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Information card for entry 1574643
Preview
| Coordinates | 1574643.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C72 H169 Ag20 O24 P12 Rh Se24 |
|---|---|
| Calculated formula | C72 H169 Ag20 O24 P12 Rh Se24 |
| SMILES | C(C)(C)OP1(OC(C)C)=[Se][Ag]234[Ag]567[Ag]89%10%11[Ag]%12%13%14([Ag])[Ag]%15%16%17[Ag]%18%19[Ag]%20%21([Ag]%15([Se]1)[Se]=P(OC(C)C)(OC(C)C)[Se]%13)([RhH]18%12[Ag]8%12%135[Ag]5([Ag]9%14[Ag]9%18([Se]=P(OC(C)C)(OC(C)C)[Se][Ag]%14%15%18[Ag]%22%23%19%21[Ag]3%20[Ag]%15([Ag]71%12([Ag]%139%14%22)[Se]=P(OC(C)C)(OC(C)C)[Se]%18)([Se]=P(OC(C)C)(OC(C)C)[Se]4)[Se]=P(OC(C)C)(OC(C)C)[Se]%23)([Se]=P([Se]%17)(OC(C)C)OC(C)C)[Se]=P(OC(C)C)(OC(C)C)[Se]5)([Ag]6%10([Se]=P(OC(C)C)(OC(C)C)[Se]2)[Se]=P(OC(C)C)(OC(C)C)[Se]8)[Se]=P(OC(C)C)(OC(C)C)[Se]%11)[Se]=P(OC(C)C)(OC(C)C)[Se]%16 |
| Title of publication | Rhodium-silver superatomic nanoclusters stabilized by diselenophosphate ligands. |
| Authors of publication | Chiu, Tzu-Hao; Pillay, Michael N.; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. |
| Journal of publication | Nanoscale |
| Year of publication | 2025 |
| Journal volume | 17 |
| Journal issue | 21 |
| Pages of publication | 13502 - 13509 |
| a | 32.578 ± 0.002 Å |
| b | 32.578 ± 0.002 Å |
| c | 32.578 ± 0.002 Å |
| α | 90° |
| β | 90° |
| γ | 90° |
| Cell volume | 34576 ± 4 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 197 |
| Hermann-Mauguin space group symbol | I 2 3 |
| Hall space group symbol | I 2 2 3 |
| Residual factor for all reflections | 0.0906 |
| Residual factor for significantly intense reflections | 0.0592 |
| Weighted residual factors for significantly intense reflections | 0.1234 |
| Weighted residual factors for all reflections included in the refinement | 0.1469 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.078 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 301026 (current) | 2025-07-06 | cif/ Updating files of 1574642, 1574643, 1574644 Original log message: Adding full bibliography for 1574642--1574644.cif. |
1574643.cif |
| 299680 | 2025-05-15 | cif/ Adding structures of 1574642, 1574643, 1574644 via cif-deposit CGI script. |
1574643.cif |
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Users of the data should acknowledge the original authors of the
structural data.