Crystallography Open Database

Information card for entry 4109421

Preview

Coordinates	4109421.cif
Original paper (by DOI)	HTML

Structure parameters

Chemical name	[Bis(1,4,7,10-tetraoxacyclododecane)lithium(I)] 1,1,3,3-tetra-tert-butyl-1,3-dimethyltrisilane-2-yl-2-ylide
Formula	C34 H74 Li O8 Si3
Calculated formula	C34 H74 Li O8 Si3
Title of publication	Isolable Silylene Anion Radical: Structural Characteristics in the Solid State and in Solution
Authors of publication	Shigeyoshi Inoue; Masaaki Ichinohe; Akira Sekiguchi
Journal of publication	Journal of the American Chemical Society
Year of publication	2007
Journal volume	129
Pages of publication	6096 - 6097
a	17.125 ± 0.0005 Å
b	13.972 ± 0.0004 Å
c	34.877 ± 0.0009 Å
α	90°
β	91.236 ± 0.002°
γ	90°
Cell volume	8343.1 ± 0.4 Å³
Cell temperature	120 ± 0.1 K
Ambient diffraction temperature	120 ± 0.1 K
Number of distinct elements	5
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for all reflections	0.0632
Residual factor for significantly intense reflections	0.0479
Weighted residual factors for significantly intense reflections	0.1327
Weighted residual factors for all reflections included in the refinement	0.1446
Goodness-of-fit parameter for all reflections included in the refinement	1.025
Diffraction radiation wavelength	0.7107 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
178840 (current)	2016-03-21	cif/4/10/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/10/94.	4109421.cif
120076	2014-07-11	Adding DOIs to range 4/10 structures.	4109421.cif
58195	2012-05-25	cif/ Adding structures of 4109421 via cif-deposit CGI script.	4109421.cif