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Information card for entry 4071033
Preview
| Coordinates | 4071033.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | Moris-77(litmdadim) |
|---|---|
| Formula | C20 H41 Li N4 O Si2 |
| Calculated formula | C20 H41 Li N4 O Si2 |
| SMILES | [Si](N1C(=[N]([Si](C)(C)C)[Li]12[N](CC[N]2(C)C)(C)C)c1cccc(OC)c1)(C)(C)C |
| Title of publication | N,N′-Bis-Silylated Lithium Aryl Amidinates: Synthesis, Characterization, and the Gradual Transition of Coordination Mode from σ Toward π Originated by Crystal Packing Interactions |
| Authors of publication | Aharonovich, Sinai; Kapon, Moshe; Botoshanski, Mark; Eisen, Moris S. |
| Journal of publication | Organometallics |
| Year of publication | 2008 |
| Journal volume | 27 |
| Journal issue | 8 |
| Pages of publication | 1869 |
| a | 16.327 ± 0.003 Å |
| b | 13.136 ± 0.003 Å |
| c | 26.795 ± 0.005 Å |
| α | 90° |
| β | 107.04 ± 0.03° |
| γ | 90° |
| Cell volume | 5494 ± 2 Å3 |
| Cell temperature | 230 ± 1 K |
| Ambient diffraction temperature | 230 ± 1 K |
| Number of distinct elements | 6 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.1598 |
| Residual factor for significantly intense reflections | 0.0745 |
| Weighted residual factors for significantly intense reflections | 0.183 |
| Weighted residual factors for all reflections included in the refinement | 0.1997 |
| Goodness-of-fit parameter for all reflections included in the refinement | 0.884 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 278158 (current) | 2022-09-25 | cod/ Reformatted the summary chemical formuale using the 'cif_filter' program. |
4071033.cif |
| 178599 | 2016-03-21 | cif/4/07/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/07/10. |
4071033.cif |
| 120075 | 2014-07-11 | Adding DOIs to range 4/07 structures. | 4071033.cif |
| 93859 | 2014-01-18 | cif/4: Small fixes, mostly wrong Z-values/formulae. |
4071033.cif |
| 47256 | 2012-03-23 | cif/4/ Distributing the new range 4 CIFs into their appropriate prefixed subdirectories. |
4071033.cif |
| 43001 | 2012-03-13 | ../uploads/cif-deposit/cod/cif Adding structures of 4071028, 4071029, 4071030, 4071031, 4071032, 4071033, 4071034, 4071035, 4071036, 4071037 via cif-deposit CGI script. |
4071033.cif |
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Users of the data should acknowledge the original authors of the
structural data.