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Information card for entry 1506910
Preview
Coordinates | 1506910.cif |
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Original paper (by DOI) | HTML |
Formula | C22 H39 N O2 Si2 |
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Calculated formula | C22 H39 N O2 Si2 |
SMILES | C(=C\C(c1ccccc1)[Si](C)(C)C)(/[Si](C)(C)C)OC(=O)N(C(C)C)C(C)C |
Title of publication | Highly enantioenriched homoenolate reagents by asymmetric gamma-deprotonation of achiral 1-silyl-substituted 1-alkenyl carbamates. |
Authors of publication | Reuber, Jenny; Fröhlich, Roland; Hoppe, Dieter |
Journal of publication | Organic letters |
Year of publication | 2004 |
Journal volume | 6 |
Journal issue | 5 |
Pages of publication | 783 - 786 |
a | 21.838 ± 0.001 Å |
b | 9.844 ± 0.002 Å |
c | 12.235 ± 0.001 Å |
α | 90° |
β | 90° |
γ | 90° |
Cell volume | 2630.2 ± 0.6 Å3 |
Cell temperature | 223 ± 2 K |
Ambient diffraction temperature | 223 ± 2 K |
Number of distinct elements | 5 |
Space group number | 33 |
Hermann-Mauguin space group symbol | P n a 21 |
Hall space group symbol | P 2c -2n |
Residual factor for all reflections | 0.0691 |
Residual factor for significantly intense reflections | 0.0522 |
Weighted residual factors for significantly intense reflections | 0.1398 |
Weighted residual factors for all reflections included in the refinement | 0.1528 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.035 |
Diffraction radiation wavelength | 1.54178 Å |
Diffraction radiation type | CuKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
Revision | Date | Message | Files |
---|---|---|---|
176729 (current) | 2016-02-18 | cif/ (antanas@echidna.ibt.lt) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 1. |
1506910.cif |
120071 | 2014-07-11 | Adding DOIs to range 1 structures. | 1506910.cif |
51539 | 2012-04-07 | ../uploads/cif-deposit/cod/cif Adding structures of 1506910 via cif-deposit CGI script. |
1506910.cif |
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Users of the data should acknowledge the original authors of the
structural data.