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Information card for entry 4088025
Preview
| Coordinates | 4088025.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C87 H106 Cl2 I4 N8 O P4 Rh2 |
|---|---|
| Calculated formula | C86 H102 I4 N8 P4 Rh2 |
| Title of publication | Synthesis, Isomerization, and Catalytic Transfer Hydrogenation Activity of Rhodium(III) Complexes Containing Both Chelating Dicarbenes and Diphosphine Ligands |
| Authors of publication | Farrell, Kevin; Müller-Bunz, Helge; Albrecht, Martin |
| Journal of publication | Organometallics |
| Year of publication | 2015 |
| Journal volume | 34 |
| Journal issue | 24 |
| Pages of publication | 5723 |
| a | 21.0952 ± 0.0002 Å |
| b | 13.1999 ± 0.0001 Å |
| c | 34.2129 ± 0.0003 Å |
| α | 90° |
| β | 109.683 ± 0.001° |
| γ | 90° |
| Cell volume | 8970.09 ± 0.15 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 8 |
| Space group number | 15 |
| Hermann-Mauguin space group symbol | C 1 2/c 1 |
| Hall space group symbol | -C 2yc |
| Residual factor for all reflections | 0.0356 |
| Residual factor for significantly intense reflections | 0.0337 |
| Weighted residual factors for significantly intense reflections | 0.0839 |
| Weighted residual factors for all reflections included in the refinement | 0.085 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.072 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 237222 (current) | 2019-11-24 | cif/ Adding structures of 4088023, 4088024, 4088025, 4088026 via cif-deposit CGI script. |
4088025.cif |
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Users of the data should acknowledge the original authors of the
structural data.