Crystallography Open Database
- COD Home
- Accessing COD Data
- Add Your Data
- Documentation
Information card for entry 7015475
Preview
| Coordinates | 7015475.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C43 H44 Mo N4 P4 |
|---|---|
| Calculated formula | C43 H44 Mo N4 P4 |
| Title of publication | One-step synthesis of Mo(0) and W(0) bis(dinitrogen) complexes with the linear tetraphosphine ligand prP4: stereoselective formation of cis-[M(N2)2(rac-prP4)] and trans-[M(N2)2(meso-prP4)]; M = Mo, W. |
| Authors of publication | Römer, René; Gradert, Christian; Bannwarth, Alexander; Peters, Gerhard; Näther, Christian; Tuczek, Felix |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2011 |
| Journal volume | 40 |
| Journal issue | 13 |
| Pages of publication | 3229 - 3236 |
| a | 9.4885 ± 0.0008 Å |
| b | 11.4201 ± 0.0011 Å |
| c | 19.3015 ± 0.0017 Å |
| α | 92.688 ± 0.011° |
| β | 90.529 ± 0.01° |
| γ | 112.629 ± 0.01° |
| Cell volume | 1927.5 ± 0.3 Å3 |
| Cell temperature | 170 ± 2 K |
| Ambient diffraction temperature | 170 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.0952 |
| Residual factor for significantly intense reflections | 0.0725 |
| Weighted residual factors for significantly intense reflections | 0.1884 |
| Weighted residual factors for all reflections included in the refinement | 0.2007 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.141 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 179858 (current) | 2016-03-25 | cif/7/01/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/01/54. |
7015475.cif |
| 120112 | 2014-07-12 | Adding DOIs to range 7 structures. | 7015475.cif |
| 35909 | 2012-02-26 | cif/7/: reorganising range 7 into a prefix-directory tree. | 7015475.cif |
| 21162 | 2011-06-21 | ../uploads/cif-deposit/cod/cif Adding structures of 7015472, 7015473, 7015474, 7015475 via cif-deposit CGI script. |
7015475.cif |
All data in the COD and the database itself are dedicated to the
public domain and licensed under the
CC0
License
.
Users of the data should acknowledge the original authors of the
structural data.