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CIF Information Card
Information card for 7015472
7015471 << 7015472 >> 7015473Preview
|
Coordinates |
7015472.cif |
Structure parameters
| Formula | - C30 H20 Br2 Cu N4 O4 S2 - |
| Calculated formula | - C30 H20 Br2 Cu N4 O4 S2 - |
| Title of publication | One-step synthesis of Mo(0) and W(0) bis(dinitrogen) complexes with the linear tetraphosphine ligand prP4: stereoselective formation of cis-[M(N2)2(rac-prP4)] and trans-[M(N2)2(meso-prP4)]; M = Mo, W. |
| Authors of publication | Römer, René; Gradert, Christian; Bannwarth, Alexander; Peters, Gerhard; Näther, Christian; Tuczek, Felix |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2011 |
| Journal volume | 40 |
| Journal issue | 13 |
| Pages of publication | 3229 - 3236 |
| a | 17.027 ± 0.003 Å |
| b | 9.5242 ± 0.0019 Å |
| c | 18.442 ± 0.004 Å |
| α | 90° |
| β | 104.05 ± 0.03° |
| γ | 90° |
| Cell volume | 2901.2 ± 1.1 Å3 |
| Cell temperature | 173 ± 1 K |
| Ambient diffraction temperature | 173 ± 1 K |
| Number of distinct elements | 7 |
| Hermann-Mauguin symmetry space group | P 1 21/n 1 |
| Hall symmetry space group | -P 2yn |
| Residual factor for all reflections | 0.1035 |
| Residual factor for observed reflections | 0.0497 |
| Weighted residual factors for the observed reflections | 0.1119 |
| Weighted residual factors for all reflections included in the refinement | 0.1182 |
| Goodness-of-fit parameter for observed reflections | 0.927 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |