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Information card for entry 4088505
Preview
| Coordinates | 4088505.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C21 H30 F6 N2 Rh Sb |
|---|---|
| Calculated formula | C21 H30 F6 N2 Rh Sb |
| SMILES | [Sb](F)(F)(F)(F)(F)[F-].[Rh]12345([NH2]C(c6c5cccc6)(C)C)([N]#CC)[c]5([c]1([c]2([c]3([c]45C)C)C)C)C |
| Title of publication | Cationic Iridium and Rhodium Complexes with C‒N Chelating Primary Benzylic Amine Ligands as Potent Catalysts for Hydrogenation of Unsaturated Carbon‒Nitrogen Bonds |
| Authors of publication | Sato, Yasuhiro; Kayaki, Yoshihito; Ikariya, Takao |
| Journal of publication | Organometallics |
| Year of publication | 2016 |
| Journal volume | 35 |
| Journal issue | 9 |
| Pages of publication | 1257 |
| a | 8.502 ± 0.005 Å |
| b | 11.007 ± 0.006 Å |
| c | 13.633 ± 0.007 Å |
| α | 96.292 ± 0.006° |
| β | 93.694 ± 0.008° |
| γ | 106.951 ± 0.006° |
| Cell volume | 1206.8 ± 1.2 Å3 |
| Cell temperature | 123 K |
| Ambient diffraction temperature | 123 K |
| Number of distinct elements | 6 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for significantly intense reflections | 0.0401 |
| Weighted residual factors for all reflections included in the refinement | 0.1148 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1 |
| Diffraction radiation wavelength | 0.7107 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 237619 (current) | 2019-11-24 | cif/ Adding structures of 4088503, 4088504, 4088505, 4088506 via cif-deposit CGI script. |
4088505.cif |
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Users of the data should acknowledge the original authors of the
structural data.