#------------------------------------------------------------------------------
#$Date: 2024-04-05 02:34:17 +0300 (Fri, 05 Apr 2024) $
#$Revision: 290976 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/52/7715241.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7715241
loop_
_publ_author_name
'Helling, Christoph'
'Döhler, Lotta'
'Kysliak, Oleksandr'
'Görls, Helmar'
'Liebing, Phil'
'Wölper, Christoph'
'Kretschmer, Robert'
'Schulz, Stephan'
_publ_section_title
;
 Metal-metal cooperativity boosts Lewis basicity and reduction properties
 of the bis(gallanediyl) CyL₂Ga₂.
;
_journal_issue                   11
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4922
_journal_page_last               4929
_journal_paper_doi               10.1039/d4dt00172a
_journal_volume                  53
_journal_year                    2024
_chemical_absolute_configuration ad
_chemical_formula_sum            'C40 H58 Cl4 Ga2 N4'
_chemical_formula_weight         876.14
_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_Hall           'P 2ac 2ab'
_space_group_name_H-M_alt        'P 21 21 21'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_block_doi                 10.5517/ccdc.csd.cc29fzb2
_audit_creation_method           SHELXL-2017/1
_audit_update_record
;
2023-07-31 deposited with the CCDC.	2024-02-14 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.2640(19)
_cell_length_b                   18.797(3)
_cell_length_c                   22.810(4)
_cell_measurement_reflns_used    9818
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      31.80
_cell_measurement_theta_min      2.18
_cell_volume                     4400.8(13)
_computing_cell_refinement       'BRUKER APEX3(v2019.1-0)'
_computing_data_collection       'BRUKER APEX3(v2019.1-0)'
_computing_data_reduction        'BRUKER APEX3(v2019.1-0)'
_computing_molecular_graphics    'ORTEP/PLATON (Spek)'
_computing_publication_material  'BRUKER AXS SHELXTL (c) 2008 / Vers. 2008/4'
_computing_structure_refinement  'SHELXL-2017/1 (Sheldrick, 2017)'
_computing_structure_solution    'BRUKER APEX3(v2019.1-0)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 512
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker D8 KAPPA II (APEX II detector)'
_diffrn_measurement_method       'Data collection strategy APEX 3/QUEEN'
_diffrn_radiation_monochromator  'Triumph Goebel mirror'
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0719
_diffrn_reflns_av_unetI/netI     0.0436
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_number            164660
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.336
_diffrn_reflns_theta_min         2.167
_exptl_absorpt_coefficient_mu    1.498
_exptl_absorpt_correction_T_max  0.75
_exptl_absorpt_correction_T_min  0.64
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
; 
 SADABS
 R.H. Blessing, Acta Cryst. (1995) A51 33-38 
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.322
_exptl_crystal_description       tablet
_exptl_crystal_F_000             1824
_exptl_crystal_size_max          0.189
_exptl_crystal_size_mid          0.094
_exptl_crystal_size_min          0.081
_refine_diff_density_max         0.756
_refine_diff_density_min         -0.421
_refine_diff_density_rms         0.082
_refine_ls_abs_structure_details
;
 Flack x determined using 6029 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.007(3)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.057
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     463
_refine_ls_number_reflns         16960
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.057
_refine_ls_R_factor_all          0.0446
_refine_ls_R_factor_gt           0.0312
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0296P)²+0.3313P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0629
_refine_ls_wR_factor_ref         0.0680
_reflns_Friedel_coverage         0.831
_reflns_Friedel_fraction_full    1.000
_reflns_Friedel_fraction_max     0.995
_reflns_number_gt                14708
_reflns_number_total             16960
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d4dt00172a2.cif
_cod_data_source_block           ch_631am
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_atom_sites_solution_secondary' value 'diffmap' was
changed to 'difmap'.

Automatic conversion script
Id: cif_fix_values 8170 2020-07-09 18:12:32Z antanas 

 Adding full bibliography for 7715237--7715242.cif.
;
_cod_original_cell_volume        4400.9(14)
_cod_database_code               7715241
_shelx_shelxl_version_number     2017/1
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.765
_shelx_estimated_absorpt_t_max   0.888
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ga1 Ga 0.18878(2) 0.67646(2) 0.13088(2) 0.01258(5) Uani 1 1 d . . . . .
Ga2 Ga -0.00094(2) 0.46654(2) 0.00508(2) 0.01373(5) Uani 1 1 d . . . . .
Cl1 Cl 0.37215(5) 0.70414(3) 0.17441(3) 0.02011(11) Uani 1 1 d . . . . .
Cl2 Cl 0.13890(6) 0.76101(3) 0.07130(3) 0.01947(11) Uani 1 1 d . . . . .
Cl3 Cl -0.09809(6) 0.46569(3) 0.08937(3) 0.02234(11) Uani 1 1 d . . . . .
Cl4 Cl 0.15000(6) 0.38596(3) 0.00247(3) 0.02386(12) Uani 1 1 d . . . . .
N1 N 0.20391(18) 0.58022(10) 0.10380(8) 0.0135(3) Uani 1 1 d . . . . .
N2 N 0.05508(18) 0.66506(10) 0.18793(8) 0.0139(3) Uani 1 1 d . . . . .
N3 N 0.05354(17) 0.56240(10) -0.01173(8) 0.0130(3) Uani 1 1 d . . . . .
N4 N -0.12017(18) 0.45058(10) -0.05748(8) 0.0154(4) Uani 1 1 d . . . . .
C1 C 0.1980(2) 0.53323(12) 0.14821(9) 0.0150(4) Uani 1 1 d . . . . .
C2 C 0.1361(2) 0.54679(12) 0.20202(10) 0.0165(4) Uani 1 1 d . . . . .
H2 H 0.149399 0.511836 0.231503 0.020 Uiso 1 1 calc R U . . .
C3 C 0.0579(2) 0.60429(12) 0.21839(10) 0.0156(4) Uani 1 1 d . . . . .
C4 C 0.2578(2) 0.46004(13) 0.14166(11) 0.0215(5) Uani 1 1 d . . . . .
H4A H 0.206775 0.432216 0.113492 0.032 Uiso 1 1 calc R U . . .
H4B H 0.257709 0.435880 0.179732 0.032 Uiso 1 1 calc R U . . .
H4C H 0.347546 0.464627 0.127512 0.032 Uiso 1 1 calc R U . . .
C5 C -0.0249(2) 0.59688(14) 0.27244(11) 0.0229(5) Uani 1 1 d . . . . .
H5A H -0.116097 0.606536 0.262526 0.034 Uiso 1 1 calc R U . . .
H5B H 0.004522 0.630879 0.302200 0.034 Uiso 1 1 calc R U . . .
H5C H -0.017059 0.548385 0.287822 0.034 Uiso 1 1 calc R U . . .
C6 C -0.0328(2) 0.60227(12) -0.04081(10) 0.0155(4) Uani 1 1 d . . . . .
C7 C -0.1512(2) 0.57699(12) -0.06435(10) 0.0172(4) Uani 1 1 d . . . . .
H7 H -0.216290 0.611839 -0.071587 0.021 Uiso 1 1 calc R U . . .
C8 C -0.1842(2) 0.50708(12) -0.07827(9) 0.0161(4) Uani 1 1 d . . . . .
C9 C -0.0045(3) 0.67947(13) -0.05342(11) 0.0228(4) Uani 1 1 d . . . . .
H9A H 0.068223 0.682910 -0.081131 0.034 Uiso 1 1 calc R U . . .
H9B H 0.018678 0.703788 -0.016873 0.034 Uiso 1 1 calc R U . . .
H9C H -0.081907 0.701890 -0.070457 0.034 Uiso 1 1 calc R U . . .
C10 C -0.2940(2) 0.49562(14) -0.12084(11) 0.0217(5) Uani 1 1 d . . . . .
H10A H -0.331170 0.541681 -0.132010 0.033 Uiso 1 1 calc R U . . .
H10B H -0.361466 0.466289 -0.102404 0.033 Uiso 1 1 calc R U . . .
H10C H -0.260903 0.471402 -0.155853 0.033 Uiso 1 1 calc R U . . .
C11 C 0.2640(2) 0.56003(12) 0.04707(10) 0.0144(4) Uani 1 1 d . . . . .
H11 H 0.266255 0.506929 0.044585 0.017 Uiso 1 1 calc R U . . .
C12 C 0.1896(2) 0.58852(11) -0.00648(9) 0.0140(4) Uani 1 1 d . . . . .
H12 H 0.187569 0.641631 -0.004052 0.017 Uiso 1 1 calc R U . . .
C13 C 0.2619(2) 0.56736(14) -0.06299(10) 0.0184(4) Uani 1 1 d . . . . .
H13A H 0.263012 0.514854 -0.066312 0.022 Uiso 1 1 calc R U . . .
H13B H 0.213918 0.586432 -0.097216 0.022 Uiso 1 1 calc R U . . .
C14 C 0.4017(2) 0.59509(16) -0.06436(12) 0.0246(5) Uani 1 1 d . . . . .
H14A H 0.445229 0.579122 -0.100778 0.030 Uiso 1 1 calc R U . . .
H14B H 0.401365 0.647754 -0.063937 0.030 Uiso 1 1 calc R U . . .
C15 C 0.4755(2) 0.56726(15) -0.01134(12) 0.0252(5) Uani 1 1 d . . . . .
H15A H 0.564743 0.587296 -0.011089 0.030 Uiso 1 1 calc R U . . .
H15B H 0.482667 0.514816 -0.013771 0.030 Uiso 1 1 calc R U . . .
C16 C 0.4054(2) 0.58787(14) 0.04512(11) 0.0199(5) Uani 1 1 d . . . . .
H16A H 0.404546 0.640356 0.048734 0.024 Uiso 1 1 calc R U . . .
H16B H 0.454062 0.568473 0.079011 0.024 Uiso 1 1 calc R U . . .
C17 C -0.0438(2) 0.71832(12) 0.19821(10) 0.0161(4) Uani 1 1 d . . . . .
C18 C -0.1669(2) 0.70925(13) 0.17258(10) 0.0194(4) Uani 1 1 d . . . . .
C19 C -0.2608(3) 0.76155(15) 0.18149(12) 0.0257(5) Uani 1 1 d . . . . .
H19 H -0.345474 0.755673 0.165406 0.031 Uiso 1 1 calc R U . . .
C20 C -0.2318(3) 0.82250(16) 0.21381(12) 0.0294(6) Uani 1 1 d . . . . .
H20 H -0.296112 0.858265 0.219125 0.035 Uiso 1 1 calc R U . . .
C21 C -0.1096(3) 0.83083(14) 0.23805(11) 0.0270(5) Uani 1 1 d . . . . .
H21 H -0.090442 0.872869 0.259488 0.032 Uiso 1 1 calc R U . . .
C22 C -0.0133(3) 0.77864(13) 0.23175(10) 0.0204(4) Uani 1 1 d . . . . .
C23 C -0.1997(2) 0.64507(14) 0.13483(12) 0.0247(5) Uani 1 1 d . . . . .
H23 H -0.118737 0.615962 0.130529 0.030 Uiso 1 1 calc R U . . .
C24 C -0.3040(3) 0.59792(16) 0.16272(15) 0.0344(6) Uani 1 1 d . . . . .
H24A H -0.384546 0.625283 0.167545 0.052 Uiso 1 1 calc R U . . .
H24B H -0.273677 0.581430 0.201122 0.052 Uiso 1 1 calc R U . . .
H24C H -0.320587 0.556821 0.137362 0.052 Uiso 1 1 calc R U . . .
C25 C -0.2432(3) 0.66799(19) 0.07333(12) 0.0357(7) Uani 1 1 d . . . . .
H25A H -0.179441 0.701376 0.057006 0.054 Uiso 1 1 calc R U . . .
H25B H -0.328525 0.691167 0.075746 0.054 Uiso 1 1 calc R U . . .
H25C H -0.249304 0.626062 0.047940 0.054 Uiso 1 1 calc R U . . .
C26 C 0.1167(3) 0.78800(14) 0.26207(12) 0.0252(5) Uani 1 1 d . . . . .
H26 H 0.172046 0.745925 0.252087 0.030 Uiso 1 1 calc R U . . .
C27 C 0.1883(4) 0.85494(17) 0.24088(17) 0.0449(8) Uani 1 1 d . . . . .
H27A H 0.196732 0.853512 0.198102 0.067 Uiso 1 1 calc R U . . .
H27B H 0.275125 0.856759 0.258689 0.067 Uiso 1 1 calc R U . . .
H27C H 0.138734 0.897283 0.252325 0.067 Uiso 1 1 calc R U . . .
C28 C 0.0998(4) 0.78949(19) 0.32892(13) 0.0405(8) Uani 1 1 d . . . . .
H28A H 0.050368 0.831944 0.340167 0.061 Uiso 1 1 calc R U . . .
H28B H 0.185676 0.790642 0.347707 0.061 Uiso 1 1 calc R U . . .
H28C H 0.052683 0.746832 0.341570 0.061 Uiso 1 1 calc R U . . .
C29 C -0.1349(2) 0.38266(12) -0.08656(11) 0.0195(4) Uani 1 1 d . . . . .
C30 C -0.2338(3) 0.33599(13) -0.06913(11) 0.0239(5) Uani 1 1 d . . . . .
C31 C -0.2444(3) 0.27132(16) -0.09951(14) 0.0353(7) Uani 1 1 d . . . . .
H31 H -0.309586 0.238129 -0.088285 0.042 Uiso 1 1 calc R U . . .
C32 C -0.1622(4) 0.25505(17) -0.14526(15) 0.0452(9) Uani 1 1 d . . . . .
H32 H -0.172432 0.211401 -0.165749 0.054 Uiso 1 1 calc R U . . .
C33 C -0.0651(4) 0.30170(17) -0.16152(14) 0.0394(7) Uani 1 1 d . . . . .
H33 H -0.008462 0.289538 -0.192904 0.047 Uiso 1 1 calc R U . . .
C34 C -0.0486(3) 0.36668(14) -0.13254(12) 0.0257(5) Uani 1 1 d . . . . .
C35 C -0.3246(3) 0.35231(14) -0.01853(12) 0.0262(5) Uani 1 1 d . . . . .
H35 H -0.314986 0.403977 -0.008995 0.031 Uiso 1 1 calc R U . . .
C36 C -0.2850(3) 0.31003(16) 0.03592(13) 0.0358(7) Uani 1 1 d . . . . .
H36A H -0.292172 0.259006 0.027706 0.054 Uiso 1 1 calc R U . . .
H36B H -0.342571 0.322471 0.068605 0.054 Uiso 1 1 calc R U . . .
H36C H -0.194739 0.321518 0.046320 0.054 Uiso 1 1 calc R U . . .
C37 C -0.4685(3) 0.3389(2) -0.03336(15) 0.0429(8) Uani 1 1 d . . . . .
H37A H -0.492361 0.366266 -0.068310 0.064 Uiso 1 1 calc R U . . .
H37B H -0.523066 0.353766 -0.000302 0.064 Uiso 1 1 calc R U . . .
H37C H -0.481858 0.288095 -0.040920 0.064 Uiso 1 1 calc R U . . .
C38 C 0.0603(3) 0.41691(15) -0.15102(12) 0.0272(5) Uani 1 1 d . . . . .
H38 H 0.070642 0.453101 -0.119224 0.033 Uiso 1 1 calc R U . . .
C39 C 0.0257(3) 0.45714(19) -0.20757(14) 0.0383(7) Uani 1 1 d . . . . .
H39A H 0.013888 0.423041 -0.239640 0.058 Uiso 1 1 calc R U . . .
H39B H 0.096270 0.490127 -0.217462 0.058 Uiso 1 1 calc R U . . .
H39C H -0.055218 0.483885 -0.201675 0.058 Uiso 1 1 calc R U . . .
C40 C 0.1910(3) 0.3794(2) -0.15809(14) 0.0408(7) Uani 1 1 d . . . . .
H40A H 0.187256 0.347273 -0.191897 0.061 Uiso 1 1 calc R U . . .
H40B H 0.210230 0.351909 -0.122610 0.061 Uiso 1 1 calc R U . . .
H40C H 0.259685 0.414827 -0.164309 0.061 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Ga1 N1 99.93(8) . . ?
N2 Ga1 Cl2 110.08(6) . . ?
N1 Ga1 Cl2 120.81(6) . . ?
N2 Ga1 Cl1 109.65(6) . . ?
N1 Ga1 Cl1 107.49(6) . . ?
Cl2 Ga1 Cl1 108.37(3) . . ?
N4 Ga2 N3 100.66(8) . . ?
N4 Ga2 Cl3 111.61(6) . . ?
N3 Ga2 Cl3 108.50(6) . . ?
N4 Ga2 Cl4 109.20(6) . . ?
N3 Ga2 Cl4 116.17(6) . . ?
Cl3 Ga2 Cl4 110.38(3) . . ?
C1 N1 C11 120.51(18) . . ?
C1 N1 Ga1 111.91(15) . . ?
C11 N1 Ga1 123.79(14) . . ?
C3 N2 C17 121.53(19) . . ?
C3 N2 Ga1 115.83(15) . . ?
C17 N2 Ga1 122.64(14) . . ?
C6 N3 C12 118.55(18) . . ?
C6 N3 Ga2 115.54(15) . . ?
C12 N3 Ga2 124.50(14) . . ?
C8 N4 C29 119.16(19) . . ?
C8 N4 Ga2 117.21(15) . . ?
C29 N4 Ga2 123.36(15) . . ?
N1 C1 C2 124.0(2) . . ?
N1 C1 C4 120.3(2) . . ?
C2 C1 C4 115.74(19) . . ?
C3 C2 C1 129.3(2) . . ?
N2 C3 C2 122.3(2) . . ?
N2 C3 C5 119.5(2) . . ?
C2 C3 C5 118.2(2) . . ?
N3 C6 C7 124.8(2) . . ?
N3 C6 C9 120.4(2) . . ?
C7 C6 C9 114.7(2) . . ?
C8 C7 C6 127.8(2) . . ?
N4 C8 C7 123.3(2) . . ?
N4 C8 C10 119.0(2) . . ?
C7 C8 C10 117.7(2) . . ?
N1 C11 C12 113.46(17) . . ?
N1 C11 C16 109.21(18) . . ?
C12 C11 C16 109.02(18) . . ?
N3 C12 C11 114.57(17) . . ?
N3 C12 C13 107.45(17) . . ?
C11 C12 C13 109.66(18) . . ?
C14 C13 C12 112.4(2) . . ?
C15 C14 C13 109.6(2) . . ?
C14 C15 C16 110.4(2) . . ?
C15 C16 C11 112.46(19) . . ?
C18 C17 C22 121.8(2) . . ?
C18 C17 N2 118.8(2) . . ?
C22 C17 N2 119.4(2) . . ?
C19 C18 C17 118.5(2) . . ?
C19 C18 C23 119.3(2) . . ?
C17 C18 C23 122.1(2) . . ?
C18 C19 C20 120.7(2) . . ?
C21 C20 C19 119.9(2) . . ?
C20 C21 C22 121.4(2) . . ?
C21 C22 C17 117.7(2) . . ?
C21 C22 C26 119.6(2) . . ?
C17 C22 C26 122.7(2) . . ?
C18 C23 C24 112.3(2) . . ?
C18 C23 C25 111.1(2) . . ?
C24 C23 C25 109.9(2) . . ?
C22 C26 C28 110.9(2) . . ?
C22 C26 C27 111.9(2) . . ?
C28 C26 C27 110.6(3) . . ?
C30 C29 C34 122.4(2) . . ?
C30 C29 N4 119.9(2) . . ?
C34 C29 N4 117.7(2) . . ?
C29 C30 C31 117.3(3) . . ?
C29 C30 C35 122.4(2) . . ?
C31 C30 C35 120.3(2) . . ?
C32 C31 C30 121.3(3) . . ?
C31 C32 C33 120.4(3) . . ?
C32 C33 C34 121.0(3) . . ?
C33 C34 C29 117.6(3) . . ?
C33 C34 C38 119.9(2) . . ?
C29 C34 C38 122.5(2) . . ?
C30 C35 C36 110.5(2) . . ?
C30 C35 C37 113.0(2) . . ?
C36 C35 C37 110.4(2) . . ?
C34 C38 C40 112.9(3) . . ?
C34 C38 C39 111.5(2) . . ?
C40 C38 C39 110.0(2) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ga1 N2 1.9035(18) . ?
Ga1 N1 1.9177(19) . ?
Ga1 Cl2 2.1529(7) . ?
Ga1 Cl1 2.1907(7) . ?
Ga2 N4 1.9036(19) . ?
Ga2 N3 1.9251(18) . ?
Ga2 Cl3 2.1660(7) . ?
Ga2 Cl4 2.1675(7) . ?
N1 C1 1.345(3) . ?
N1 C11 1.483(3) . ?
N2 C3 1.337(3) . ?
N2 C17 1.445(3) . ?
N3 C6 1.337(3) . ?
N3 C12 1.486(3) . ?
N4 C8 1.336(3) . ?
N4 C29 1.447(3) . ?
C1 C2 1.405(3) . ?
C1 C4 1.514(3) . ?
C2 C3 1.397(3) . ?
C3 C5 1.504(3) . ?
C6 C7 1.411(3) . ?
C6 C9 1.508(3) . ?
C7 C8 1.394(3) . ?
C8 C10 1.503(3) . ?
C11 C12 1.536(3) . ?
C11 C16 1.544(3) . ?
C12 C13 1.539(3) . ?
C13 C14 1.527(3) . ?
C14 C15 1.520(4) . ?
C15 C16 1.526(3) . ?
C17 C18 1.403(3) . ?
C17 C22 1.403(3) . ?
C18 C19 1.391(3) . ?
C18 C23 1.520(3) . ?
C19 C20 1.395(4) . ?
C20 C21 1.379(4) . ?
C21 C22 1.400(4) . ?
C22 C26 1.513(4) . ?
C23 C24 1.528(4) . ?
C23 C25 1.534(4) . ?
C26 C28 1.535(4) . ?
C26 C27 1.535(4) . ?
C29 C30 1.400(3) . ?
C29 C34 1.405(4) . ?
C30 C31 1.403(4) . ?
C30 C35 1.515(4) . ?
C31 C32 1.376(5) . ?
C32 C33 1.378(5) . ?
C33 C34 1.399(4) . ?
C34 C38 1.523(4) . ?
C35 C36 1.529(4) . ?
C35 C37 1.536(4) . ?
C38 C40 1.524(4) . ?
C38 C39 1.537(4) . ?
