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Information card for entry 1549753
Preview
| Coordinates | 1549753.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C36 H8 Ag Al2 F59 O6 |
|---|---|
| Calculated formula | C36 H8 Ag1.0019 Al2 F59 O6 |
| SMILES | [Ag]12([cH]3cc(F)c(c[cH]13)F)[cH]1cc(F)c(c[cH]21)F.[Al]([F][Al](OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F)(OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F)OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F)(OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F)(OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F)OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F |
| Title of publication | Facile and systematic access to the least-coordinating WCA [(R<sup>F</sup>O)<sub>3</sub>Al-F-Al(OR<sup>F</sup>)<sub>3</sub>]<sup>-</sup> and its more Lewis-basic brother [F-Al(OR<sup>F</sup>)<sub>3</sub>]<sup>-</sup> (R<sup>F</sup> = C(CF<sub>3</sub>)<sub>3</sub>). |
| Authors of publication | Martens, Arthur; Weis, Philippe; Krummer, Michael Christian; Kreuzer, Marvin; Meierhöfer, Andreas; Meier, Stefan C.; Bohnenberger, Jan; Scherer, Harald; Riddlestone, Ian; Krossing, Ingo |
| Journal of publication | Chemical science |
| Year of publication | 2018 |
| Journal volume | 9 |
| Journal issue | 35 |
| Pages of publication | 7058 - 7068 |
| a | 13.1028 ± 0.0012 Å |
| b | 29.39 ± 0.003 Å |
| c | 14.129 ± 0.0012 Å |
| α | 90° |
| β | 99.674 ± 0.004° |
| γ | 90° |
| Cell volume | 5363.6 ± 0.9 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 9 |
| Hermann-Mauguin space group symbol | C 1 c 1 |
| Hall space group symbol | C -2yc |
| Residual factor for all reflections | 0.0782 |
| Residual factor for significantly intense reflections | 0.0633 |
| Weighted residual factors for significantly intense reflections | 0.1652 |
| Weighted residual factors for all reflections included in the refinement | 0.1793 |
| Goodness-of-fit parameter for all reflections included in the refinement | 0.994 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 228840 (current) | 2019-11-17 | cif/ Updating files of 1549751, 1549752, 1549753, 1549754, 1549755, 1549756, 1549757, 1549758, 1549759, 1549760 Original log message: Adding full bibliography for 1549751--1549760.cif. |
1549753.cif |
| 209346 | 2018-08-02 | cif/ Adding structures of 1549751, 1549752, 1549753, 1549754, 1549755, 1549756, 1549757, 1549758, 1549759, 1549760 via cif-deposit CGI script. |
1549753.cif |
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Users of the data should acknowledge the original authors of the
structural data.