Crystallography Open Database

Information card for entry 1507357

Preview

Coordinates	1507357.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C50 H46 Cl14 N2 O6 P2 Pt
Calculated formula	C48 H44 Cl8 N2 O6 P2 Pt
SMILES	[Pt]1(Cl)(Cl)[P]2(O[C@@H]([C@H](O[P]31[C@@H]1C(=C([C@H]3[C@H]3C(=O)N(C(=O)[C@@H]13)c1ccccc1)C)C)c1ccccc1)c1ccccc1)[C@@H]1C(=C([C@H]2[C@@H]2[C@H]1C(=O)N(C2=O)c1ccccc1)C)C.ClC(Cl)Cl.ClC(Cl)Cl
Title of publication	Phosphinites derived from the 7-phosphanorbornene skeleton: first results in asymmetric catalysis.
Authors of publication	Clochard, Magali; Mattmann, Eric; Mercier, François; Ricard, Louis; Mathey, François
Journal of publication	Organic letters
Year of publication	2003
Journal volume	5
Journal issue	17
Pages of publication	3093 - 3094
a	15.186 ± 0.001 Å
b	13.755 ± 0.001 Å
c	16.028 ± 0.001 Å
α	90°
β	112.33 ± 0.001°
γ	90°
Cell volume	3096.9 ± 0.4 Å³
Cell temperature	150 ± 1 K
Ambient diffraction temperature	150 ± 1 K
Number of distinct elements	7
Space group number	4
Hermann-Mauguin space group symbol	P 1 21 1
Hall space group symbol	P 2yb
Residual factor for all reflections	0.0672
Residual factor for significantly intense reflections	0.0598
Weighted residual factors for significantly intense reflections	0.1583
Weighted residual factors for all reflections included in the refinement	0.1628
Goodness-of-fit parameter for all reflections included in the refinement	1.005
Diffraction radiation wavelength	0.71069 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
176729 (current)	2016-02-18	cif/ (antanas@echidna.ibt.lt) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 1.	1507357.cif
120071	2014-07-11	Adding DOIs to range 1 structures.	1507357.cif
53852	2012-04-20	cif/ Adding structures of 1507357 via cif-deposit CGI script.	1507357.cif