Crystallography Open Database
| COD Home |
|---|
| Accessing COD Data |
|---|
| Add Your Data |
|---|
| Documentation |
|---|
CIF Information Card
Information card for 7015475
7015474 << 7015475 >> 7015476Preview
|
Coordinates |
7015475.cif |
Structure parameters
| Formula | - C43 H44 Mo N4 P4 - |
| Calculated formula | - C43 H44 Mo N4 P4 - |
| Title of publication | One-step synthesis of Mo(0) and W(0) bis(dinitrogen) complexes with the linear tetraphosphine ligand prP4: stereoselective formation of cis-[M(N2)2(rac-prP4)] and trans-[M(N2)2(meso-prP4)]; M = Mo, W. |
| Authors of publication | Römer, René; Gradert, Christian; Bannwarth, Alexander; Peters, Gerhard; Näther, Christian; Tuczek, Felix |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2011 |
| Journal volume | 40 |
| Journal issue | 13 |
| Pages of publication | 3229 - 3236 |
| a | 9.4885 ± 0.0008 Å |
| b | 11.4201 ± 0.0011 Å |
| c | 19.3015 ± 0.0017 Å |
| α | 92.688 ± 0.011° |
| β | 90.529 ± 0.01° |
| γ | 112.629 ± 0.01° |
| Cell volume | 1927.5 ± 0.3 Å3 |
| Cell temperature | 170 ± 2 K |
| Ambient diffraction temperature | 170 ± 2 K |
| Number of distinct elements | 5 |
| Hermann-Mauguin symmetry space group | P -1 |
| Hall symmetry space group | -P 1 |
| Residual factor for all reflections | 0.0952 |
| Residual factor for observed reflections | 0.0725 |
| Weighted residual factors for the observed reflections | 0.1884 |
| Weighted residual factors for all reflections included in the refinement | 0.2007 |
| Goodness-of-fit parameter for observed reflections | 1.141 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |