Crystallography Open Database

Information card for entry 4087860

Preview

Coordinates	4087860.cif
Original paper (by DOI)	HTML

Structure parameters

Common name	[(PMe)3Au(MeCN)]4-(POM)2
Formula	C28 H60 Au4 N8 O40 P4 Si W12
Calculated formula	C28 H60 Au4 N8 O40 P4 Si W12
Title of publication	Polyoxometalate-Gold(I)/H+ Complexes: Air-Stable, Efficient, Polyvalent, and Bifunctional Catalysts
Authors of publication	Hueber, Damien; Hoffmann, Marie; de Frémont, Pierre; Pale, Patrick; Blanc, Aurélien
Journal of publication	Organometallics
Year of publication	2015
Journal volume	34
Journal issue	20
Pages of publication	5065
a	16.1463 ± 0.0004 Å
b	12.769 ± 0.0002 Å
c	23.6131 ± 0.0005 Å
α	90°
β	130.002 ± 0.001°
γ	90°
Cell volume	3729.27 ± 0.15 Å³
Cell temperature	173 ± 2 K
Ambient diffraction temperature	173 ± 2 K
Number of distinct elements	8
Space group number	13
Hermann-Mauguin space group symbol	P 1 2/c 1
Hall space group symbol	-P 2yc
Residual factor for all reflections	0.0631
Residual factor for significantly intense reflections	0.0532
Weighted residual factors for significantly intense reflections	0.1346
Weighted residual factors for all reflections included in the refinement	0.1395
Goodness-of-fit parameter for all reflections included in the refinement	1.143
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
237056 (current)	2019-11-24	cif/ Adding structures of 4087860 via cif-deposit CGI script.	4087860.cif