Crystallography Open Database

Information card for entry 4107704

Preview

Coordinates	4107704.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	Cs8 Hf4 O97 Si2 W20
Calculated formula	Cs7.98 Hf4 O97 Si2 W20
Title of publication	Synthesis and Catalysis of Di- and Tetranuclear Metal Sandwich-Type Silicotungstates [(γ-SiW10O36)2M2(μ-OH)2]10- and [(γ-SiW10O36)2M4(μ4-O)(μ-OH)6]8- (M = Zr or Hf)
Authors of publication	Yuji Kikukawa; Syuhei Yamaguchi; Kazutaka Tsuchida; Yoshinao Nakagawa; Kazuhiro Uehara; Kazuya Yamaguchi; Noritaka Mizuno
Journal of publication	Journal of the American Chemical Society
Year of publication	2008
Journal volume	130
Pages of publication	5472 - 5478
a	12.6813 ± 0.0001 Å
b	12.6813 ± 0.0001 Å
c	61.5483 ± 0.0009 Å
α	90°
β	90°
γ	90°
Cell volume	9897.91 ± 0.18 Å³
Cell temperature	153.1 K
Number of distinct elements	5
Space group number	92
Hermann-Mauguin space group symbol	P 41 21 2
Hall space group symbol	P 4abw 2nw
Residual factor for significantly intense reflections	0.0835
Weighted residual factors for all reflections included in the refinement	0.2133
Goodness-of-fit parameter for all reflections included in the refinement	1.064
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
209531 (current)	2018-08-10	cif/4/ Removing duplicate rows from the ATOM_TYPE loop in entries 4027882, 4063366, 4072663, 4072770, 4072771, 4074460, 4075100, 4076241, 4076242, 4076244, 4077512, 4080938, 4081765, 4082054, 4082696, 4084845, 4101406, 4101407, 4101408, 4107704, 4108487, 4109677.	4107704.cif
176467	2016-02-16	cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4.	4107704.cif
120076	2014-07-11	Adding DOIs to range 4/10 structures.	4107704.cif
55853	2012-05-07	cif/ Adding structures of 4107704 via cif-deposit CGI script.	4107704.cif