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Information card for entry 4075084
Preview
| Coordinates | 4075084.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C108 H172 Cl4 Cu4 Ge4 I4 N8 O8 Si8 |
|---|---|
| Calculated formula | C108 H172 Cl4 Cu4 Ge4 I4 N8 O8 Si8 |
| SMILES | C[Si](C1=C(N([Ge@@](Cl)([Cu]23[I]4[Cu]5([I]2[Cu]2([I]3[Cu]4([I]52)[Ge@@]2([n]3ccccc3C(=C(N2[Si](C)(C)C)c2ccccc2)[Si](C)(C)C)Cl)[Ge@@]2([n]3ccccc3C(=C(N2[Si](C)(C)C)c2ccccc2)[Si](C)(C)C)Cl)[Ge@]2([n]3ccccc3C(=C(N2[Si](C)(C)C)c2ccccc2)[Si](C)(C)C)Cl)[n]2ccccc12)[Si](C)(C)C)c1ccccc1)(C)C.O1CCCC1.O1CCCC1.O1CCCC1.O1CCCC1.O1CCCC1.O1CCCC1.O1CCCC1.O1CCCC1 |
| Title of publication | Reactivity of Pyridyl-1-azaallyl Germanium(II) Chloride: Synthesis of Novel Lithium Germinate [{(PhC⋮C)3Ge}3GeLi(Et2O)3] and Ge(II)−M(I) (M = Cu and Au) Adducts |
| Authors of publication | Leung, Wing-Por; So, Cheuk-Wai; Chong, Kim-Hung; Kan, Kwok-Wai; Chan, Hoi-Shan; Mak, Thomas C. W. |
| Journal of publication | Organometallics |
| Year of publication | 2006 |
| Journal volume | 25 |
| Journal issue | 11 |
| Pages of publication | 2851 |
| a | 22.2933 ± 0.0008 Å |
| b | 22.2933 ± 0.0008 Å |
| c | 14.1706 ± 0.0007 Å |
| α | 90° |
| β | 90° |
| γ | 90° |
| Cell volume | 7042.7 ± 0.5 Å3 |
| Cell temperature | 293 ± 2 K |
| Ambient diffraction temperature | 293 ± 2 K |
| Number of distinct elements | 9 |
| Space group number | 114 |
| Hermann-Mauguin space group symbol | P -4 21 c |
| Hall space group symbol | P -4 2n |
| Residual factor for all reflections | 0.1191 |
| Residual factor for significantly intense reflections | 0.0509 |
| Weighted residual factors for significantly intense reflections | 0.1132 |
| Weighted residual factors for all reflections included in the refinement | 0.1467 |
| Goodness-of-fit parameter for all reflections included in the refinement | 0.916 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 178639 (current) | 2016-03-21 | cif/4/07/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/07/50. |
4075084.cif |
| 120075 | 2014-07-11 | Adding DOIs to range 4/07 structures. | 4075084.cif |
| 49055 | 2012-03-27 | ../uploads/cif-deposit/cod/cif Adding structures of 4075084 via cif-deposit CGI script. |
4075084.cif |
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