Crystallography Open Database
| COD Home |
|---|
| Accessing COD Data |
|---|
| Add Your Data |
|---|
| Documentation |
|---|
CIF Information Card
Information card for 7015468
7015467 << 7015468 >> 7015469Preview
|
Coordinates |
7015468.cif |
Structure parameters
| Formula | - C35 H42 Cl F6 Ir N3 O12 P - |
| Calculated formula | - C35 H42 Cl F6 Ir N3 O12 P - |
| Title of publication | Unprecedented diastereoselective generation of chiral-at-metal, half sandwich Ir(III) and Rh(III) complexes via anomeric isomerism on "sugar-coated" N-heterocyclic carbene ligands. |
| Authors of publication | Shibata, Teppei; Hashimoto, Hideki; Kinoshita, Isamu; Yano, Shigenobu; Nishioka, Takanori |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2011 |
| Journal volume | 40 |
| Journal issue | 18 |
| Pages of publication | 4826 - 4829 |
| a | 12.6224 ± 0.0013 Å |
| b | 15.2989 ± 0.0018 Å |
| c | 22.254 ± 0.003 Å |
| α | 90° |
| β | 90° |
| γ | 90° |
| Cell volume | 4297.4 ± 0.9 Å3 |
| Cell temperature | 193.1 K |
| Number of distinct elements | 8 |
| Hermann-Mauguin symmetry space group | P 21 21 21 |
| Hall symmetry space group | P 2ac 2ab |
| Residual factor for observed reflections | 0.0455 |
| Weighted residual factors for all reflections included in the refinement | 0.0968 |
| Goodness-of-fit parameter for observed reflections | 1.002 |
| Diffraction radiation wavelength | 0.7107 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |