Crystallography Open Database

Information card for entry 4115709

Preview

Coordinates	4115709.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C42 H39 B F20 P2 Si W
Calculated formula	C43 H37 B F20 P2 Si W
Title of publication	High Oxidation-State (Formally d0) Tungsten Silylene Complexes via Double Si-H Bond Activation
Authors of publication	Benjamin V. Mork; T. Don Tilley
Journal of publication	Journal of the American Chemical Society
Year of publication	2001
Journal volume	123
Pages of publication	9702 - 9703
a	27.488 ± 0.0001 Å
b	15.5223 ± 0.0002 Å
c	21.3367 ± 0.0003 Å
α	90°
β	90°
γ	90°
Cell volume	9103.88 ± 0.18 Å³
Cell temperature	273.2 K
Ambient diffraction temperature	155 K
Number of distinct elements	7
Space group number	29
Hermann-Mauguin space group symbol	P c a 21
Hall space group symbol	P 2c -2ac
Residual factor for all reflections	0.0363
Residual factor for significantly intense reflections	0.03
Weighted residual factors for all reflections	0.0377
Weighted residual factors for significantly intense reflections	0.0366
Goodness-of-fit parameter for all reflections included in the refinement	1.468
Diffraction radiation wavelength	0.7107 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
176467 (current)	2016-02-16	cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4.	4115709.cif
120077	2014-07-12	Adding DOIs to range 4/11 structures.	4115709.cif
69431	2012-12-14	cif/ Adding structures of 4115709 via cif-deposit CGI script.	4115709.cif