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Information card for entry 4071854
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| Coordinates | 4071854.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | 15a |
|---|---|
| Chemical name | [N-(benzylideneimino)acetimidato-N',O] [N-(benzylamino)acetimidato-N',O]methylsilicon(IV) |
| Formula | C19 H22 N4 O2 Si |
| Calculated formula | C19 H22 N4 O2 Si |
| SMILES | [Si]12(OC(=NN1Cc1ccccc1)C)(OC(=N[N]2=Cc1ccccc1)C)C |
| Title of publication | Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation |
| Authors of publication | Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel |
| Journal of publication | Organometallics |
| Year of publication | 2008 |
| Journal volume | 27 |
| Journal issue | 20 |
| Pages of publication | 5285 |
| a | 8.32 ± 0.002 Å |
| b | 9.969 ± 0.002 Å |
| c | 11.555 ± 0.002 Å |
| α | 91.54 ± 0.02° |
| β | 99.44 ± 0.03° |
| γ | 90.17 ± 0.02° |
| Cell volume | 945 ± 0.3 Å3 |
| Cell temperature | 240 ± 2 K |
| Ambient diffraction temperature | 240 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.0615 |
| Residual factor for significantly intense reflections | 0.0431 |
| Weighted residual factors for significantly intense reflections | 0.1208 |
| Weighted residual factors for all reflections included in the refinement | 0.1278 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.128 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 178607 (current) | 2016-03-21 | cif/4/07/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/07/18. |
4071854.cif |
| 171438 | 2015-12-11 | cod/ (antanas@echidna.ibt.lt) Replacing '’' sequences with a quotation mark ("'") in _chemical_name_systematic tag values in multiple entries. |
4071854.cif |
| 91935 | 2013-12-29 | cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs. |
4071854.cif |
| 47256 | 2012-03-23 | cif/4/ Distributing the new range 4 CIFs into their appropriate prefixed subdirectories. |
4071854.cif |
| 44079 | 2012-03-15 | ../uploads/cif-deposit/cod/cif Adding structures of 4071848, 4071849, 4071850, 4071851, 4071852, 4071853, 4071854 via cif-deposit CGI script. |
4071854.cif |
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Users of the data should acknowledge the original authors of the
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