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Information card for entry 4066487
Preview
| Coordinates | 4066487.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | Alkyl Amide Imide Tantalum |
|---|---|
| Formula | C19 H49 N2 Si3 Ta |
| Calculated formula | C19 H49 N2 Si3 Ta |
| SMILES | [Ta](N([Si](C)(C)C)[Si](C)(C)C)(=N[Si](C)(C)C)(CC(C)(C)C)CC(C)(C)C |
| Title of publication | Preparation of the Alkyl Complex Ta(═NSiMe3)[N(SiMe3)2](CH2But)2. Preferential Oxygen Insertion in Its Reaction with O2and a Ligand Exchange in the Alkoxide Ta(═NSiMe3)[N(SiMe3)2](OCH2But)2† |
| Authors of publication | Chen, Shu-Jian; Xue, Zi-Ling |
| Journal of publication | Organometallics |
| Year of publication | 2010 |
| Journal volume | 29 |
| Journal issue | 21 |
| Pages of publication | 5579 |
| a | 11.58 ± 0.014 Å |
| b | 11.882 ± 0.014 Å |
| c | 20.84 ± 0.02 Å |
| α | 90.005 ± 0.014° |
| β | 90.129 ± 0.014° |
| γ | 94.043 ± 0.015° |
| Cell volume | 2860 ± 6 Å3 |
| Cell temperature | 173 ± 2 K |
| Ambient diffraction temperature | 173 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.0725 |
| Residual factor for significantly intense reflections | 0.0483 |
| Weighted residual factors for significantly intense reflections | 0.1345 |
| Weighted residual factors for all reflections included in the refinement | 0.1673 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.125 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 178556 (current) | 2016-03-21 | cif/4/06/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/06/64. |
4066487.cif |
| 91935 | 2013-12-29 | cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs. |
4066487.cif |
| 34330 | 2012-02-24 | cif/4/ Reorganising CIF range 4 into a prefix tree. |
4066487.cif |
| 33909 | 2012-02-13 | ../uploads/cif-deposit/cod/cif Adding structures of 4066487, 4066488 via cif-deposit CGI script. |
4066487.cif |
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