#------------------------------------------------------------------------------
#$Date: 2022-06-23 10:09:03 +0300 (Thu, 23 Jun 2022) $
#$Revision: 276163 $
#$URL: file:///home/coder/svn-repositories/cod/cif/8/10/54/8105457.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_8105457
loop_
_publ_author_name
'Lo, Kong Mun'
'Lee, See Mun'
'Tiekink, Edward R.T.'
_publ_section_title
;
 Crystal structure of trans-dichloridobis(4-chlorophenyl-\kC
 1)(1,10-phenanthroline-κ2 N,N′)tin(IV) dimethylsulphoxide
 solvate, C26H22Cl4N2OSSn
;
_journal_issue                   6
_journal_name_full
'Zeitschrift für Kristallographie - New Crystal Structures'
_journal_page_first              1327
_journal_page_last               1329
_journal_paper_doi               10.1515/ncrs-2020-0302
_journal_volume                  235
_journal_year                    2020
_chemical_formula_moiety         'C24 H16 Cl4 N2 Sn, C2 H6 O S'
_chemical_formula_sum            'C26 H22 Cl4 N2 O S Sn'
_chemical_formula_weight         671.00
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2018/3
_cell_angle_alpha                90.322(2)
_cell_angle_beta                 101.7830(10)
_cell_angle_gamma                95.7800(10)
_cell_formula_units_Z            2
_cell_length_a                   8.29660(10)
_cell_length_b                   11.4971(2)
_cell_length_c                   14.3311(2)
_cell_measurement_reflns_used    19043
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      76.1710
_cell_measurement_theta_min      3.8430
_cell_volume                     1330.91(3)
_computing_cell_refinement       'CrysAlisPro [1]'
_computing_data_collection       'CrysAlisPro [1]'
_computing_data_reduction        'CrysAlisPro [1]'
_computing_molecular_graphics    'ORTEP-3 for Windows [4]'
_computing_publication_material  'SHELXL-2018/3 [3]'
_computing_structure_refinement  'SHELXL-2018/3 [3]'
_computing_structure_solution    'SHELXT 2014/5 [2]'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 5.2558
_diffrn_detector_type            AtlasS2
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, AtlasS2'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0431
_diffrn_reflns_av_unetI/netI     0.0252
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            31273
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        67.070
_diffrn_reflns_theta_max         67.070
_diffrn_reflns_theta_min         3.151
_diffrn_source                   'micro-focus sealed X-ray tube'
_exptl_absorpt_coefficient_mu    12.252
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.904
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   'CrysAlisPro [1]'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.674
_exptl_crystal_description       prism
_exptl_crystal_F_000             668
_exptl_crystal_size_max          0.084
_exptl_crystal_size_mid          0.069
_exptl_crystal_size_min          0.025
_refine_diff_density_max         0.793
_refine_diff_density_min         -0.808
_refine_diff_density_rms         0.087
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     318
_refine_ls_number_reflns         4736
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.033
_refine_ls_R_factor_all          0.0269
_refine_ls_R_factor_gt           0.0258
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0426P)²+1.1680P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0675
_refine_ls_wR_factor_ref         0.0684
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4566
_reflns_number_total             4736
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            suppl_ncrs-2020-0302_suppl.cif
_cod_data_source_block           shelx
_cod_database_code               8105457
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.426
_shelx_estimated_absorpt_t_max   0.749
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sn Sn 0.36930(2) 0.30312(2) 0.66369(2) 0.01552(7) Uani 1 1 d . . . . .
Cl1 Cl 0.58737(7) 0.31493(5) 0.56764(5) 0.02063(14) Uani 1 1 d . . . . .
Cl2 Cl 0.09880(7) 0.26656(5) 0.71406(5) 0.02011(13) Uani 1 1 d . . . . .
Cl3 Cl 0.52383(10) 0.86349(6) 0.81157(5) 0.03120(16) Uani 1 1 d . . . . .
Cl4 Cl 0.82578(10) 0.06247(7) 1.03909(6) 0.03801(18) Uani 1 1 d . . . . .
N1 N 0.2863(3) 0.12878(18) 0.57746(16) 0.0184(4) Uani 1 1 d . . . . .
N2 N 0.2061(3) 0.33982(18) 0.51583(16) 0.0169(4) Uani 1 1 d . . . . .
C1 C 0.3322(3) 0.0264(2) 0.6092(2) 0.0218(6) Uani 1 1 d . . . . .
H1 H 0.394660 0.022332 0.672256 0.026 Uiso 1 1 calc R U . . .
C2 C 0.2909(4) -0.0759(2) 0.5519(2) 0.0254(6) Uani 1 1 d . . . . .
H2 H 0.326125 -0.147958 0.576092 0.030 Uiso 1 1 calc R U . . .
C3 C 0.2003(3) -0.0718(2) 0.4617(2) 0.0246(6) Uani 1 1 d . . . . .
H3 H 0.171920 -0.140975 0.422707 0.029 Uiso 1 1 calc R U . . .
C4 C 0.1486(3) 0.0354(2) 0.4262(2) 0.0215(5) Uani 1 1 d . . . . .
C5 C 0.0530(3) 0.0485(2) 0.3320(2) 0.0252(6) Uani 1 1 d . . . . .
H5 H 0.020092 -0.018062 0.290398 0.030 Uiso 1 1 calc R U . . .
C6 C 0.0090(3) 0.1548(3) 0.3016(2) 0.0250(6) Uani 1 1 d . . . . .
H6 H -0.055669 0.161384 0.239344 0.030 Uiso 1 1 calc R U . . .
C7 C 0.0590(3) 0.2574(2) 0.3624(2) 0.0200(5) Uani 1 1 d . . . . .
C8 C 0.0235(3) 0.3704(2) 0.3326(2) 0.0225(6) Uani 1 1 d . . . . .
H8 H -0.040011 0.381467 0.270766 0.027 Uiso 1 1 calc R U . . .
C9 C 0.0818(3) 0.4642(2) 0.3940(2) 0.0216(5) Uani 1 1 d . . . . .
H9 H 0.060517 0.541032 0.374709 0.026 Uiso 1 1 calc R U . . .
C10 C 0.1728(3) 0.4459(2) 0.4855(2) 0.0187(5) Uani 1 1 d . . . . .
H10 H 0.212197 0.511567 0.527386 0.022 Uiso 1 1 calc R U . . .
C11 C 0.1514(3) 0.2466(2) 0.45509(19) 0.0175(5) Uani 1 1 d . . . . .
C12 C 0.1961(3) 0.1346(2) 0.48790(19) 0.0179(5) Uani 1 1 d . . . . .
C13 C 0.4036(3) 0.4873(2) 0.70437(19) 0.0164(5) Uani 1 1 d . . . . .
C14 C 0.4987(3) 0.5674(2) 0.6606(2) 0.0208(5) Uani 1 1 d . . . . .
H14 H 0.540881 0.542577 0.607824 0.025 Uiso 1 1 calc R U . . .
C15 C 0.5335(3) 0.6834(2) 0.6927(2) 0.0224(6) Uani 1 1 d . . . . .
H15 H 0.597244 0.737702 0.661466 0.027 Uiso 1 1 calc R U . . .
C16 C 0.4742(3) 0.7188(2) 0.7704(2) 0.0216(6) Uani 1 1 d . . . . .
C17 C 0.3787(3) 0.6415(2) 0.8166(2) 0.0215(5) Uani 1 1 d . . . . .
H17 H 0.338752 0.666654 0.870063 0.026 Uiso 1 1 calc R U . . .
C18 C 0.3433(3) 0.5264(2) 0.7824(2) 0.0202(5) Uani 1 1 d . . . . .
H18 H 0.276664 0.472931 0.812566 0.024 Uiso 1 1 calc R U . . .
C19 C 0.5097(3) 0.2137(2) 0.78222(19) 0.0181(5) Uani 1 1 d . . . . .
C20 C 0.6772(4) 0.1961(3) 0.7825(2) 0.0262(6) Uani 1 1 d . . . . .
H20 H 0.723278 0.216779 0.728690 0.031 Uiso 1 1 calc R U . . .
C21 C 0.7740(4) 0.1488(3) 0.8614(2) 0.0284(6) Uani 1 1 d . . . . .
H21 H 0.885270 0.135597 0.861585 0.034 Uiso 1 1 calc R U . . .
C22 C 0.7046(4) 0.1213(2) 0.9395(2) 0.0260(6) Uani 1 1 d . . . . .
C23 C 0.5435(4) 0.1386(3) 0.9405(2) 0.0298(6) Uani 1 1 d . . . . .
H23 H 0.497990 0.119328 0.994788 0.036 Uiso 1 1 calc R U . . .
C24 C 0.4474(4) 0.1850(3) 0.8602(2) 0.0270(6) Uani 1 1 d . . . . .
H24 H 0.335709 0.196495 0.860426 0.032 Uiso 1 1 calc R U . . .
S1 S 0.87717(10) 0.62990(7) 0.88798(6) 0.03572(18) Uani 1 1 d . . . . .
O1 O 1.0591(3) 0.6200(2) 0.90976(19) 0.0444(6) Uani 1 1 d . . . . .
C25 C 0.7802(5) 0.4842(3) 0.8759(3) 0.0483(9) Uani 1 1 d . . . . .
H25A H 0.808993 0.444670 0.821750 0.072 Uiso 1 1 calc R U . . .
H25B H 0.659833 0.485292 0.865036 0.072 Uiso 1 1 calc R U . . .
H25C H 0.818189 0.442254 0.934347 0.072 Uiso 1 1 calc R U . . .
C26 C 0.8222(5) 0.6689(4) 0.9972(3) 0.0538(10) Uani 1 1 d . . . . .
H26A H 0.865773 0.615351 1.046895 0.081 Uiso 1 1 calc R U . . .
H26B H 0.701339 0.663516 0.988386 0.081 Uiso 1 1 calc R U . . .
H26C H 0.869202 0.749140 1.016443 0.081 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn 0.0259 5.4591 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C13 Sn C19 106.31(9) . .
C13 Sn N1 162.17(9) . .
C19 Sn N1 91.51(8) . .
C13 Sn N2 91.61(8) . .
C19 Sn N2 162.03(8) . .
N1 Sn N2 70.56(8) . .
C13 Sn Cl1 95.43(7) . .
C19 Sn Cl1 95.39(8) . .
N1 Sn Cl1 81.94(6) . .
N2 Sn Cl1 81.33(5) . .
C13 Sn Cl2 94.23(7) . .
C19 Sn Cl2 95.55(8) . .
N1 Sn Cl2 84.49(6) . .
N2 Sn Cl2 84.17(5) . .
Cl1 Sn Cl2 162.76(2) . .
C1 N1 C12 119.3(2) . .
C1 N1 Sn 123.29(18) . .
C12 N1 Sn 117.29(16) . .
C10 N2 C11 118.5(2) . .
C10 N2 Sn 124.52(17) . .
C11 N2 Sn 116.85(17) . .
N1 C1 C2 121.7(3) . .
N1 C1 H1 119.1 . .
C2 C1 H1 119.1 . .
C3 C2 C1 119.9(3) . .
C3 C2 H2 120.0 . .
C1 C2 H2 120.0 . .
C2 C3 C4 119.7(2) . .
C2 C3 H3 120.1 . .
C4 C3 H3 120.1 . .
C12 C4 C3 117.0(3) . .
C12 C4 C5 119.2(2) . .
C3 C4 C5 123.8(2) . .
C6 C5 C4 120.9(2) . .
C6 C5 H5 119.5 . .
C4 C5 H5 119.5 . .
C5 C6 C7 120.8(3) . .
C5 C6 H6 119.6 . .
C7 C6 H6 119.6 . .
C11 C7 C8 117.8(2) . .
C11 C7 C6 119.2(2) . .
C8 C7 C6 123.0(3) . .
C9 C8 C7 119.1(3) . .
C9 C8 H8 120.4 . .
C7 C8 H8 120.4 . .
C8 C9 C10 119.6(2) . .
C8 C9 H9 120.2 . .
C10 C9 H9 120.2 . .
N2 C10 C9 122.4(2) . .
N2 C10 H10 118.8 . .
C9 C10 H10 118.8 . .
N2 C11 C7 122.6(2) . .
N2 C11 C12 117.2(2) . .
C7 C11 C12 120.2(2) . .
N1 C12 C4 122.4(2) . .
N1 C12 C11 118.0(2) . .
C4 C12 C11 119.6(2) . .
C14 C13 C18 118.1(2) . .
C14 C13 Sn 121.28(19) . .
C18 C13 Sn 120.30(18) . .
C13 C14 C15 121.2(3) . .
C13 C14 H14 119.4 . .
C15 C14 H14 119.4 . .
C16 C15 C14 119.2(3) . .
C16 C15 H15 120.4 . .
C14 C15 H15 120.4 . .
C15 C16 C17 121.5(2) . .
C15 C16 Cl3 118.5(2) . .
C17 C16 Cl3 119.9(2) . .
C18 C17 C16 118.3(3) . .
C18 C17 H17 120.8 . .
C16 C17 H17 120.8 . .
C17 C18 C13 121.6(2) . .
C17 C18 H18 119.2 . .
C13 C18 H18 119.2 . .
C24 C19 C20 118.8(3) . .
C24 C19 Sn 121.5(2) . .
C20 C19 Sn 119.4(2) . .
C21 C20 C19 120.4(3) . .
C21 C20 H20 119.8 . .
C19 C20 H20 119.8 . .
C22 C21 C20 118.6(3) . .
C22 C21 H21 120.7 . .
C20 C21 H21 120.7 . .
C23 C22 C21 121.7(3) . .
C23 C22 Cl4 119.5(2) . .
C21 C22 Cl4 118.8(2) . .
C22 C23 C24 119.0(3) . .
C22 C23 H23 120.5 . .
C24 C23 H23 120.5 . .
C19 C24 C23 121.6(3) . .
C19 C24 H24 119.2 . .
C23 C24 H24 119.2 . .
O1 S1 C25 105.85(17) . .
O1 S1 C26 106.97(17) . .
C25 S1 C26 97.9(2) . .
S1 C25 H25A 109.5 . .
S1 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
S1 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
S1 C26 H26A 109.5 . .
S1 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
S1 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sn C13 2.168(2) .
Sn C19 2.180(3) .
Sn N1 2.316(2) .
Sn N2 2.335(2) .
Sn Cl1 2.4812(6) .
Sn Cl2 2.4918(6) .
Cl3 C16 1.743(3) .
Cl4 C22 1.751(3) .
N1 C1 1.328(4) .
N1 C12 1.353(4) .
N2 C10 1.334(3) .
N2 C11 1.358(3) .
C1 C2 1.403(4) .
C1 H1 0.9500 .
C2 C3 1.360(4) .
C2 H2 0.9500 .
C3 C4 1.410(4) .
C3 H3 0.9500 .
C4 C12 1.412(4) .
C4 C5 1.436(4) .
C5 C6 1.360(4) .
C5 H5 0.9500 .
C6 C7 1.437(4) .
C6 H6 0.9500 .
C7 C11 1.404(4) .
C7 C8 1.411(4) .
C8 C9 1.372(4) .
C8 H8 0.9500 .
C9 C10 1.400(4) .
C9 H9 0.9500 .
C10 H10 0.9500 .
C11 C12 1.430(4) .
C13 C14 1.388(4) .
C13 C18 1.404(4) .
C14 C15 1.391(4) .
C14 H14 0.9500 .
C15 C16 1.381(4) .
C15 H15 0.9500 .
C16 C17 1.390(4) .
C17 C18 1.390(4) .
C17 H17 0.9500 .
C18 H18 0.9500 .
C19 C24 1.353(4) .
C19 C20 1.423(4) .
C20 C21 1.395(4) .
C20 H20 0.9500 .
C21 C22 1.383(4) .
C21 H21 0.9500 .
C22 C23 1.373(4) .
C23 C24 1.401(4) .
C23 H23 0.9500 .
C24 H24 0.9500 .
S1 O1 1.494(3) .
S1 C25 1.775(4) .
S1 C26 1.785(4) .
C25 H25A 0.9800 .
C25 H25B 0.9800 .
C25 H25C 0.9800 .
C26 H26A 0.9800 .
C26 H26B 0.9800 .
C26 H26C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
C12 N1 C1 C2 0.6(4) . . . .
Sn N1 C1 C2 -174.6(2) . . . .
N1 C1 C2 C3 -0.6(4) . . . .
C1 C2 C3 C4 0.1(4) . . . .
C2 C3 C4 C12 0.3(4) . . . .
C2 C3 C4 C5 179.9(3) . . . .
C12 C4 C5 C6 0.5(4) . . . .
C3 C4 C5 C6 -179.1(3) . . . .
C4 C5 C6 C7 0.9(4) . . . .
C5 C6 C7 C11 -1.4(4) . . . .
C5 C6 C7 C8 176.8(3) . . . .
C11 C7 C8 C9 0.9(4) . . . .
C6 C7 C8 C9 -177.4(3) . . . .
C7 C8 C9 C10 -1.1(4) . . . .
C11 N2 C10 C9 0.9(4) . . . .
Sn N2 C10 C9 176.38(19) . . . .
C8 C9 C10 N2 0.2(4) . . . .
C10 N2 C11 C7 -1.1(4) . . . .
Sn N2 C11 C7 -176.88(19) . . . .
C10 N2 C11 C12 176.9(2) . . . .
Sn N2 C11 C12 1.1(3) . . . .
C8 C7 C11 N2 0.2(4) . . . .
C6 C7 C11 N2 178.5(2) . . . .
C8 C7 C11 C12 -177.8(2) . . . .
C6 C7 C11 C12 0.6(4) . . . .
C1 N1 C12 C4 -0.1(4) . . . .
Sn N1 C12 C4 175.38(19) . . . .
C1 N1 C12 C11 -178.7(2) . . . .
Sn N1 C12 C11 -3.2(3) . . . .
C3 C4 C12 N1 -0.3(4) . . . .
C5 C4 C12 N1 -179.9(3) . . . .
C3 C4 C12 C11 178.3(2) . . . .
C5 C4 C12 C11 -1.3(4) . . . .
N2 C11 C12 N1 1.4(4) . . . .
C7 C11 C12 N1 179.5(2) . . . .
N2 C11 C12 C4 -177.3(2) . . . .
C7 C11 C12 C4 0.8(4) . . . .
C18 C13 C14 C15 -0.2(4) . . . .
Sn C13 C14 C15 -173.9(2) . . . .
C13 C14 C15 C16 1.0(4) . . . .
C14 C15 C16 C17 -0.9(4) . . . .
C14 C15 C16 Cl3 178.2(2) . . . .
C15 C16 C17 C18 -0.1(4) . . . .
Cl3 C16 C17 C18 -179.2(2) . . . .
C16 C17 C18 C13 1.0(4) . . . .
C14 C13 C18 C17 -0.9(4) . . . .
Sn C13 C18 C17 172.9(2) . . . .
C24 C19 C20 C21 0.8(4) . . . .
Sn C19 C20 C21 174.2(2) . . . .
C19 C20 C21 C22 -1.1(4) . . . .
C20 C21 C22 C23 0.6(5) . . . .
C20 C21 C22 Cl4 -179.7(2) . . . .
C21 C22 C23 C24 0.1(5) . . . .
Cl4 C22 C23 C24 -179.6(2) . . . .
C20 C19 C24 C23 0.0(4) . . . .
Sn C19 C24 C23 -173.3(2) . . . .
C22 C23 C24 C19 -0.4(5) . . . .
