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Information card for entry 4085418
Preview
| Coordinates | 4085418.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C48 H112 N8 Si6 Th2 |
|---|---|
| Calculated formula | C48 H112 N8 Si6 Th2 |
| Title of publication | Thorium Triamidoamine Complexes: Synthesis of an Unusual Dinuclear Tuck-in‒Tuck-over Thorium Metallacycle Featuring the Longest Known Thorium−σ-Alkyl Bond |
| Authors of publication | Gardner, Benedict M.; Lewis, William; Blake, Alexander J.; Liddle, Stephen T. |
| Journal of publication | Organometallics |
| Year of publication | 2015 |
| Journal volume | 34 |
| Journal issue | 11 |
| Pages of publication | 2386 |
| a | 13.9997 ± 0.0003 Å |
| b | 21.9902 ± 0.0005 Å |
| c | 20.9322 ± 0.0005 Å |
| α | 90° |
| β | 91.306 ± 0.002° |
| γ | 90° |
| Cell volume | 6442.4 ± 0.3 Å3 |
| Cell temperature | 120 ± 2 K |
| Ambient diffraction temperature | 120 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/n 1 |
| Hall space group symbol | -P 2yn |
| Residual factor for all reflections | 0.0528 |
| Residual factor for significantly intense reflections | 0.0514 |
| Weighted residual factors for significantly intense reflections | 0.1215 |
| Weighted residual factors for all reflections included in the refinement | 0.1221 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.191 |
| Diffraction radiation probe | x-ray |
| Diffraction radiation wavelength | 1.54184 Å |
| Diffraction radiation type | CuKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 178743 (current) | 2016-03-21 | cif/4/08/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/08/54. |
4085418.cif |
| 140239 | 2015-07-05 | cif/ Updating files of 4085415, 4085416, 4085417, 4085418, 4085419, 4085420 Original log message: Adding full bibliography for 4085415--4085420.cif. |
4085418.cif |
| 130856 | 2015-02-04 | cif/ Adding structures of 4085415, 4085416, 4085417, 4085418, 4085419, 4085420 via cif-deposit CGI script. |
4085418.cif |
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Users of the data should acknowledge the original authors of the
structural data.