Crystallography Open Database

Information card for entry 1568739

Preview

Coordinates	1568739.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C104 H166 B2 Si4
Calculated formula	C103.988 H165.972 B2 Si4
Title of publication	A donor-supported silavinylidene and silylium ylides: boroles as a flexible platform for versatile Si(ii) chemistry.
Authors of publication	Sarcevic, Julijan; Heitkemper, Tobias; Ruth, Paul Niklas; Naß, Leonard; Kubis, Maximilian; Stalke, Dietmar; Sindlinger, Christian P.
Journal of publication	Chemical science
Year of publication	2023
Journal volume	14
Journal issue	19
Pages of publication	5148 - 5159
a	11.975 ± 0.002 Å
b	14.7 ± 0.003 Å
c	14.916 ± 0.003 Å
α	90.82 ± 0.003°
β	103.725 ± 0.003°
γ	90.717 ± 0.003°
Cell volume	2550.1 ± 0.8 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	4
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0691
Residual factor for significantly intense reflections	0.0576
Weighted residual factors for significantly intense reflections	0.152
Weighted residual factors for all reflections included in the refinement	0.1608
Goodness-of-fit parameter for all reflections included in the refinement	1.084
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
284214 (current)	2023-06-05	cif/ Updating files of 1568738, 1568739, 1568740, 1568741, 1568742, 1568743, 1568744, 1568745, 1568746, 1568747, 1568748, 1568749 Original log message: Adding full bibliography for 1568738--1568749.cif.	1568739.cif
282161	2023-04-01	cif/ Adding structures of 1568738, 1568739, 1568740, 1568741, 1568742, 1568743, 1568744, 1568745, 1568746, 1568747, 1568748, 1568749 via cif-deposit CGI script.	1568739.cif