A C34A 119.3(10) . . ?
C32B C33B C34B 120.4(12) . . ?
C33A C34A C35A 120.5(10) . . ?
C33B C34B C35B 119.7(13) . . ?
C34A C35A C30A 120.2(10) . . ?
C30B C35B C34B 119.5(12) . . ?
C25A C24A C29A 120.9(11) . . ?
C25A C24A Sb1A 118.7(9) . . ?
C29A C24A Sb1A 120.0(9) . . ?
C29B C24B C25B 119.8(12) . . ?
C29B C24B Sb1B 119.8(9) . . ?
C25B C24B Sb1B 120.4(9) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
N1A C1A 1.340(15) . ?
N1A C5A 1.353(13) . ?
N1A Pt1A 2.009(8) . ?
N1B C1B 1.350(16) . ?
N1B C5B 1.359(14) . ?
N1B Pt1B 2.026(8) . ?
C1A C2A 1.380(15) . ?
C1A C12A 1.476(14) . ?
C1B C2B 1.402(17) . ?
C1B C12B 1.480(16) . ?
C2A C3A 1.363(17) . ?
C2B C3B 1.393(17) . ?
C3A C4A 1.384(18) . ?
C3B C4B 1.370(18) . ?
C4A C5A 1.406(14) . ?
C4B C5B 1.390(13) . ?
C5A C6A 1.480(16) . ?
C5B C6B 1.467(17) . ?
C6A C11A 1.384(15) . ?
C6A C7A 1.428(14) . ?
C6B C11B 1.401(17) . ?
C6B C7B 1.443(14) . ?
C8A C9A 1.390(17) . ?
C8A C7A 1.398(16) . ?
C8B C9B 1.390(19) . ?
C8B C7B 1.391(18) . ?
C9A C10A 1.395(19) . ?
C9B C10B 1.39(2) . ?
C10A C11A 1.362(19) . ?
C10B C11B 1.373(19) . ?
C7A Pt1A 2.080(10) . ?
C7B Pt1B 2.078(13) . ?
Pt1A C13A 2.072(10) . ?
Pt1A Sb1A 2.5040(7) . ?
Pt1B C13B 2.063(13) . ?
Pt1B Sb1B 2.4912(8) . ?
Sb1A C18A 2.121(11) . ?
Sb1A C30A 2.129(10) . ?
Sb1A C24A 2.142(10) . ?
Sb1B C18B 2.136(13) . ?
Sb1B C30B 2.140(12) . ?
Sb1B C24B 2.142(12) . ?
C12A C17A 1.389(17) . ?
C12A C13A 1.423(14) . ?
C12B C17B 1.387(18) . ?
C12B C13B 1.422(16) . ?
C13A C14A 1.422(15) . ?
C13B C14B 1.409(16) . ?
C14A C15A 1.388(18) . ?
C14B C15B 1.37(2) . ?
C15A C16A 1.381(18) . ?
C15B C16B 1.428(19) . ?
C16A C17A 1.383(16) . ?
C16B C17B 1.375(16) . ?
C18A C23A 1.400(14) . ?
C18A C19A 1.420(13) . ?
C18B C19B 1.327(17) . ?
C18B C23B 1.399(17) . ?
C19A C20A 1.373(16) . ?
C19B C20B 1.402(19) . ?
C20A C21A 1.392(16) . ?
C20B C21B 1.33(2) . ?
C21A C22A 1.334(14) . ?
C21B C22B 1.414(19) . ?
C22A C23A 1.410(16) . ?
C22B C23B 1.385(19) . ?
C25A C26A 1.390(17) . ?
C25A C24A 1.400(19) . ?
C25B C26B 1.364(18) . ?
C25B C24B 1.414(15) . ?
C26A C27A 1.38(3) . ?
C26B C27B 1.385(17) . ?
C27A C28A 1.36(3) . ?
C27B C28B 1.385(17) . ?
C28A C29A 1.397(18) . ?
C28B C29B 1.42(2) . ?
C29A C24A 1.400(17) . ?
C29B C24B 1.366(16) . ?
C30A C31A 1.394(14) . ?
C30A C35A 1.399(14) . ?
C30B C35B 1.380(19) . ?
C30B C31B 1.410(15) . ?
C31A C32A 1.398(15) . ?
C31B C32B 1.382(16) . ?
C32A C33A 1.384(15) . ?
C32B C33B 1.38(2) . ?
C33A C34A 1.390(16) . ?
C33B C34B 1.39(2) . ?
C34A C35A 1.392(15) . ?
C34B C35B 1.391(18) . ?
